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By Ralph Hultgren, Bernard York, David W. Mitchell

It is a well-known fact that magnesium-alloy castings are apt to be coarse grained if the melt is not superheated several hundred degrees above the melting point before casting. (The casting temperature varies according to the shape of the mold. A typical casting temperature is perhaps 1400°F.) British practice is to heat to 900°C. (1650°°F.) for 15 min., cool rapidly to casting temperature, and cast.1 In Germany superheating is carried out at 850° to 900°C. (1560° to 1650°F.) depending on the amount of scrap used. It is stated that further refinement will be obtained by prolonging the period of superheating or by increasing the superheat temperature to 950°C. (1740°F.).2 In the United States superheating is carried out at i600° to 1700°F. (871° to 927°C.), perhaps even higher in some places. It is stated that superheating effects are found as low as 1500°F. (816°C.), but several hours are required.3 These commercial treatments lead to grain sizes in sand castings that may vary from 4 to 8 grains per sq. mm.§ in heavy sections and from 60 to l00 in 3-in sections to perhaps 380 in thin sections. It is also generally known that the refining effect of superheating is lost if the melt is held for some time at lower temperatures before casting. Aside from these very qualitative statements, there is little to be found in the literature as to the effect of temperature and time of superheat on the final grain size. Because of the uncertainty of these factors, the Office of Production Research and Development of the War Production Board placed a research contract with the University of California, supervised by the War Metallurgy Committee. This research, which was done under the "Restricted" Project NRC-550, is the basis of this paper, which has been released for publication by the O.P.R.D. The material studied was an alloy prepared from carbothermic magnesium. The temperatures required for grain refinement proved to be widely different from those used in practice, as described in the statements in the first paragraph. This difference is attributed to the fact that the magnesium in the specimens was of carbothermic origin instead of the electrolytic magnesium in common use. MATERIALS AND METHODS The magnesium alloy studied was one of the most popular sand-casting alloys, with a nominal composition of 9 per cent aluminum, 2 per cent zinc, and 0.r per cent (minimum) manganese and the balance magnesium. This is designated

Jan 1, 1945

By Byron Bird

WHILE Mr. Fahrenwald has been working on the fundamentals of ore-dressing, in Idaho, the Northwest Experiment Station of the U. S. Bureau of Mines, in cooperation with the University of Washington, has been studying the corresponding fundamentals for the closely-allied subject of coal-washing. In this work many of the principles outlined in Mr. Fahrenwald's paper have been touched on, one important exception being that phase of his studies where conditions were approximated between those existing on a table and those existing in a hindered-settling classifier. During the past three years this work has been given over almost exclusively to a study of coal-tabling to devise better methods of cleaning fine sizes of coal, particularly the coals of the Northwest, which are very difficult to wash. One important result of this study thus far has been the development of a satisfactory hindered-settling coal classifier, now in use in several commercial plants. Recently table stratifica-tion has been the subject for study. This latter phase of the work with coal,. as well as the earlier portion dealing with hindered-settling classification, has in a measure paralleled Mr. Fahrenwald's work with ore. Without going into details about the results of the coal experiments, I shall merely say that, from a quali-tative standpoint, they are, in general, concordant with Mr. Fahrenwald's, but that from a quantitative stand-point the results, particularly those with, table strati-fication, are somewhat different. These differences may disappear as the work progresses-Mr. Fahrenwald is further ahead with his experiments than we are at the Northwest Station-but if not, the disparity would not be surprising, and indeed would be what one might reasonably expect when investigators work on two very dissimilar materials and use different apparatus and methods of study. However, this- mention of our coal-washing experiments is made only in passing. A principle of general application that may be estab-lished from Mr. Fahrenwald's paper is that different types of stratification should be used in successive' gravity-concentration processes to. obtain best results.

Jan 3, 1927

By W. R. Ingalls

SOME months ago, I had occasion to make an investigation that introduced the subject of blue powder that is produced as a byproduct in zinc dis-tillation. Although every zinc smelter is aware that more or less blue powder production is inevitable and there is a common practice as regards the treatment of it, the specific and quantitative data respecting the subject were more imperfect than would have been expected. I had reports from eight important works. Some of the data were especially determined for my investigation. Speaking generally, there is a good deal of uniformity in the figures, all of which show that the blue powder product, bears a large proportion to the ore originally charged into the retorts; that a large proportion of the retort capacity is devoted to the redistillation of blue powder; and that of the spelter product of a furnace about 30 per cent. is derived from blue powder, i.e., it is zinc that has been distilled twice. The figures from the works are given in the following table:

