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By Akira Yazawa

The similarities and differences in copper, nickel and lead smelting processes are discussed based on the sulfur-oxygen chemical potential diagrams and the free energy minimization assessments using a thermodynamic software. The prominent features of copper smelting are ascribable to the fact that copper has a strong affinity for sulfur but weak for oxygen and the liquid phase immiscibility between Cu and Cu2S. During the oxidation of sulfides, nickel metal is not stable except at temperatures higher than 1500°C, well miscible with its sulfide, and is oxidized more easily than copper. Metallic lead looks as stable as copper during the oxidation of the concentrate but Pb and PbS. are much more miscible with each other and the vaporization loss is considerable. In the reductive smelting of oxides, the effects of oxygen potential and temperature on the copper contents in slag are not significant due to the monovalent character of copper and the reduction of copper content in slag is not easy in practice. The effect of the slag compositions on the oxidic metal contents of slag is much more significant for lead than either copper or nickel. Due to the immiscible nature between Pb and Fe, high grade lead bullion is easily obtained and lead is more tolerant to impurities.

Jan 1, 1998

By S. Gupta

Froth flotation is a process commonly employed for the selective separation of phosphate from unwanted mineral. Column flotation has become widely accepted in the mineral processing industry, including phosphate industries, due to its ability to improve selectivity, lower operating cost, lower capital cost, and superior control. In this work, a hybrid model is developed that combines a physicochemical model with artificial neural networks. The physicochemical model is based on axial dispersion with first order collection rates. A new approach, in which both frankolite (the desired mineral containing phosphate) and gangue (undesired product) are modeled, enables prediction of grade of the recovered product. Thus, two basic parameters are required in this model: flotation rate constants for frankolite and gangue. Artificial neural networks are used to predict flotation rate constants. The model also takes into account the particle size distribution and predicts grade and recovery for each particle size range. The model then combines grade and recovery for each particle size range to determine the overall grade and recovery of the column. The model is validated against laboratory column data.

Jan 1, 1998

By Douglas A. Bartley, Davey Bickford, Raphael Trousselle

The long awaited arrival of a high accuracy detonator to reach the explosives end user will provide new opportunities the blasting community to become better equipped and able to improve upon the current approaches and methodologies used in blast design as they apply to the mitigation of adverse effects from blasting. This paper will detail the approach and findings throughout a several month research project to quantify the high accuracy detonator benefits and to mitigate a long standing vibration problem at a hard rock stone quarry in the state of New York. The tests conducted in this study were designed to provide important information as to the relationship between the use of high accuracy detonators and overall blast performance in terms of ground vibration prediction, control and improved rock fragmentation.

Jan 1, 1998

A chartered bus with about 30 attendees of the just completed 1998 SME Annual Meeting headed toward Green Cove Springs, FL, which the author had been told was located somewhere south of Jacksonville, FL. In conjunction with the meeting in Orlando, RGC (USA) Mineral Sands provided a tour of its facility. The author had worked with heavy minerals on a laboratory scale, performing the usual gravity and magnetic separations, but had never been to a heavy mineral mine and processing facility. Years ago as a metallurgist, the author once applied for a job in a heavy mineral operation in Florida -it may have been the same operation. After turning north on to Highway 95, the endless billboards promoting beach-front retirement communities proved the Atlantic ocean was just a few miles away (although the author never caught a glimpse of it). After another hour, the bus suddenly turned west and continued inland for about 65 km (40 miles). The thought occurred, "We are talking about beach sands, what are we doing heading away from the ocean?" As the bus continued inland, the author was struck by the flatness of the land and by the lakes, rivers and wetlands. He was also impressed by the many fine stands of pine and hardwoods. The office of RGC (USA) Mineral Sands is located about 16 km (10 miles) south of Green Cove Springs. Upon leaving the bus, members of the tour were greeted by Graeme Sloan, general manager, and Elliot Mallard, manager of mining. They provided some general information about the operation, including a slide show. RGC's Florida operation produces four concentrates: zircon (ZrSiO,), rutile (TiO,), ilmenite (FeTiO,) and leucoxene (an alteration product of ilmenite containing 67% to 70% TiO,). With a work force of about 170, the annual production of the above products is about 23,27, 45 and 14 kt (25,000 30,000 50,000 and 15,000 st), respectively. RGC also has other mineral sand operations, in addition to gold and base metal mines, mostly in Australia.

