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By R. Van Hille, S. Lacour, A. E. Lewis, K. Peterson

"This paper compares thermodynamic modelling results with those obtained for copper sulphide removal from aqueous solution in both continuous and batch experiments at laboratory scale. Sulphide precipitation has been demonstrated to be an effective method for heavy metal removal. The advantages are the high degree of metal removal at low pH, low quantities of sludge formation, the ease of de-watering and low reactor retention time due to high reactivity of sulphides. However, the low solubility of sulphide species can lead to spontaneous nucleation of fines, which are difficult to remove.Theoretical modelling was carried out using ASPEN Plus™ and OLI systems Inc ESP process. Both simulators were used to calculate copper sulphide recovery and residual aqueous copper concentrations as a function of pH. The predictions were then compared with experimental results. Both simulations predicted that all of the inlet copper would precipitate as sulphide CuS(s) over the entire range of pH and sulphide: copper molar ratios investigated. The simulation results were strongly influenced by the number of chemical species and the nature of the thermodynamic data taken into account in the model.The continuous experimental studies were carried out in a fluidised bed reactor (FBR). Copper sulphate was reacted with sodium sulphide and the solid precipitated directly onto the pellets in the FBR. The use of sulphide was motivated by high sulphate levels in local acid mine drainage and the ultimate integration of the metal removal process with a biological sulphate reducing process that produces an aqueous sulphide stream.A maximum dissolved copper removal of 99.6% (AAS analysis) and a total removal efficiency of 95.8% (dissolved copper minus fines) were achieved. Stoichiometry of the precipitate was determined from SEM/EDAX analysis (atomic percentages) and was close to 1/1, irrespective of the operating conditions."

Jan 1, 2003

By Alan Campoli

The Eclipse System was developed by Minova USA Inc. formerly Fosroc Inc. to improve the performance of 5/8-inch deformed rebar fully grouted into a one inch borehole. An 1/8-inch offset bolt head combined with specially formulated Eclipse Lokset resin cartridge results in reduced gloving and increased mixing efficiency. The benefits of the Eclipse System have been demonstrated, under the supervision of MSHA, in Kentucky, West Virginia and Illinois coal mines in partnership with Excel Mining Systems, a leading roof bolt manufacturer. Over 100,000 units have been installed to date. Eclipse system bolts exposed during overcast construction at the Panther Mine of Cumberland Resources displayed an extremely well mixed, uniform resin anchorage over the entire bolt length.

Jan 1, 2003

By Katsunori Okaya, Toshio Inoue

"Movement of mill charge in the centrifugal mill is essentially dissimilar from that in the vibration mill with circular path despite the apparently similar mode in the motion of mill body. This dissimilarity is the reason for the substantial advantage regarding the comminution intensity of the centrifugal mill over the conventional vibration mill accounting approximately to one order of magnitude.Bradley et al. (1983) developed a math model regarding the mill charge as a lump. This model is presented in a simple equation with which motion of the mill charge can be predicted in terms of the parameters describing the specification and the operation of the centrifugal mill. This equation can be used to explain the power draft of the mill as well as the stability of mill operation. More recently, on the other hand, a numerical simulation technology called discrete element method (DEM) has become a vital vehicle for estimating the motion of the grinding media in the mill. The authors developed a mill simulator called ‘Mill Solver’. Mill Solver is designed to simulate various types of mills including centrifugal and vibration mills. The principle of this simulator is to calculate individual kinetic events of interaction of balls in the mill in a minute time interval, hence the mill performance can be constructed for estimation."

Jan 1, 2003

By Kathleen M. Kowalski-Trakofler

This paper discusses human judgment and decision making under stress. The authors review selected recent literature across various disciplines and suggest a definition of stress within the context of decision making during the management of emergencies. They also discuss fieldwork by the Pittsburgh Research Laboratory, NIOSH, which explores traumatic incident stress, the relationship between previous training and performance under stressful conditions, and human behaviour in underground mine fires. The authors assert that stress is one of the factors that decision makers must contend with in most life-or-death situations. They suggest that a better understanding of individual judgment and decision making activities whilst under stress would yield a better understanding of how people reach the choices they make in emergencies. This enhanced understanding would be of enormous value to emergency managers, researchers and policymakers.

