Search Documents

By Naoki Hiroyoshi

It is generally accepted that ferric ions are effective for leaching chalcopyrite as an oxidant and ferrous ions contribute to the leaching only as a source of the oxidant ferric ions. However, this paper shows that ferrous ions are more useful for leaching chalcopyrite than oxidant ferric ions in sulfuric acid solutions in air at ambient temperatures. Leaching experiments and dissolved oxygen consumption measurements were carried out with a very pure chalcopyrite and 0.001 - 1 mol dm-3 sulfuric acid solutions containing 0 - 0.1 mol dm-3 ferric or ferrous ions at 303 K. Chalcopyrite oxidation with dissolved oxygen was promoted by ferrous ions but suppressed by ferric ions. As a result, the amount of extracted copper was larger with ferrous ions than with ferric ions. Effects of Thiobacillus ferrooxidans on the ferrous promoted chalcopyrite leaching were also investigated and discussed based on the experimental data.

Jan 1, 1999

By Joachim Ulrich

The spreading and splashing behaviour of single tin, lead, copper, aluminium and steel droplets impacting on a solid surface were experimentally examined. The droplet impact was observed using a high speed video imaging technique. The onset of splashing and the mass of the secondary droplets of impacting tin and lead droplets was quantified by the weight difference of the droplets before melting and the splat after the impact. The spread factor and the mass of the secondary droplets in dependence of the impact velocity is shown for different droplet materials, initial droplet diameters, target temperatures in ambient air and inert gas atmosphere. An empirical found correlation predicting the transition from spreading to splashing is presented by means of dimensionless numbers.

Jan 1, 1999

By A. J. Meir, Paul G. Schmidt

"We present a novel approach to the mathematical analysis and computational simulation of fully three-dimensional, nonlinear, viscous, incompressible MHD flow in complex configurations involving several liquid and solid conductors. Such configurations arise in numerous metallurgical processes. Employing the current density rather than the magnetic field as the primary electromagnetic variable, it is possible to avoid artificial or highly idealized boundary conditions for electric and magnetic fields and to account exactly for the electromagnetic interaction of the flow region with the surrounding space. In addition, the approach lends itself naturally to finite-element based discretization techniques. As an application, we simulate the stationary flow of an electrically conducting fluid around a solid spherical particle of arbitrary conductivity, in the presence of crossed uniform electric and magnetic fields, and compute the Lorentz, pressure, and viscous forces exerted on the particle. This problem arises in connection with the electromagnetic filtration (purification) of molten metals before the casting stage.IntroductionNumerous metallurgical processes are governed by MHD effects resulting from the macroscopic interaction of liquid metals with applied or induced currents, electric and magnetic fields. Frequently these effects are technologically exploited in order to drive or to control the flow of metallic melts. Typical examples include the electromagnetic stirring of molten metals before the casting stage [1]; electromagnetic turbulence control in induction furnaces [2]; electromagnetic damping of buoyancy-driven flow during solidification [3]; and the electromagnetic shaping of ingots in continuous casting [4]."

Jan 1, 1999

By B. A. Firth

Australia is the largest exporter of coking and thermal coal to the international market. This market has required that the coal being presented to the customer has a particular level and consistency of quality. In this context, the Australian industry has developed coal preparation practices that allow this criteria to be met while maximising the recovery of coal from the resource. This has required on- going developments in both coarse and fine coal cleaning technology over the past 30 years. Coal flotation has undergone a number of developments with regard to maximising recovery from the overall plant circuit. This includes innovative flotation circuits (split feed), methods of enhancing the use of reagents and control of pH. During the 1990s, there have been major changes in flotation as practised in Australian coal preparation plants. Columns have become the preferred technology for both greenfield developments and plant upgrades. This paper will outline the above developments with a number of plant examples and the reasoning that has driven the change. The ongoing research that is being carried out on new cells to optimise the overall fine coal circuit will also be discussed.

