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By G. Lissens

In this work the electrochemical combustion of dissolved organic species in a single compartment cell containing a titanium mesh cathode and a boron doped diamond anode has been studied, The organic molecules involved were complexing agents such as EDTA (ethylenediaminetetraacetic acid) or NTA (nitrilotriacetic acid) used in metal plating shops and bright nickel plating bath additives, From batch experiments, it is shown that complete decomplexing of EDTA and NIA is feasible. Complete TOC (Total Organic Carbon) removal from solutions containing 0.01 M EDTA, 0.02 M NTA and bright nickel plating bath additives could also be achieved. Recycling experiments show that decomplexing of EDTA and NTA solutions can be obtained at an average electrical energy input of ~20kWh.kg-1 of complexing agent. Decomplexing rates of respectively 3.l3 mmol.Ah-1 for EDTA and NTA have been obtained, The Instantaneous Current Efficiency (ICE) was 71% for EDTA and 95% by NTA, Simultaneous recovery of Cu from a 0.01 M Cu-EDTA solution has also been evaluated. A solution (1.8 dm3) containing 0.01 M EDTA and 528 ppm of Cu was treated in a single compartment cell at a current density of 2 A.dm-2. 73% of the TOC could be removed and a final copper concentration of 8 ppm was obtained.

Jan 1, 2003

By Adrian Moore, John Wilson, Alan Richards, Emad Gad

Project C9040 – ‘Structure Response to Blast Vibration’, funded by the Australian Coal Association Research Program (ACARP), involved the investigation of the structural response from blast vibration of three houses of brick veneer construction subject to a wide range of ground vibration levels. This paper summarises the findings of a house subject to vibration levels up to 220 mm/s (8.7 in/s). Damage attributable to blast vibration was not observed until vibration levels exceeded 70 mm/s (2.8 in/s).

Jan 1, 2003

By Frank Cappuccitti, Stephen Chryssoulis, Stamen Dimov

Surface organic microanalysis of platinum (Pt) and palladium (Pd) minerals by TOF MS1 is an attractive complement and potential alternative to conventional collector screening methods. Its attractiveness lies on its ability to focus on individual Pt and Pd mineral particulates, therefore providing a more targeted approach. The only requirement is knowledge of the occurrence (mineral composition, grain size and association) of Pt/Pd in the feed sample. This newly developed technique can detect, and identify collectors and quantitate loadings on individual Pt/Pd mineral particulates at plant concentration levels. Using this technology, collector loadings were measured on Pt and Pd metal plates and on PtS2 and PdS particulates which had been exposed together to aqueous solutions of different collectors. Thus, data were obtained on collector selectivity, the effect of sulphur; and of depressants, the latter in combination with TOF-LIMS2 results. Staged rougher tests on North American and UG-2 ores linked Pt/Pd flotation kinetics with collector loadings and ultimately grade/recovery.

Jan 1, 2003

Since the early 1990s it has been evident that electricity demand has outstripped investment in generation and transmission. At the same time, concerns were being expressed about the risks associated with the run down of the Maui gas field. It is axiomatic that the necessary investments firstly require a stable and supportive regulatory and fiscal environment, and secondly that such investments have long lead times. A unwillingness by successive Governments to fund the necessary infrastructure, however, lead to the profound restructuring of the electricity with the ultimate objective of transferring the investment risk from Government to the private sector. Successive power crises since 1992 result from a failure to put in place a regulatory framework necessary to provide the environment to allow the private sector to make the needed investments within the necessary timeframe. The electricity sector has now stabilised to the extent that the regulatory risks associated with generation investment have been reduced. This does not mean that risk has been eliminated, however, and both economic and environmental issues will continue to constrain investment in some power proposals particularly those in the South Island and especially any South Island coal or gas thermal proposal. This is firstly because of several very simple economic issues:  1. while the South Island may have significant coal resources it lacks a significant electricity market; 2. except for a six to ten week period in a dry year, low cost hydro will price any large-scale South Island thermal out of the market which will restrict any large scale thermal station to a dry year and/or peaking load; 3. except for a six to ten week period in a dry year, export capacity on the HVDC link to the North Island is constrained to around 964 MWe (and 482 MWe from North to South in dry years); and 4. construction of any new thermal plant in the northern half of the North Island will price any South Island thermal station out of the market. There are also significant environmental issues associated with the establishment of a large scale thermally based power station in the South Island. Because the South Island lacks any large scale economically proven gas reserves, the environmental constraints considered are those associated with coal production. A coal mine dedicated to power generation will have significant on-site impacts associated, in particular those associated with disposal of opencast overburden and visual impacts. These will, however, be partially offset by the relative remoteness of such sites to population centres. What cannot be offset, however, is the off-site impacts, in particular, CO2, SOx and NOx emissions, water disposal and acid mine drainage.

