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By M. Brennan, A. Majumder

"The mineral processing research community has devoted enormous efforts to the modelling of mineral separators over the last 50 years. While many efforts have been made to use only fundamental physics as a basis for the models, fluid flow patterns in separators are not simple while the motion of particle swarms through fluids is extremely complex.Sluices are the simplest forms of the flowing film concentrators and have been used in the mineral industry since at least the 15th century (Agricola, 1556). Flowing film concentrators, in general, still have widespread applications in the mineral industry and their designs vary according to the specific need.Particle separation in a sluice appears deceptively simple, but the separation mechanism has proven complex and difficult to quantify. Separation in the sluice takes place in a flowing film a few millimetres thick. The particles are suspended by turbulent eddies and motion relative to the fluid takes place in socalled hindered settling mode. The difficulty arises because the presence of the particles influences the flow pattern and when the particles are fully transported by the flow, the flowing slurry may not have the same viscosity as water and does not have the same density. For this reason a universal theory which can explain the behaviour of a suspension in a sluice or any other gravity equipment has still not been developed. Few attempts have been made to analyse the mechanisms involved in the concentrating processes of pinched sluices and Reichert cones.Fluid flow behaviour and slurry transportation characteristics in open channels have, however, been active research topics in the disciplines of fluid mechanics, chemical engineering and civil engineering for many years. As a result, an extensive literature is available, which has led to the development of the model described in this paper.In an effort to test the extent to which fundamental fluid mechanics can provide a prediction of particle separation, a study on a simple parallel-sided sluice has been carried out using glass beads at various particle concentrations and flow rates, and the actual particle separation taking place compared to predictions from modelling.The modelling strategy was divided into two parts; the first was to predict the horizontal slurry flow velocity profile and the second to predict the solid particle concentration over the depth of the flow at different flow conditions. The predictions were then validated with measured data sets. This can easily be done if the slurry flow is split at different fractional flow depths so that the mass flow of solids over different flow heights is measured accurately over a fixed period. Mass flow splits can then be calculated by integrating the product of the predicted slurry velocity profile and the predicted solids concentration profiles from the base of the sluice bed to the slurry free surface."

Jan 1, 2003

By M Titley, E Maidens

Many gold deposits were mineralised by fluids and processes that also altered the host rocks. This alteration may often be a useful visual aid that distinguishes barren, low-grade from high-grade regions in a rock mass. Alteration intensity is commonly used in gold deposits as a visual tool, along with face sampling or grade control support, to define oreblocks and guide excavation in underground and open pit mining. However, alteration is not often used at the resource estimation stage. Mineralised lodes are usually defined by geologists using a ægeo-grade envelopeÆ, where a number of constraints are considered, including an (arbitrary) cut-off grade; the ænaturalÆ grade break between high- and low-grades; and geological features including structural, lithological or alteration continuity. The geo-grade envelope is usually thought to satisfy the requirements of stationarity for grade estimation, and is considered a single domain. This paper examines a modelling technique combining gold grade and alteration, applied to the Wallaby deposit in Western Australia, to imbue a greater level of detail to the grade estimation in a region tested by relatively sparse drilling. This was achieved by utilising the correlation of gold grade and alteration, along with the spatial characteristics of the alteration, when estimating grades within a number of lodes. The alteration-driven estimation was utilised in conjunction with an unfolding approach, and the use of probability estimates, to overcome geometric data constraints. This technique allows greater control and most likely provides a more reliable estimate of the mineable resources than a global grade cut-off when visual control is to be a major vector in grade control.

