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By Turgut Yalcin

"High-grade concentrates are achieved in flotation columns primarily due to the use of thick froth layers and wash water, both of which facilitate the drainage of hydrophilic minerals from the froth. However, conventional columns employ tall, non-agitated recovery sections for bubble-particle attachment that require high headroom and special gas spargers as well as imposing particle size limitations. These disadvantages can be all alleviated by carrying out the recovery part of the process in a mechanical or pneumatic cell which generate froth more conveniently and efficiently.This paper describes the combining of mechanical and column flotation in a single unit and discusses the influence of various parameters on the performance of the system.INTRODUCTIONIn a flotation process, some of the minerals lifted up to the froth phase may drain back to the pulp due to various reasons such as weak attachment of particles to air bubbles, bursting of air bubbles, agitation of froth, etc. Weakly floating and entrained hydrophilic minerals drain at a faster rate than the strongly floating minerals, and effective exploitation of such differential drainage can lead to cleaner concentrates.For a given mineral, if the rate of flotation from pulp to froth is k1 (min·1) and the rate of drainage from froth to pulp is k2 (min""1), then the net (overall) flotation rate of the mineral, k (min-1 ), will be [Lynch et al., 1981 ]:"

Jan 1, 1997

By Orlando C. Gaspar

The presence of ?ne-grained mineral intergrowths, the complex distribution of deleterious minor elements, and the variable base-metal contents in some assemblages commonly pose technical problems for the processing of volcanogenic massive sul?de ores. The bene?ciation of most massive sul?de ores from the Iberian Pyrite Belt requires extremely ?ne grinding to liberation sizes of K80= 15 µm to 25 µm. For several deposits, mapping of the ore types and metal zoning pat-terns has shown that the different ore types are distributed as ore lenses within the massive sul?des. Mineralogical, textural, and metallogenetic studies have provided an understanding of the distribution of both the vertical and the horizontal metal zonation in the orebodies. Because the ef?ciency of ore processing is affected by ore textures, and because the same mineral commonly has different textures and varies in chemical composition, a relationship between textures of the feed and the middlings must be established for all ore types de?ned at the deposit scale. Quantitative mineralogical methods have been developed to provide, on a timely basis, the information needed to optimize the concentration processes for the massive sul?de ores at the Aljustrel and Neves-Corvo deposits, Iberian Pyrite Belt, Portugal.

Jan 1, 1997

By Simon C. Dominy, Alwyn E. Annels, Paul Wheeler, Suzanne P. Barr, G. Simon Camm

Abstract-Narrow veins are an important world-wide source of silver, tin, uranium and particularly gold. To potential financiers, this style of mineralization is viewed as high risk because of the often relatively small resource involved and high cost of estimation. In many cases diamond core drilling will not enable resource estimation beyond the inferred and indicated categories. Exploratory underground development is required to define measured resources. The definition of geological and grade continuity are major factors in narrow vein assessment. A measured resource must be based on strong geological and grade continuities. Narrow veins, generally less than 3 m wide, are complex geological phenomena, which commonly display unpredictable geometry and grade distribution. Variations in structural continuity, dip, strike, width, mineralogy and specific gravity are common. Veins may be composite, with ore-grade mineralization restricted to a specific structural domain. Branches, intersections and braided zones are common features. Potentially high-grade zones are often localized within ore shoots, which are surrounded by barren/low-grade regions. Resources must be determined as closely as possible to reality and reflect the distribution of the commodity in the rock. Estimation has three main requirements: (1) geological study to determine orebody nature; (2) estimation of tonnage and grade, and (3) the presentation of this information using a classification that is clear, unambiguous and bankable. Estimation methods employed are either classical or geostatistical; however, classical methods are often used because of the difficulties in applying geostatistics. Grades generally show a strong positively skewed distribution testifying the presence of high-grade values. Problems exist in the applicability of cutting outlier values risking over- or underestimation of grade. It is generally believed that where resource estimates are in error, poor geological control is usually the cause. Overestimation can lead to the closure of a mine through lost revenue and capital. An understated estimate can result in an opportunity missed for profit and/or greater economies of scale. Definition of reserves involves the consideration of economic and engineering data, to decide which part of the resource is economically mineable. Geology plays a similarly important role at this stage in the assessment of likely mining method, dilution, recovery etc. Throughout resource/reserve estimation, it is crucial that the amount and quality of the data and the geologist’s experience are relevant. The impact of geological understanding on estimation is often undervalued or assumed to be of lesser importance than finding grades and tonnages. This paper discusses the geology of narrow vein deposits and the importance of geology in their evaluation.