Jan 1, 2003

By W. H. Langer

Natural aggregate is the number one non-energy mineral resource in terms of value and volume and is a necessary commodity for sustainable communities. While aggregate is a non-renewable resource, supplies are nearly inexhaustible on a global scale. Natural aggregates have characteristics that differentiate them from most other mineral commodities: a high number of potential extraction sites, a high volume to value ratio, significantly different set of potential environmental impacts, and regional importance combined with a narrow economic transportation radius. Because of these and other differences, resource management policies for aggregates should differ from ?general? mineral resource policies, even though the end goal is the same for both ? ensuring sustainable resource management. To achieve the goals of sustainable aggregate management each stakeholder ? government, industry, the public, and non-governmental organizations ? will need to accept certain responsibilities, one of the most important of which is to become informed about natural resource issues. Sustainability is about making trade offs among competing objectives, and people disagree about the appropriate balance among the goals of economic prosperity, social equity, and environmental health. One of the primary purposes of mineral indicators is to provide information to decision makers and the public so as to ensure that the public debate about policy choices is grounded in fact. We identify the unique aspects of aggregate resource management and introduce the concepts of sustainable mineral resource management. We then present mineral indicator sets for aggregate resources from Italy, the United Kingdom, and Slovenia to demonstrate that effective mineral indicators should be specific to the resource in question and the public values and objectives.

Jan 1, 2003

By Thomas Barkley

Recent developments in hardware and software have made accurate measurement of Underground Face (Development) Drilling a reality. New and compact laser profiling equipment makes it possible to measure drilled material left on the face as well as the actual tracks of the holes drilled in the rounds. Utilization of these available technologies makes it possible to correctly define the drilling accuracy and the blasting pull. Through the use of actual face round measurements, I will show the level of definition and amount of information that can be collected.

Jan 1, 2003

Based on experimental and computer simulation results from our group, we report a systematic, atomic level analysis of carbon dissolution from carbonaceous materials in molten iron. Experimental results on graphite/Fe-C-S system were obtained using carbon dissolution studies, XRD and FESEM investigations and were supplemented with Monte Carlo simulations. Three basic mechanisms, namely carbon atom dissociation rate, interfacial phenomena and mass transfer in the melt were found to be responsible for the overall dissolution process. While mass transfer in the melt is governed by the concentration gradients, melt composition and temperature; impurities present in ash play a significant role in the interfacial phenomena. For less ordered forms of carbonaceous materials, carbon atom dissociation rate depends strongly on the degree of long-range order and is an important rate controlling mechanism in the overall dissolution process. A systematic comparison of dissolution rates for a variety of coal-chars, natural and synthetic graphites has been carried out in an attempt to identify rate-controlling mechanisms. The structure of the carbonaceous material appears to be an important underlying factor in the carbon dissolution process.

Jan 1, 2003

By Yi Luo

The potential influences of mining subsidence on structural stability, integrity and functionality of guyed tower structures have not been systematically studied before. This paper presents a ease study where a guyed steel tower of a telecommunication company was mined under by a longwall operation. Prior to mining, every aspect of the subsidence influences to this structure was studied. The pre-mining assessment indicated that the structure could experience vibration problem in the second half of the dynamic subsidence process. Bawd on the study, a simple mitigation measure was recommended and implemented and the structure was successfully protected.