Jan 1, 2003

By F. M. C. C. Vieira

Four mining alternatives for exploiting an ultra-deep orebody were assessed through a multidisciplinary evaluation process which involved: the generation of a 3D geological model; the design and scheduling of life-of-mine layouts; the analysis of anticipated ventilation and cooling conditions; the study of rock-related risks of mining in ultra-deep stress environments; the logistic implications of transporting men, rock and materials; and, lastly, the economic implications of each option. Once results from the integrated mine design assessment were available, mine planners were faced with an important problem to solve: how to identify the optimal mine design alternative when numerous assessment measures and multiple decision criteria needed to be considered simultaneously? To address this ‘multiple-attribute decision problem’ and arrive at the ‘optimal layout for ultra-depth’, a generic decision methodology that uses principles of ‘utility’ was applied. The methodology assumes that ‘single-value risk estimators’ do not account for the inherent variability of real conditions. Therefore, risk estimators were represented by statistical distributions of their incremental changes, where applicable. The stochastic variables, once defined, are used as inputs in the ‘utility’-based layout decision scheme. This ‘utility’-based decision methodology offers a framework for mine design decisions to be made objectively, when complex trade-offs between multiple risk domains need to be considered simultaneously. Upon applying it, one of the layouts emerged as the preferred alternative. Keywords: Utility; mine design; multiple-attribute decision; layout selection

Jan 1, 2003

By S. K. Gilman, V. E. Hugo

A common problem encountered in the mineral sands industry is that the mineralogical measurements used in defining the resource are not readily converted to metallurgical recoveries, which are used to predict the quantity of the final products. The problem stems from the different objectives of the exploration and metallurgical assessment programmes, and is often compounded by the use of different laboratory techniques and mineral definitions. Common mistakes include the misapplication of routine analysis, incorrect interpretation of mineral recovery, the confusion of mineral recovery with product yield and inconsistent definition of the same mineral. Experience has shown that unless these potential mistakes are identified, the measurement techniques used during exploration and metallurgical assessment are not compatible, often resulting in large errors in the prediction of mineral production. There are no easy solutions to the problem, as there is no universal assay technique which can cost effectively characterize all the mineral sands resources. The recommended course of action will therefore require several iterations to optimize the assay technique to suit the resource. Fundamental to the success of the measurement technique is the understanding of the mineralogy, its behaviour during mineral processing and the quality requirements for the final products.

Jan 1, 2003

By Chu Yong Cheng

Synergists can be used in solvent extraction to improve the selectivity of extractants for metals. Research work carried out by the SX group at the AJ Parker Cooperative Research Centre for Hydrometallurgy / CSIRO Minerals has shown that the pH isotherm of nickel with Versatic 10 was significantly lowered by the addition of the synergist Acorga CLX50. The paper discusses how this synergistic shift can be used to alleviate a gypsum formation problem at Bulong nickel laterite operation in Western Australia. Metal pH isotherms were obtained with Versatic 10 and synergist CLX50 using synthetic leach solutions. In terms of pH50, the extraction order of the metals with 0.5 M Versatic 10 alone was Cu > Zn > Ni > Co > Mn > Ca > Mg, whilst the extraction order with Versatic 10 and 20% by volume CLX50 was Cu > Ni Zn > Co > Mn > Ca > Mg with the pH50 (Mn-Co) significantlyincreased. This is significant because the isotherms of valuable metals Ni, Cu, Co and Zn shift more towards low pH than those of the waste metals Mn, Mg and Ca, resulting in a possible good separation of Ni, Cu, Co and Zn from Mn, Mg and Ca. The use of intermediate precipitation, solids/liquid separation and re-leach in the three Western Australian nickel plants make these processes complicated and costly in capital and operation. The research work carried by the SX groupat the AJ Parker Centre has led to the development of direct SX (DSX) processes to recover nickel and cobalt from leach solutions using synergistic organic systems. Semi-continuous tests with a BHP Billiton pilot plant leach solution showed that Ni and Co together with Zn and Cu were separated from the major impurities, Mn, Mg, Ca, and Cl, in the first SX circuit. The co-extracted impurities were easily scrubbed. After stripping, Ni and Co together with Zn and Cu were concentrated, resulting in a much smaller second SX circuit in the down stream processes.

Jan 1, 2003

By J Mar·n, R Anderson, S Strohma, R Harvey

Xstrata is the operator of both Minera Alumbrera Ltd (50 per cent Xstrata, 50 per cent Wheaton River) and Ernest Henry Mining Pty Ltd, (99.99 per cent Xstrata), both copper-gold deposits, using conventional SAG/ball milling at current capacities of 36 Mt/yr and 10.3 Mt/yr respectively. Alumbrera is located in Catamarca Province, in the north west of Argentina. Ernest Henry is located in Cloncurry, north west Queensland, Australia. Both operations started in late 1997, with commercial production achieved in early 1998. Different designs and equipment are in use for both operations, however the evolution of SAG milling performance, although logically related to their specific features, reflect similar trends of consistent increases in throughput. This paper will discuss the main changes to the SAG mill liners in both operations and the results achieved to date. A summary of the operating strategies will be included.