Jan 1, 2003

By J. Simmons, P. Ziemkiewicz

Acid-Base Accounting (ABA) is an analytical procedure that provides values to help assess the acid-producing and acid-neutralizing potential of overburden rocks prior to coal mining and other large-scale excavations. This procedure was developed by West Virginia University scientists during the 1960s. After the passage of laws requiring an assessment of surface mining on water quality, ABA became a preferred method to predict post-mining water quality,and permitting decisions for surface mines are largely based on thevalues determined by ABA. In order to predict the post-mining water quality, the amount of acid-producing rock is compared to the amount of acid-neutralizing rock, and a prediction of the water quality at the site (whether acid or alkaline) is obtained. We gathered geologic and geographic data for 56 mined sites in West Virginia, which allowed us to estimate total overburden amounts, and values for maximum potential acidity (MPA), neutralization potential (NP), net neutralization potential (NNP), and NP/MPA ratios for each site based on ABA. These values were correlated to post-mining water quality from springs or seeps on the mined property. Overburden mass was determined by three methods, with the method used by Pennsylvania researchers showing the most accurate results to actual overburden mass. A poor relationship existed between MPA and post-mining water quality, NP was intermediate, and NNP and the NP/MPA ratio showed the best prediction accuracy. In this study, NNP and the NP/MPA ratio gave identical water quality prediction results. Therefore using NP/MPA ratios, values were separated into categories: <1 should produce acid drainage, between 1 and 2 can produce either acid or alkaline water conditions, and >2 should produce alkaline water. On our 56 surface mined sites, NP/MPA ratios varied from 0.1 to 31, and six sites (11%) did not fit the expected pattern using this category approach. Two of eight sites with ratios <1 did not produce acid drainage as predicted (the drainage was neutral), and four of 40 sites with a ratio >2 produced acid drainage when they should not have. These latter four sites were either mined very slowly, had non-representative ABA data, received water from an adjacent underground mine, or had a surface mining practice that degraded the water. In general, an NP/MPA ratio of <1 produced acid or neutral drainage sites, between 1 and 2 produced mostly alkaline drainage sites, while NP/MPA ratios of >2 produced alkaline drainage with a few exceptions. ABA is a good tool to assess overburden quality before surface mining and to predict post-mining drainage quality after mining. The interpretation from ABA values was correct in 50 out of 52 cases (96%), excluding the four anomalous sites, which had acid water for reasons other than overburden quality.

Jan 1, 2003

By Yoichi Takeda

Copper solubility in Si02-CaO-FeOx slag equilibrated with copper matte in 10% S02 atmosphere at 1573K was estimated. Essential parameters are activity coefficients of copper oxide and sulfide, oxygen and sulfur potentials and activity of copper in the slag-matte system. A large number of experiments provide proper parameters to calculate copper solubility in slag. A classical thermodynamic model postulating CUOO.5 and CuSo.; molecules assists in estimating copper solubility in slag. Additions of Si02 and CaO reduce copper solubility almost in any condition. Copper loss, that is function copper solubility and slag volume, in the silica saturated Si02-FeOx binary slag is minimally equilibrated with less than 66% copper matte while copper loss in the 50% FeOx-SiOrCaO ternary slag saturated with 2CaOSi02 is minimally equilibrated with over 66% copper matte. This slag composition has potential for continuous copper converting, direct copper production or high-grade matte production.

Jan 1, 2003

By A. M. Hefny, F. P. Siew, P. G. Ranjith

Fracture initiation and propagation, being one of the most intensive subjects in rock mechanics; contribute significantly to the deformation of jointed rock masses. An experimental study on fractured granitic rock was carried out to determine the peak strength of specimen under triaxial loading conditions. The commonly observed failure mode for rock specimens in this study was found to be the shearing of the plane of weakness. The minimum peak strength of fractured rock is observed when the joint orientation is approximately 70° to the horizontal axis. Based on experimental test data, an empirical expression was developed to accommodate the effect of joint orientation and joint trace length in estimating the peak strength of fractured rocks. The predicted values of peak strength using the proposed equation well agree with the experimental results carried out on singly fractured specimens under triaxial loading conditions. The threshold stress values of crack initiation and propagation depend on joint geometrical parameters, their degree of interconnectivity, as well as surrounding stresses on the fracture plane.