Jan 1, 2003

By M. Özer, G. Önal, F. Arslan

"The use of ultrasonic in industrial processes has increased during the last few years. Ultrasonic vibrations are used in sieving, grinding, ore washing, cleaning, and flotation in mineral industry. There are also some attempts for the utilization of ultrasonic treatment in separation and removal of fine particles from gases and liquids. In Kalemaden A.S. (Turkey) four different types of clay mixtures (1. A mixture of clays from Balikesir-Düvertepe and Istanbul-Sile, 2. A mixture of clays from Ukrania and Balikesir-Düvertepe, 3. Sögüt-Kadikelimesi, 4. A mixture of clays from Sögüt and Istanbul-Sile) and kaolin from Balikesir-Düvertepe (Turkey) are concentrated before their use in ceramic production. Dewatering is the important step in those types of concentration plants. Sedimentation of concentrated clay has always been difficult and taken long times due to their nature and having small particle sizes. Flocculants can be used to enhance the sedimentation, but they are not preferred by the ceramic industry since they affect the quality of ceramic products. For this purpose, ultrasonic treatment is used in the sedimentation of clays mentioned above for solving the problems encountered related to the ceramic industry and promising results were obtained.Kaolin sample, subjected to this experimental study, from Balikesir-Düvertepe region of Turkey was brought from the plant as a pulp in containers and throughly mixed with a stirrer before sedimentation experiments. A two liter graduated cylinder and an ultrasonic bath (with 25 kHz frequency and 0.5 KW power) were utilized in the tests. Superfloc A-120 (1% concentration) was used as a flocculant. The settling distance was reported against the settling time during the experiments. Initial and final pulp densities were also determined. The effects of several parameters such as pulp density, flocculant addition, and ultrasonic treatment on the sedimentation of kaolin were investigated and the results are represented in terms of settling distance versus settling time."

Jan 1, 2003

By Wieslaw Wszolek, Kazimierz Trybalski, Ryszard Tadeusiewicz

"The present work is an attempt of neural networks application to the description of complex technological processes of useful minerals enrichment. Neural networks are among the most convenient tools that have been added recently to the professional toolbox of modelling specialists, and they are particularly useful in realisation of multiple practical tasks, characterised by great complexity and relatively low amount of available a priori knowledge about the nature of the modelled processes. They are successfully applied in a wide variety of problems related to data processing and analysis, their prediction, classification or process control. The object of the study was the technological site for copper ore enrichment by floatation, being a part of technological line in the Ore Enrichment Plant ZG „Polkowice”, KGHM „Polska Miedz” S.A.The main floatation is described by parameters measured by the supervision and control system, which can be grouped with respect to the functions performed for the object:a) input function: aFG - copper contents in the feed material for the main floatation [% Cu]b) control: LFG I - level in the first section of the floatation unit [%], LFG II - level in the second section of the flotation unit [%], LFG III - level in the third section of the floatation unit [%], LFG IV - level in the fourth section of the floatation machine [%]. These quantities compose the five elements long input vector.c) output function: ? - copper contents in the waste from main flotation (final waste) [% Cu]The measurement data, containing the above-mentioned parameters, have been collected during the normal operation of the plant. The data contain momentary values of the parameters, registered every 10 minutes, covering the period of 196 hours of the plant’s operation (1176 measurements for each quantity).For construction of the model used in the study classical multi-layer perceptron-type neural network has been used, with one hidden neuron layer, trained by the error back propagation method."

Jan 1, 2003

By J. D. Miller, C. L. Lin

The appropriate software and hardware necessary to adapt an X-ray CT analyzer for the determination of coal washability was developed and successfully tested for well-characterized samples under laboratory conditions. Evaluation of the CT-based analyzer under simulated on-line conditions is also presented to verify the on-line capabilities of the newly developed X-ray CT analyzer for the control of coarse coal cleaning circuits. The investigation shows that the data obtained from CT washability analyses compare favorably with experimental sink float data. Further, image frequency was considered to evaluate the CT-Based coal washability analyzer for simulated on-line conditions. Specifically, the number of observations (image spacing) needed for accurate sampling and the total time required to perform the calculations for a representative data set were determined. Key words: Coal washability, Computer simulation, X-ray CT analysis

