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By David Rees

Tomago Aluminium, a 400,OO tonnes per annum primary aluminium smelter in Australia, has installed Ozone for biological control of its process water. The system was designed in Australia by Ionics Watertec Engineering, whilst ANCO Australia monitors the water quality and provides technical support for the project. The motivation was initially to reduce operating costs, however investigations indicated that there were substantial environmental benefits to be achieved by the elimination of a part, or all of, the chemicals being used to control the system. Also the existing chemicals appeared to be losing their ability to control biological growth in the system, in particular, the legionella bacteria. Ozone water treatment commenced in January 1998 and after a short transition period has operated without chemical addition since. There appears to be no doubt that the biological control is effective, the clarity and purity of the water has improved and initial testing indicates that the corrosion control rate is acceptable, although some chemical corrosion control may be introduced after further testing around the total circuit to guarantee protection

Jan 1, 1999

By M. K. Pathak, A. K. Mukhopadhyay, D. C. Panigrahi

Changes in machinery operating and design parameters often result in unexpected vibrations or changes in the vibration patterns. Vibration in a system is an undesirable element that can cause machinery distress. Potential damage can be prevented by identifying the vibration level that is due to the changed operational parameters. This is necessary for the safe and reliable operation of plant equipment. This paper presents a documented study on vibration events that resulted from alterations in operating and design parameters in a mine ventilation fan and analyzes the causes by defining the sequence of events that led to its performance deficiency. This paper is based on experimental effort to study the vibration behavior of a ventilation fan under varying operating conditions.

Jan 1, 1999

By J. L. Cupp, R. C. Ford, B. R. Romig

The Climax Molybdenum Mine, located near Leadville, Colorado, is the site of a lengthy mining history spanning more than 80 years. In the 1960’s, extraction of molybdenum from oxide ore located adjacent to the massive molybdenite sulfide deposit resulted in the construction of an earthen core dam to impound fine-grained oxide tailing in the Eagle River Valley. Through recognized value of water storage and reclamation opportunities, a tailing removal project was initiated in 1993 to convert the impoundment facilities to a post-mining beneficial land use of developed water resources. An evaluation of the effect residual materials and lake dynamics would have on in-stream water quality was performed. Eagle Park Reservoir stands as a model for future reclamation efforts that involve water delivery to highly sensitive receiving waters. This paper provides a case study on project development, the evolution of water quality assessment, and the regulatory framework that contributed to this project’s success.

Jan 1, 1999

By Ricardo Badilla-Ohlbaum

Copper has been used by man for a very long time and unlike certain other metals, it is an essential element for life. Its toxicity arises both from a deficit and excess copper exposure/intake. The focus of the current discussions in countries of the European Union (EU) and in some USA States, is based on the concerns, independent of the scientific facts and the economic status of these claims, of the negative influence of copper and other metals on health and the environment. These discussions have influenced the new regulations of copper in drinking water, and the approach to regulate the appropriate levels of copper in surface water, soils and sediments. To illustrate the challenges ahead for copper, the evidence by which the current US Environmental Protection Agency (USEPA), the World Health Organization (WHO) and EU recommendation and regulations regarding copper in drinking water have been derived is presented and discussed. The gaps between the demands for new standards of health and the environment and the practical scientific tools to achieve these goals are presented, and the need to develop new regulating paradigms is also illustrated. The introduction of methodologies for the regulation of essential elements and acute inorganic substances in drinking water is discussed, as well as the status of the present approach contained in the International Program of Chemical Safety Environmental Health Criteria, (EHC) N° 170. The impact of the possible restrictions on the use of copper in the EU because of health and environmental concerns in terms of the world market for copper is discussed.

Jan 1, 1999

By Yin Zhang, Xiaoyu Huang, Mi Wang, Bencheng Du, Youduo He

"Burners are important facilities for blast furnace stoves to raise hot-blast temperature up to 1200°C. Common types of two-ring ceramic burners have very long flames so that part of combustion occurs in the upper part of the chequers and will cause damage to the refractory materials. Using computer simulation to analyze the turbulent diffusion flame in the combustion chamber, some good results were obtained. A new type of ceramic burner will be installed by Anshan Steel Complex in stoves of blast furnace number 4. A pilot experiment was done on the new burner. The experimental data have shown that the mixing condition was improved and the length of flame was shorter with the new type of ceramic burner.IntroductionPulverized-coal injection can give significant operating saving, reducing coke rate in blast furnace(BF) operation. However, during high rates of coal injection, extra heat must be compensated in hearth to maintain certain raceway adiabatic flame temperature. One of the effective methods for heat compensation is to raise hot-blast (HB) temperature up to 1200°C. Nowadays, since the fuel being combusted in stoves is BF gas only, in which the calorific value is down to round 3000 kJ/m3 , to increase the combustion ability and to provide a suitable length of flame in combustion chambers of stoves becomes more important. In other words, designing a good ceramic burner which will affect to HB temperature and stove lifetime is drawing more attention."