Jan 1, 1997

By M. C. Bétournay, J. E. Udd

"The legacy of abandoned mines in Canada creates issues that impact on both the health and safety of Canadians and the environment. Solutions to the problems of abandoned minesites require a detailed understanding of site conditions, the engineering solutions which may be relevant, and planning for effective use of the land. In this paper, the authors outline the basic thrusts that have been developed at CANMET to address this problem. These include: multiprovincial agreements to develop a national database; methods of site rendering; a ten-year research program to develop engineering approaches; the review of a large number of case studies; and outlining the associated risks. Examples of the applications of this research are provided in the areas of: municipal, provincial, and federal co-operative projects; site-specific applications; and international linkages."

Jan 1, 1997

By A. I. A. Salama, M. W. Mikhail

"A comprehensive software package has been developed at the Western Research Centre to meet many of the coal preparation requirements in the Canadian coal industry. This package performs three main functions: (1) data handling and manipulation; (2) data analysis, including the generation of washability data, performance evaluation and prediction, density and size modelling, evaluation of density and size partition characteristics, and attrition curves; and (3) graphics output.The software described in this paper is potentially a valuable tool for coal preparation plant engineers and operators for evaluating process performance and adjusting plant density separator cutpoints. Moreover, the analytical laboratory technician could find this package very useful in manipulating and presenting laboratory results."

Jan 1, 1997

By Marcondes Lima Costa

Abstract-The Amazon region is characterized by the development of deep chemical weathering represented by widespread lateritic covers and soils. Two distinct periods of laterite formation can be distinguished: mature laterites from the Eocene-Oligocene (and locally from the end of the Cretaceous), and immature laterites from the Pleistocene. The older laterites occur on plateau landscapes, and the younger ones on widespread hilly to flat lowlands. Both types show complete or truncated profiles, generally covered by deep yellow to brown topsoils. The mature laterite profiles contain high concentrations of gibbsite and/or aluminum phosphate, whereas the immature ones are poor in these minerals. The Amazon region is rich in mineral deposits related to lateritic profiles. Some mineral deposits are of primary origin but were concentrated to economic grades by lateritic processes. The most important ore deposits are of iron, aluminum (bauxite), kaolin, manganese, gold, nickel, copper and phosphate. These are mainly related to mature profiles. The wide spectrum of ore deposits and mineralogical and geochemical complexity of the Amazon laterites has been promoted by: (1) the prevalence of ideal conditions for laterite formation throughout much of the Tertiary; (2) the presence of varied basement lithologies due to contrasting geological environments; and (3) a variety of epigenetic alteration types. The lateritic profiles show a well-developed ore zonation which is related to specific lateritic horizons. Iron and gold deposits occur in the ferruginous horizon, which is nearest the surface; the central aluminous horizon hosts bauxites, aluminum phosphate, strontium and gold; and the lower clayey horizon contains deposits of manganese, nickel, copper and kaolin. Resistate phases which residually accumulate throughout entire profiles include titanium (as ilmenite and anatase), chromium (as chromite), tin (as cassiterite), yttrium (as xenotime), and niobium (mainly as ilmenorutile). Epigenetic alteration, caused by swamp environments developed above truncated lateritic profiles, has led to the formation of high-grade kaolin and refractory bauxites. The laterites in the Amazon region contain most of all known kinds of ore mineralization related to laterite processes.