Jan 1, 2003

By Sharif Jahanshahi

Calcium ferrite slags are often associated with Professor Yazawa due to his pioneering work on the thermodynamics of this type of melts. Over the past years CSIRO has invested some effort in studying physico-chemical properties of such melts to fill in some gaps in our knowledge and explore opportunities for application of the understanding developed. These investigations cover thermodynamics, transport properties of calcium ferrite based slags, as well as the kinetics of reactions of such slags with refractories. The present paper provides an overview of some of these studies and highlights some of the interesting behavior of such melts. The oxidation state of copper and arsenic in calcium ferrite based slags are predominantly Cu+ and As3+, respectively, at oxygen potentials below 10.1 atm. The concentration ofCu2+ in such slags becomes significant at oxygen potentials of greater than 10'1 atm at 1300 ?C. The activities of CuOo.s and AsOl.S in calcium ferrite slags show strong deviations from the Raoultian Law, while that of CoO is very close to ideal behaviour with respect to pure solid CoO. Addition of Si02 to calcium ferrite slags can have significant effects on the activities of FeO and Fe2O3 and hence the stability of magnetite phase. Transfer of oxygen in calcium ferrite slags is fast with diffusivity of 2xlO?3 cm2/s at 1350 °C and activation energy of 16 kcal/mol Presence of solid phases, such as magnetite, has pronounced effect on the viscosity of calcium ferrite slags. The observed dependence on solid loading and shear rate indicates deviation from Newtonian behaviour. The interfacial tension between copper mattes and calcium ferrite slags is strongly dependent on the matte grade, with the determined values being much lower than the corresponding ones for interfacial tension between similar mattes and iron silicate slags. MgO, Cr2O3 and MgCr2O4 have low solubility in calcium ferrite slags and their solubility increases with increasing copper oxide content of the slag at 1300 °c. The oxidation state of the slag has strong effects on phase transformation, dissolution rate and disintegration of refractories in calcium ferrite slags. Other key factors with major impact on slag-refractory interactions include viscosity and surface tension of slags as well as the contact angle between slag and refractory material.

Jan 1, 2003

By David G. Hulbert, Daniël J. Oosthuizen, Bernard Muller, Daniël de V. van der Spuy

"OVERVIEWExpert Online is a software system that aims to mimic an informed expert on a minerals processing plant. The primary objective of Expert Online is to provide operators with effective training and on-the-job assistance. Training will mostly be done off-line (e.g. using simulators of the plant), while on-the-job assistance will help the operator during normal operation to run the plant in an effective manner. Although Expert Online focuses on the operator, it is expected to also be of value to other plant personnel, including supervisors and plant managers.Expert Online will make use of novel artificial intelligence technology (developed by MINTEK) known as the Interpreting Expert System (IES). Previously the IES was only able to explain the actions taken by the controller. Expert Online will extend this functionality to also take the process dynamics into account.Expert Online is being developed by a South African consortium comprising MINTEK (focusing on the research and development of the system as a whole), Lonmin (globally one of the biggest platinum producers, with plants suitable to test Expert Online on) and the University of Natal (academic partner, providing consultation and focusing on complex process modelling). The initial application of Expert Online will be on milling- and flotation plants.This paper discusses the structural design of Expert Online for implementation on the latest version of MINTEK’s open control platform, PlantStar, as well as several advances and additions since the previous implementations of the Interpreting Expert System."

Jan 1, 2003

By Carin Laubscher, Francis W. Petersen, Jaap P. Smit

"Waste streams, such as acid mine drainage, are often characterised by low pH values and high concentrations of heavy metals, dissolved solids, calcium and sulphates. Although lime remediation effectively removes most of the heavy metals as hydroxides, it is less effective at lowering levels of sulphates. Various methods of removing sulphates from effluents exist, such as precipitation with lime, precipitation with barium salts, co-precipitation with calcium carbonate, reverse osmosis, and ion exchange. Mintek developed a chemical precipitation (SAVMIN) process to treat acid mine drainage, which entails the addition of lime to precipitate the metal hydroxides, and the subsequent formation (precipitation) of calcium sulphoaluminate or ettringite. The key to the viability of the new technology lies in the correct use, regeneration and recycling of Al(OH)3 used to precipitate the ettringite. The water produced by this process is suitable for disposal to watercourses or for agricultural, domestic or industrial consumption. No brines are produced as the salts are converted to solid hydroxides, gypsum and calcium carbonate.The SAVMIN process has been tested successfully during several laboratory scale operations, and during two pilot plant operations at Stilfontein Goldmine for Anglogold and Navigation Plant, Witbank for Anglocoal. During the pilot plant campaign at Navigation Plant, metal and mineral precipitation was achieved with lime addition. The sulphate concentration in the water was reduced from 2136 mg/L to an average value of 102 mg/L and the calcium concentration was reduced from 727 mg/L to an average value of 70mg/L.The SAVMIN process generates a number of different waste streams including metal hydroxide sludge from neutralisation, gypsum sludge from the gypsum crystallisation steps, and calcite sludge from carbonation. The metal hydroxide sludge is composed of Mg, Ca, Mn and Fe hydroxide, and could be disposed of on a slimes dam. Gypsum sludge was greater than 99% CaSO4.2H2O. This gypsum could be used for dump or road capping, underground backfilling, production of wallboard and cement. The calcite sludge is pure CaCO3, which is recycled back to the neutralisation stage."

