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By M. Misra

The removal of lead and other heavy metals present in an active US Army small arms firing range soil was evaluated in a pilot scale test program at Ft. Polk, Louisiana. Two different acid based extraction processes in conjunction with conventional physical separation methods were used. Physical separation processes consisting of screening and gravity operations removed most of the coarse lead particulates and slugs. Hydrochloric acid leaching followed by precipitation of lead as hydroxide recycled clean soil containing less than 500 mg/L. total lead and less than 5 mg/L TCLP lead. Lead extraction efficiency with hydrochloric acid was 96 percent. The results of lead removal by physical separation in conjunction with acetic acid leaching were not consistent over the whole test period and the total soil processed.

Jan 1, 1998

ITEC Environmental Colorado has begun reprocessing the tailings from old mining sites near Boulder, CO. And if the technology behind ITEC's pilot project at Gold Hill proves successful and profitable, the company plans to launch similar reprocessing operations in other parts of the state. The pilot project is under the watchful eye of state and federal authorities. They hope the technology becomes the answer to cleaning up old mining sites throughout the West. Remining and environmental cleanup on an economic basis, then, are ITEC's hopes in one the most environmentally conscious counties in the state. Clean up the mine dump sites and recycle the land, for a profit. In June 1998, ITEC Mineral Inc., ITEC Environmental Colorado's Canadian parent, acquired the Gold [ ] Hill Mill facility in Boulder County. Included in the acquisition was 4.4 hm2 (11 acres) containing the Gold Hill Mill and 283 hm2 (700 acres) of additional properties adjacent to the facility. ITEC estimates that there are about 910 kt (1 million st) of dump rock in the area. That is enough to make the operation viable. ITEC will sell the metals recovered through its reprocessing operations. However, due to low metals prices, ITEC is not expecting to make much money on the recovery of precious and base metals. Instead, the company plans to resell the reclaimed land for residential and commercial development or open space. The Gold Hill Mill site is the first of 17 sites in Colorado that ITEC Mineral hopes to clean up and recycle the land. Most notable among the sites is the historic Central City/Black Hawk mining district, which ITEC believes holds considerable potential. The Gold Hill Mill is located 14 km (9 miles) west of the city of Boulder and less than a half mile from the small town of Gold Hill. The mill was. last operated in 1992. The operation was forced to close that year due to environmental and cash flow problems. Gold Hill is in the middle of a region with more than 32 Mt (35 million st) of mine tailings. Independent geologists have' established the average grade of the Gold Hill mine tailings to be 4.5 to 5.3 g/t (0.13 to 0.155 oz/st) of gold and 28 to 44 g/t (0.83 to 1.29 oz/st) of silver. According to these studies, the Gold Hill mine tailings are five times richer in precious metals than the tailings of the Norebec Manitou property in Canada that ITEC is also remining, reclaiming and restoring. Upon acquiring the mill, ITEC undertook a refurbishing program that included adding a second ball mill. This increased the Gold Hill Mill's capacity to 180 t/d (200 stpd). The operation employs 15 people. "The Gold Hill Mill site will demonstrate the efficiency of our integrated remining, reclaiming and restoration process," said Maxine Stewart, president of Denver, CO -based ITEC Environmental. "The abundance of similar mine sites in Colorado presents a number of opportunities to bring the benefits of the ITEC system to other communities around the state." Holly Huyck is technical advisor to the Clear Creek Watershed Advisory Group. She said: "ITEC is cleaning up an orphan mine site that otherwise would continue to contaminate the Boulder Creek watershed with acid and excess metals. This is a win-win situation: ITEC gains marketable minerals while it reclaims mined land and helps to improve the watershed."

Jan 1, 1998

Direct force measurements were conducted using an atomic force microscope (AFM) to study the mechanism of copper-activation of sphalerite. The force measurements were conducted between a sphalerite plate and a hydrophobic glass sphere in xanthate solutions of various pHs. The glass sphere may represent the hydrophobic air bubbles interacting with minerals during flotation. The force measurements conducted with unactivated sphalerite in 10') M KEX solutions did not show the presence of hydrophobic force. On the other hand, the results obtained with copper-activated sphalerite at pH 9.2 and 4.6 showed strong hydrophobic forces. However, the results obtained at pH 6.8 showed no evidence of hydrophobic force, which provides an explanation for the difficulty in floating sphalerite at neutral pH.