Jan 1, 2003

By W. Kuckshinrichs

Metallic raw material flows are characterized by a complex global network of producers and consumers, as well as by a multitude of ecological, economic and social impacts across national boundaries and on different scales. This leads to the need to develop methodologies, which allow identifying obstacles that prevent metallic raw material flows to contribute to sustainable development. From a scientific point of view CRC 525 (Martens 2003) has developed an holistic indicator set consisting of approximately 80 different indicators. This set is taking into account the multi-dimensional character of sustainable development. Moreover the indicators reflect different system boundaries according to different actor levels and decision contexts. The full indicator set is important in scientific considerations and suitable for scientific awareness creation. However, to fulfil the function of a decision support approach for political and economic decision-makers some modifications are of central concern. At first a reduction of the full indicator set by selection of core indicators enables decision-makers to deal with complex issues of contrary economic and societal protection targets. Secondly, as thresholds of indicators justify societal call for action, they are discussed against its political or scientific origin. The proposed methodology is exemplified by indicator-based studies of the material flow of aluminium.

Jan 1, 2003

By P. M. Solozhenkin

"Galvanochemical process (GChP)) cleaning of sewages is realized in the field of shortcirquited galvanic elements from the mixture current the materials place in purification’s solution and form multitude galvanopairs without external electric field in presence oxygen of the air. The galvanochemical process is electrochemical process utilizing galvanic pairs: coke - iron, iron - copper and others and process does not require chemical reagents.The effect of basic parameters of the cleaning effectiveness have been studied depending on oxidizing of galvanopairs. Adjusting nature, type of galvanic pairs and forming three component system possible to enlarge emf circuits to 2.378 V.The role of ?2, as basic agent, for generation of hydrogen peroxide and hydroxyl ions.It was stated, that removing of metal ions from solutions occur mainly on account of sorption and hydrolytic sedimentation of iron oxihydrates.Determined separate stages of the process: coagulation, sorptions of admixtures on freshly formed ferric oxides and oxidizing destruction of organic components of effluents in presence of ?2 ? ?2?2. Shown efficiency of the method for removing of Cu, Cr, Ni, Zn, As ions, as well as fluoride, phosphate and cyanide anions and oil products, surface-active and flotation reagents. Cleaned water can be recycled for some processes non-critical toward residual concentration of admixtures, as total salt contents is lowered on 60-75 % and reaching limits of concentration for toxic components.The concept of high power unit creation was developed, and galvanochemical pulsator is presented. The pulsator is not expensive, and exploitation expences are low, as well as servise is simple with high effectiveness, and capacity. The galvanoflotation process is developing, combining galvanochemistry and flotation of hydrofobic admixtures (oil, surface-active agents).The galvanochemical flotators are presented."

Jan 1, 2003

By A. González

Arsenic is one of the main contaminants present in Chilean copper concentrates and its abatement represents a challenge for the process metallurgy, particularly under the strong environmental requirements in the global community. The possibility to form ferric arsenate directly from a gas phase by means of a heterogeneous reaction between an arsenic gas bearing and iron oxide was studied at laboratory scale. A thermodynamical analysis for the system Fe-As-O-S has been initially made, in order to obtain the stability conditions for the ferric arsenate or other FexAs2O2 type compounds. Experiments were made using an hematite sample suspended in a thermogravimetric device. AS4O6 gas generated from solid AS203 that was passed through the iron oxide sample and its instantaneous weight change was recorded directly. A kinetic study for the AS4O6 volatilization was made to control the gas composition. A chemical control between 300 and 600°C with an apparent activation energy of around 14 Kcal/mol As2O3 was determined. The samples after the reactions were chemically and XRD analysed. Arsenates detected corresponds to complex compounds. Results shows a dependence on temperature and oxygen content in the gas phase. The kinetics for iron arsenates formation is slow, reaching an arsenic capture of 6% after 80 minutes of reaction when an oxygen content of 50% is fed continuously at 800°C and 3,56% As in the gas. Experiences made at the same temperature but under higher oxygen content in a closed reactor, allowed arsenic capture close to 60%. For higher temperatures the capture is considerably lower.