Jan 1, 2003

By E M. Rykaart

The design of soil covers as part of the remediation initiatives for mine waste facilities is common practice and more and more engineers are faced with designing these facilities. The design issues associated with these soil covers are complex and requires a good understanding of unsaturated flow. More engineers are making use of numerical models to predict how cover designs would perform, and this has been necessitated by the high non-linearity associated with solving unsaturated flow problems. There are numerous numerical models available to the prospective users and they are all simplifications of reality using different assumptions. The users of these models often do not understand the limitations of the models but rather select a model based on ease of use, and that lends to increasingly erroneous designs being proposed for construction. This paper describes a comparative evaluation of a cover design using four different codes available today; SoilCover, SWIM, HYDRUS-2D and HELP. The paper does not propose to measure these codes up against each other and make statements about which is better than the other but rather illustrates how the assumptions in each code affect the outcome. The data set used for the comparative study is a well calibrated data set that that has been collected over a long period in time and that has been collected according to strict controls. The authors present the pitfalls of numerical modelling of the surface flux boundary conditions, as well as present guidelines towards appropriate use of these modelling tools.

Jan 1, 2003

By Robert E. Mazurak

Mines and plants for sale, downsizing, bankruptcies, consolidation, slab imports, minimill growth displacing traditional integrated steel-making. These are some issues for North American iron ore and integrated steel producers. But the blast furnace still remains the workhorse of the ironmaking industry. And direct reduction and other alternate ironmaking technologies have yet to make any serious inroads in North America. How come? This article addresses the current state of primary ironmaking in the changing North American steel industry, the direct reduction market and new technologies under development that may hold some promise.

Jan 1, 2003

By S. Ersayin, I. Iwasaki

The application of a magnetic field was shown to be effective in controlling iron losses in a pilot-scale cationic silica fIotation in the processing of magnetic taconite concentrates. The design of a magnetic field distribution device and batch flotation test results using a 1.42-m3 (50 cu ft) WEMCO flotation cell are reported. Major losses of iron units in froth products were in the -25-µm (-500-mesh) fraction, and the application of a magnetic field decreased the flotation of fine magnetite, thereby improving the selectivity of separation. The "as-received" sample was sufficiently magnetized, and no further benefit was gained by the magnetizing treatment. The selectivity was somewhat adversely affected by demagnetizing the sample, though its effect was minimal due to the magnetic field. The device is simple in construction, low cost and may be readily installed in existing equipment. Key words: Iron ore, Flotation, Taconite concentrates, Cationic silica flotation, Magnetic field, Flexible magnetic sheet, Magnetizing, Demagnetizing