Jan 1, 1997

By Keith Haddock

"The Sheerness Mine, a new surface coal mine located near Hanna, Alberta, went into full production in mid-1995. The mine, which is operated by Luscar’s subsidiary Forestburg Collieries (1984) Ltd., has the design capacity to supply up to 2.1 million tonnes of sub-bituminous coal per year to the adjacent Sheerness Generating station under a 30-year contract. This paper documents the construction phase of this project and highlights the major equipment purchases as well as the construction of the mine facilities. The paper also focuses on some of the areas where cost savings have been achieved that have allowed the mine to come on stream six months ahead of schedule, and under budget. Project ReviewMine DescriptionThe Sheerness Mine is located 25 km southeast of the town of Hanna in southeastern Alberta (Fig. 1). The mining property occupies the western portion of the Sheerness CoalField and borders the Montgomery Mine, operated by Manalta Coal Ltd. in the east, and Highway 36 in the west. The Montgomery Mine and the Sheerness Mine exclusively supply the total coal requirement of the adjacent Sheerness Generating Station. The station is owned jointly by Alberta Power Limited (APL) and TransAlta Utilities Corporation (TAU). APL is the operator. Manalta’s Montgomery Mine has supplied coal to the Sheerness Station since its opening in 1986. Coal is shipped by truck from the mines over a network of haul roads to the coal receiving hoppers located on the east side of Highway 36."

Jan 1, 1997

By C. Doyle, J. Brennan, C. Díaz, J. Hrepic, K. Cushnie

"In 1991/1992, INCO undertook a successful R&D program aimed at extending the lining lives of the top blown rotary converters (TBRCs)at its Copper Cliff Nickel Refinery (CCNR) and the electric furnace at INMETCO. At the laboratory scale, this effort was divided into three phases. In the first part, mineralogical work was performed on six refractories that were either currently being used to line these vessels or were considered suitable alternatives. In the second part, this mineralogical knowledge was used to help determine the compositions of slags that would not corrode the bricks at the operating temperature (1600°C) of the above furnaces. Finally, several important properties of the six refractories were measured to complete their evaluation as candidate linings. This paper reports the results of all three phases of the laboratory scale R&D work.The mineralogical work showed that rebonded fused grain magnesite-chrome (RFG-MC) bricks consist principally of periclase with minor amounts of free chromite and trace quantities of silicates monticellite and sometimes olivine. The bricks are principally held together by periclase-periclase direct bonding. Of note, the bulk of the chromite exists as exsolved precipitated blebs within the periclase grains. These likely redissolve at high temperature.Slags on the periclase liquidus coexist stably with these refractories. Examples are presented using CaO-MgO-Al2O3-SiO2 slags at~1600°C.Finally, the two refractories manufactured using close to 100% fused grain material generally outperformed the others in terms of physical properties and certainly were superior in their resistance to slag penetration damage."

Jan 1, 1997

By A. Mcdonald, F. W. Breaks, T. F. Morris, S. A. Averill, D. C. Crabtree

Gahnite, a zinc-bearing spinel, is a resistate mineral that may be used as an indicator mineral of polymetallic deposits in high-grade metamorphic terrain. The Ontario Geological Survey recently completed sur?cial mapping and sampling programs in the Separation Lake area of north-western Ontario and Kinniwabi Lake area of northeastern Ontario in which gahnite was recovered from samples of sur?cial sediments. Ternary plots of the composition (ZnO, MgO, FeO[t]) of gahnite recovered from these sur?cial studies reveal three distinct groups: Group 1 is characterized by low (< 1 wt%) MgO values; Group 2 by higher (>1 wt%) MgO values; and Group 3 by higher FeO(t)values than Groups 1 and 2. The composition of in situ gahnite recovered from volcanogenic massive sul?de mineralization, Zn-rich Sedex-type mineralization and peraluminous rare-element mineralized granite and pegmatite also was determined. The composition of the gahnite obtained from sur?cial samples was compared with that of in situ material. Gahnite from the peraluminous rare-element granite and pegmatite overlapped very well with sur?cial gahnite of Group 1. Gahnite from volcanogenic massive sul?de mineralization and Sedex-type mineralization overlapped well with sur?cial gahnite of Group 2. These results suggest that determination of gahnite composition in indi-cator mineral surveys may be useful in exploration programs when assessing the mineral potential of a region.