Jan 1, 1999

By N. Can

Kinetics and mechanism of the chemical interactions between Si3N4 and TiC were investigated by isothermally reacting samples under nitrogen and argon atmospheres at temperatures between 1600°C and 1700°C? The initial composition of the powder compact contained 20, 30 and 40 volume per cent TiC? Kinetic analysis were performed by measuring mass losses and composition of the titanium carbonitride (TiC1-xNx) at predetermined time intervals? It was found that in the Si3N4-TiC system the degree and rate of the reactions increased with increasing temperature and content of TiC in both nitrogen and argon atmospheres? Si3N4 in the presence of TiC was stable in nitrogen atmosphere and the reactions were confined to Si3N4/TiC and TiC/N2 interfaces? At both interfaces interchange reaction occurs by simultaneous diffusion of nitrogen towards the centre of the particle and desoprtion of carbon in the opposite direction resulting in formation of titanium carbonitrides with various compositions? Reaction products under nitrogen atmosphere were B-SiC, TiCl1-xNx and N2? The maximum "x" value in TiC1-xNx was found to be 0?67 under nitrogen atmosphere? Si3N4 was found to be unstable in argon atmosphere in the presence of TiC and dissociated into liquid silicon and nitrogen gas within approximately four hours of reaction time, depending on temperature? The reaction mechanism in the initial stages of the interaction between Si3N4 and TiC under argon atmosphere proceeds similar to reactions under nitrogen atmosphere? However, considerable amount of Si3N4 dissociates within the first half hour? Liquid silicon aggressively attack both TiC1-xNx and unreacted or partially reacted TiC particles through cracks and pores and diffuses into interier part of the particle forming liquid solutions? After this stage, reactions under argon atmosphere proceeded according to Si-Ti-C ternary system?

Jan 1, 1999

By Vaughan R. Voller

"Solidification systems from conduction controlled freezing of a pure material through to alloy phase change that include flow and segregation processes are described. The components in a general solidification model-variables, governing transport equations, and local scale relationship-are outlined. A central focus is the presentation of an explicit procedure for coupling between macroscopic and local scale variables.IntroductionSince the seminal work of Byres et al.[!] in the 1940's there has been a steady progress in modeling solidification systems with increasing levels of complexity. The object of this paper is to track the evolution of these solidification models and present a general modeling approach that applicable to a wide range of the solidification systems of current interest.Solidification SystemsIn a broad sense the underlying physics in a solidification process occur at two distinct length scales:1. The macroscopic scale of the process over which the governing transport equations of heat, mass and momentum hold.2. The local scale at the solid-liquid interface where the solidification phenomena are operative."

Jan 1, 1999

By S. Duyvesteyn, L. Enloe, P. A. Schmitz, W. P. Johnson

The characteristics of gold leaching from carbonaceous matter by sodium cyanide, and sorption of gold cyanide to carbonaceous matter in autoclaved and non-autoclaved gold ore from Barrick Goldstrike Mines Inc. (BGMI), Nevada, was investigated. Much greater gold cyanide complex sorption was observed for the carbonaceous matter in high preg-robbing ores relative to the low preg-robbing ores. This observation corroborates previous reports that have attributed observed preg-robbing behavior to the carbon in the ore. Gold cyanide complex sorption was found to be reversible for carbonaceous matter from low preg-robbing ore, but was irreversible for carbonaceous matter from high preg-robbing ores. Autoclaving the ore appeared to enhance the sorptive behavior of the carbonaceous matter from both high and low preg-robbing ores.

Jan 1, 1999

By W Shamu

The mechanical properties of rock samples of identical lithologicalcomposition may vary significantly due to existence of materialdiscontinuities. Laboratory tests were carried out to determine the effect of material discontinuities on rock sample mechanical properties. The investigations consisted of detecting discontinuities, observing the failure mechanisms during uniaxial compressive strength tests, and analysing of the factors affecting the strength. A non-destructive testing method has been adopted to assist in thedetection of discontinuities. Laboratory testing proved that fractures leading to failures initiated on the detected discontinuities. The location, orientation, size, density and extent of the discontinuities contribute to different modes of failure and these affect the mechanical parameters of rock samples. Four modes of failure were distinguished for hard and brittlecylindrical rock samples. These modes were referred to as simple shear failure, multiple shear failure, multiple fracturing and vertical splitting. To evaluate the effect of discontinuities on mechanical parameters, the ratio of uniaxial compressive to tensile (Brazilian) strength was calculated and analysed for the different modes of failure. It was found that the value of the ratio depended on the mode of sample failure. The lowest value of the ratio was observed for shear mode of failure and the highest for vertical splitting mode of failure.

