Search Documents

By Ernest K. Yanful, Paul H. Simms

The lysimeter is a useful tool for evaluating the performance of mine waste covers or liners. A major problem with its application is the possibility for preferential flow into or away from the lysimeter, if the lysimeter soil is finer or coarser than the barrier soil or sub-base soil. Analysis of a field lysimeter using a two-dimensional unsaturated-saturated liquid flow model suggested that preferential flow would occur and little or no water would be collected; however, in the field, the lysimeters collected significant amounts of water. A similar discrepancy was found between the observed and predicted water balance of a simple laboratory test simulating the lysimeter design. Vapour flow and partial flow, two phenomena not generally simulated in conventional flow models, are possible explanations for the difference between field and laboratory observations.

Jan 1, 2000

By R. W. Smith, D. L. Taylor, K. A. Altman

Recent research has shown that traditional sensitivity, what if and best case/worst case analysis of metallurgical data has the potential to over estimate the value of mining projects. Use of simulations, which rely on the input of statistical information, may provide more realistic predictions of the value of future projects. Actual metallurgical data is used to demonstrate that analyzing the data from a statistical perspective can give insight into completing an optimum amount of metallurgical testing and a mechanism to determine that samples used for the testing are truly representative of the ore that will be processed.

Jan 1, 2000

By M. Okido, R. Ichino, K. Kuroda

"Compound semiconductor, ZnTe, was electrodeposited in an acidic solution with K2TeO3, ZnSO4 and Na2SO4 solution. Since the reduction potential Te(IV)/Te(O) is remarkably noble from the solution comparing to Zn(II)/Zn(O), code position of Te and Zn was thought to be difficult from this solution. Resulting from EQCM analysis, furthermore, Te(IV) reduced to Te(O) and Te(-II) in this order so that Te catholically dissolved from the electrode surface at more negative potential. But ZnTe alloy were formed by the UPD of Zn at -0.7V at 298K on Te surface in lmM K2TeO3, 100mM ZnSO4 and 100mM Na2SO4 solution adjusted at pH 4. Content of Te in the deposits is, however, more than 80%.Electrolytic temperature is well known to affect on the deposits characteristics. The higher bath temperature was, the better ZnTe crystal was detected in this study. Thermal electrode method is a. process of heating only substrate by flowing ac current in substrate. This process makes the surface temperature of substrate higher than boiling point of the solution, 373K. From EDX analysis, deposits without thermal current were Te-rich, Te content in the deposits with thermal current decreased with increasing of thermal current. Te content was 62% for 5A ac current, 51 % for I OA and 45% for 20A, respectively. The deposits that produced with ac current of IOA were closed to the stoichiometric ratio, i.e. ZnTe.Consequently, thermal electrode method is more effective to obtain a good crystallized ZnTe without heat treatment after deposition.IntroductionThe current subject of solar cell materials is silicon. Compound semiconductors including GaAs and II-VI group are generally used in the developing field of digital information such as the rapid cellular phone and car telephone. Compound semiconductors consist of more than 2 kinds of element. There are many materials for these compound semiconductors such a SiC, InSb, CdS for binary system and CuinSe2 for ternary system. It becomes generally difficult, to produce high quality crystal with increasing of kinds of element due to a complicated structure and a compound ratio of element. Semiconductor materials as a device are usually simple binary compounds and/or these mixed crystals. Properties of compound semiconductors have variety of the forbidden band and lattice constant and that can be change easily by addition of another element for the usage of the solar cell. Since most compound semiconductors are direct interband transition type, which has steep optics absorption edge and large light absorption coefficient."

Jan 1, 2000

By J. A. Oraniscak

Longwall mining operations continue to increase extraction rates and the potential to generate higher amounts of airborne respirable dust (ARD). The National Institute for Occupational Safety and Health (NIOSH) has gathered data from underground longwall surveys and laboratory crushing tests to identify the important factors influencing the amount of ARD levels generated. Coal-seam characteristics, operational parameters (i.e.,cut sequence, mining height, etc.), extraction rates and dust-control parameters (i.e., airflow, water flow, etc.) were examined to determine their influence on ARD levels measured at longwalls during actual mining operations. ARD generated by a laboratory crusher while crushing bituminous coal samples collected from underground longwalls was also examined to determine if there were cor relations with coal-seam properties. Results from the longwall and laboratory data collected indicated that low-ash, high-volatile coals (low moist fuel ratio or MFR coals) generate higher amounts of ARD. It was found that face ventilation and water application to the coal product are essential elements to controlling longwall ARD levels.