Jan 1, 2003

Vertical flow systems (SAPS, vertical flow wetlands) are increasingly used for passive treatment of mine drainage that is net acid. Data on 30 systems in eastern US show that well designed systems typically add about 40 g/d/m2 of alkalinity to influent net acid water. If they are designed with a conservative loading rate of 25 g/d/m2 and carefully constructed, they produce net alkaline water. Alkalinity added depends on influent acidity, Fe, pH, and retention time, and ranges widely, from 7 to 484 mg/L, so this is not a useful design criterion. Some waters may benefit from retention times longer than the conventional 12 - 16 hours, but the design must be partly based on cost-benefit considerations. Systems with fine limestone added to the compost layer perform better than average, perhaps to an alkalinity generation rate of 80 g/m2/d. A variety of problems are noted in the 30 systems and others reported in the literature. Systems with high influent Fe (> ~75 mg/L, varying with pH) tend to gradually decrease in flow rate because of precipitation and settling of Fe hydroxides on top of the compost layer. Some high-Fe systems precipitate Fe in the limestone layer, suggesting inadequate compost thickness, or short-circuiting through thin spots. Systems with Al exceeding about 10 mg/L tend to plug because of Al hydroxide precipitation in the limestone layer. Flushing only removes a small part of this precipitate, but can extend life. Some systems are ineffective because of failure of the inflow system. Some systems are uneconomic because they are oversized. A continuing program of inspection and maintenance is necessary for long-term performance.

Jan 1, 2003

By J Mauk, J Rowland, S Rabone

Most epithermal Au-Ag deposits in the Hauraki Goldfield are hosted in late Miocene andesites. Broken Hills is an exception, being one of the few economic deposits hosted in rhyolite. Investigation of Broken Hills provides the opportunity to collate structural data that may be compared with that collected from andesite-hosted deposits in order to evaluate the importance of rock type on vein development. The rhyolite host rock at Broken Hills is strongly flow-banded, but this anisotropy does not appear to affect the orientation of mineralised structures. There is a range of structures at Broken Hills: veins, faults, fractures, and large breccia pipes. Veins generally strike north-south, with localised changes in strike and thickness. Slip vectors determined from striations indicate near pure dipslip on the main lode, indicating an extensional tectonic setting. The orientations of vein deflections are parallel to slip vectors. This correlation is common in modern extensional fault arrays where fault growth and linkage produces subvertical deflections in fault orientation (eg TVZ). There are three main types of breccias: 1. Primary breccias related to rhyolite emplacement. 2. Jigsaw type secondary breccias that are that developed during the life of the hydrothermal system. 3. Breccia pipes. Broken Hills was a dynamic epithermal mineralising system.

Jan 1, 2003

By G. Barelli, C. Giusti, W. H. Langer

Natural aggregate – sand, gravel, and crushed stone – is the number one non-energy mineral resource in the world in terms of both volume and value. A plan for the sustainable development of aggregate resources can include: 1) policies and economic incentives to encourage identification and protection of potential resources, 2)efficient quarrying and processing of aggregate, 3) efficient use of primary aggregates, 4) greater use of recycled, waste, or substitute material, 5) inclusion of costs of all environmental impacts in price of material, 6) reclamation to beneficial secondary uses, and 7)identification of objectives, targets, actions, and sustainability indicators. Quarrying can also contribute to sustainable ecosystems through natural habitat reclamation.

Jan 1, 2003

By M. Kawakami

In relation to the designing of a new-type blast furnace, the reaction of carbonaceous materials with C02 is expected to occur at as low temperature as possible. In order to get a highly reactive carbonaceous material at low temperature, the reaction kinetics was investigated by measuring such quantities as the reaction rate from weight loss, the amount of CO adsorption and specific surface area by BET method. The reaction rates were large in the order of the Bintyo char, metallurgical coke, graphite and glassy carbon. If the rate was converted to the rate per unit area, however, those of the Bintyo char was smaller than that of graphite. Thus, it is suggested that the rate of the Bintyo char is influenced by the pore diffusion of C02. The rate had a positive relation with the amount of CO adsorption, showing that the rate determining step would be the desorption of CO from the active side on the surface. The rate independent of surface area was derived, combining al\ the obtained data.