Jan 1, 1999

Chile, which hosts around 30 per cent of the worldÆs copper resources, is now the largest producer and exporter of copper. Chilean copper output accounts for more than one-quarter of total worldwide production. An increase to around 40 per cent is forecast by the end of the century. In addition, Chile ranks eighth in silver production and 11th in gold output. In Chile, mining generates more than eight per cent of the countryÆs GDP and the total value of mineral exports is more than US $7.85 billion corresponding to more than 25 per cent of South AmericaÆs mineral production. The rate of growth of Chilean mineral production is indeed impressive. Table 1 shows that in the period 1969 - 1998, copper annual production increased 564 per cent from 667 000 t to 3 764 000 t. Gold production went up 27 times from 1827 to 49 770 kg. Silver output grew 1219 per cent from 95 650 kg produced in 1969 to 1 166 380 kg in 1998. Several facts explain this dramatic increase of production, but the most important was the success of exploration sustained over the same period. This resulted in the discovery of several world-class deposits which when developed into mines, account for much of the production increases. Therefore, this summary review shows the success of basic exploration carried out during the last 30 years in the Chilean territory. The review is based on data already published in different specialised mining books or magazines. It only includes those world-class discoveries not the lesser discoveries important at local scale. All figures were calculated using 1998 $US dollar and average estimated metal prices valid for 1999: copper $US 1653 per t ($US 0.75 per pound), gold $US 9452 per kg ($US 294 per ounce) and silver $US 177 per kg ($US 5.5 per ounce).

Jan 1, 1999

Several years and millions of dollars later, the mining and extractive industries have now started to receive and implement industry based standards aimed at achieving better performance and output from the employee. IFAP in conjunction with the mining and quarrying industry has developed a range of training courses aimed at achieving the benefits that can be gleaned from application of these standards. The establishment of a career path and appropriate training packages for personnel involved in the handling and use of explosives provides industry with a training system that previously did not exist. The opportunity to receive quality training based on industry standards and aimed at achieving industry goals will now enable the industry to optimise itÆs explosives applications.

Jan 1, 1999

By S. Neven

The smelting of copper anode slimes, a material which contains mostly lead, silver, copper and selenium, has been practiced for many years with a view to recovering the silver and associated small amounts of gold. However, a theoretical understanding of the process has been lacking and this handicaps efforts to improve and intensify smelting operations. In the past few years work has been done in this area and this work will be reviewed in the paper. The underlying thermodynamics of the oxidation of silver-copper selenide mattes has been developed and used as a basis for the construction of a computational thermodynamics model which attempts to predict the composition of all condensed phases during the course of smelting. The model will be outlined and its successes in matching experimental data, as well as its current deficiencies, will be considered. Supporting work on the thermodynamics of silver solubility in slags, on activity-composition relationships in the Ag-Se system and work in progress on the oxidation state of copper in the slags will be reviewed. These projects are designed to provide further detailed data which will improve the robustness of the thermodynamic model.

Jan 1, 1999

By P D. Katsabanis

Image analysis has been proposed to be an accurate and convenient means of measurement of blast fragmentation. The paper compares the results of image analysis to screening using laboratory scale rock piles. The muckpiles ranged from uniform distribution samples to well graded samples following the Rosin-Rammler distribution.Deviations between screened and imaged distributions were observed in most cases due to the loss of fines. Addition of fines in the system improved the result derived by image analysis considerably. It is suggested that techniques for the prediction of fines be evaluated for modifying the size distributions produced by image analysis.

Jan 1, 1999

By Sheldon Shepherd

Fifty years ago, belt scales were mechanical devices based on a complex weight balancing design. Today's systems use load cells to assess material weight, belt speed sensors and microprocessor-based integrators to continuously compute the rate of material transferred along a conveyor. Belt scales have become important assets to a plant. They help maximize the use of raw materials, control inventories and aid in the manufacture of a consistent product. Choosing and installing a belt scale system may seem complicated but it can be simplified by following a few guidelines.