Jan 1, 2000

By A. Burger Pintér

To be meaningful the sharing of ideas about the National Environmental Management Act (NEMA) and social issues within the context of Mining and Metallurgy (M&M) requires an honest scrutiny of the M&M/social environment relationship, both past and present. It is not a secret that this relationship has been and is fraught with difficulties. Thus from all perspectives (M&M, society and environmental and social consultants) such a dissection, that highlights the realities, both good and bad, is uncomfortable. For this section of the colloquium to have any value, the honest but difficult approach needs to be taken.

Jan 1, 2000

By J. A. Herbst, S. L. Blust

Optimization of blasting, crushing, and grinding operations is filled with challenges. One of the more difficult tasks is accurately sampling and determining the size distributions of blasted and crushed materials at a reasonable cost. The task is difficult because of the large size of fragments and the tonnage involved. However, the size distribution measurements are necessary for models that predict the performance of mine-through-mill operations. This paper is concerned with the use of video sampling for this task at National Steel Pellet Company's operation in Keewatin, Minnesota Data gathering, data analysis, model building, and mine-to-mill simulation are all described.

Jan 1, 2000

By Nora M. Hutt, Kevin A. Morin

Geochemical static tests are a basic component of geochemical assessments and predictions for acidic drainage, and include acid-base accounting and total-metal contents. A key database for such information is the International Static Database (ISD), which currently contains more than 45,000 static-test analyses from over 200 minesites. Such large databases are useful in identifying general trends and, just as important, the percentage of exceptions. General trends and significant exceptions can be seen in the ISD by comparing one parameter against another. This paper shows that bulk neutralization potential (bulk NP) obtained from acid titration is often a good indicator of neutralizing capacity above values of 10 t CaCO3/1000 t. Other types of calculated neutralizing capacity are then compared to bulk NP to determine if they, in fact, reliably represent actual neutralizing capacity and if they can substitute for the more time-consuming and expensive bulk NP. For example, bulk NP correlates better with Carbonate NP (from carbonate analyses) and Total-carbon NP (from total-carbon analyses) than with (Ca+Mg) CaNP (from solid-phase analyses of calcium and magnesium). This means that, in general, (Ca+Mg) CaNP is a less accurate substitute for bulk NP than the other types, and thus requires intensive site-specific justification if a substitution is attempted. This also means that measurement of the frequently less-expensive parameters of total carbon and carbonate can often substitute, within site-specific error bars, for the bulk-NP titration. However, the ISD also shows that non-carbonate minerals make the primary contribution to neutralization in up to 20% of samples, so Carbonate CaNP and Total-carbon CaNP do not always reveal the full neutralizing capacity of a sample.

Jan 1, 2000

By Michael G. Li

Prediction of acid rock drainage (ARD) for low-sulphide, low-neutralisation potential (LSLNP) mine wastes is methodologically different from that for normal sulphidic mining wastes. In this paper. LSLNP wastes are conveniently defined as those with S2 < 1% and ABA-NP2 < 20 kg CaCO3 eq/t. The distinctiveness of ARD prediction for LSLNP materials originates from their frequently low oxidation rates and is mainly attributable to two reasons. First, the utilisation efficiency of available carbonate neutralisation potential (CNP2) rapidly deteriorates when the sulphide oxidation rate per unit mass of waste drops below a certain level. Reducing the flushing rate of a waste has the same effect as increasing the oxidation rate. Second, silicate neutralisation becomes increasingly important as oxidation rates diminish, and can no longer be ignored in LSLNP materials as it often is for normal sulphidic mine wastes. In this paper, the effects of oxidation rate, pore gas CO2 partial pressure, and flushing rate on ARD prediction for LSLNP materials are theoretically demonstrated with the help of modelling using the computer program MINTEQA2. A new methodology for ARD prediction for LSLNP materials is presented in terms of a prediction procedure. Finally, a case study is given to validate some of theoretical aspects discussed and to illustrate the use of the newly proposed ARD prediction procedure.