Jan 1, 1998

By Dai Wang

Stoppings are necessary ventilation control devices for effective air distribution underground. However, one of the major problems underground mining has is that every stopping is a potential leaking source. Since air always flows from a point of high pressure to one of lower pressure, and the total pressure at every point in intake airways is higher than that in the return airways, air will always tend to leak from intake to return (Tien, 1996). In many mines, less than half of the air entering the mine actually gets to the working areas; the rest of it simply short-circuits directly to return airways through leaky stoppings instead (Timko and Thimons, 1983). Leakage through a stopping occurs because of pressure drops across the stopping and available leaky path in stoppings. Empirical equation has been widely used to characterize the relation the amount of leakage and variables that affect leakage. However the use of this equation requires accurate information for constants which are not always readily available. It is the attempt of this paper to derive an equation similar to the Atkinson Equation that can readily be applied to characterize pressure-leakage relationship for any given stopping.

Jan 1, 1998

By Garston Blackwell

Abstract - During geostatistical estimation of block grades, the kriging process produces a measure of error, the kriging variance or the kriging standard deviation. Estimation of the block error depends on the semi-variogram model for a deposit, which reflects fundamental characteristics of a deposit such as (1) nugget effect, (2) range of influence of grades, (3) different local spreads of data as a function of average grade (proportional effect), (4) nested structures, and (5) underlying anisotropies in the data; this model may be affected by sampling or assaying limitations, however. Because the kriging error incorporates so many features of both the deposit and data to be used for estimation, it may offer a substantial improvement on block classification over traditional procedures such as data density. Practice indicates that the relative kriging standard deviation (RKSD) is particularly useful for block classification in measured, indicated and inferred categories. Plots of RKSD in plan and section also can be used to demonstrate where extra drilling and sampling would be most advantageous for upgrading the class of some blocks. Moreover, the use of grade and RKSD filters can show where material near cut-off grade is poorly defined, indicating sampling target areas to improve block classification in the vicinity of the ore-waste boundary.

Jan 1, 1998

By J. S. Lee

Alkyl hydroxamates are well known collectors for oxide copper minerals as evidenced by the large amount of published literature. Our studies on a wide variety of copper ores from around the world have shown that alkyl hydroxamates will recover most of the "floatable" oxide copper minerals from an ore. They are available commercially, and they offer many advantages over alternative technologies for oxide copper recovery. In spite of this, the full potential of hydroxamates has not been exploited in the industry. The objective of this paper is to provide relevant practical aspects and guidelines to facilitate successful application of hydroxamates in operating plants. A critical analysis of the available information and data, based on several case studies, notation testing, and microscopic analysis indicates that alkyl hydroxamates can effectively recover well-defined oxide minerals of copper, but not copper occurrences such as Cu-bearing goethite (often misidentified as cuprite) which report as Acid Soluble copper in chemical assays. Prior to any notation testing with hydroxamates, it is necessary to assess the various modes of occurrence of Acid Soluble copper using microscopic and microprobe analysis.

Jan 1, 1998

By Paul Shimizu

BHP Robinson contracted Minnovex Technologies to implement a Comdale Expert System at their greenfields operation in Ely, Nevada. The expert system has resulted in a significant increase in tonnage. Other benefits have also been realised, including a reduction in operation upsets (having a positive effect on downstream processes, i.e. flotation) and reduced production variances between crews. The expert system is written in a unique manner using trend based logic with minimal hard limits. The result is a robust system that requires minimal operator supervision while producing very high results. The development, success and acceptance of the system can be attributed to the strong team that was assembled for this project. The team not only consisted of BHP Metallurgists and Minnovex but most importantly included operations.