Jan 1, 2003

By Yongfu Yu, Xiaotie Wang, Fuguang Zhang, Liping Che

"Rare Earth water dregs is the drained waste dregs, which contains over 0.2 percent thorium dioxide and about 6-10 percent di-Rare Earth trioxide, which is beyond the standard of draining off that China governments set, so that the Rare Earth water leach dregs must be sacked and laid down in storehouse, which costs lots of money. It is a pity that the RE and thorium compounds very useful elements in industry are discarded. A lot of work must be carried out so that this resource was fully developed.In this paper, four separation techniques of recovery Rare Earth minerals and enrichment thorium element and reduction thorium content of drained dreg for the different test samples of Rare Earth water leach dregs which is radioactive waste dregs got from diverse locus are studied, respectively, and the separation characteristic and the separation process are described, using several combination processes of classification and gravity and flotation separation which were prepared according to the characteristic of test samples and technology. The test results show that the combination processes are the more remarkable separation techniques and the flotation reagents used in test can be applied to utilizing synthetically radioactive waste dregs. Through the combined technique process, three parts of products were obtained, namely, Rare Earth concentrate collected, the thorium product enriched and a large amount of the waste dregs product that can be directly drained and the total quantity is 50%-60%. In order to determine optimum technical condition, the effect factors of separation process were investigated in the test."

Jan 1, 2003

By S. Wakita, K. Aoki, Y. Mito, K. Date

It is of great importance to prevent a leakage of hazardous substances from underground storage plants, because this certainly leads to a fatal disaster for human societies. Therefore, effective grouting system needs to be developed, which can inject cement grout into low-permeable rock masses. Authors have carried out a series of laboratory injection tests using a fracture model and field tests in low-permeable rock masses. In these tests, not only was the superiority of dynamic grouting confirmed, but also the relationship between grouting-efficiency and injection parameters was investigated. In this paper, the results of laboratory injection tests and field tests together with theoretical approaches to them are mentioned. L’empêchement de la fuite des substances dangereuses des galeries de stockage est un traitement très important pour protéger la société humaine contre la comtamination catastrophique. Par conséquent, un procédé d’injection efficace doit être mis au point, qui peut injecter du coulis de ciment dans le rocher ayant une perméabilité basse. Les auteurs ont effectué une série d&apos;essais d&apos;injection en laboratoire en utilisant un modèle de rupture et d&apos;essais sur le terrain dans le rocher ayant une perméabilité basse. Dans ces essais, était non seulement la supériorité du l’injection dynamique confirmée, mais aussi le rapport entre l’efficacité de l’injection et les paramètres d&apos;injection a été étudié. Dans cet article, les résultats des essais d&apos;injection en laboratoire et des essais sur le terrain ainsi que les méthodes théoriques pour les essais sont mentionnés. Es ist wichtig, Durchsickerns gefährlicher Substanzen aus unterirdischen Lagerstellen zu verhindern, weil dies für die menschliche Gesellschaft unter Umständen zu verheerenden Unfällen führen kann. Daher muß ein effizientes VerfugesSystem entwickelt werden, welches erlaubt den Mörtelschlamm in wenig durchlässige Felsenmassen einzuspritzen. Die Autoren haben eine Serie von Laboreinspritzungsversuchen mit einem Bruchmodell und Feldversuche an wenig durchlässigen Felsenmassen durchgeführt. Diese Versuche zeigten nicht nur die Überlegenheit des dynamischen Verfugens, sondern wurde dabei auch das Verhältnis zwischen Verfugen und Leistungsfähigkeit sowie den Einspritzungparametern untersucht. In dieser Studie werden die Ergebnisse der Laboreinspritzungtests und die Feldversuche zusammen mit den entsprechenden theoretischen Ansätzen erläutert.

Jan 1, 2003

By Jurgens J. Louw, Vincent C. Smith, Gareth C. Smith, Agit Singh, Dave G. Hulbert

"The flexibility of the PlantStar control platform has enabled Mintek to investigate and easily develop new control strategies for both milling and flotation. This includes a Solids Feed Controller, a Safety Limit Controller, Mill Power Optimiser and Flotation Optimiser, amongst others.The solids feed controller was developed for minerals processing plants using a specialised time delay compensator. Using conventional time delay compensators that are purely model based, results in robustness problems due to model uncertainties. The Mintek Solid Feeds Controller makes use of a plant model, but compensates for model inaccuracies, giving more controller stability and a more robust delay compensation algorithm.The safety limit controller has been developed to switch smoothly between normal and safety control loops without bumping the process. The safety loop output is chosen in accordance with a predefined list of priorities and whether the respective constraint boundaries are exceeded.The Mill Power Optimiser helps to find the power peak on the mill power curve. This insures maximum grind with maximum throughput. It also prevents power dips due to mill overloads, making the milling circuit easier to operate.The flotation optimiser algorithm analyses trends of all accessible variables in the process. The algorithm uses this information to calculate operating conditions that will control the residence times, mass pulls and circulating loads within a flotation circuit to a specified setpoint. Research is being done to now optimise these setpoints in order to achieve better recovery."