Jan 1, 2003

By Vladimir Kislik

Competitive complexation/solvation theory of solvent extraction constitutes a general framework for interpretation and quantification of ion-molecular interaction data in extraction systems. Depending on extracting metal -- solvent affinity constant and metal concentration ratios, four possible stages of extraction behavior and interacting mechanisms, are considered. Affinity constant ratios are easily acceptable through the independent measurements of three-component systems. Once determined and tabulated, the affinity constant ratio data may be used in any system of interest. Mathematical descriptions of the results are introduced for different interactions. Active solvent (including water) concentrations in the organic phase and temperature are included to the quantitative consideration. The theory allows direct comparison of the complexing/solvating power (competition order) of various extractants, active solvents and diluents. As a result, predictions for the extraction effectiveness and selectivity are possible. Some metal extraction systems are analyzed on the base of the theory. Analysis gives a key for preliminary quantitative prediction of suitable extraction systems.

Jan 1, 2003

By B. Tiryaki, M. Ayhan, O. Z. Hekimoglu

"This paper discusses the aspects of tracking cutters related to the computer-aided design of shearer drums. A comprehensive computer analysis of drum dynamic parameters for multi-tracking tool arrangement is not presently available, as the current computer programs mainly consider the aspects of single tracking. Despite the fact that the single-tracking arrangement is recommended for efficient cutting, some major drum manufacturers have been seen to persistently adhere to multi-tracking, probably due to a lack of information. Further studies in this field are believed to contribute greatly to the current understanding of the computer-aided design of shearer drums.A number of laboratory simulation trials and long-term underground investigations were carried out in detail on tracking cutter arrangement, and an equation required for a computer program was derived. The results obtained from computer assessment of dynamic parameters for drums with multi-tracking arrangement were found to be in accordance with those of the underground trials, indicating the validity of the equations. The procedure adopted for the computer appraisal of the shearer drums designed with a multi-tracking concept, as described in this study, is therefore recommended to be considered in the currently employed computer programs."

Jan 1, 2003

By Guo Xueyi

The electrochemical couple behavior of manganese dioxide with ferrous/ferric ions in acidic chloride medium was investigated, It was proven that the dissolution of Mn01 is due to the electrochemical couple reaction between MnO2/Mn2+ and Fe2+/lFe3+ in the solution, The driving force for the process originates from the rest potential difference of the two couples. The reduction of Mn02 is controlled by clectrochemical kinetics, whereas the conversion of F e2+ to Fe3+ is limited by diffusion, The factors such as the Mn2+, Fe2+, Fe3+, Cl concentration, pH of the solution and the temperature, have much influence on the kinetics of the couple process, This study will be useful to elucidate the mechanism for the leaching of manganese nodule from the deep ocean as well as manganese dioxide ores in land,

Jan 1, 2003

By D V. Bright

Oroya Mining LimitedÆs Mt Gibson Gold Project, 280 km north east of Perth, is one of Western AustraliaÆs more recent discoveries of a major gold resource. Modern gold mining commenced in 1986, on a shallow laterite reserve of 6.62 million tonnes averaging 1.50 g/t gold. By the end of 1998, mining had progressed from an initial three shallow laterite pits to a series of 14 open pits with maximum depth of 100 m, on three separate trends with a combined strike length of over 10 km. The Project has yielded 868 400 ounces of gold from 16.5 million tonnes of ore at an average recovered grade of 1.64 g/t gold, from near surface laterite, supergene and primary sulfide ores. This includes a 160 m deep underground decline operation which mined 120 000 tonnes at an average grade of 9.1 g/t gold and a four million tonne Dump Leach on a synthetic base which yielded 68 900 ounces. The Project was placed on Care and Maintenance in 1999 pending drilling to refresh reserves. Hosted by strongly tectonised and altered Archaean volcanic rocks within and adjacent to a major regional shear, primary gold mineralisation occurs as structurally emplaced sulfide and quartz lodes. On the main Gibson Trend, multiple zones of mineralisation occur within a zone up to 600 m in overall width. The overall footprint of known mineralisation exceeds 20 km2 and the potentially mineralised domain exceeds 100 km2. The current estimate of a combined resource of 9.4 million tonnes averaging 2.47 g/t gold (749 500 ounces) is derived from a database of 10 500 drill holes, of which only four per cent test below 100 m vertical depth. Ore envelopes which remain open at depth and major gaps in the drilling pattern beyond the currently defined resources promise straightforward potential to define additional resources. Oroya Mining Limited and its joint venture partner Barrick Australia are targeting a major gold mining operation from this potentially world-class mineralised system. Oroya has the exclusive right to produce up to 500 000 ounces and is working toward the completion of a feasibility study into a resumption of mining using the existing 1986-built 1 Mtpa processing plant. The joint venture is in the early stages of testing the depth and lateral potential of the Mt Gibson mineralised system. Mining options currently under review include progressive open pit extension and amalgamation leading to one or more large open pits, and underground operations. It is too early in the development of the Project to offer definitive economic models of potential large-scale mining operations.