Jan 4, 1922

By John T. Norton, Robert J. Anderson

The purpose of this paper is to report evidence, regarding metal structures, that is contradictory to the amorphous-metal hypothesis of Beilby, and particularly evidence that is opposed to the proposition that a vitreous amorphous layer is produced by polishing a piece of metal. According to the theory of Beilby, which has been developed by Rosenhain and others, polishing a piece of metal greatly affects the condition of the metal at or near the surface polished, making that surface entirely different in character from the metal beneath. A vitreous amorphous surface film is said to be formed. The polishing process, on the basis of Beilby's explanation, is well known and does not require discussion here, but it is advisable to seek the precise meaning of the term "amorphous." According to Beilby, "amorphous means non-crystalline in the most intimate sense of the word; the molecules arc not marshalled in crystalline order and orientation." According to Rosenhain, the amorphous condition is that assumed by a metal when the crystalline arrangement is completely broken up so that the atoms exist in a state of disorderly arrangement similar to that which exists in the liquid state. Thus, from the point of view of the phase rule, the "amorphous phase" is regarded as being identical with the liquid phase. Amorphous metal is often likened to an undercooled liquid. A crystalline substance is one in which the atoms are arranged in space according to some definite repeating geometrical pattern. The existence of amorphous metal has not been definitely proved. The evidence offered here that amorphous metal probably does not exist is of a direct nature and is afforded by x-ray diffraction effects given by a number of metals and alloys when polished, cold-worked, and annealed. Considerable of the experimental work was carried out with substantially pure aluminum and the aluminum alloy duralumin, but many of the observations made on these materials were checked by similar observations on copper, iron, tin, zinc, lead, mild steels, and

Jan 1, 1925

By T. Sterry Hunt

AT the meeting of the Institute in Easton, October, 1873, I made a communication on the Ore Knob copper mine, in Ashe County, North Carolina (Transactions, vol. ii, p. 123), in which I called attention to the chemical decomposition alike of the pyritous lode and the inclosing gneiss rock to a depth of 60 feet, by which the feldspar of the latter had been converted into clay, and the whole rock very much softened. Such a decomposition is well known to be almost universal in the crystalline rocks of the Appalachians south of the Potomac ; and if it is only seen in rare and exceptional cases farther to the northward, this, as I have elsewhere pointed out, is due to the fact that the decomposition began and ended in the ages anterior to the drift period, and that the decayed portions which still remained were at that time removed from the surface, except in some localities which were protected from the eroding agency. I have lately had an opportunity of studying a remarkable instance of this kind in an examination made last month for the corporators of the Hoosac Tunnel.* The locality is at the western base of Hoosac Mountain, the western slope of which rises rapidly 1300 feet above the town of North Adams, in Berkshire County, Massachusetts, itself 700 feet above the sea level. Through this mountain, as is well known, a tunnel for the Troy and Boston Railroad has lately been opened, a distance of 25,081 feet from east to west. The rock of the mountain consists of mica schist and micaceous gneiss, including in its western half a great mass of harder feldspathic and quartzose strata in part a granitoid gneiss, the strata for the most part dipping to the eastward with variable angles, but with occasional western dips, apparently due to inversion. The crystalline strata of the mountain crest and sides are in many places exposed, and present rounded surfaces, often deeply grooved and striated, but with no appearance of decay. At the western base of the mountain, however, the gneissic rock is in a state of complete decomposition, which was well displayed in opening the tunnel, which, for a distance of several hundred feet, was driven through highly inclined strata so much decomposed that they were excavated with pick and shovel, and without the aid of blast- * See, for a detailed account of this examination, Dr. Hunt's report, published by the General Court of Massachusetts in House Document No. 9, 1875.