Jan 1, 1997

"Le présent article porte sur la diminution des rejets de concentrateurs produits durant l’exploitation et le traitement des minerais métalliques.Le minerai dilué envoyé au traitement a, très souvent, un certain pourcentage du stérile qui affecte directement la rentabilité des opérations souterraines et amplifie l’impact négatif sur l’environnement. Les essais de la séparation du stérile et du minerai effectués en milieu dense sur quelques types de la minéralisation d’or, ont démontré les deux possibilités qu’offre cette technique:• Dans le cas d’un minerai riche, il a été possible de séparer la part importante du toutvenant (minerai dilué contenant le minerai et le stérile) provenant de la dilution, tout en ayant un taux de récupération élevé (supérieur à 96%).• Dans le cas d’un minerai ayant une teneur sub-économique à cause d’une dilution importante, il est possible de produire un concentré ayant une teneur économique à l’entrée de l’usine de traitement, en éliminant une partie du tout-venant.En plus la séparation du stérile peut accroître, en outre, la rentabilité de l’exploitation minière, car le fait d’éliminer la partie de stérile le plus tôt possible diminue certains coûts (transport, traitement et autres). On conclue que la pré-concentration du minerai (séparation du stérile et du minerai) est probablement une seule solution actuellement étudiée qui diminue l’impact environnemental de la mine, sans avoir des conséquences négatives sur la rentabilité de l’exploitation souterraine."

Jan 1, 1997

By J. K. Szymanski

"RÉSUMÉPour maintenir de bonnes performances technique et économique dans l’exploitation par chambres vides (open stope) il est primordial d’assurer un contrôle efficace des limites réelles des chantiers d’abattage. C’est pour cette raison que, de plus en plus souvent, les opérateurs miniers utilisent un dispositif de laser (Cavity Monitoring System: CMS) qui permet de mesurer les dimensions réelles de chantiers en vue de calculer principalement la dilution et les pertes du minerai ainsi que d’autres paramètres. Malheureusement, il n’existe présentement aucune méthodologie commune, qui permettrait d’interpréter ces résultats selon les mêmes critères pour faciliter d’évaluations juste et précise de la réalisation par rapport à la planification en vue d’en apporter de corrections, dans les différentes opérations minières, si nécessaire. Dans la première partie du présent article on discute les principales séquences d’exploitation utilisées dans l’extraction par chambres vides. Par la suite, à l’aide des sections transversales et longitudinales on illustre toutes les phases des travaux miniers. Ceci en vue de permettre au lecteur de comprendre mieux c’est qui peut se passer effectivement dans les chantiers d’abattage. Par après on donne les définitions générales de principaux facteurs de performance technique. Finalement, l’exemple numérique, élaboré à partir des résultats de l’arpentage au laser effectué par la mine Bousquet 2 dans un chantier d’abattage, donne les détails concernant les définitions ainsi que les valeurs de nombreux facteurs de performance technique, qui pourraient être utilisés, par après, par les opérateurs miniers dans le suivi de leurs exploitations souterraines."

Jan 1, 1997

By Richard Klimpel

"Over the last 15 years, there has been a number of plant scale sulfide mineral flotation tests organized by this author specifically aimed at understanding how flotation rate varies with reagent type and dosage. With regard to the Interaction of collector dosage, particle size, and frother type, the eight specific trends listed in the paper (Illustrated with data from two specific case studies) are qualitatively the same for almost all plants studied in some depth. The Interaction of flotation rate K and equilibrium (Infinite time) recovery R in the plant has been denoted as the R/K trade-off. The effect of collector dosage on the rate of flotation of specific particle size intervals is particularly interesting and once understood, is quite useful In understanding how industrial flotation plants respond to changing reagent type and dosage. The location and magnitude of the R/K trade-off can be different for various ores and various plant configurations, but the RIK trade-off is almost always present. The purpose of this paper is to clearly describe and illustrate the nature of this very Important flotation system Interaction so that operating engineers have a starting reference point for beginning successful plant Improvement studiesIntroductionIt is well recognized by industrial froth flotation plant operators that improving existing sulfide circuit performance is often difficult due to the self-compensating systems nature of the froth flotation system, e.g. Klimpel (1988, 1989, 1995). Extensive plant testing with existing and new reagents by this author throughout the world has clearly shown that one of the more important self-compensating mechanisms is the Interaction between collector dosage, frother type, and particle size. The term self-compensation in flotation simply means that as the plant operator consistently changes one parameter in the same direction, the nature of the froth flotation system Is such that the circuit will eventually begin to resist this controlled parameter change by automatic (uncontrolled) changes In other parameters and the overall circuit performance will go through a maximum or minimum (hence causing the operator to stop the parameter change)."

