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By Ian G. H. du Preez

It is illustrated how differences in the basic chemistry of individual metal ions can be exploited to develop new or improved separating agents. Factors like coordination number preferred by the specific metal ion, the degree of coordinate saturation reached by the metal ion and its relation to the phase transferability of the complex species, kinetic factors as opposed to thermodynamic factors controlling the success of the separation, the nature and type of the donor atom employed in a separating agent in relation to the preferences of the metal ion, the significance of stereochemical factors and the hydrophobicity of the media are some of the important factors which are discussed and applied for the development of pa1ladiwn(TI) and nickel(TI) specific separating agents, respectively.

Jan 1, 1999

This paper discusses the potential role of underground space and tunnelling in urban planning in Australia. The paper gives examples of the infrastructure and commercial applications of underground space which have been effectively used overseas but have been slow to be considered as a part of urban planning in Australia. In particular, the paper looks at underground quarrying and underground commercial development and their potential use in the urban environment. Existing sites and potential sites for quarrying and/or commercial use have been classified using a system developed by the author. Underground quarrying may provide some solutions for planning problems involving sand and aggregate supplies, waste disposal and other uses. Commercial development involving underground excavation may be accepted if the cost of underground commercial development can be shown to be equivalent to the cost of above ground development. The paper concludes that one role of the underground construction industry is to promote tunnelling and underground space amongst architects, town planners and planning decision-makers. The Australian Underground Construction and Tunnelling Association (AUCTA) and the Australian Society for Trenchless Technology (ASTT) should be instrumental in actively promoting the use of underground space in society.

Jan 1, 1999

By Toshihiko Emi

The quest for cleaner steel is driven by increasingly stringent requirements from the manufacturing and construction industries. Key issues are the occurrence and removal of inclusions; These are discussed in the context of the unit processes of deoxidation, refining, transfer and casting of molten steel. Process thermodynamics and kinetics are also discussed. Recent progresses achieved and problems yet to be solved are elaborated, and an integration of the unit processes into a system to produce extra clean, steels with better performance is presented.

Jan 1, 1999

By May Nyman

Due to the vast diversity of chemical media in which metal separations are executed, a wide range of ion separation materials are employed, This ,results in an ongoing effort to discover new phases with novel ion exchange properties. We present here the synthesis of a novel class at, thermally and chemically stable microporous, niobate-based materials. Ion exchange studies show these new phases are highly selective for Sr2+ and other bivalent metals.

Jan 1, 1999

By C. Yao, T. M. Yegulalp

The scale effect on rock properties has been discussed and studied since the introduction of the weakest-link idea by Weibull (1939). In this study, the capabilities of a dynamic lattice network model to simulate failure of rock under uniaxial tension is utilized. A number of randomly distributed microcracks that contribute to the development of uneven stressfields are introduced. In addition, each unit element in the model is assigned a random value representing its strength properties. Each application creates a randomly created specimen that is subjected to uniaxial tension. The specimens are grouped into three sets according to their size. The results of the study show that the scale effect is present in a statistical sense, i.e., the observed statistical distributions of strength for each specimen group is distinctly separate, and they follow the expected inverse relationship between strength and size. The observed probability distribution for each group of specimens give rise to the estimation of a different set of parameters. In this paper, the potential relationships among these parameters as a function of specimen size is investigated.

Jan 1, 1999

By M. V. T. Da Silva, J. C. Harrison

Eldorado Gold Corporation of Vancouver, B.C. owns and operates three gold mines. The São Bento underground gold mine in Minas Gerais State, Brazil produced 105,907 ounces in1997. The La Colorada and La Trinidad open pit, heap leach mines in Mexico produced over 83,000ounces in 1997. With a deteriorating gold market plaguing the industry throughout 1997 Eldorado had to take critical measures at each mine to enhance gold production while lowering cash operating costs. Each mine had its own unique problems to confront. This case study will discuss three distinct courses of action taken at the three mine sites.