Jan 1, 2003

By M. Kwasniewski, M. Takahashi

Prismatic samples of a medium-grained sandstone from Slask Colliery (Upper Silesian Coal Basin, Poland) were tested under uniaxial compression, conventional triaxial compression and true triaxial compression conditions. The conventional triaxial compression tests were carried out at confining pressure (p) equal to 12.5, 25.0 and 37.5 MPa. In the true triaxial compression tests the minimum principal stress (s3) was equal to 25.0 MPa and the intermediate principal stress (s2) was 1.5, 2 and 2.5 times higher than s3. Results of the studies show that confining pressure strongly inhibited dilatant behavior of rock samples tested under conventional triaxial compression conditions; the increasing confinement resulted in the growing compaction of the rock material. The effect of dilatancy was also highly suppressed by the intermediate principal stress. While important dilatant, negative volumetric strain corresponded to the peak differential stress at low intermediate principal stress conditions, at high intermediate stresses the rock material was damaged to much lesser extent. As a result, faulting of rock samples in the post-peak region was much more violent and was accompanied by a strong acoustic effect. Les échantillons parallélépipédiques du grès à grains moyens de la mine ‘Slask’ (Bassin Houiller de Haute Silésie, Pologne) ont subi les essais de compression monoaxiale (compression simple), de compression triaxiale conventionnelle (compression triaxale de révolution) et de compression triaxiale vraie. Les essais de la compression triaxiale conventionnelle ont été effectués à la pression de confinement de 12,5, 25,0 et 37,5 MPa. Dans les essais de compression triaxiale vraie la contrainte principale minimale (s3) était de 25,0 MPa et la contrainte principale intermédiaire (s2) était 1,5, 2 et 2,5 fois supérieure de s3. Il résulte des essais que la pression de confinement inhibe fortement le processus de dilatance dans les échantillons testés dans les conditions de compression triaxiale conventionnelle; l’augmentation de la pression provoquait l’augmentation du compactage du matériau rocheux. Le phénomène de dilatance était également limité de façon significative par la contrainte principale intermédiaire. Alors que l’importante déformation volumique négative correspondait à la contrainte différentielle ultime avec les faibles contraintes principales intermédiaires, dans les conditions de fortes contraintes intermédiaires, le matériau rocheux subissait l&apos;endommagement de façon beaucoup moins importante. En résultat, la rupture des échantillons rocheux au stade post-maximum était beaucoup plus violente et accompagnée d’un fort effet acoustique. Prismatische Probekörper des mittelkörnigen Sandsteines aus dem Bergwerk ‘Slask’ (das Oberschlesische Kohlengebiet, Polen) wurden unter der einaxialen Druckbeanspruchung, konventionellen dreiaxialen Druckbeanspruchung und der echten dreiaxialen Druckbeanspruchung geprüft. Konventionelle dreiaxiale Druckversuche wurden bei dem Manteldruck von 12,5 25,0 und 37,5 MPa durchgeführt. Bei den echten dreiaxialen Druckversuchen betrug die kleinste Hauptspannung (s3) 25,0 MPa und mittlere Hauptspannung (s2) war 1,5-, 2- und 2,5-mal höher als s3. Aus den durchgeführten Versuchen ergibt sich, dass der Manteldruck die Dilatanzentwicklung bei den Probekörpern unter der konventionellen dreiaxialen Druckbeanspruchung stark bremst; die Erhöhung des Druckes rief die ansteigende Kompaktion des Gesteinsmaterials hervor. Die Dilatanz wurde auch durch die mittlere Hauptspannung beschränkt. Während die wesentlichen volumetrischen, dilatanten Verformungen der Grenzdifferenzspannung bei den niedrigen mittleren Hauptspannungen entsprachen, bei den hohen mittleren Hauptspannungen wurde das Gesteinsmaterial viel weniger beschädigt. Im Ergebnis war der Scherbruch der Gesteinsproben im Post-Peak-Bereich viel heftiger und mit kräftigen akustischen Effekten verbunden.