Jan 1, 1997

By Samantha Beeson, Collin Poole

"This paper examines the development of two new selective flocculation techniques for recovering KCI values from low grade carnallite potash ore.Direct recovery of KCI was achieved using one of two mid-range molecular weight polymers, one non-ionic and the other strongly cationic, in conjunction with the same selective anionic dispersant. From initial response studies on pure minerals and selective flocculation tests on synthetic mixtures, investigations were extended to recover KCI values from a natural carnallite potash ore. A single-stage process achieved products grading up to 61.3% KCI at recoveries up to 85.4% for the cationic flocculant suite and up to 64.8% KCI with recoveries as high as 90.3% for the non-ionic flocculant suite, with dispersant and flocculant dosages of 150-250gr1 and 10-75gr1, respectively. These results clearly demonstrate not only the feasibility of treating such problematic ores at low reagent dosages, but also the potential elimination of desliming prior to froth flotation.The experimental results presented are considered in terms of the reagent adsorption phenomena present in the system and various aspects of floe formation and cleaning.IntroductionAs high-grade sylvinite potash ores become scarce, lower grade sylvinite and carnallite potash ores are becoming more attractive. However, these ores often contain large amounts (up to 15% by weight) of water-insoluble slimes which must be removed prior to KC! flotation, owing to their high adsorptive capacity for the amine collectors used. The slimes are generally removed by scrubbing followed by hydroclassification and any residual material not eliminated is blinded with reagents such as guar gum or starch to inhibit interference in subsequent KC1 flotation.An alternative approach used commercially in Canada by Agrium Inc. involves water-insoluble slimes flotation prior to KC! flotation. In this process, the slimes are selectively flocculated and then separated by froth flotation. Losses of KC! to the slimes product and associated brine requirements are both reported to be less than those encountered in conventional desliming, but the technique is somewhat limited in its application at present."

Jan 1, 1997

By R. White, C. Doyle, B. Martin, C. Díaz, J. Hrepic, G. Cuthbert

"A program initiated to improve the service life of the magnesite-chrome refractory in the top blown rotary converters at INCO’s Copper Cliff Nickel Refinery identified slag corrosion as a major wear mechanism. Target slag compositions were established to produce a non corrosive slag. A plant program to achieve this target slag by the addition of controlled amounts of do lime and MgO was instituted. Addition to rates of the slag modifiers was optimized based on the slag composition assays achieved and the requirement to address corrosion effects on the high alumina content ladle refractory. A60% gain in TBRC refractory performance was eventually achieved and has been maintained yielding a net annual savings of $700,000. A significant gain in available converter operating time has also been realized.IntroductionINCO’s Copper Cliff Nickel Refinery utilizes two top blown rotary converters (Fig. 1) to smelt a blend of semi-refined nickel concentrates, producing a granulated nickel matte suitable for the adjacent carbonyl based nickel refining operation. The converter, or TBRC, operation is a batch process composed of feed charging and melting, oxidation of the excess sulphur in the matte, and reduction of residual nickel oxide. The final matte, containing about 78% nickel, is tapped at 1600°C from the converter and is granulated in a sluice equipped with high pressure water jets."

Jan 1, 1997

By D. Pacey

"This paper reviews the installation, start-up, and operation of a comprehensive monitoring and targeting management technique in which all plant utilities (i.e., electricity, natural gas, compressed air, and water) are managed as controllable resources in the same way that raw materials, mined ore, personnel and capital are managed.The essential elements of monitoring and targeting (M&T) include:•gathering in a systematic, disciplined way the utility information by energy account centres;•closely monitoring the utilities used in each centre and comparing them with production on a common time base (e.g., kWh/ton per day);•bench marking and target setting to pro-vide attainable energy reduction goals which can be further refined as they are achieved; and•establishing an implementation plant that may provide efficiency enhancing benefits to various operating areas within the plant.The M&T system will reduce utility consumption per unit of production on a continuing basis.This would translate into sustained operating cost and waste. M&T will also provide better information for assessing the plant operation and progressively implementing further enhancements."