Jan 1, 1999

A hidden asset in most exploration and mining activities is data. Common practice involves the spending of large amounts of money to discover, define and prove the viability of a mining project. Some organisations have used operations research analysis and internal costing methods to allocate a value to their data and to compare the costs of data maintenance to other more tangible activities like plant and equipment maintenance. Those organisations, which do not undertake such an analysis often, have little knowledge or understanding of the extent and the worth of their data. Often the organisations lack of knowledge and understanding of the data is indicated by their failure to fully exploit or realise their opportunities. The focus of this paper is to discuss new technologies that optimise the management and security of collected and derived data. The technologies discussed are components of the software systems acQuire and MineSight.

Jan 1, 1999

By S. K. Kawatra, A. K. Bakshi, T. C. Eisele

An on-line rheometer, suitable for use with slurries, has been developed at Michigan Technological University. This rheometer can be used with both Newtonian and non-Newtonian slurries, and produces complete shear-rate/shear stress curves which characterize the time-independent rheology of the slurry. The sensor utilizes the Hagen-Poiseuille equation and Boyle's Law to calculate the shear rate, slurry flowrate, and shear stress from a series of pressure measurements. The design of the unit allows the measurement sample to be continuously collected from operating process streams in the often-hostile on-line environment. The shear rate/shear stress curves can be used to conveniently calculate the apparent viscosity at any given shear rate, and also to measure any yield stress or other deviations from Newtonian behavior.

Jan 1, 1999

A key premise to this paper is that most people involved in the design and implementation of drilling and blasting operations could benefit from a greater understanding of the geological materials, deposits and landforms they are dealing with. The second key ingredient for successful blasting is the concept of blasting objective. Mine operators and blasting contractors must be clear on what drives their costs (blasting leverage) and should formulate blasting objectives and operational targets which help in this regard. Many operators ignore geology descriptors and features apart from the name of the rock and start crudely quantifying the rock mass properties in terms of uniaxial compressive strength, or even worse still as hard or soft. This occurs too early in the design process and not much attention is paid to the geological materials, geological structures and the characteristics of the deposit they intend to excavate. In effect the rock type name and the strength descriptor become the site geology. Furthermore many blasting operators do not formalise their blasting objective, do not set operational targets and do not measure results to the degree required for continuous improvement. In this paper a number of civil, surface mine and underground mine blasting applications are tabulated in terms of typical blasting objectives and common geological materials. A good description of geological materials can convey a lot of useful information for blasting operators if they are able to accommodate this knowledge. In addition a clear statement of the blasting objective and associated operational targets will maximise the likelihood of achieving blast-driven downstream productivity improvements. The æStarting at Both EndsÆ combination is deemed extremely useful for any continuous improvement blasting program.

Jan 1, 1999

By T. A. E. Breen

A new high intensity grinding technology has been developed and is now being commercialized by Hicom International of Australia. This has led to the development and manufacture of Hicom 120 grinding mills which are now being sold internationally for a range of mining industry applications. The first commercial process application has been for the diamond sector, where the ability of the mill to remove host kimberlite rock by attritioning, with no damage to the thereby liberated diamonds, is seen to be a most beneficial attribute. There are, however, many other mineral industry applications for this mill. The design of the Hicom mill is unique. Based on a high speed centrifugal motion of the grinding chamber, very high power intensity is delivered to the grinding process. Most significantly, a high acceleration field, 50 times stronger than gravity is produced, creating very high power input per unit of mill volume, and exceptionally fast particle breakage rates, typically 50 - 100 times greater than those in conventional tumbling mills. A mill developing such forces has significant implications to comminution technology and practice.

Jan 1, 1999

By D Caffrey

To demonstrate the advantages of using electronic delay detonators over pyrotechnic detonators, a trial using the DNES Dynatronic System was conducted at the KCGM Mount Charlotte operation in 1998. The trial clearly demonstrated that accurate control over the firing delay time between blastholes can lead to fragmentation improvement and ground vibration energy control which are two important issues for the Mt Charlotte underground operation. Excellent fragmentation was achieved by employing a 12 ms delay sequence. Detailed fragmentation analysis has shown a 10 to 20 per cent passing increase for the rock fragment size from 0.1 to 0.4 m compared with the pyrotechnic detonator firing. There was no increase in ground vibration level on the surface with the electronic detonator firing even though the electronic detonator firing had a much shorter blast duration than the pyrotechnic detonator firing. In fact, our energy calculation has clearly shown that much less energy had been propagated to the surface from the blast using electronic detonator firing.