Jan 1, 1875

By R. A. Morse, C. R. Stewart, F. F. Craig

This paper preFents the results of a series of model flow test on a number of large limestone cores, having different pore configurations. For limestone cores having substantially sandstone type porosity, the production characteristics for solution and external gas drives are similar. For cores whose pore spaces were microscopically heterogeneous (i.e., consisted of combinations of solution cavities, matrix. and fissures), the production characteristics lor solution and external gas drives vary widely. The degree of divergence between gas-oil relative permeability relationships calculated from solution or external gas drive tests is an indication of heterogeneity of rock pore structure. The results of water floods on cores depleted by solution gas drive for each of these two general types of limestone porosity are also shown. Generalizations are made on the water flood recovery that could be expected from each of these two types of limestone porosity. The similarity between solution drive field performance and model solution drive performance on cores from the same formation is shown for several cases. This indicate? the feasibility of predetermining limestone field performance from such large core tests. Photomicrographs of plastic-impregnated rock thin sections of the samples tested are presented as an aid in understanding the flow test performances. INTRODUCTION During the past 15 years. reservoir engineers and research workers have developed methods of testing rock and fluid samples and applying the results, through calculation, to allow reasonably satisfactory predictions of oil recoveries and performances to be expected in sandstone oil recervoirs. It has been determined that representative fluid flow data can be obtained on rock samples as small as three-fourths in. in diameter by one in. long in most sandstones. However, little has been accomplished toward the laboratory determination of fluid flow characteristics in limestones. There has been a great deal of speculation as to the influence of variations in pore size, shape, and degree of interconnection upon oil recovery processes, and a great deal of thought has been given to the interpretation of limestone field perfomance. It has been generally recognized that predictions of reservoir performance based on oil displacement tests on small limestone core samples the size of those used for sandstone tests can often be misleading because of the improbability of obtaining a representative sample in such a small core. Obviously, if there are present in the rock, pore openings of the magnitude of 1/16 in., or fractures or solution channels up to one in. or more in length, it will be impossible to cut any sample less than one in. in any dimension which would represent the flow geometry of the gross rock system. In some formations, the individual openings in the rock are of such size that it would be impossible to obtain a good sample of the flow system even in the total core available from conventional-sized well cores. However, by increasing to the maximum the size of the sample used, it should be possible to obtain representative flow data from the majority of limestone reservoir materials which can be used for prediction of future primary production performance or response to be expected from secondary recovery measures. The only alternatives to obtaining good laboratory test data to serve these purposes are extrapolation of primary performance data obtained by partial depletion of a field, or obtaining information from pilot tests. It has been shown previously, and will be demonstrated further by the work reported in this paper, that extrapolation of solution gas drive performance for an estimate of gas injection response can be very misleading in reservoirs of heterogeneous type porosity. Although it cannot be expected that laboratory information can ever eliminate the necessity of small-scale pilot operations, it is expected, as is now the situation with sandstone reservoirs, that laboratory tests should provide reliable information for screening of

Jan 1, 1953

By F. Osmond

When a metal (whether a simple substance, an alloy, or a compound) presents, in each of the smallest parts to which it can be redueed by mechanical division, a constant chemical composition, it is defined as chemically homogeneous. But chemical hombgeneity by no means necessitates mechanical homogeneity. There are no perfectly amorphous metals. Crystalline forces, on the one hand, and tensions or compressions, on the other band, determined by icequalities of temperature in the mass during heating or cooling, give rise in every metal to the formation of geometric elements of structure. These elements may, moreover, assume perfect crystalline forms, with their planes of cleavage; or embryonic crystalline forms, segregated in the midst of. a paste of confused organization; or pseudo-crystalline forms of expansion and contraction, like those produced in the drying of gelatinous precipitates or (most frequently) these different forms associated. 111 either case the adhesions between two adjoining structural elements, respectively homogeneous, may be very different from the interior cohesion of each of these elements. The mechanical properties of this complex aggregate cannot be simple, and, when it is submitted to strains sufficient to produce deformation, the results may be very different according to the type of structure or the manner in which it is affected by the strains. It may be fairly said that a metal does not present a single resistance to tension, or a single resistance to compression, etc., but in fact, at least theoretically, as many resistances to tension, compression, etc., as it may possess coexistent features of structure; only, in any single test, it is the weakest of the resistances involved which makes itself evident. For further explanation, let us imagine a cylinder A B (Fig. I), formed of two similar halves A and B, placed together upon their common base x y. Such a system evidently presents no resistance to axial tension, while it would resist axial compression like a single

Jan 1, 1894

By L. P. Teas

The year 1932 has been one of exceptional significance for the Gulf Coast. Because of many new oil fields found, the most outstanding of which, Conroe, has assumed national importance, and because of new prospective areas extending through Montgomery, Polk, Tyler and Newton counties into Louisiana, there has been a stampede of operators to the Coast. During the year, development and discoveries have shown a marked trend away from the shallow or intermediate depth type of salt dome fields, with their treacherous flanking sands, to the deep-seated type of domes with their more continuous blanketing sands. The potency of some of the deep-seated domes such as Thompsons and Conroe, in Texas, and Iowa in Louisiana, has for the time at least, dispelled the disappointment of such deep-seated domes as Mykawa or Sheppard's Mott. Whether the newer deep-seated prospects, as yet little developed, will prove Conroes or Mykawas remains to be seen. In any event there is much for us yet to learn of the Coast. During 1932 a total of nine new oil fields and four new gas areas were discovered, which compares with seven new fields in 1931 and three fields in 1930. Of the nine new oil fields two were in Coastal Louisiana. This is the largest number of new oil fields found on the Coast in a single year since 1929, when 11 new fields were discovered. Not only because of the number of new fields has 1932 been notable but also because these new fields represent new productive areas that total 16,000 acres or more, or over 70 per cent of the total productive area known on the entire Coast at the beginning of 1932. In addition to the fields discovered in 1932, four new areas, or extensions around domes or fields already producing, and at least 11 new oil sands and three new gas sands have come to light. We may well say that 1932 has been the banner year for the Gulf Coast, in spite of depressed economic conditions and continued and more emphatic restriction of production. With the exception of 1901, when oil was discovered on the Coast and 1924, the year in which geophysical prospecting was in:lugurated, 1932 has been its most outstanding year.