Jan 1, 1997

By A. Desbiens, R. del Villar

"This two-part paper summarizes the design and implementation of a distributed PIbased control strategy installed at the B grinding circuit, at the Kidd Creek Division of Falconbridge Ltd. Part I details the design of the control strategy using a grinding circuit dynamic simulator (DYNAFRAG). The first step consisted of sampling campaigns and data processing to calibrate DYNAFRAG. Then, several control alternatives were designed and tested with the simulator. The main feature of these strategies is their ability to regulate or keep within an upper and lower limit five output variables (circulating load, rod mill density, cyclone feed and overflow densities and pump box level) with only three manipulated variables (rod mill water, pump box water and rod mill tonnage). By simulation on DYNAFRAG, it was possible to discriminate among several control structures. The preferred control strategy uses a saturation algorithm, which allows the adequate regulation of two measured variables with only one actuator. Controllers located in interacting loops are appropriately tuned, taking into account the existing process coupling. Part II will present the implementation of the selected control strategy.IntroductionSteady state simulators are used to predict the stationary state of a given process under specific operating conditions. Tradi - tionally, steady state simulation has been applied for process flowsheet design, for evaluating process modification benefits or for determining key operating parameters in process operation optimization. Dynamic simulators add a new dimension to process simulation since they allow the prediction of the process transient behaviour, resulting from the application of a different set of operating conditions and/or from natural disturbances or equipment failure. Dynamic simulators can also be used for the training of new operators or for the design of control strategies."

Jan 1, 1997

By R. Le

"The principles of noise control aredescribed with particular emphasis on personalactive units as opposed to passive ear muffspresently in general use. A discussion followsfor their potential use in a mining environment.RÉSUMÉNous décrivons brièvement quelquesprincipes de contrôle de bruit à l’usage person-nel, puis nous passons en revue quelquescasques commerciaux dotés de ces circuits àprincipe actif. Enfn nous discutons de leurusage potentiel dans le contexte minier.IntroductionLe casque à principe actif est un produitqui existe commercialement, mais encore peurépandu en usage, sûrement à cause du prix,mais aussi de sa méconnaissance par le grand public. Il arrive parfois qu’un journaliste trouvele produit fantastique et le médiatise commeune réalisation de son pays (ou de sa province),mais peu savent qu’il s’agit là d’un principe quia commencé dans les années 30. Par delà lesensationnel, il reste que si l’on veut mettre lamain sur un de ces casques pour l’essayer, on nesait où l’obtenir. De plus, les casques n’utilisentpas tous le même principe actif. C’est la raisonpour laquelle nous faisons cette brève compara-ison. Nous le faisons en mettant l’accent pourune possible utilisation dans le domaine minier,car c’est dans ce milieu que les usagers sontconfrontés aux bruits les plus intenses qui peu-vent endommager leur système auditif, ce quin’exclut pas les autres situations (travaux publics, foresterie, écoute hi-f, etc.)."

Jan 1, 1997

By C. M. Clapperton, K. E. Darke, A. J. Boyce, C. M. Rice, S. D. Redwood

"The Kori Kollo gold deposit is hosted by a c.15 Ma sericitized dacite stock in the LaJoya district on the Bolivian Altiplano. The mineralization is of the Bolivian polymetallic vein(BPV) type, with a signi?cant amount of the gold reserves contained in the oxide cap.Field and microscopic studies, K-Ar dating, ??34S values of pyrite, alunite and jarosite, and ??18O values of alunite and jarosite demonstrate that some of this gold is supergene. Two types of supergene gold are present: minute gold grains, 1 to 10 microns across, of high fineness and associated with jarosite and iron oxy-hydroxides; and ‘invisible’ gold, which is probably sorbed onto minerals such as jarosite and iron oxy-hydroxides.Pyrite ??34S values fall in the limited range -3.5 ± 0.6‰, consistent with a magmatic origin. Sulfate ??34S values are homogeneous and overlap closely with those of pyrite (-1.2 ± 2.1‰), which supports petrographic evidence that sulfates replaced pyrite. By contrast, sulfate ??18O values are inhomogeneous with a large range (alunite +2 to 26‰, jarosite -5 to +18‰). These data are interpreted as reflecting kinetically controlled reactions involving various proportions of atmospheric oxygen and local meteoric water. This is typical of supergene alteration and is due to the seasonally dry climate of the Altiplano.The oxide-zone mineralogy is dominated by sulfates and iron oxy-hydroxide minerals with some phosphates and halides, which indicates that the groundwaters were acidic, oxidizing and relatively saline. Under these conditions the most likely complexes responsible for gold mobilization are halides.Geological data and K-Ar ages indicate that oxidation of the BPV deposits began at least around 11 Ma and possibly up to 15 Ma ago, and that supergene alteration lasted until around 4 Ma. During this period, erosion was minimal. Although supergene processes have been active on the Bolivian Altiplano since the Middle Miocene, in contrast to Northern Chile, enrichment of gold has not occurred."