Jan 1, 1999

By Sharon K. Young

What might an ideal leach-to-cathode/product system look like in the next century? The paper looks at the synergies of the 60's and 70's that led to the highly effective copper leach SX-EW system of the 90's. Standing in the year 2020 focuses on what breakthrough technologies might make possible a next generation leach/extraction/metal recovery system. Many of the pieces of such a technology have been developed, even piloted: in situ leaching, enhanced bioleaching, heap leaching of fine particles, resin in pulp, ion exchange, alternate anode reaction electrowinning, novel anode coatings. With nearly non-existent research on the part of individual large companies, the greatest challenge may not be inventing the technologies but rather inventing an industry "will to create."

Jan 1, 1999

By D. Einarson, B. Strickland

The decision to accelerate development of Stillwater Mining’s East Boulder Mine was made in March of 1998. It required the completion of conceptual designs by July of 1998. This was accomplished through teamwork and close cooperation of mine personnel, engineering firms and vendors, all working toward the common goal of developing an efficient and workable design. Early in the project, representatives of Stillwater Mining, Kilborn International, Parsons Brinckerhoff Transit and RailSystems, Continental Conveyor, and H.A. Simons met to develop methods to bring the mine into production at a highly accelerated rate and to solve potential bottlenecks, including the movement of personnel, materials, and muck through a 5.6 km(3-1/2 mile) adit. This interaction, including companies not normally associated with the mining industry, led to innovative approaches and designs produced by Kilborn Engineering and Stillwater Mining.

Jan 1, 1999

By P Cepuritis, G Chitombo a, I Brunton

There is a significant amount of past evidence that links blasting and occurrences of slope failure. Particularly of great concern at Telfer Gold Mine is the effect of open pit blasting on the stability of the footwall slope above the underground portal and the stability of underground structures. For this reason, Newcrest Mining Ltd invited JKMRC to conduct necessary field measurements and numerical modelling with the following objectives:assess the dynamic stability of the footwall slope above the portal; assess the characteristics of current and future blasts in the open pit; and prepare open pit blasting guidelines that will minimise the detrimental effect of blasting on slope stability. To achieve these tasks it was necessary to develop a scaled distance attenuation curve for blast vibrations. In order to validate the developed vibration attenuation curves it was necessary to monitor vibrations from a production blast. Using JKMRC blast design software tools, the vibration of the production blast was also modelled from the blast design and vibration results from single hole blasts. The intention was, assuming that the observed and modelled vibrations were close in terms of frequency and amplitude, to use the software tools to model the vibrations of future blasts and assess their likely effect on slope stability. Numerical modelling of the dynamic stability of the footwall slope was done using the FLAC finite difference code and the UDEC distinct element code. The results of the numerical modelling and of the field measurements of the blast induced ground vibrations were combined into the blast design rules that relate distance between the slope and the blast, charge weight per delay and number of blasts necessary to cause failure of the slope.

Jan 1, 1999

By I. H. Bonekamp

Norddeutsche Affinerie has operated an Outokurnpu type flash smelter for more than 25 years. In recent years, the concentrate smelting capacity was increased to 750,000 tpy, double of the initial design capacity. Maintaining this high performance level requires very good metallurgical process control. It is not enough to base this control on thermodynamics and kinetics since the furnace is highly dynamic. Understanding these dynamics and being able to quantify them can have significant financial benefits. A mass and energy balance model was developed and is discussed based on measured data. At this time the model is based on the major elements copper, iron, sulfur and silica. With it is possible to quantify the differences of the various material streams such as matte, slag, flue dust, matte carry-over to settling furnace, etc. Comparing the reconciled energy balance model with the fundamental thermodynamic model makes it possible to quantify the dynamics. These dynamics are related to input parameters using methods such as statistics and neural nets. In the future this database will be used to improve the understanding of the dynamic process as well as the dynamic process control.

Jan 1, 1999

By James A. McGrath

"The predominant key word associated with all commercial blasting methods is “safety”. Safetyshould take precedent over all other aspects of the entire explosives industry which on a wholehas had an excellent track record as to number of injuries per unit of hours worked at all blastsites throughout our country."