Jan 1, 1933

By Sheldon Rideout, E. L. Kamen, B. S. Lement, Paul A. Beck, W. D. Manly

The 1200°C isothermal sections of the following ternary phase diagrams were investigated: Cr-Co-Nil Cr-Co-Fe, Cr-Co-Mot and Cr-Ni-Mo. In all these systems the u phase was found to form extended solid solutions. Two new ternary phases of unknown structure were identified. The existence range of intermediate phases of transition elements was correlated with 3d electron vacancy concentrations. THE occurrence of extensive ternary d solid solutions in the Cr-Co-Ni and in the Cr-Co-Fe systems was described in a brief note.' More recently d- solid solutions were also found in the Cr-Fe-Mo system by two independent groups of investigators.2,3 The existence of binary d phases in the V-Co and V-Ni systems, predicted in ref. 1, was experimentally discovered recently by Duwez and Baen and independently by W. B. Pearson, J. W. Christian, and W. Hume-Rothery.5 Duwez and Baen stated two general conditions for the occurrence of the d phase in alloys of the transition elements: "(1) The atomic diameters of the two metals do not differ by more than 8 per cent. (2) One of the two metals has a body-centered cubic structure while the other is face-centered cubic, at least in one of its allotropic forms." In the course of an extensive research program conducted at this Laboratory under the sponsorship of the NACA, several ternary systems, containing d solid solutions and also certain new ternary phases, were investigated. The present report describes the investigated portions of the 1200°C isothermal sections of the following ternary phase diagrams: Cr- Co-Ni, Cr-Co-Fe, Cr-Co-Mo, and Cr-Ni-Mo. It was found that the range of existence of the d phase in these four ternary systems, as well as in one of two ternary systems which were investigated by others, can be fairly consistently described in terms of electron vacancy concentrations. This supports the suggestion of Sully and Heal" that the d phase is an electron compound. Experimental Procedure The ternary alloys were prepared by vacuum induction melting in zirconia and alumina crucibles. Lot analyses of the metals used are given in Table I. Specimens of all alloys were annealed at 1200°C in an atmosphere of purified 92 pct helium and 8 pct hydrogen mixture. Alloys consisting mainly of