Jan 1, 1998

The paper presents the results of laboratory blasting and grinding experiments on a low-grade iron ore, investigating how blasting will influence the subsequent crushing and grinding operations. Increased blasting energy will lead to a reducti

Jan 1, 1998

By R. G. Reddy

Solid state reduction of roast movat chromite ore with carbon was carried out as a function of C/FeO ratio and temperature in the range 800°C to 900°C by thermogravimetry analysis (TGA). A two stage mechanism, (1) the reduction of FeO present in Roast Movat with carbon monoxide; and (2) the regeneration of CO by the oxidation of carbon with CO2 was proposed. The rate controlling step is the carbon oxidation reaction. A kinetic equation, that of random nucleation, was proposed. The activation energy for the reduction was determined to be 55800 J/mole and is compared to those activation energies determined for other chromite ores.

Jan 1, 1998

By A J. Ryan

The Ernest Henry copper-gold Mineral Resource is the major asset heldby Ernest Henry Mining Pty Ltd, comprising A$6.4 billion of containedmetal. The case history presented below describing the evolution andevaluation of this resource generally observes best industry practice and is a good example of effective due diligence in the resource delineation and estimation process. Early reconciliation data from mine production confirms the accuracy and validity of the resource estimate, providing valuable assurance to the mine owners.

Jan 1, 1998

By E. Peuraniemi, S. Strömberg, S. Jyrkönen, A. Jokilaakso

Several sulfidic raw materials have been flash oxidized in a laboratory furnace in oxidizing atmospheres at temperatures of 500-1100°C. Chemical analysis was used to determine the oxidation degree, and optical and scanning electron microscopy combined with energy dispersive analysis were used for characterization of the reacted particles. The studied materials included both Cu and Ni concentrates and mattes. In fixed conditions, the temperature dependence of sulphur removal rate was found to be equal for all the copper concentrates studied. Nickel concentrates and Cu- and Ni-mattes were, however, found to be less reactive. Most of the particles were found to spheroidize and to fragment to small droplets under intensively oxidizing conditions. The product particles were frequently found to be iron oxide cenospheres or dense spheres with a composition of mixed Cu-(Ni-)Fe oxides.

Jan 1, 1998

By Serge Payant, Michael G. Li, Lionel J. J. Catalan

Alkaline solution rinsing for decommissioning of an acid-leached residue was evaluated by column experiments, neutralization tests and solid characterization by XRD and SEM. It was found that consumption of a strong alkali during residue neutralization was much greater than that required to neutralize the soluble acidity. The excess alkalinity was consumed by solid-phase conversions unnecessary for the success of decommissioning. Alkaline rinsing did not reduce the time requirement for decommissioning when compared with plain water rinsing. Since no benefit is gained to compensate for the additional costs associated with excess alkali consumption, we conclude that strong alkaline solution rinsing is in fact inferior to simple water rinsing.

Jan 1, 1998

By Tom Palangio, Ralph M. Olmstead

Video inspection of boreholes with cameras developed specifically for the mining industry is now possible. These designs are reliable, cost effective, and have the flexibility to be used in other applications.

Jan 1, 1998

By Noris Del Be1 Belluz

Drilling underground in the Grasberg dewatering drifts has routinely hit water aquifers with high flow rates and pressures. Two types of holes are used. Pilot holes probe ahead of the tunnel development to intersect aquifers ahead of the face. And dewatering holes dewater rock formations that will drain water from the Grasberg pit and allow tunnel development to proceed safely. Recently, static pressures of >8.3 MPa (> 1,200 psi) have been recorded with flows from a 100 mm (4 in.) HQ core hole measured at 5,700 L/min (1,500 gpm). The waterflows can be slightly acidic, necessitating the use of stainless-steel collar gear to resist corrosion. These rates were anticipated and contingencies were planned early on to deal with these conditions. PT Freeport Indonesia (PTFI) established procedures to maintain the safety of the drill crews, to enable coring of the rock, and to maintain the safety of the miners driving the drifts. The collar gear controls the waterflows because these drill holes are a vital source of water for the concentrator.