Jan 1, 2003

By K Bojarska

Examination of wastes aimed at evaluation of their usefulness for utilisation needs applying modern chemical testing methods. The XRD-XRF-ICP-GC/MS set of test methods constitutes an integrated testing system enabling ecochemical examination of wastes. As far as the problem of time-consuming operations is concerned, the offered system fits in a market-oriented field of activity of accredited chemical laboratories. Within a reasonable period of time, it allows to obtain information about mineralogical and chemical properties of wastes. It provides full range of information beginning from mineral composition (XRD) through chemical composition including the number of elements and organic compounds (XRF-ICP-GC/MS) up to the contents relating to the amounts of ingredients, both organic and inorganic in the leaching tests (ICP-GC/MS). The XRD-XRF-ICP-GC/MS testing system proves to be of particular importance in obtaining reliable results enabling to perform precise assessment (from ecochemical point of view) of wastes to evaluate their usefulness for utilisation in building materials, in civil engineering and reclamation works.

Jan 1, 2003

By L S. Barbour, M K. Meiers

Soil covers for mine waste are subject to changes in structure as a result of root development, and wet/dry or freeze/thaw cycling. The purpose of this study was to evaluate the changes in the hydraulic conductivity of three non-compacted clay covers over time. The covers are located on a sodic/saline overburden fill (30-Dump) at the Syncrude oilsands mine in Fort MacMurray, Alberta, Canada. Monitoring of these covers for temperature, matric suction, and water content by the University of Saskatchewan has been ongoing for more than three years. The three covers (D1, D2, and D3) were constructed in 1999 and are 50 cm, 35 cm, and 100 cm thick. The covers are comprised of a surface layer of reclaimed peat/mineral mix over a secondary reclaimed mineral soil (glacial till or glaciolacustrine clay), placed over a sloping shale surface. Field measurements of hydraulic conductivity within the secondary layer were obtained using a Guelph Permeameter during the 2000, 2001, and 2002 summer field seasons. Repeated measurements were made within the D1, D2, and D3 covers at depths of approximately 40 cm, 30 cm, and 60 cm, respectively. The values of hydraulic conductivity for the covers were similar to each other during each of the field study seasons. The mean hydraulic conductivity of the secondary layer increased every year: 2.5 + 10-6 cm/sec to 2.1 + 10-4 cm/sec to 4.3 + 10-4 cm/sec from 2000 to 2001 to 2002. Soil temperature data shows that one freeze/thaw cycle occurred each year at the measurement depths.

Jan 1, 2003

By William R. Yernberg

The combined 76th Annual Minnesota Section of SME meeting and 64th Annual University of Minnesota Mining Symposium were held April 8and 9, 2003, in Duluth, MN. This year’s theme was “Stakeholders, Partners in Change.” The meeting included four keynote speakers, technical presentations and a tradeshow. Engineers, executives, mining managers and suppliers from throughout the United States and eastern Canada attended the meeting. Reflecting the theme of the meeting, all agreed that the mine owners, the government, the community and the employees are all “stakeholders.” They must be “partners in change” for the iron ore mining industry to survive in the region. Compared with past meetings, where improved technology was the primary focus, this year the focus was on the dramatic restructuring of the entire industry. As noted by several of the speakers, “This time, the change is not in technology.”

Jan 1, 2003

By Andy J. Robinson, Mark D. Claassen

Railroad companies and transit authorities have been slow to acknowledge that for many—utility crossings, a direct pipe installation below live rail can be just as effective as a more intrusive traditional cased crossing. Properly designed and specified pipe jacking work, and specifically pressure-balanced microtunneling, coupled with careful specification and analysis of geotechnical monitoring and, where necessary, ground improvement measures, can produce a low-risk, low ground movement solution to the needs of utility companies and municipalities whose services need to pass below urban and rural rail corridors. This paper discusses the design, geotechnical and ground improvement aspects of microtunnel crossings below active heavy and light rail lines and crossings beneath active subway tunnels.

Jan 1, 2003

By Tsutomu Yamamura

The electrolytic reduction mechanism of rare-earth chlorides such as LaCl3, CeCl3, NdCl3, ` SmCl3 and DyCl3 in alkali chloride baths has been investigated in NaCl, KCI and eutectic LiCI- KCI by means of electrochemical transient methods. The thermodynamic behaviors of rare-earth containing species have been discussed in the frame of Electrode potential - P02- diagram. Low current efficiency found in the case of Nd electro-winning has been attributed to the dissolution of Nd into the bath. The analyses of electrochemical measurement required the elucidation of the effects of the factors such as under-potential deposition, metal dissolution, moisture and oxygen partial pressure.

Jan 1, 2003