Jan 1, 1952

By Y. Nakada, U. F. Kocks, B. Chalrners

THE orientation dependence of work hardening has previously been studied over the entire range, i.e., including special orientations of high symmetry, in aluminum1-3 and silver.* The differences between various orientations are substantial, and the trend is the same in all fcc crystals. However, there are quantitative differences in behavior between aluminum and silver at room temperature, particularly in the (100) orientation. While many experiments on gold have been reported,5'9 none included the special orientations. We therefore undertook tension tests on gold crystals of the axial orientations (100),(110), (Ill), (211), and, as a representative of single slip, one whose Schmid factor was 0.5 (hereafter referred to as m = 0.5). Single crystals of dimensions 1/4 by .1/4 by 6 in. were grown from the melt1' at a rate of 4 in. per hr, using gold of 99.99 pct purity obtained from Handy and Harman. A growth rate of 1/8 in. per hr, or a purity of 99.999 pct,ll produced no difference in results. The crystals were annealed at 1000°C in air for 24 hr and furnace-cooled down to room temperature, after which they were electro-polished in a solution of potassium cyanide (40 g), potassium ferrocyanide (10 g), soda (20 g), and enough distilled water to make 1 liter of solution, at a current density of 0.02 amp per sq mm. After 2 or 3 hr, a very smooth surface was obtained by this method. Nine m = 0.5, two (loo), one (110), three (Ill), and one (211; crystals were tested at room temperature in a floor-model Instron machine at a tensile strain rate of 0.5 pct per min. The accuracy of the stress measurement was k10 g per sq mm up to 500 g per sq mm, k2 pct for higher stresses. The strain measurement was accurate to t2 pct. The scatter of stress at a given strain among the crystals of the same orientation was small, *5 pct being the largest. The representative stress-strain curves for various orientations are shown in Fig. 1. Table I summarizes the work-hardening parameters as used by seeger.12 Results of other investigators are also included in this table for comparison. There are no previous data for the corner orientations. Values for m = 0.5 crystals agree fairly well with those of Berner. Tm is defined as the stress at which the stress-strain curve begins to deviate from linearity of Stage 11. However, in practice this is a very difficult value to estimate because each investigator has a different idea of linearity. Therefore, the comparison with the values of other investigators may not be valid. In the present experiment, (100) crystals had the highest 111, followed by (111) crystals. The work-hardening rate in Stage I1 was highest for the (111) crystal followed by the (100) crystals. Our value for 0x1 of m = 0.5 orientation agrees very well with those of other investigators. 1) Single-Slip orientation (m = 0.5). These crystals were oriented so that the primary-slip vector was contained in one side face. The dimension perpendicular to this side should then not change if single slip indeed takes place. Within the accuracy of measurement, this dimension did not change during the deformation. Since the accuracy is k0.2 pct, the amount of secondary slip is less than 0.7 pct of the slip on the primary-slip system at 30 pct tensile strain. This is in conformity with the results obtained by Kocks" for aluminum crystals. The tensile axis moved toward (211) during the deformation. Slip bands, Fig. 2(a), were very fine and closely spaced. Some deformation bands were observed. There were no clear-cut cross-slip traces such as the ones observed on aluminum m = 0.5 crystals. 2) (111) Crystals. The orientation of the tensile axis was stable during the deformation. From this observation, one can deduce that at least three slip systems must have operated, and probably all six because the remaining three all have cross-slip relation to one of the first three.' It was very difficult to observe the slip markings. Consequently, we could not confirm by this method that six systems were operative during the deformation. At high strains (above 50 pct shear strain), this orientation had the highest stress-strain curve. At 80

Jan 1, 1964

By E. H. Roberts, L. G. Swenson, F. C. Nix, R. A. Morgen

THE binary system lead-antimony has been the subject of comprehensive investigations in these laboratories by Dean' and his associates. The effect of a third constituent on this system, particularly on the lead-rich alloys in which dispersion hardening was found, has a commercial value as well as an academic interest. This paper covers the effect of the addition of copper, bismuth and tin, all of which are likely to be found in commercial lead-antimony alloys, and is divided into three parts, as follows: I. The System Lead-Antimony-Copper II. The System Lead-Antimony-Bismuth III. The Lead Corner of the System Lead-Antimony-Tin These three systems are of three different types, and hence may be considered as covering three general kinds of additions. Bismuth forms no compounds with either lead or antimony and forms solid solutions with both. Copper forms several compounds with antimony as well as solid solutions but with lead it forms a two liquid layer system and no appreciable solid solution. Tin is soluble in both lead and antimony in the solid state and also forms a compound with antimony. The effect of small amounts of bismuth on the lead-antimony alloys is small, having no appreciable effect on the solubility of antimony. The temperature of the solidus floor is lowered appreciably by the presence of bismuth, cutting down the range of heat treatment. Copper, on the other hand, due to compound formation, increases the apparent solubility of antimony. The excess antimony is tied up with the copper finally and so is not available for dispersion hardening. The net result of addition of small amounts of copper is to shift the dispersion hardening peak of the

Jan 1, 1928

Discussion of the paper of N. V. Hansell, presented at the Cleveland Meeting, October, 1912, and published in Bulletin No. 72, December, 1912, pp. 1497 to 1,517. C. Q. PAYNE, New York (communication to the Secretary*) :-Mr. Hansell has presented in his paper a very interesting and valuable summary of the various methods of enriching iron-ores which have been developed during recent years. Particularly striking in this connection is the high degree of enrichment of the concentrates from magnetic iron-ores which is now commercially feasible. Magnetic concentrates containing from 6 7 to 139 per cent. of metallic iron, showing an efficiency of 90 and even 95 per cent. in. their separation, are not now uncommon. Such results exceed those obtained by gravity methods of treatment of all copper-, lead-, and zinc-ores, and are only equaled in the cyaniding of gold-ores and in the flotation treatment of certain copper-ores. It is of interest to note that the-type of magnetic field which is employed in securing these results, in the Gröndal (wet) and the Ball & Norton (dry) systems of treatment is the same in each case : viz., a field of alternating north and south poles. The credit for developing this simple and useful field, which has found so wide an application both in this country and abroad, is due to two American inventors and engineers, Clinton M. Ball and Sheldon Norton. At the same time, it should be noted that part of the improvement in the grade of the magnetic concentrates, especially in the case of the wet treatment of finely mineralized ores, is due to a well-devised scheme of mill-treatment, whereby a rough concentrate is usually obtained as an intermediate product, which is then recrushed and reseparated in obtaining final clean products.