Jan 1, 2000

By Peter Halbach

The two HYFIFLUX cruises of the German RV SONNE (SO 99/1995 and SO 134/1998) were organized in the framework of a co-operation between several German universities and two European marine research partners. It is a multidisciplinary program for the study of hydrothermalism with its associated geological, mineralogical, and biological processes in the North Fiji Basin (NFB) in the SW-Pacific. The main achievements of the HYFIFLUX cruises were detailed multibeam Hydrosweep mapping in order to identify the detailed tectonic setting, water sampling at hydrothermally active vents, mineral sampling at inactive sites with sulfide, sulfate, and silica mineralizations, and sampling of basaltic rocks, (Halbach et al. 1999). Oceanic accretion in the NFB is characterized by a double spreading system (Auzende et al. 1994),with one spreading axis located in the median part of the basin (Central Fiji Ridge, CFR) and the second one located immediately west of the Fiji platform (West Fiji Ridge). Most of our investigations were done in the northern part of the N 15° segment of the CFR, which corresponds to area A of our program, area D is located farther south in the NFB and corresponds to the N-S segment of the CFR (Fig. 1). During previous works under the French-Japanese STARMER project, the active ?White Lady? mound and the extinct Père Lachaiseí site were sampled; these samples were studied by Bendel et al. 1993. Here an inactive hydrothermal field was studied, where there were many sediment-covered chimneys in various stages of disintegration, (Bendel et al. 1993). However, the area immediately southwest of the nodal circular basin, which is the triple point junction of the medium-spreading Central Fiji Ridge (about 6 cm/yr spreading rate

Jan 1, 2000

By V. D. Tathavadkar

Chromite ore is of immense importance for the extraction of metallic chromium and chromium chemicals. The mineralogy and crystal structure of chromite phase are therefore important part of our investigation on the extraction chemistry of chromium species. In this investigation, we have studied the effect of the processing parameters, i.e., the temperature and the oxygen potential on the microstructure and composition of mineral phases formed in the Cr2O3 ?Al2O3 -FexOy -MgO system. In particular the importance of the spinodal decomposition reaction is emphasized in the extraction of chromium as sodium chromite and sodium chromate. Experiments were carried out in order to study the differences in the crystallography of different chromite minerals. Phase equilibria in natural chromite minerals were investigated by calcining chromite mineral in air, argon, and 5% hydrogen + argon atmospheres over a temperature range from 200 to 1200 °C. The effect of the oxygen partial pressure and temperature on the phase constituents of the calcined product has been discussed. The microstructural changes were examined using scanning electron microscope (SEM) and the changes in elemental composition in different phases were analysed by electron probe micro analyser (EPMA). The results obtained from EPMA studies were used to calculate lattice parameter of the spinel lattice, and these values were compared with the values obtained from X-Ray powder diffraction data. On the basis of the experimental data, the mechanism of the spinodal decomposition of complex spinel phases is described under the influence of oxygen partial pressure and temperature.