Jan 1, 1998

By Garland Likins

The Texas Department of Transportation, now considering using Augered Cast-In-Place (ACIP) Piles (also known as Continuous-Flight-Auger or CFA Piles) in their foundations, awarded a research project to Professor Mike O'Neill at the University of Houston (UH) to study the advantages and potential difficulties with ACIP/CFA piles. ACIP/CFA piles were installed on three sites for UH; they had extra instrumentation and additional measurements by UH staff during installation which are beyond the scope of this paper. Independent visual logging of the pile was done by an experienced inspection firm. The main advantages of ACIP/CFA piles are their speed of installation and their economy. Potential savings are substantial. Disadvantages include an unknown structural condition of the shaft. Inspection is critical, but many simultaneous observations make accurate inspection difficult. Because of resulting uncertainty, many engineers have avoided ACIP/CFA piles in the past.

Jan 1, 1998

By G. F. Vander Voort

Over the past twenty years, steelmakers have introduced improved practices for reducing the inclusion content of steels. The success of these practice changes can be monitored in a variety of ways. Chemical analysis of the bulk sulphur and oxygen contents provides a relatively simple means to assess the impact of these changes. However, microscopical test methods are still needed to assess the nature of the inclusions present. Traditional chartbased measurement methods have wide acceptability, and their data are well understood by both purchaser and producer for heat acceptance purposes. However, these methods do have inherent weaknesses which limit their usefulness for quality control, SPC, and database applications. Image analysis-based chart measurements are an improvement over manually generated chart ratings, but the data still do not lend themselves to databases and statistical comparisons. ASTM Committee E-4 on Metallography has developed a stereologicallybased image analysis standard test method, E 1245, which provides the necessary data in a form which is easily databased and analyzed statistically. This paper describes E 1245 and shows how data from different heats and melting practices can be compared statistically to ascertain valid test differences.

Jan 1, 1998

The Inquiry into the 1994 accident at Moura No. 2 Colliery included in it's findings that mine escape and rescue options for persons in underground coal mines were in need of review. The Inquiry recommended the establishment of industry working groups to report to the Queensland Chief Inspector of Coal Mines on matters including escape strategy and life support for escape from mines.One of these task groups examined issues relevant to self-escape from Australian underground coal mines and formulated recommendations and guidelines in response to the terms of reference and scope.

Jan 1, 1998

By C. Bemelmans, L. Chia, T. O’Keefe

Lead alloys function effectively as oxygen-evolving anodes in copper SX-EW operations, and they are highly resistant to corrosion. However, the presence of an organic (from solvent extraction circuits) in the electrolyte seems to enhance solution line attack. Laboratory tests showed that lead is soluble in D2EHPA, Acorga and LIX 984 to a limited, yet measurable, degree. Lead alloys and various lead phases formed on the anode were tested to evaluate their effect on the corrosion process in organic media. Possible causes for anode corrosion and mechanisms responsible for their initiation are discussed.

Jan 1, 1998

By Peter M. Herzig

In 1994 and 1998 the German research vessel R/V Sonne undertook detailed mapping and sampling of the largely uncharted offshore areas of the Tabar-Lihir-Tanga-Feni island chain in the New Ireland Basin of Papua New Guinea. The New Ireland Basin occupies a fore-arc position with respect to the formerly active Manus-Kilinailau arc-trench system and hosts a series of Pliocene to Recent alkaline volcanoes which are built on rifted Miocene sedimentary basement. Several of the volcanoes possess high-level porphyry stocks and active geothermal systems, including gold-depositing hot springs and the giant (40 million ounces) Ladolam gold deposit on the island of Lihir. On the southern flank of Lihir island, a group of three volcanic cones were discovered at water depths from 1.000-1.500 m. The volcanoes are located in a narrow zone of recent seismic activity and elevated heat flow (up to 100 mW/m2). The recovered volcanic rocks consist of fresh alkali-olivine basalts, clinopyroxene-rich basalts (ankaramites), porphyritic phlogopite basalts, and trachybasalts. Unusual gold-rich hydrothermal precipitates were recovered from the summit of the 600 m high Conical Seamount located only about 10 km south of Lihir Island. 1200 kg of sampled material systematically collected with a TV-guided grab from the top plateau (150 x 200 m, 1.050 m water depth) are intensely mineralized with pyrite, marcasite, minor sphalerite, chalcopyrite, galena, tennantite/tetrahedrite, and orpiment/realgar together with traces of anglesite, cerrusite, and amorphous silica in stockwork-like veins. Bulk samples of the vein mineralization consist mainly of clays, silica, and disseminated sulfides, and have an unusual high gold content ranging from 1.2-44.0 ppm Au. In some of these samples, grains of native gold (about 1 micron in diameter) were identified by SEM in pyrite and sphalerite. The gold-rich material also contains high concentrations of silver (up to 1000 ppm) and typical epithermal elements such as As (2.6 wt.%), Sb (0.2 wt.%), and Hg (34 ppm). Similar to epithermal deposits on land, which usually have only low base metal contents, the samples from Conical Seamount contain only minor amounts of Zn (max. 4.5 wt.%), Cu (2.0 wt.%), and Pb (2.0 wt.%). Many of the samples recovered from Conical Seamount are virtually identical to the gold ore at Lihir.