Jan 1, 1999

By Richard Scales, Giles Hellyer, Ian Travers, Dean French, Peter Bellairs

"The Mt Whaleback iron ore mine is located in the Hamersley Province situated about 1OOOkm to thenorth of Perth, the capital city of Western Australia. A small but significant portion of the waste in Mt Whaleback presents problems due to its ability to react with normal commercial bulk explosives resulting in premature detonations, two of which occurred at the mine in 1983 causing great consternation as well as disruption to the mining operation. The techniques and procedures developed to overcome this problem were based on the use of tough durable, acid and heat resistant liners to provide a physical barrier separating the explosive from the rock togetherwith the development of an accurate down the hole remote temperature logging technology. The liner technology was developed due to the inability to produce a reliable inhibited ANFO despite exhaustive mine based testwork."

Jan 1, 1999

By H. Dijkman

The PAQUES Bio Systems' core technology, marketed under the name THIOPAQ®, consists of various high-rate biological processes for metal-sulfur-water systems, complemented with common solid/liquid and gas separation steps. Sulfur species are converted to sulfide, which is a valuable component as it can be used for metals reduction and precipitation. Selective recovery of valuable metals can be employed, leading to revenue from metal values. In this paper, biotechnological systems for the treatment of metal sulfate solutions and dilute SO, gases are described. These installations can be designed to either produce predominantly aqueous (NaHS) or gaseous (H2S) sulfide. The emphasis here is on hydrogen sulfide gas. The main case history discussed is the demonstration plant that ran on hydrogen gas at Kennecott Utah Copper. Three years of operating experience clearly show that sulfate reduction with hydrogen gas is a viable option. Furthermore, the selective recovery of copper from leach water with the hydrogen sulfide produced was shown to be very effective.

Jan 1, 1999

By Viktor Tokle, C. W. Dawson

The Devico directional core drilling system and its capabilities are described, with reference to other directional drilling technologies and the advantages and disadvantages of these systems. The advantages and disadvantages of a number of borehole navigation systems are also presented. A discussion of the applications of the technology follows, illustrated by case histories. Finally, the environmental impacts and benefits of the technology, in comparison to more conventional systems, are presented.

Jan 1, 1999

By M. S. Moats

A considerable amount of research has been conducted to determine the causes of anode passivation. Chemical and electrochemical reactions that occur after passivation have received little attention. Chronopotentiometry, linear sweep voltammetry, cyclic voltammetry, and impedance spectroscopy have been used to elucidate three reactions that occur after passivation of commercial copper anodes. These involve the dissolution of silver and subsequent cementation and transformation of selenides, the oxidation of lead sulfate to lead oxide, and oxygen evolution. The amount of silver dissolution depends on the silver content of the anode, the time to passivation, and the molar ratio of Ag/(Se+Te). The oxidation of lead from PbSO4 to PbOx explains a potential plateau of oxygen evolution. Silver affects the duration of oxygen evolution on the PbOx. Anodes containing kupferglimmer display a characteristic oxygen evolution potential. It is believed that kupferglimmer provides a lower overpotential for oxygen evolution than the other slime phases or passivated surface.

Jan 1, 1999

By E. J. Peuraniemi

Recently commissioned Kennecott-Outokumpu flash converting was developed to replace the approved but environmentally outdated Peirce-Smith -converting to satisfy the globally tightening emission regulations. In the present study, dust formation and reaction mechanisms of two copper mattes with different experimental parameters were studied in lean suspension conditions. Both mattes had very high copper content of approximately 75 wt% and low iron content of 4.5 wt% and 1.2 wt% Fe. A laboratory scale, vertical laminar-flow furnace with a low feeding rate was used to simulate the phenomena taking place in the reaction shaft of a flash converter. Experimental conditions included temperature of 1300 °C with reaction gas oxygen contents of 20 vol%, 50 vol%, and 75 vol%. In the experiments, sieved particle fractions were fed to the furnace and sampled after short reaction time intervals by quenching them into a water film. Collected particles were analysed chemically for their main elements to define their removal rates. Also, optical and scanning electron microscopy with EDS-analyser were applied to determine phenomena occurring during reactions. Kinetics of oxidation as well as ignition of particles are discussed. Changes in particle morphology, size, and composition are reviewed to describe dust formation and reaction mechanisms.