Jan 1, 2000

By Tadashi Aiura, Yasuhiro Miura

"A small amount(0.2mass%) of Scandium(Sc) was added to the 7.NOl and 5083 Al alloys as a refiner and stabilizer of microstructure, and the resulting microstructures were discussed in comparison with the effects of the conventional additives. The followings are summarized: 1) in the as-solidified structure, a ·decreased tendency of constitutional supercooling and increased solubility of Mg were recognized for the Sc-added 5083 alloy. Sc is a -better microstructure refiner for the 7N01 alloy than Zr, in a sense that it does not suppress the favorable effect of· coexisting Ti. 2) Sc effectively suppresses recrystallization both in the 5083 and 7N01 alloys. 3) The rod like primary Al3Sc crystals formed during solidification, as well as the fine dispersion of Al3Sc precipitates formed by subsequent heat treatment, can act as a strong recrystallization suppresser. IntroductionThe 7N01 and 5083 alloys are the most popular industrial Al alloys and they are widely' used for various structures because of their superior properties. Fine macro and micro structures of the materials are required for obtaining acceptable sec resistance,consistent appearance of anodized surface and good weldability, as well as good mechanical properties. In order to produce fine grain structures, transition metals, such as Cr, Zr, and Mn, have been conventionally added.It has been reported that Sc is an efficient refiner [l, 2] and can be an alternative for the conventional and also suppresses recrystallization in Al alloys [3,4]. Scandium is the lightest transition element and forms an equilibrium intermetallic phase. The equilibrium phase, Ll2-Al3Sc, is coherent with the matrix, and of _spherical shape. A fine dispersion of the spherical precipitates is obtained by quenching and aging after solutionizing annealing. The authors have already reported a part of the experimental results on the effect of Sc on the as homogenized microstructure of the 5083 alloy [5]. In the present study, the effects of Sc on the macro and micro structures of the industrial high strength Al alloys(7N01 and 5083) for extrusion are investigated, and the superior role of Sc as a grain refiner is shown"

Jan 1, 2000

By A. E. Dabbagh

Saudi Arabia’s mineral potential offers development target that compliment the national effort to diversify the income of this oil and gas economic based nation. Ma’aden, a joint stock company with paid-up capital of US$1 billion, has from its inception in 1997, actively developed in-house engineering and management skills to transform the Arabian shield’s mineral potential into such real projects. Gold mine operating facilities of 100,000 oz/yr underground and 50,000 oz/yr open pit are de-scribed, as well as 3 targets, two of which are underdevelopment; Al Hajar (3,000 tpd at 2.5 gpt Au)and Al Amar (5,000 tpd at 20 gpt Au). Emphasis is also on exploitation of phosphate rock and down-stream fertilizer products, based on the Kingdom’s107,000 sq. km. northern basin geological reserve. Al Jalamid, the prime target, represents 216 million tonnes of these P2O5 reserves. Saudis and expatriates, together, lead international engineering companies and contractors operating and developing these facilities.

Jan 1, 2000

By J. J. Gusek

Passive treatment of mine drainage using constructed wetlands has been employed on coal and metal mine sites since about 1985. The technology has advanced significantly since then; there are currently over 600 of these systems treating coal mine drainage in the Eastern U.S. at flow rates of hundreds of liters per minute. Passive treatment performance at three metal mines discussed in this paper has been positive for a wide variety of flows, water chemistry, and climates. The sites include a high-altitude underground copper mine, acidic seepage from a gold heap leach pad, and pumped effluent from an active underground lead mine in Missouri.

Jan 1, 2000

By J. E. Jacoby

Scrap recycling has become an increasingly important source of metal units for the aluminum industry during the past 25 years. Aluminum scrap from the manufacture and recycling of cans, automobiles, buildings and other products has created an industry that melts these products and delivers the metal in molten or sow form to companies that make cast parts or fabricated products This rapidly developing recycling industry has contributed a large number of severe (Force 3) molten aluminum explosions (25) with associated fatalities (19) to the Aluminum Association data accumulated during the past nineteen years. The explosions that occurred in recyclers plants represent 17% of the total explosions, 33% of the Force 3 explosions and 37% of the fatalities reported. These explosions can be prevented! This paper will identify causes of these explosions and procedures that can be used to prevent them.

Jan 1, 2000

By Gregory Witte

This paper will explore the technology behind and applications of smart motor control centers (MCCs) being used today in mineral processing facilities. The two technologies to be discussed are solid-state motor controllers that can be installed in MCCs and the complementary digital communication networks that can transmit operational parameters of the solid-state devices to the supervisory system. The toughness and reliability of solid-state technologies have led to a dramatic increase in their usage throughout the mining industry. Products such as solid-state motor protectors, controllers, and variable frequency drives have demonstrated greater flexibility and performance in a variety of applications than their electromechanical and mechanical counterparts. The three key trends apparent in the solid-state devices are: 1. A shift to smaller, smarter, more integrated devices, which allows a single solid-state device to serve the purpose of multiple electromechanical devices but in a much smaller form factor. 2. Distribution of control logic in motor control devices rather than conveyed through a hard wired connection to a central automation system. 3. Embedded network communication that allows supervisory systems to have an expanded view into critical loads and sensors. In applications, the use of smart actuators and sensors with integral local intelligence and communication allow a supervisory controller to send high level commands and let the smart device coordinate its own work The ability of smart field devices to return noncontrolled, nonpoled information opens a whole array of new capabilities for preventive maintenance and diagnostics and forms the basis for an effective motor management program. The smart motor control devices this paper will explore are the smart motor protectors (SMP), smart motor controllers (SMC), and variable frequency drives (VFD).