Jan 1, 1998

Longwall mining has historically been considered an application for only deep reserves. This has changed in the recent past as longwall has become competitive with surface mining. Many resources marked for stripping now he in the domain of longwall. Today, the best longwall mines compete with strip mines operating in even the lowest stripping ratios. Longwall mining has become more widely applicable than it ever has been in the past and it is now generally considered the method of choice in situations where high levels of coal production are required. But the best way to use longwall mining has become less certain with the opportunities that highwall access provides. Wall-to-wall mining is the use of retreating longwall developed from and retreating toward a highwall. As a surface mine reaches its ultimate highwall, the opportunity for longwall punch mining or wall-to-wall mining is obvious. There are several clear operating advantages to operating a longwall in this way and where highwalls are available, the best economic decision will generally favor planning a direct approach. Yet wall-to-wall is not applicable in every situation even when highwalls are available. Moreover, the advantages of wall-to-wall mining do not always justify the cost of trenching or box cuts to access coal . However, many tactical advantages of operating from the highwall can be realized with the use of specially equipped blind drilled or raised bored shafts. This paper discusses novel techniques for a shaft assisted mining system which permits the addition of conveyor structure and mine systems from the surface to the face for advance and retreat mining with longwall, shortwall or room and pillar panels.

Jan 1, 1998

By D Chappell

Coromandel Peninsula gold mineralisation has an epithermal style which involves extensive alteration of host rocks and addition of pyrite over large volumes of rock. These altered rocks therefore have high potential for generating acid rock drainage. Natural acid groundwater discharges occur in altered rocks, but not in propylitically altered rock. There is little calcite available in mineralised rocks to neutralise this acid. In contrast, the mesothermal veins of the Otago Schist cause little alteration of the host rock, and that alteration has similar mineralogy to the host rock. Calcite is a common mineral in host and mineralised zones, and sulphides are generally subordinate. Hence acidification of Otago rocks is unlikely. This lack of acidification in Otago facilitates arsenic mobility in solution, up to hundreds of ppm. Arsenic is insoluble under acidic conditions in the Coromandel. Base metals are soluble under acidic conditions of the Coromandel, but they are immobilised by adsorption on to the widespread clay minerals where the solutions are neutralised. Base metals are generally immobile in Otago, but when they are mobilised, adsorption is less effectiveas an attenuation mechanism because clay minerals are rare.

Jan 1, 1998

By Donald J. McKee

The product sizing and tonnage from a grinding circuit are the end result of a series of linked size reduction stages which always involve: fragmentation in mining; degradation in transport of ore; crushing and finally grinding. A case study is presented which illustrates the substantial effect on autogenous mill throughput of different mining practice. It is shown that it is possible to model each of the size reduction steps of fragmentation, degradation, crushing and grinding. The way in which this predictive capability is used is dependent on the operating constraints of each mine-mill combination.

Jan 1, 1998

By Boyd GL

Backfill applied to highwall mining is foreseen as a means to increase recovery of mineable coal to levels comparable with underground longwall mining. This paper describes the progress of research to demonstrate the role required of backfill to achieve real increases in coal rCCOvCrCd h\ hi'eh ss-all mining methods.

Jan 1, 1998

By Qi Jingyue, Wang Zhongquian, Yang Nianhua

Qinling Tunnel is the longest tunnel in China. The rock stratum is very hard rock - intact mixed gneiss. At the beginning of the construction, drift-pilot excavation is very costly due to the use of regular drill and blasting methods. After tests on the acoustic impedance match between rock and explosive, watergel explosive, which has a high velocity of detonation and high brisance, has been used for hard rock blasting. In addition, different cut plans have been compared. It was found that four-large-hole cut is the most effective. And the number of drillholes and specific charge cut down and the average advance reaches more than 94% of the blastholes depth. Thus, the difficult problem of hard rock blasting in drift pilot is successfully solved, while safe and quick construction is guaranteed.

Jan 1, 1998