Jan 3, 1913

By S. Shapiro, R. G. Ames

Background Research on the respiratory health of coal miners has focused predominately on the relationship between coal mine dust exposure and ventilatory function impairment (Lapp et al., 1972; Jacobsen, 1976), on the prevalence of coal workers' pneumoconiosis (Lainhart et al., 1969; Morgan et al., 1973), and on coal miner mortality (Ortmeyer et al., 1974; Rockette, 1977). Lesser attention has been paid to the effects of other mining exposures. For example, underground exposure to diesel exhaust emissions (Reger et al., 1980; Ames et al., 1982,1984). An omission in US coal mining research, however, has been identified by the US Office of Technology Assessment (OTA) as the failure to study the effects of inhaled polyvinyl chloride (PVC) thermal decomposition and combustion products (Seltzer, 1979). These products may be released in the mine environment by cable fires, cable explosions, smoldering cables, and conveyor belt fires. In addition to the OTA concern, recent findings of chronic respiratory conditions and other health complications resulting from exposure to PVC decomposition and combustion products in firefighters (Peters et al., 1974; NBS, 1980; NIOSH, 1982; Wallace, 1982), and in survivors of several large scale PVC-fueled fires (Dyer and Esch, 1976; Wallace, 1981, 1982), add immediacy to the concerns. PVC decomposition and combustion PVC decomposition is initiated at temperatures far below ignition (Hartstein and Forshey, 1974; Wallace, 1981). Hence, exposures to decomposition products from smoldering cables may be important health hazards in addition to cable insulation combustion products. Hydrochloric acid (HCL) appears to be the principle toxic substance from the thermal decomposition of PVC since up to 60% by weight is released as HCL (Barrow et al., 1979). HCL is released both as a gas and as an adsorbant on soot particles (Stone et al., 1973), thus allowing penetration of respiratory defenses. In addition, laboratory results indicate that phosgene (carbonyl chloride), a potentially lethal gas, may be produced in significant quantities from electrical arcing of wires covered with PVC insulation (Woolley, 1971; Brown and Birky, 1980). Health concerns related to PVC Toxic effects resulting from high level exposures to PVC pyrolysis and combustion products in animals (Cornish and Abar, 1969) and in humans (Wallace, 1981) is beyond question. Analyses have reported acute, or short-term, health effects resulting from exposure to PVC decomposition and combustion products (Peters et al., 1974; Polakoff et al., 1975). Recently, however, several studies have found that acute effects are often followed first by apparent healing, and then by delayed chronic effects. This pattern of consequential respiratory involvement among persons involved in major PVC-fueled fires has been noted in firefighters, specifically the 1975 New York Telephone Exchange fire (Dyer and Esch, 1976; Wallace, 1982), and the survivors of the 1977 Beverly Hills Supper Club fire (Wallace, 1981). An obstructive syndrome (low FVC and FEV1) was seen in 15% of workers three months following fighting a PVC-fueled fire (Colardyn et al., 1976). Long-term respiratory symptoms seen in studies of survivors of PVC-fueled fires include the bronchitis symptoms of cough and phlegm, and lung dysfunction (Wallace, 1981). Additional support for the thesis of longer-term respiratory effects resulting from PVC-fueled fires is derived from the finding that four persons who initially survived the Beverly Hills Supper Club fire died within nine months of the fire of severe respiratory impairment (Wallace, 1981).

Jan 1, 1986

By William Paxton Hewitt

The San Carlos lead deposit in northeast Chihuahua yielded approximately one million tons of galena ore from a blanket-like deposit. Countryrock, composed of Cretaceous limestones and calcareous shales as old as late Albian-early Aptian, and an underlying undated quartzite series, has been warped into a northwest trending anticline and has been invaded by a light-colored holocrystalline igneous rock. Magnetite and contact metamorphic minerals heterogeneously mixed with variable amounts of pyrite, sphalerite and galena, are concentrated along the anticlinal axis where they replaced magnesia-rich argillaceous sediments above the quartzite contact. Magnetite and associated silicates were deposited under near-contact conditions. Following a period of post-magnetite shattering, pyrite, sphalerite and galena were introduced at lower temperatures. Galena and associated dolomite or magnesite, the final phase of mineralization, are concentrated at the top of the deposit near the anticlinal crest and extend upward into isoclinally folded dolomitic argillites. INTRODUCTION AND ACKNOWLEDGEMENTS The stoped outlines of the San Carlos Mine are a pattern for a stratiform blanket-like deposit. But the close association of mineralization with an anticlinal axis, an observed relation between high grade galena mineralization and the apices of isoclinal folds, and the petrographic story of mineralization introduced into shattered areas make the deposit an example of structural control of ore de-

Jan 1, 1970

Executive-A. R. LEDOUX, chairman. Membership-J. V. W. REYNDERS, chairman. Finance-J. V. N. Dorr, chairman. Library-E. GYBBON SPILSBURY, chairman. Papers and Publications-BRADLEY STOUGHTON, chairman. Nominations-POPE YEATMAN, chairman.