Jan 1, 1999

By A. K. Bakshi

An on-line rheometer, suitable for use with slurries, has been developed at Michigan Technological University. This rheometer can be used with both Newtonian and non-Newtonian slurries, and produces complete shear-rate/shear stress curves which characterize the time-independent rheology of the slurry. The sensor utilizes the Hagen-Poiseuille equation and Boyle's Law to calculate the shear rate, slurry flowrate, and shear stress from a series of pressure measurements. The design of the unit allows the measurement sample to be continuously collected from operating process streams in the often-hostile on-line environment. The shear rate/shear stress curves can be used to conveniently calculate the apparent viscosity at any given shear rate, and also to measure any yield stress or other deviations from Newtonian behavior.

Jan 1, 1999

By John B. Dale

A primary objective of copper mining, smelting and refining operations is the cost- effective, efficient, and environmentally-acceptable control of the level of various metal ions throughout the processing and effluent treatment flowsheets. Effective ionic control maximizes product and by-product quality, allows for broad flexibility in sourcing impurity laden ores, minimizes capital and operating costs, and can achieve zero discharge operations. In order to meet increasingly stringent cost, environmental and product quality requirements, separation technologies are needed that can selectively remove and recover deleterious or valuable ions. Ideally, the subsequently obtained salts or metals can be recycled in the process, disposed of in an environmentally acceptable manner, or sold as valuable by-products. The use of MRT, a highly selective separations technology, has been demonstrated to be a cost effective, efficient, and environmentally- sound treatment for a wide range of cations and anions that are commonly found in copper electrorefining and electrowinning circuits, as well as in environmental treatment operations. These include heavy and transition metals, precious metals, halides and alkali/alkaline earths. This paper will review a number of areas of interest including: recovery and refining of platinum group metals from copper anode slimes, recovery of copper from acid mine drainage streams, extraction of Bi, Sb and C1 from copper electrorefining and electrowinning circuits.

Jan 1, 1999

By Thomas C. Anderson

Thirty-four retaining walls are part of the $46 million upgrade of a 1942 depressed highway in Highland Park, Michigan near Detroit. This project will close a missing link between two newer roadways, I-75 and the John Lodge Freeway. The existing 75 ft. wide, six lane Davison Freeway is being replaced by a eight to ten lane, 200 ft. wide depressed highway in a limited right of way. The highway will be 20-25 ft. deep and 1.5 miles long. A design/build decision by the Michigan DOT saved about 37% of the engineers estimated cost of $19 million for the walls. The successful pre-qualified specialty contractor utilized an innovative solution for the walls consisting of tiedback/cantilevered walls on the north side and mechanically stabilized earth walls on the south side. All of the walls have an identical cast-in-place architectural facing.

Jan 1, 1999

By C. C. Nolan

As the size of the mills get larger and the liners get heavier, a better means had to be found to handle liner replacement. McLellan Industries is famous for their innovative ideas and was called upon by an engineering company to develop a mill liner crane. The first crane was developed for Similkameen about 1969 to serve a 32' 0 x 14' Long SAG Mill. The next was Island Copper in Port Hardy, B.c., the same size as Similkameen in 1970. At that time, we took existing hydraulic cranes and modified them to meet the mill configuration. In 1973, we developed a completely new approach for the Southern Peru copper mine at Tacna, Peru for a Ball Mill, size 16'-6" 0 X 19' Long. Each installation required a design study to meet the change in mill size, trunnion size, elevation of floor to feed trunnion, area at the feed or discharge end of the mill. We have supplied self-propelled units as well as lift in. When there is no room at the feed end and if the mill has a trunnion overflow discharge, we have the mill supplier provide a structural frame to span the sump and move the mill liner handier into position with the use of the overhead crane or a mobile crane.