Jan 1, 1999

By T. C. Eisele

Previous work by the authors has shown that the performance of a flotation column can be improved by the use of horizontal baffles. These baffles prevent axial mixing and also reduce "churning" of the froth by breaking up or preventing the formation of large air bubbles. In this paper, results from tracer experiments are presented that show the effects of horizontal baffles on the reproducibility and stability of the column operation. The baffles prevent random disturbances, such as unusually large air bubbles and turbulence, from rapidly propagating along the height of the column. Because these factors are responsible for much of the variations in column performance between tests, the result is that the horizontal baffles make the column performance more reproducible, with fewer short-term variations.

Jan 1, 1999

By P. J. Cook

Comminution is one of the fundamentals of mineral processing, requiring large expenditures to be made on capital equipment, installation, power and maintenance. The trend toward lower grades and higher operating costs, mean mining operations are becoming increasingly marginal. The challenge is to improve and more importantly, utilise crushing and milling technologies that provide for reduced capital and operating costs whilst providing increased unit efficiencies. The Svedala Barmac Autogenous Crushing Mill presents such an opportunity by providing many of the cost savings and production increases required by its ability to produce a finer mill feed size and realise reduced energy consumption. This paper briefly describes the operation of the Svedala Barmac Autogenous Crushing Mill and reviews its benefits towards improving the efficiency of crushing and milling operations.

Jan 1, 1999

By L. Z. Villanueva

An investigation and evaluation has been performed to determine the potential utilization of electron beam irradiation technology for sulfur oxides removal from reduced-S02-strength metallurgical gases from copper smelters. These off-gases, though too weak to be converted to usable, concentrated: sulfuric acid by conventional means, are characterized by SO2 content higher than 2,000 ppm and a complex chemical composition, including high oxygen content and its generation occurring in a cyclical, fluctuating pattern. This work was based on information supplied by principal smelter companies in Chile. A laboratory facility with flow rate of 20 Nm3/h and equipped with an electron accelerator of beam energy 8.00 keV, has been used for testing. Influence on SO2 removal efficiency of operational parameters such as gas temperature, water vapor content, ammonia feed ratio and irradiation dose was established. The main conclusion of this work, from experimental laboratory tests as well as engineering studies, is that the Electron Beam Process (EBDS) is a cost-effective, simple and appropriate chemical process means for emission abatement. EBDS can, on a site-specific basis, adequately augment SO2 removal to upgrade overall abatement as required and in an optimal manner.

Jan 1, 1999

By D. N. Collins

A sampling program was conducted in which both spoon and isokinetic sampling techniques were used to collect samples from the reaction shaft. The samples were then characterised by chemical, XRD and mineralogical analysis. Further information was acquired by measuring the oxygen potential and temperature at the bottom of the shaft using disposable probes. Comparison of the results of the two sampling methods showed that the spoon samples were devoid of material less than 25 m. Sulfur analyses on the samples provided information on the extent of reaction, plume shape and recirculation patterns. Disposable probe measurements showed the measurable particle temperatures ranged from 1150 to 1700 °C and that the material falling into the bath had a normalised oxygen potential similar to the slag. These latter measurements combined with the sulphur elimination and mineralogical analyses provided further information on the extent of reaction and enabled the reaction sequence to be ascertained.

Jan 1, 1999

Maximising margins in competitive markets demands superior productivity. Unfortunately, management systems developed early this century for other industries often drive counterproductive behaviours choking mining productivity. Many executives and managers waste valuable time and effort relying on simply training and communicating to improve managerial practices and attitudes. In covering practical human behaviour, the paper explains why this fails - and explains how to use systems to successfully drive improved managerial practices and attitudes. It highlights use of modern performance Measurement, Analysis and Reporting systems to drive behaviours and improve margins - without capital investment - and make executive and managerial work easier and more effective.

Jan 1, 1999

By M. Charles Gilbert

Basement rocks in southern Oklahoma are divided into two groups. One group is the Lower Cambrian Wichita Igneous Province, a diverse igneous suite that crops out in the western Arbuckle Mountains and in the Wichita Mountains. These largely bimodal igneous rocks were emplaced in an intracratonic-rift environment. The other group, the older, is a set of Precambrian rocks of the Eastern Arbuckle Province, yielding ages between 1,350 and 1,400 Ma, exposed in the core of the eastern Arbuckle Mountains. These are deeply eroded mesozonal granitic rocks and associated granitic gneisses cut by numerous dikes ranging in composition from diabase to rhyolite. The southern Oklahoma igneous rocks have long been utilized mostly as dimension and crushed stone. Most of the early quarries were in granite of various red hues for monuments and facing stones. Large crushed-stone quarries are now exploiting both granite and rhyolite, which is used chiefly as aggregate and railroad ballast. The exposed basement rocks in Oklahoma represent an underdeveloped and accessible resource.

Jan 1, 1999