Jan 12, 1919

By H. I. Altshuler

THE mines operated by the Compañia de Real del Monte y Pachuca, Pachuca, Mexico, are in two districts, the Pachuca, and Real del Monte. The principal area of mineralization is within a rectangle roughly 10 miles from east to west and 6 miles from north to south. It contains a number of veins from 2 to 20 ft. wide, which are exploited by this mining company. The scattered position of the producing mines led to the construction of two mills between 1906 and 1908; the Loreto mill, in Pachuca, averaged 2600 tons daily, and the Guerrero mill, in Real del Monte, milled 1270 tons daily. On Feb. 1, 1929, the management decided to enlarge the Loreto mill to take the combined tonnage of both mills at that time. This economic measure required the centralization of ore delivery, which would also afford a material saving in the cost of ore transport. The centralization would give the company the following advantages over the former system of operation: 1. Beneficiation at a single mill, closer to source of materials and supplies than the abandoned- Guerrero mill. The refinery is, also in the Loreto patio. 2. Ore delivery to surface at one point (San Juan Pachuca shaft) instead of at four. 3. Elimination of aerial tramways. To show what would be required to effect this centralization, it is necessary to describe the means by which the ore was delivered to the two mills, prior to centralization. The heart of the Real del Monte district is roughly four miles from that of the Pachuca section. The producing mines in these two districts were: Pachuca district: Santa Ana mine Camelia group

Jan 1, 1934

The Library of the above-named Societies is open from 9 A. M. to 10 P. M. except on holidays. It contains about 70,000 volumes and 90,000 pamphlets, including sets of technical periodicals and publications of scientific and technical societies. Members of the Institute, with few exceptions, are forced to spend a portion of their time in localities isolated from sources of information. To these the Library, through its Library Service Bureau, can render valuable service through correspondence; letters requesting information will receive especial attention. The Library is prepared to furnish references, and photographic copies of articles on mining and metallurgical subjects; to determine the existence of mining maps, and to furnish general information on the geology and mineral resources of all countries. All communications should be made as definite as possible so that the information received may be what is desired and not include collateral matter which may not be of interest. The time spent in searching for such collateral matter will be saved, and the information will be sent more promptly and in more usable shape.

Jan 4, 1918

By Walter B. Devereux

Metallic copper is a product of native metallurgy in various parts of Mexico, and by somewhat varied processes. While recently examining copper mines in the State of Jalisko, I had an opportunity of witnessing Mexican copper smelting by a process which I have not seen described, and which is interesting from the fact, that a fine quality of copper is produced from sulphurous ores in three metallurgical operations, and apparently without excessive loss. The process was carried on in buildings which were part of a plant erected by an American more than twenty-five years ago for the purpose of smelting and working copper. After a few years this man met with accidental death, and the works have been but little used since. Located in the centre of a high range of mountains, far from any town or seaport, and inaccessible except over difficult mule trails, these substantial buildings, filled with furnaces and heavy machinery,

Jan 1, 1883

By Kenzo Murao, Sei Nakao

HISTORY OF ASHIO SMELTER The Ashio copper mine, which formed the main part of Furukawa mining industry, is located inland of Kanto area, and is known as the oldest copper mine of Japan. The mining started even since 1610, and Mr. Furukawa began management in 1877. Afterwards, within a short period, the mine became to have the highest productivity in the Far East. The total quantity of mined copper reached approximately more than 800 thousand tons. The mother rock of the ore deposit in Ashio was rhyolite, and was formed of sissurefulling and irregular clod that was called Kajika deposit. The lode was nzrrow of 6 to 7cm. The mineral was formed mainly of chalcopyrite, including also pyrite, pyrrhotite, and arsenopyrite that were not favorable. After the founding of the copper mine, the Ashio smelter started the operation of Mabuki process as the beginning in 1611, and subsequently adopted the processes of the blast furnace, reverberatory furnace, and flash smelting furnace of the present use. As indicated above, the copper ore of Ashio mine included arsenic. For the purpose to remove it, the operation of the arsenic trioxide production using MacDougall's multiple hearth roaster was started in 1918, and it maintained the status of having the most qualified technique within the country. However, as the completeness in the disposition of anti-pollution and safety had been requested in those years, we studied and developed a unique equipment in 1970. It excludes the heavy metals especially arsenic and copper from the waste water of sulfuric acid process of Flash Smelter's exhaust gas.