Jan 1, 1997

By D. G. Tisdale, W. Curlook, J. M. Toguri

"In this study, the vapour phase reduction of titanium tetrachloride conforms to the traditional Kroll chemistry, but employs argon as an inert carrier gas and requires a higher reaction temperature of 1150°C to 1250°C. A vapour phase reaction is advantageous because titanium is the only condensed phase present, and the metal can be collected free of magnesium or magnesium chloride, in marked contrast to the titanium sponge produced by the conventional Kroll process. The yield of metallic titanium from the reaction was determined as magnesium additions ranged from 36% to 168% of the stoichiometric requirement. Yields of over 99% were obtained when an excess of magnesium was present. Although the collection efficiency was low, metallic titanium was collected at the reaction site, where all other species were present as vapours. Magnesium and chlorine concentrations in the collected titanium were less than 0.3%.IntroductionA proposed method (Curlook, 1987) for titanium production has been investigated as an alternative to the conventional Kroll process (Kroll, 1940). The advantages of the new process include a simplified means of recovering the product metal, and a potential for lower overall energy consumption and greater product purity. A higher reaction temperature for the reduction of titanium tetrachloride results in a vapour phase reaction, rather than the conventional liquid phase reaction. This is the major conceptual difference between the proposed and the established (Kroll) processes.This study focussed on optimization of the process chemistry and briefly examined the issue of product deposition and collection. The reduction of titanium tetrachloride with magnesium, to produce metallic titanium and gaseous magnesium chloride:"

Jan 1, 1997

By C. Stapel, P. D. Roberts, D. G. Jones, W. G. Macdonald, R. J. De Meijer

"Measurement of natural radioactivity has been used in both a qualitative and a quantitative way in mineral exploration, particularly in the search for uranium. In the last ?ve years, the Kernfysisch Versneller Instituut (KVI) and British Geological Survey (BGS) have designed, built and tested a new detector system that greatly improves quantitative applications in mineral exploration, especially on the sea?oor and in the nearshore zone. The new system is an enhancement of an earlier BGS design. The major improvements comprise the use of a highly sensitive ?-ray detector, together with new data processing, from which concentrations of natural radio nuclides may be deduced in real time. After laboratory analysis of samples, these concentrations can be converted into mineral percentages. Once the mineralogy of an area has been characterized, this conversion can also be done in real time.Thus far the system has mainly been used to map heavy-mineral concentrations in coastal subtidal and intertidal sediments. For such work the multi-sensor detector probe is towed on the sea?oor and various parameters are recorded continuously. The probe contains, in addition to the gamma-ray detector, a water-pressure sensor (giving water depth) and an acoustic device to measure bottom roughness. The system, when used together with high-precision positioning systems such as D-GPS,enables the production of detailed maps of bathymetry, bottom roughness, and sea?oor radioactivity or mineral distribution. These maps allow mineral concentrations to be readily correlated with sea-bed topography and sediment type. In the same way, ?-ray detectors could be used advantageously during dredging operations to provide on-line assessment of the mineral content of the dredged sediment as well as to guide the direction of dredging. Additionally, the same technique could be used to monitor the subsequent fate of a dredge spoil after dumping on the sea?oor.Natural radioactivity arising from potassium and the thorium and uranium decay series has potential use for the fast and reliable assessment of siliciclastic and phosphatic impurities in limestones. Detection of such impurities may preclude the use of the limestone for chemical or cement production.Apart from its use in exploration, the technique has signi?cant potential in mineral processing, particularly of heavy minerals. It can be applied as on-line quality control in dry and wet separation processes and for process control, by using decisions based on the results to control valves and other instrumentation. In addition, it can also be used in environmental monitoring of waste arising from mineral extraction and processing. In conclusion, the technique described has a diversity of applications in exploration, mining and mineral processing."

Jan 1, 1997