Jan 1, 1998

By S. Nygren

Nalco Chemical Company and a North Carolina Phosphate operation have formed a successful supplier/customer team effort that has resulted in major improvements in the operation of the clay thickening circuit at the Aurora, North Carolina concentrator. A Nalco OPTICUS® Automated Process Control System for thickener and flocculant control was installed in 1994. The paper will discuss in detail the development and refinement of the OPTICUS system over the past three years. The paper will survey the development and networking of process control for monitoring, controlling and operating four 325-foot Dorr-Oliver thickeners, three 80-foot high-rate Enviro-Clear thickeners and control links to the facility's clay/gypsum blending operation.

Jan 1, 1998

The capability for on-line measurement of the quality characteristics of conveyed coal now enables mine operators to take advantage of the inherent heterogeneity of those streams and split them into wash and no-wash stocks. Relative to processing the entire stream, this reduces the amount of coal that must be washed at the mine and thereby reduces processing costs, recovery losses, and refuse generation levels. In this paper, new approaches for optimal control of the segregation process, using time series models and empirical distributions, are presented and demonstrated using field data.

Jan 1, 1998

Both safety and productivity in underground gassy coal mines can be improved substantially if an appropriate gas management system is introduced. A strong direct relationship exists between the gas emission rate, roof and floor strata relaxation zones characteristic, mining activities and gas drainage practices. Detailed knowledge of geological factors, gas and coal-rock properties, as well as mining systems are necessary for the methodology used in predicting overall underground gassiness, and planning gas capture and ventilation systems. Early gas emission calculations for various mining activities, particularly for the longwall mining system are essential. A reasonably accurate prediction of gas make as well as the design of ventilation, gas recovery (drainage holes) techniques can be made using 'Floorgas' and 'Roofgas' computer simulations, provided sufficient geological, mining, and gas data are made available.

Jan 1, 1998

In most States of Australia it is a legislative requirement for underground mines to have a separate means of egress from the normal means of ingress to permit the safe evacuation of workers to the surface in event of an emergency. Such egress may be in the form of a ladderway equipped shaft/underlie or trafficable incline/decline. Additionally, there is a general requirement to have one or more airways, separate to the main shaft or other principal entrance of an underground mine, extending to the lowest level to permit ventilation to all parts of the mine. Fulfilling these requirement is difficult in the development phase of a mine when access underground is achievable by only a shaft or decline in the process by being sunk. What is frequently practiced in Australia is for production to then commence, sometimes in association with continuing development, in the same configuration without the establishment of this separate method of egress to the surface nor additional airway/s with reliance on refuge chambers to cater for back up in any emergency. Not only, could this jeopardise the health and safety of workers in case of an underground emergency it could be construed as a statutory breach of legislation. While recognising that refuge chambers are often used throughout underground operations nowadays their equipping and the criteria for their location needs to be bought into focus. This presentation discusses how such legislative requirement can be met alongside the use and appropriateness of refuge chambers.

Jan 1, 1998

Little knowledge is available that considers the effects of continuous miner position on the possible respirable dust exposure of the remote mining machine operator. Such information could be very useful for increasing the awareness of the remote operator as to those parts of an extended cut that generate higher levels of respirable dust. This data could be used to develop guidelines for positioning the remote operator to reduce his potential exposure. This work details the effects of continuous miner position on dust levels measured on the machine and at the remote continuous miner operator location.

Jan 1, 1998

By M. H. Foroughi

This paper discusses the effects of seam inclination and lateral stresses on the stress distribution in pillars in inclined coal seams. The average pillar stress is a function of the overburden weight, the mine depth, the effective extraction ratio and the angle of seam inclination. Normal and shear stresses in the pillar are computed by numerical modeling. In medium dipping seams, leaving a pillar with its axis normal to the stratification causes a shearing stress concentration in the top and bottom corners of the pillar. This results in the pillar possibly becoming less stable in comparison to pillars in horizontal coal seams. Therefore, to reduce the stresses, it may be necessary to leave the pillar at an angle of b deviated from the normal axis to stratification. A mathematically approximate formula for determining b is proposed, and the results are confirmed by numerical modeling.