Jan 1, 2003

Effective strata control, utilising fully encapsulated roof bolts, is dependent on the installed quality of the reinforcement elements. One mechanism by which fully encapsulated roof bolts may become less than fully effective is by gloving (glove fingering) and un-mixing of the resin. Following some small roof failures containing gloved bolts, investigations have been undertaken in some New Zealand coal mines to determine the extent of, and mechanisms involved in, the gloving of fully encapsulated roof bolts for a range of roof types and installation methods. Gloving, in this context, refers to the resin cartridge partially or completely enveloping a length of the bolt, typically with unmixed resin filler and catalyst/hardener remaining within the cartridge. Results have shown that gloving and un-mixing is a systematic and widespread phenomena, occurring across a range of resin and/or bolt manufacturers, and across a variety of roof types. Gloving was found in bolts installed using: hand held pneumatic and continuous miner mounted hydraulic methods, under run of mine (ROM) conditions by mine workers, and under controlled "best practice" conditions. The roofs bolts investigated are all 1800mm (6ft) long, and have shown that, on average, 485mm (-19") of the bolt length is gloved and/or unmixed. This equates to a 27 percent reduction in effective bolt length. The effected length of bolt is sufficient to impact on the load transfer/reinforcement capabilities of the bolt system, and hence impacts on the design assumptions and subsequent stability assessments. Furthermore, there is a direct relationship between the mechanism for the gloving of bolts and an increased occurrence of resin loss and reduction in encapsulations length in soft (less than 10 MPa) and/or highly fractured rock. Investigations have concentrated on developing an understanding of the mechanisms involved. This has been undertaken using both field installations and recovered bolts, as well as test bench trials. The mechanisms involved have been confirmed as being: the development of a pressure front as the bolt encounters the resin and is spun up the hole, which, in turn, leads to over-pressurisation and radial expansion of the resin cartridge, resulting in an increase in diameter of the plastic resin cartridge, which allows the bolt to be spun up into the cartridge without making sufficient contact to shred the cartridge or the hardener tube, resulting in an unmixed portion of resin.

Jan 1, 2003

By P Barrette

The manual gravimetric drying moisture determination methods currently employed by most mineral processing plants fail to provide timely and accurate information required for automatic control. The costs associated with transporting and handling concentrates represent a major portion of the overall treatment price. When considering the cash flow of a mining operation that is governed by both the smelter contract, with moisture penalties and the quantity and quality of the concentrates shipped, any tool that provides real-time feedback on the process is vital (Edwards, RP 1994). The introduction of an on-line moisture sensor would become a welcome addition to the process control field instrumentation package now applied. A novel on-line determination system for ore concentrate moisture content would replace the tedious manual procedure. Since the introduction of microelectronic-based control systems, operators have strived to reduce the treatment costs to the minimum. Therefore a representative and timely determination of on-line moisture content becomes vital for control set points and timely feedback. Reliable sensors have long been on the æwish listÆ of mineral processors since the problem has always been that you can only control what you can measure, (Konigsmann, 1990). Today, the task of moisture determination is still done by the classical technique of loss in weight utilising uncontrolled procedures. These same methods were introduced in the earliest base metal concentrators. Generally, it is acceptable to have ore concentrate moisture content vary within a range of seven to nine percent, but controlling the moisture content below eight percent is a difficult task with a manually controlled system. Many times, delays in manually achieving reliable feedback of the moisture content results in the moisture varying from five to twelve percent before corrective actions can be made. This paper first reviews the traditional and widely available methods for determining moisture content in granular materials by applying physical principals and properties to measure moisture content. All methods are in some form affected when employed on mineral ore concentrates. This paper introduces and describes a unique and promising novel on-line moisture sensor employed for mineral processing de-watering applications, which not only automates the tedious tasks but also results in reliable moisture feedback that can be used in the optimisation of the de-watering process equipment such as pressure or vacuum filters and fuel-fired driers. Finally, two measurement applications will be presented to indicate the usefulness and to summarise the measurement requirements for the proposed method of employing drag force and mechanical properties of the material itself to determine the moisture content. The commercial model of the equipment is described with the features and benefits to the users summarised.

Jan 1, 2003

By P. C. Thakur

The history of coal mining in the United States of America and the rest of the world is replete with mine explosions and consequent loss of lives. Serious efforts in the USA to recover methane prior to mining and post mining started about forty years ago. CONSOL Energy Inc. and government agencies, e.g., the erstwhile US Bureau of Mines developed several techniques of methane drainage, such as in-mine horizontal drilling, vertical gob wells, hydrofracing of vertical wells and horizontal drilling from surface. With the current technology, thirty to sixty percent of total methane emissions from a mine can be captured making the mines much safer and more productive. Drained methane is often marketed to defray the cost of methane drainage. This paper is an anthology of these developments and describes how coalbed methane, which used to be a bane, has become a boon for the coalmining industry.

Jan 1, 2003