Jan 1, 1999

By Daniel J. Dobbels, Eric R. Drooff, James R. Wheeler

Construction of Boston’s C11A1 Section of the Central Artery (I-93)/Tunnel(I-90) Project beneath the existing MBTA Red Line Subway at South Station required excavation to depths in excess of 33.5 m (110 ft) through permeable sand and gravel subject to almost 27.4 m (90 ft) of hydrostatic groundwater pressure. As tacked drift tunnel underpinning system was designed to provide positive support to the active station prior to mainline tunnel construction. As part of this system, a permeation grouting program was developed to facilitate tunnel excavation. This paper describes the design and implementation of the grouting program, in sit testing, and the overall performance of the grouted soil mass.

Jan 1, 1999

By S. Shrivastava, R. G. Reddy

Spent potliner is generated in the electrolytic process of reducing alumina to make aluminum metal using molten fluoride electrolytes. Spent potliner (SPL), obtained at the end of the pots life contains a small amount of cyanide and fluoride which present environmental problems. SPL became a listed hazardous waste under RCRA (KO88) in July, 1990. One of the possible uses of spent potliner is as a substitute for Calcium Fluoride (CaF2) as a fluidizer in iron- and steelmaking and in the glass industry. A low viscosity and a low melting point are prime requirements for accomplishing the above. In the present study, viscosity measurements were performed. Effect of various additives, such as sand, limestone, dicalcium silicate dust, and MgO baghouse dust on the viscosity of SPL was studied. The results showed that with the addition of sand and limestone, very high fluidity of SPL melt can be obtained at significantly low temperatures. The results suggest that spent potliner mixed with additives could potentially be used as a substitute fluidizer.

Jan 1, 1999

By J. E. Dutrizac, R. J. C. MacDonald, J. B. O'Reilly

"Sometime around 3000 B.C., primitive metallurgists working in the mountainous regions of Asia Minor bordering on the Black Sea (Pontus) produced a soft, easily fused metal today known as lead. It appears certain that the first metal was made by reductive smelting of galena, but whether this recovery arose by the accidental inclusion of galena in the stones of a fire hearth or whether it occurred as a consequence of simple pyrometallurgical experiments on a series of interesting ""stones"" will likely never be known with certainty. The properties of galena, high metallic lustre, great density and facile cleavage, must have excited the ancients, and such ""stones"" would have been the object of primitive testing111 - Shortly after the discovery of lead, the ancients found that the controlled oxidation of this metal at elevated temperatures yielded smaller amounts of a more interesting material, silver. Again, it is uncertain if the production of silver by primitive cupellation techniques was the result of a fireside accident or the consequence of a deliberate experiment, but the important fact is that silver was produced shortly after the discovery of lead. The techniques for making lead and silver spread gradually throughout the entire civilized world, likely as a result of both technology diffusion and independent rediscovery. The physical properties of lead could not have been overly attractive to the ancients, but silver was a different matter altogether. The gleaming white lustre and relative immunity to oxidation quickly assigned silver to the precious materials category, a status it still enjoys. In early times, argentiferous galena was inevitably processed only for its silver values; lead was generally an unwanted byproduct and was frequently discarded as litharge (PbO) during the cupellation process. The silver was eagerly sought, however, and resulted in considerable mining activity culminating in the famous Athenian silver mines at Laurium at the southern end of the Athenian peninsula."

Jan 1, 1999

By D. Kang, K. N. Han

The adsorption behavior of silver in ammoniacal solutions on activated carbon was studied. In addition to the concentration of ammonia, the parameters that affect adsorption include temperature, degree of agitation and anion and cation concentrations. In the study, it was found that the adsorption of silver from ammoniacal solutions is dependent on the initial silver concentration in the solution. It was also found that the recovery of silver from ammoniacal solutions is not as effective us gold. The adsorption rate was relatively slow overall, despite a rapid initial adsorption. The apparent activation energy ,for the adsorption was measured at 30.2 kJ/mol. It was believed that the kinetics of the silver adsorption on activated carbon was limited by a mixed control mechanism.

Jan 1, 1999