Jan 1, 2003

Cannington is a Broken Hill type deposit discovered by BHP Minerals, now BHP Billiton, in 1990. The deposit is located south east of Cloncurry, Queensland, Australia. The deposit occurs in the Eastern succession of the Mount Isa Inlier within the Soldiers Cap Group. The mineralisation is interpreted to be confined to two limbs of a synform wrapped around a core amphibolite. The silver, lead and zinc mineralisation is zoned within silicic and mafic units. There is a strong association between silver and lead. The combination of mafic and silicic zoning, differing relative grades of silver, lead, zinc and iron, the relative position of the mineralisation on the synform limbs and differing metallurgical performances have resulted in the identification of ten different ore types, four of which are currently extracted. Ordinary Kriging (OK) is used as the resource estimation methodology for the silver, lead and zinc mineralisation. This modelling approach has performed quite well for resource reporting and long term mine planning. However the limitations of this modelling technique to adequately provide information on a local stope scale has lead to the geological staff to consider alternatives to this approach. Limitations of the current modelling method apply to both the geometry of the orebodies and the grade variability. Since early-2000 the Cannington geologists have been experimenting with modelling both the distribution of the mineralisation types using Probability Field conditional simulation (PF) and the distribution of grade using Sequential Gaussian Simulation (SGS). This approach to local modelling of mineralisation type and metal grades using conditional simulation (CS) has undergone a full evaluation by comparing grades estimated for stopes using both the (OK) resource model and conditional simulation (CS) models. The mine planning staff have used the CS derived models, and have found improvements in grade predictions over the currently utilised Ordinary Kriging û derived resource model.

Jan 1, 2003

By M. Hermanus

1. INTRODUCTION It gives me great pleasure to extend my warmest greetings to everyone attending the 30th International Conference of Safety in Mines Research Institutes. I would also like to bid a special welcome to all of the international delegates who have travelled to Johannesburg to take part in what surely be a most rewarding session of deliberations. As you come together over next four days, you will have a wonderful opportunity to exchange ideas and information on strategies and practices for the implementation of sustainable patterns of development. The objectives of this meeting are both timely and far-reaching, as countries around the globe work towards the sustainable use of the world resources. Each of you brings a high level of expertise to these deliberations. I know that you will make the most of this opportunity to address the challenges and opportunities to highlight the most innovative and technologically efficient methods of social protection in order to ensure an increase in the quality of life, health, safety and living environment for the peoples of the Africa. Our country, although endowed with an immense and diverse array of mineral deposits, is perhaps best known in the mining industry for the fact that it is the world’s biggest producer of gold. Although South African gold production has declined over the past years and the industry faces serious problems, it is a myth that the South African industry is moribund. There is a new energy coursing through the South African producers which will ensure their powerful presence for many years to come, based not only on their domestic production but also and probably increasingly on their external operations. Africa features prominently in the latter category.

Jan 1, 2003

By Jerome P. Downey

Technologies developed within the field of extractive metallurgy to recover, concentrate, and purify metals and industrial minerals from ores, have served as the foundation for all of the subsequent environmental remediation, materials recycling, and waste management technologies. This paper discusses the application of classical extractive engineering principles to the development of a thermal process for the recovery of mercury from solid wastes. Process development is presented as a series of logical stages, which begin with a thorough characterization of the site-specific waste, move on to bench and pilot scale testing of the process options, and end with a functional process flowsheet. This paper also presents thermodynamic data on many mercury species of interest to the minerals, power, and chemical industries. These data can be used to model the speciation and recovery of the mercury as a function of various process parameters.