Jan 1, 2000

By K Gottliebsen

Many hydrometallurgical and chemical processes produce large amounts of acid waste. This is illustrated by the copper S/X-E/W process used at the Mount Gordon mine in North Queensland, which produces a tank house bleed in the form of a concentrated sulphuric acid stream. The bleed stream is necessary to remove impurities such as iron that decrease the efficiency of the electrowinning process. However, this bleed stream comes at a high financial cost due to large quantities of make up sulphuric acid required as well as the need to neutralise the bleed stream prior to disposal. The present work describes the approach taken to develop a solvent extraction process for the selective recovery of sulphuric acid from copper tank house bleed liquor. The proposed extraction system was investigated using a branched long chain aliphatic tertiary amine tris(2-ethylhexyl)amine (TEHA) as the extractant, Shellsol 2046 as the diluent and octanol as a modifier. Computer simulations were used to determine the optimum operating conditions for the recovery process. It was found that the process was able to selectively recover up to 90 per cent of the sulphuric acid from the copper electrolyte. This is recovered as a pure aqueous acid stream at a concentration of up to 130 g/L that can be recycled back into the tank house circuit or other areas of the process. The raffinate acid concentration was reduced from 180 g/L to as low as 18 g/L, significantly reducing waste disposal and the environmental impact of the copper process. The equilibrium data and simulation results were also compared with an alternative extractant, CYANEXR 923. Finally the efficiency of the TEHA extraction system was investigated on a pilot-scale in a pulsed perforated plate column. This information was used in order to scale the process for an industrial application. The same methodology applied in this case study could be used to provide innovative and cost-effective solutions to waste streams encountered in other hydrometallurgical or chemical processes.

Jan 1, 2000

By Takayoshi Fujii, Mitsumasa Hoshi, Chikashi Suenaga, Yoshiaki Suzuki

"In a bid to renovate its Saganoseki Smelter & Refinery and to establish a leading production unit in terms of global competitiveness, Nippon Mining & Metals undertook major - restructuring efforts since 1993.One of its themes was the shift from a two-flash furnaces operation to a single-flash furnace operation. The shift was successfully completed in 1996 while maintaining the production at the same level (330,000 metric tons per year of copper) by adopting such measures as improvements in pneumatic concentrate dryers, the concentrate feeding system, concentrate burners, the furnace cooling system, and a new cryogenic oxygen plant was constructed.With a view to realizing high matte grade operation (at 65%Cu) and increasing the concentrate feeding rate, further steps were taken the capacity of waste heat boiler was expanded and technical improvements were added, including optimization of the smelting reaction in the furnace shaft. As a result, the smelting capacity, as of the year 2000, has increased to 450,000 metric tons per year of copper.IntroductionThe feed rate to the flash furnace was doubled to 140 t/h from 70 t/h in 1996. Teething problems, as a result of the renovation, were almost solved by the end of 1996, and the operation of the single furnace operation has become stable.The main theme was the shift from a two-flash furnaces operation to a single-furnace operation to maintain the production capacity at the same level, namely 330,000 metric tons of copper per year. Then, in a bid to further renovate the Saganoseki Smelter & Refinery and to establish a leading production unit in terms of global competitiveness, further enhancement of the flash furnace's productivity was planned.The purpose of this plan was to raise the copper production capacity to 450,000 mtpy building on the potentialities of existing plants and without installing new equipment."