Jan 1, 1976

By W. C. T. Yeh, T. G. Oakwood, A. A. Hendrickson, R. H. Hammar

The objective of the research is to determine whether solid-solution strengthening effects observed in dilute solutions of silver can be accounted for by the influence of the solute addition on the dislocation structure oj- the crystals. The additions of both tin and indium produced only small changes in the dislocation densities and arrangements in silver crystals. However, as found previously, small solute additions have large effects on the tensile properties; the inj-luence of the tin and indium additions on the temperature dependence of the flow stress and the easy-glide range is especially strong; It is concluded that the indirect strengthening effect of the solute due to variations in the dislocation density as proposed by Seeger is of minor importance and that solute atom-dislocation interactions are responsible for the observed strengthenirzg effects. The experimental results were combined with those of Rogausch to test the concenlvatiorz dependence of solute strengthening. Both the first and one-half power dependences of the critical resoleed shear stress on concentratiorz fail in very dilute solutions. THE objective of the research is to determine whether solid-solution strengthening effects observed in dilute solutions of silver can be accounted for, at least in part, by the influence of the solute addition on the dislocation structure of the crystals. It is recognized that the addition of solute atoms may influence the strength properties of a metal through both "direct" and "indirect" effects. The former refer to the strengthening mechanisms that result from the interaction of solute atoms with dislocations; in the latter case, the strengthening effects arise as a result of solute's influence on quantities such as dislocation density, dislocation arrangement, stacking-fault energy, diffusivities, the elastic constants, and so forth. It is clear that the correct interpretation of solid-solution strengthening phenomena cannot be given until the importance of indirect strengthening effects is properly evaluated. In the particular case of close-packed metal crystals, Seeger showed that solute strengthening effects in dilute solutions of copper and silver might be accounted for by an increase in dislocation density due to the addition of the solute. Seeger's argument was that the strengthening effects extrapolated from more concentrated solutions indicate that small concentrations of impurities raise the critical resolved shear stress much more than is predicted by a concentration-independent dislocation density. The above idea was a very reasonable one. The dislocation theories of work hardening of Taylor,2 Cot-trell, 3 Mott, 4 and seeger5 had already associated the increased flow stresses with increased dislocation densities in deformed metals; investigations of the dislocation structure of metal crystals had provided a logical basis for expecting an increased dislocation density in crystals containing impurities (see for example, Ref. 6). The numbers involved seem reasonable, too. It can be expected that the flow stress of the crystal would increase as the one-half power of the dislocation density.' Solute additions of 1 at. pct to metal crystals result in strength increases by factors in the range of three to ten. If one assumes that the strengths of the pure metal crystals are determined by their dislocation densities, then dislocation-density increases of one to two orders of magnitude as a result of solute addition would be required to account for the observed strengthening—not an unreasonable expectation. In addition to the effect of the solute addition on dislocation density, one might also anticipate important strengthening contributions to result from the solute's influence on the dislocation arrangement. Parker and washburns have reviewed a number of experimental evidences which show important strengthening effects due to the presence of subboundaries. Further, lattice strains due to impurity segregation would be expected to influence the distribution as well as the dislocation density of the as-grown crystal. As pointed out in the reviews of Chalmers,6 Elbaum,9 and winegard,lo micro segregation of impurities occurs at all interfaces of crystals in cellular growth; the impurity gradient results in lattice strains which can be reduced with the presence of dislocation arrays in the region of the impurity gradient. Hence, one would expect the presence of a solute to favor the formation of dislocation subgrain structures and that the subgrains would have an important influence on the strength of the crystal. The experimental observations that concern the possibility of an important strengthening contribution through the influence of the solute on the dislocation density or arrangement are not in agreement. Haasen has reviewed the observations of Meakin and Wils-dorf,12 Howie,13 and Bocek 36 and concluded that the solute's influence on dislocation density is not sufficient to account for strengthening effects in concentrated solutions but might, as seegerl suggested, make an important contribution in very dilute solutions. On the other hand, Hendrickson and Fine 14 concluded that changes in the dislocation density and dislocation width accounted for the solid-solution strengthening effects observed in silver-based aluminum solid solutions. Goss et a 1.I5 observed dislocation arrays in Ge-6 at. pct Si, Ge-0.2 at. pct Sn, and Ge-0.2 at. pct B crystals that were not observed in germanium crystals of

Jan 1, 1968