Jan 1, 1999

By S. W. White

Plasma arc technology is increasingly being used to process a number of waste materials. In present research, plasma technology is being investigated to treat waste magnesium baghouse dust, which is a waste material from the Magnetherm process. This dust contains mostly MgO, but also contains NazO, CaO, and KzO. Plasma energy is to be used along with a reducing agent to produce pure gaseous magnesium while keeping the other materials in a slag. The magnesium will then be collected by rapid quenching. A non-transferred arc plasma torch is ideal for this reaction because of its high enthalpy and improved energy efficiency over conventional methods. Another advantage of plasma is that it allows for the pre-heating or pre-reacting of fine particles before contact with the melt. Thermodynamic calculations using the Gibb energy minimization method were used to determine the most stable compositions of the materials at various temperatures. Energy balances have also been calculated. These results conclude that we can recover approximately 98% of the magnesium with a proper quenching technique. The calculated results are compared with the experimental data, and good agreement between them was observed.

Jan 1, 1999

By Alexander I. Raitchenko

"Although one takes into account only thermal expansion usually at analysis of convection onset, the essential factors include magnetic and electric fields. If Lorentz-force originating from intercrossed electric and magnetic fields' action is directed downwards its effect strengthens gravitational action, and value of critical Rayleigh number (limit value for convection onset) must decrease; increasing of critical Rayleigh number should be observed in case of Lorentz-force directed upwards. Extent of such an influence is determined by relation of Lorentz-force to hydrostatic head in gravitational field. Competition between electromagnetic force due to nonuniformity of electroconductivity (on account of its temperature dependence) and electromagnetic buoyancy force may have ambiguous effect: both increase or decrease of critical Rayleigh numbers. Proposed conception is applicable to analysis of situations in liquid conductors and conductive gases.IntroductionStatic or dynamic situations in fluid media are determined besides properties of these media by a variety of external influences. However one correlate~ the onset of the convection and its development with influences of the minimum quantity of external causes frequently. Most known and usual factors are the gravitational and temperature fields. The number of processes includes heat generation in media volume, and theoretical analysis in these cases takes into account this interior heating together with boundary temperature conditions. But explanation of many natural and technical events is not complete and cogent within limits of thermo-gravitational terms. The whole complex of acting factors which influence convective processes in techniques and nature is greater in many cases. In particular the action of · electromagnetic nature often has not less importance than gravitation one. Stability or instability of a current layer in the plasma must be determined by non-uniformity of electroconductivity owing to non-uniformity of temperature [1]. The presence of Joule dissipation in the plasma through which the electric current flows stipulates initiation of origin of overheated instability [2]. It is known that electroconductivity of arc in the boundary zone changes sharply with radial distance [3], and this must influence its stability essentially. If the intercrossed electric current and magnetic field begin to act on an electroconductive fluid besides the non-uniform temperature field and the gravity, the conditions for the onset of the convection change radi- . cally: both the temperature field and their solutions have to be changed also. The analysis of equilibrium single-time correlation functions of fluctuations must be employed for situations with enlarged number of factors as this was in case for the Rayleigh-Benard problem where the object is a horizontal layer of liquid. This can be carried out by taking into account the detached forces' correlations [ 4, 5]"

Jan 1, 1999

By J. F. Stenebråten, W. P. Johnson, D. R. Brosnahan

Carbonaceous material (CM) from ores of varying preg-robbing activity from Barrick Goldstrike Mines Inc. (BGMI), Nevada, was characterized in terms of its functional group content, hydrocarbon content, elemental composition, and humic acid content. FT-IR analyses showed neither the presence of hydrocarbons nor of carboxylic, phenolic, or sulfhydrol functionalities. FT-IR bands present included C=C stretching in aromatic rings and C-O-C stretching, indicating presence of oxygen as ether linkages in the carbon matrix. Calculated atomic oxygen to carbon (O/C) ratios did not reveal a trend between maturity of CM and preg-robbing behavior, possibly due to low resolution of electron microprobe analysis. However, the atomic O/C ratios agree with other chemical analysis, indicating that the organic carbon is very mature, similar to or higher in grade than anthracite coal.