Jan 1, 1998

By James Su

The Green River Valley in Kent, Washington, is a fast growing area containing retail facilities, warehouse factories and industrial businesses, including the Boeing Space Center. Traffic from Interstate - 5 to the West Valley Highway is highly congested. Accordingly, a new corridor, including a bridge across the Green River, was designed and constructed between 1996 and 1997. This paper presents a case history of the design elements and issues associated with the construction of the pier foundations of the bridge. Subsurface conditions were evaluated using both deep test borings and CPT soundings to evaluate the strength and consolidation properties of the supporting soils. Subsurface conditions consisted of alternating layers of loose and medium dense silty sand and sandy silt. Engineering analysis included an assessment of liquefaction as well as pier supporting capacity and associated settlement. The constructed foundations included 6-foot-diameter piers cased to a depth of 120 feet below the ground surface. The pier casings were driven to the design tip elevation and the soil inside the casing was removed by drilling. Despite performing borings and CPT soundings at specific pier locations, occasional trees, buried thousands of years ago through geologic processes, were surprisingly encountered during pier construction. This presented unique and difficult driving and drilling conditions. During drilling, the water level inside the piers was maintained near the ground surface to create a balance of hydrostatic pressure and prevent boiling of soils the bottom of the casing. After the casings were installed, the soil inside the casing was excavated, the rebar cage was installed and the pier was filled with concrete using treme techniques. Construction of the piers is complete and the completed piers have experienced negligible settlement. Owner: City of Kent Engineering Department Timothy La Porte, Project Manager Kent, Washington General Contractor: Mowat Construction Company, Kirkland, Washington Foundation Contractor: Condon - Johnson & Associates, Inc., Tukwila, Washington

Jan 1, 1998

By Katsuya Kase, Kaname Takeya, Keaji Ohmori, Yoshiyuki Asakawa

"The reduction-diffusion process (the R-D process) using Ca as a reducing agent has been practiced in industry in the production of the SmCos type, the Nd-Fe-B type and the 1b-Fe-Co type magnetic materials. The advantages of the R-D process are the generally high yield of rare earth metals and the single-stage conversion of a mixture of oxides and metal powders into a product of rare earth alloy powders. On the other hand, one of its disadvantages is the slightly high contents of oxygen and calcium. This disadvantage is remarkable in the Nd-Fe-B type. Singe-phase Nd2Fe14B alloy powders with low content of 0 and Ca, is obtained by choosing appropriate raw materials and performing the R-D process in a controlled way. These alloy powders are very suitable for the production of Nd-Fe-B sintered magnets and expected higher magnetic properties by adopting advanced magnet production method.IntroductionThe hard magnetic rare earth transition metal intermetallics, especially, have attained considerable technical importance. Examples are the alloys based on the intermetallics SmCo5[1], SmC017[2], NchFet4B[3], or the recently developed alloy SnuFe11Nx[4]. The reduction-diffusion process using Ca as a reducing agent has been well known as an economical method of producing rare earth based magnet materials[5]. The reduction-diffusion process has been practiced in industry in the production of the SmCos type, the Nd-Fe-B type and the 1b-Fe-Co type magnetic materials. The advantages of the reduction-diffusion process are the generally high yield of rare earth metals, the single-stage conversion of a mixture of oxides and metal powders into a product of rare earth alloy powders, the elimination of the crushing process of the alloy ingot, the inessentiality to special equipment, etc. On the other hand, one of its disadvantages is the slightly high content of oxygen and calcium. This disadvantage is remarkable in the Nd-Fe-B type. An outline of basic studies of the reduction-diffusion process was reviewed from the particular viewpoint of the production of magnet materials by Ogawa [6]."