Jan 1, 2003

By D Landriault, G W. Wilson, L Langetine and

Engineered soil covers are used for final closure options for both waste rock and tailings disposal facilities. Currently, cover construction requires excavation of appropriate cover material from a nearby site. If no suitable materials are available, the mine operation may have to ship appropriate materials long distances to the site before the construction of the cover can even begin. This has led to the proposal to engineer cover materials using existing waste materials from the mining operation. The paper presented here describes the results of a laboratory scale testing program to evaluate the potential for blending waste rock, smelter slag and tailings for the creation of a suitable cover material at a site in Canada. Tailings from the local mill, waste rock and slag were collected in the field and blended to create a material with an air entry value similar to the tailings and with physical strength similar to the waste rock. Testing indicated this mixed material could be blended at a consistency of a paste and was suitable for pumping. It can also be compacted to a high-density material. The preliminary results show that it may be possible to blend waste rock, slag and tailings into a material that can be utilised in the construction of a water retaining cover.

Jan 1, 2003

By Edwin Itzig-Heine, Daniel Traylor, Bernard Tarralle, Michael McKenna

This paper discusses the challenges associated with the design and construction of a dual-cell, “figure eight” shaped shaft in saturated, soft ground for the Northeast Interceptor Sewer project in Los Angeles. The shaft will be excavated to a depth of41 m and used to launch two EPB TBMs. The specifications required concrete diaphragm walls, embedded below the shaft invert, and a grout curtain beneath the wall. To control water pressure and basal stability without a grout curtain, wall panels were embedded deeper than required into a stiff, cohesive deposit. Details of wall panel excavation using a Hydrofraise are presented.

Jan 1, 2003

By Catherine Williams-Beam

Thallium is more toxic to humans than mercury, cadmium, lead, copper or zinc. Its chemical behavior resembles the alkali metals (K, Rb, Cs). It occurs almost exclusively in natural waters the monovalent thallous cation. The solubilities of thallous compounds are relatively high so that monovalent thallium is readily transported through aqueous routes into the environment. The major sources of thallium are the base metal sulfides and precious metal bearing sulfides. Therefore, it is often present as a contaminant constituent in waters emanating from heavy metal sulfide bearing deposits. Thallium can be effectively removed from wastewater to <2 µg/L by reductive precipitation of thallium sulfide. Effective thallium sulfide precipitation requires a controlled solution potential/pH combination. The required potential can be effectively achieved by utilizing a particulate iron slurry or packed column environment. Experimental results will be presented and discussed.

Jan 1, 2003

The Ekati Diamond Mine is located on permafrost terrain in CanadaÆs Northwest Territories. The mine rock consists of: diamond-bearing and barren kimberlite; and surrounding waste rock such as granite. The kimberlite occurs in several vertical æpipesÆ that are, or will be, mined using open pits. Early predictions of drainage chemistry at Ekati identified the potential for ARD due to sulfide oxidation from both waste rock and kimberlite. This was surprising for the kimberlite, because neutralisation potentials (NP) are typically hundreds of kg CaCO3 equivalent/t. However, subsequent testwork showed that substantial portions of the NP ædisappearedÆ quickly, apparently due to the unusual non-carbonate mineralogy. In any case, additional predictive work concluded much of the rock was benign and there would be no ARD. Shortly after mining started, ARD appeared from both the waste rock and kimberlite, although a few years passed before the company and its consultants recognised that at least some of the acidic water was ARD. Numerous other processes have been put forward as possible explanations for the remaining acidic drainage, although none have been either confirmed or eliminated. Because: the causes of the ARD and acidity are not known; no causes have been eliminated and more have been added; drainage chemistry was not predicted accurately; and future mining will encounter similar rock. I believe the Ekati Diamond Mine needs high-level assistance to understand current chemistry and to avoid problems with future drainage. Organisations like INAP, MEND3, and universities could provide this assistance.

Jan 1, 2003