Jan 1, 1999

By N Belluz, L Johnson, N Wiwoho, P Manning

The Kucing Liar skarn deposit is located in the Ertsberg mining district, which also contains other skarn deposits and the Grasberg porphyry copper û gold deposit. The Ertsberg district is located in the province of Irian Jaya, IndonesiaÆs easternmost province. Mining development began in the Ertsberg district in 1972 with the mining of the Ertsberg deposit. Daily production in the district now averages about 230 000 tonnes of ore, with the bulk of the ore coming from the Grasberg open pit and the balance from underground mining of skarn deposits. During 1998, 45 218 additional metres of drilling were conducted to delineate and understand the Kucing Liar orebody. The deposit was first intersected in drill holes in 1994 and then was intersected in underground workings located about 1000 metres from the discovery drill hole in 1995. Initially, the two intersections were thought to be different orebodies but are now realised to be different parts of the same orebody. The Kucing Liar deposit consists of magnetite û copper û gold replacement and skarn mineralisation in favorable Tertiary and Cretaceous units. The deposit is approximately 2000 metres in length and averages about 200 to 250 metres in thickness. The width varies from 400 to 600 metres. Drilling in 1998 was directed towards delineating the deposit on its NW and SE ends and to determine its down dip extension. Reserves for the deposit at the end of 1998 stand at 320 million tonnes at 1.4 per cent copper, 1.4 g/t gold, and 5.3 g/t silver. Many important questions remain to be answered concerning the relationship of the Kucing Liar orebody to the major faults in the district and to the Grasberg intrusive complex which contains the Grasberg orebody. Continued exciting developments are anticipated as work to understand the deposit by drilling and geologic study continues.

Jan 1, 1999

By H. H. Murray

Recently developed clay deposits that will impact regional and world markets are described. These deposits, their location, geology, and physical properties are delineated. Kaolins from the State of Para in Brazil and from Ukraine; bentonites from Argentina and India; and palygorskite and sepiolite from China are world class deposits that when processed using modem technology will produce excellent products. Other deposits that may affect regional markets are l<aolins from China, Australia and Indonesia; bentonites from Georgia (formerly USSR) and China; and palygorskite from India and Ukraine. New ball clay deposits that will affect regional markets are in China and Indonesia.

Jan 1, 1999

By Y Wei, H-B Mnhlhaus

Particles are by far the easiest objects to simulate, because their dynamics is simple. Determining the motion of particles and their interaction, a wide variety of deformable structures can be constructed by connecting particles that have mass, position, and velocity, and that respond to forces. Starting from this simple idea we have derived what we call the particle-lattice method for the solutions of boundary value problems of deformation and fracture of solid mass. The problem of rock breaking by blasting operations as well as fracture and flow of rocks fragments involve momentum transfer between solid and fluid; gas flow and reactive mass transfer. In this paper we outline the method and describe briefly the salient features of the algorithm. We derive relationships between the contact properties for the discrete model and the properties of the underlying continuum and fluid flow coupling procedure. Finally we illustrate the potential of the method by means of example solutions related to the dynamic fracture and flow in jointed rock by blasting.

Jan 1, 1999

By N. Kanari

The kinetics of oxychlorination of MgO by Cl2+O2 was studied in the temperature range of 850 °C - 1025 °C, using thermogravimetric analysis. The effects of C12/02 ratio, gas velocity, temperature and partial pressure of reactive gases on the reaction rate were investigated. The oxychlorination process was characterized by an apparent activation energy of about 214 kJ/mol. The reaction orders with respect to C12+O2. C12 and O2 at 950 °C were about 0.65.0.98, and -0.37, respectively. Some data about oxychlorination kinetics of MgO, Cr2O3, and MgCr2O4 contained in chromite were compared. Efficiency of using oxychlorination for the removal of iron oxides contained in magnesia was demonstrated.

Jan 1, 1999