Jan 1, 2000

By Toshiyuki Hiranami, Keizou Uematsu

"AbstractionSpray freeze drying method was proposed to fabricate ·ceramic: powder granules for high performance ceramics. Obtained granules and their green compact were characterized by SEM and immersion liquid technique. Granules have a spherical shape of about l 00 µ m in diameter, ·and no binder segregation was found with the immersion liquid technique. The granule had sufficient strength for usual handling, while the strength was much lower than that of granules prepared by conventional spray-drying. Unlike the conventional green compacts, granule interfaces were not observed in the green body made with the spray-freeze dried granules.IntroductionIt was well kn9wn that spray-dried granules have binder segregation layer on their surfaces. The trace of this segregation layer survives in the later processes i.e. compaction and firing, and behaves as fracture origins in the sintered bodies. The origin of this problem is solvent drying process from slurry droplet surface in spray drying system. As alternative method we propose a freeze drying process for granule preparation, in which solvent is remove by sublimation though the process, binder segregation can be prevent.In this study, we applied spray freeze drying method to fabricate alumina powder granule, and characterized the obtained granules, and their green compacts and sintered bodies.Experimental procedure.Alumina powders and additives aqueous solution were mixed for 24 hours using a ball mill to· prepare the slurry for spray freeze drying. .The solid loading of the slurry was 30vo1%. Deflocculant (PAA-NH4 type) was added 0.5mass%, and the binder (PVA). 1.0, 2.0 or 3.0mass% of alumina. Obtained slurries were sprayed into liquid nitrogen to make frozen granules. The granules were freeze dried.For the characterization of the granules, immersion, liquid technique observation and single granule strength test were carried out. Strength of individual granule wa5 measured using micro compression testing machine (MCTM, SHIMADZU). Granule strength was calculated from following equation."

Jan 1, 2000

By C. Restarick, R. G. Robins, R. M. Taylor, I. Ennis

Lime addition to acid mine drainage waters (AMD), possibly accompanied by aeration, has been the basis for their remediation by precipitation of predominantly metal hydroxides. An efficient novel alternative technique causes precipitation of double M(II)-M(III) hydroxy sulfates which readily precipitate and are easily dewatered. When the Fe(II)/Fe(III) + Al(III) ratio of the AMD is appropriate, the Green Precipitate (GP) Process provides a more effective alternative to normal liming/aeration. The process can be adapted to give a continuous in-line treatment by the choice of suitable computer-controlled reactors designed to improve the liming efficiency, reduce scaling and control the rate of treatment. The processes are described in terms of the chemistry involved.

Jan 1, 2000

By K. Iwami, K. Abe

"Onahama Smelter and Refinery has been operated-since 1965 arid currently produces 243,000 metric tons per year of cathode copper. The Onahama tankhouse consists of conventional-type No.1 and 2 tankhouses with the capacity of 123,000 metric tons per year and No.3 tankhouse with 120,000 metric tons per year, adopting jumbo tank system, using hazelett anode respectively.In October, 1996, for the purpose of improving the - anode verticality, new anode copper body press machine has been installed in No.1, 2 tankhouses; by increasing Walker type anode copper weight by 35kg to 365kg. Consequently, it is possible to raise current density from 191 to 222 A/m2 and the No.1 and 2 tankhouses capacity was increased by 15,000 metric tons per year to 138,000 metric tons per year.At present, the refining capacity is 258,000 metric tons per year in total including No.3 tankhouse.This figure is the largest one in Japan.IntroductionSince the Onaham tankhouse was put into operation in 1965, the cathode copper production has increase with much labor cost saving.The following two cases to increase Walker type anode copper weight by 35kg to 365kg were studied.a) To increase the cathode copper production by raising current density.b) To save the labor cost by prolonging the anode cycle in order to decrease the exchanging time of electrodes.So the electrolytic tests were carried out to confirm· the effect of current efficiency, cathode copper quality and working conditions for space adjustment.As a result, we concluded that it was indispensable to introduce the anode body press machine to keep usual current efficiency and cathode copper quality with same workers, and to be possible to increase cathode copper production.In addition, the high-speed press machine was needed to maintain same working time and which specifications were decided through various investigations. In October 1996, the new anode body press machine made by Kawazoe Machine Works, Ltd. has been installed in No.1 tankhouse."

Jan 1, 2000