Jan 1, 1998

By Mark Tjerkstra

In ,1993, the WMC Resources Ltd.-owned Kalgoorlie Nickel Smelter, underwent a capacity upgrade. This capacity increase was offset by .air quality control restrictions limiting the smelter's availability to 80%. As the direct. result of this limitation, WMC Resources Ltd commissioned a double absorption contact ,acid ,plant for the desulphurisation of furnace waste gas in August 1996. The history and the impact of the acid plant on S02 emissions and air quality is reviewed. General descriptions of the other aspects of the Kalgoorlie Nickel Smelter's Environmental Project are also included in the paper. Information on 'the design features? and operating practices that relate to or contrast with practices at operations visited by KNS personnel prior to acid plant commissioning provide the paper's focus. Smelter operation has changed markedly from unstable operation prior to 1997 to continuous" operation with little down time due to mechanical or process failures resulting in increased smelter availability to more than 90%

Jan 1, 1998

By H. Sis

The pressure filtration behavior of dispersed and flocculated alumina slurries at high percent loadings is discussed with an objective to determine the effect of surfactant type and concentration on slurry properties. A high purity alumina powder was used as a model solid. Dispersion of the alumina was controlled by surfactants that are considered to act by electric and steric stabilizers. The effect of both the ionic and nonionic surfactants was investigated. Surface charge measurements of the slurries were carried out by electrokinetic sonic amplitude (ESA) method to understand the mechanisms. The effect of surfactant type and concentration on the kinetics of pressure filtration and final cake properties are discussed.

Jan 1, 1998

By David W. Mogk, Tamara Darsow, Macgregor L. Fogelsong, Robert M. Hunter, Frank M. Stewart, Edwin H. Abbott, Courtney A. Young

Abstract: Development of cost-effective techniques for recovering precious metals from their ores has been the goal of metallurgists for hundreds of years. Today, metallurgists are increasingly called upon to design processes for ores that are refractory to conventional recovery techniques. These challenges and the addition of environmental costs (including site remediation) to the total cost of mining have stimulated a search for alternatives to conventional processes, such as cyanidation. This paper describes the progress made to date in development of an innovative alternative to cyanidation, termed bisulfide leaching, for extracting gold, silver and platinum-group elements from refractory ores and concentrates. While bisulfide leaching can be implemented abiotically, significant benefits accrue from its practice as a bioprocess that integrates the steps of precious-metals liberation and extraction. In many applications, bisulfide leaching appears to offer significant advantages over the traditional cyanidation process. Dissolved bisulfide and hydrogen sulfide are much less toxic than dissolved cyanide and hydrogen cyanide. Recommended workspace exposure limits and harmful concentrations for hydrogen sulfide gas are higher than those for hydrogen cyanide gas. While the facilities required to practice the bioprocess on an industrial scale would be similar to that of cyanidation plants, chemical reagent costs could be 80 percent less. The bioprocess may also offer advantages in the leaching of ores and concentrates that are not amenable to cyanidation. For example, bisulfide leaching of ores containing carbonaceous material may produce higher gold recoveries if the "preg-robbing" characteristic of the material can be controlled biologically or with dissolved sulfide binding. Moreover, in that precious metals are much more soluble than base metals in bisulfide solutions, bisulfide leaching offers distinct advantages over cyanidation for selective dissolution of precious metals from base-metal concentrates. Thus, the bioprocess uses the natural sulfur cycle to mitigate pollutant production and to enhance precious-metals recovery.

Jan 1, 1998

By M. H. Col

Within the last few years, there have been numerous techno-logical advancements within material handling due, in part, to the introduction of conveying systems and mobile material handling systems to the industry. Although the traditional material handling methods are still commonly used, the introduction of conveyors to the industry has provided companies with some very efficient and economical options. These "new" systems change with the industry to accommodate rigorous demands, ease of operation, and low operating cost requirements. The number of mobile material handling systems utilized in mining operations is increasing, especially in heap leaching applications. Ten years ago, mobile material handling systems like Mobile Stacking Conveyors (MSC) were considered a novelty. There were two (2) MSC's in actual operation and only one of those in a heap leaching application. Today there are numerous proven systems operating at mine sites around the world-La Coipa, Zaldivar, Florida Canyon, Cananea, El Abra, Chuquicamata, and Radomiro Tomic. The popularity of mobile systems is due to the benefits realized by individual projects. As technology advances, so do the concepts behind mobile material handling systems. Implementing self leveling mechanisms, Programmable Logic Controllers, and Global Positioning Systems to control the equipment are just a few of the recent advances that will be discussed in this paper. We will also discuss current proven systems, and touch on what we see as some of the future advances.

Jan 1, 1998