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By Jaeheon Lee

Gold-copper alloys are shown to form during the cementation of gold on copper in a solution containing 0.25M [S2O32-] at 25oC. The alloy composition is strongly dependent on the initial Cu:Au ratio in solution and ranges from Au3Cu to AuCu3. XPS results for Au, Cu, S, and O are reported as a function of depth through an entire deposited film with an initial solution containing 20 ppm [Au] and 30 ppm [Cu]. The deposit contained about 20 atomic % gold and was predominantly Cu3Au. Underpotential deposition (UPD) theory is discussed as a mechanism for explaining the formation of these alloys. Several other systems that produce alloys during contact reduction/cementation are also discussed.

Jan 1, 2003

The history of soft and hard rock underground mining is blemished with regional instabilities of mine workings. Whilst the potential consequences of regional instability events are recognised to be high, there is a false perception that the probability of them occurring is very low. In fact, Australia has averaged more than one event per year for the past 20 years. At least five fatalities and over $100 million of losses have been associated with the events. As such, they are a core risk to underground mining and have a significant effect on the quadruple bottom line of business û safety, environment, community acceptance and economics. This paper explores the important roles that risk management has in reducing the probability and consequences of regional instabilities. It concludes that education and continuing professional development are essential elements for effectively managing the risk.

Jan 1, 2003

By Richard W. Kimball, Fred B. Estep, Dwayne E. Easterling

This paper discusses the overall challenges to construct a 15,125.7 m (49,625 LF),wastewater drainage tunnel in Cobb County, Georgia by a joint venture of Gilbert Southern Corp. and S.A. Healy Co. and a construction manager Parsons, with Jacobs Associates as a subcontractor. The goal of the project is to provide wastewater retention during peak usage and is connected to a treatment facility near the Chattahoochee River. The primary component of the project is the TBM-driven hard rock tunnel. Additional works include drill and blast areas; four intake interceptors, two construction shafts and a 33.5 m (110 ft), diameter pump station shaft.

Jan 1, 2003

By John A. Herbst, Alexander Potapov, Xiangjun Qiu

"High Fidelity Simulation is a name applied to the use of first principles modeling tools including Discrete Element Modeling (DEM), Computational Fluid Dynamics (CFD) and Discrete Grain Breakage (DGB) to mathematically describe and study processing systems. Over the past few years, significant advances have been made in High Fidelity Simulation applications, particularly as many mineral processors have been drawn to the study and use of DEM of grinding mills for optimization purposes. This presentation provides an introduction to High Fidelity Simulation, with an emphasis on DEM. It will include insights into current applications of these tools including the optimal design (wear and throughput) of mill lining systems and media selection, the analysis and design (flow and efficiency) of the back-end of grate discharge mills. Advantages of full mill simulations versus individual sub-process simulations will be demonstrated for a SAG mill with different discharge system designs.INTRODUCTIONHigh Fidelity Simulation is providing mineral processors with the opportunity to analyze the behavior of mineral processing equipment from a fundamental or microscale point of view. In the past complex phenomena such as tumbling mill grinding had to be analyzed using black box tools such as residence time distributions for transport and classification functions for passage of particles through grates; while breakage had to be analyzed using PBM models who derived their form from theory but required direct measurement of kinetics. Today with the help of DEM, CFD and DGB these can be analyzed at a very fundamental level.The key element of DEM simulation is the application of Newton’s laws of motion to individual objects or discrete elements. Using this simulation method one can describe the position, velocity (both translational and rotational) of all objects and the transfer of momentum to other objects (Mishra and Rajamani, 1992; Cleary, 1998; Nordell et al, 2001)."

Jan 1, 2003

By F. Ma, F. Yang, T. Zhao, P. Dai, Z. Shao, D. Zuo

With the development of modern digital technique, computers have been widely used to monitor and control in retrofitting traditional industries. In Chinese coal industry, some analog monitoring and control systems have been replaced by the modern computer digital systems. According to the development status of Chinese coal industry, this paper presents some technique and its applications of modern digital computer monitoring and control for safety mining production process. The technique has been used in the full digital monitoring and automation control for hoists, coal mining machines, belt transport machines, and whole coal mining production process. With the technique, it has been achieved the better economical and social benefits in safety mining production in China.

Jan 1, 2003

By Douglas Morrison

By applying modern 3D numerical modelling techniques to the analysis of a pillar cascade failure in a room and pillar mine, it has been possible to simulate the collapse and develop an understanding of the role of low rock strength areas within the mine. The cascade collapse occurred in a normal strength area but would not have occurred without the influence of a low strength rockmass in one section of the mine. The numerical analysis made it possible to develop a realistic assessment of the residual pillar strength. With the introduction of regular empirical pillar performance assessments, critical pillars or groups of pillars can now be identified proactively. This has led to an aggressive extraction ratio of 90% that manages pillar failure, avoids pillar and roof collapse and prevents surface subsidence. Since the mine also has significant waste products, the use of backfill for ground support has made it possible to significantly improve the performance of strategically located pillars, and so achieve even higher extraction ratios.

Jan 1, 2003

By Kari Moen, John Rasmus Leinum, Jarle Hjelen, Terje Malvik

"Industrial minerals may contain the same elements in approximately the same amount. In these cases backscatter electron imaging or chemical analysis are not sufficient to identify the minerals. Another problem arises when micro textures are not detectable in traditional imaging or the grain size is smaller than the X-ray spatial resolution.As a supplementary technique in these cases, application of crystallographic information by electron backscatter diffraction (EBSD) in the scanning electron microscope (SEM) may be a suitable method. The technique has been demonstrated on three Norwegian mineral raw materials and one Italian marble and shows that it has some advantages compared to traditional techniques.• quantitative measurements by ebsdCommon automatic techniques describing the mineral contents and the occurrence of minerals in free and locked particles, are based on optical-, backscattered electron (BSE)- or X-ray-signals. There are various commercial software systems on feature analysis by backscattered and X-ray signals in combination with image analysis (e.g. Oxford Inca Feature, CSIRO QemScan).Especially in silicates, the occurrence of similar elements in the different minerals is common. Sometimes the various minerals not only contain the same elements, but also approximately the same amount of each element. In these cases BSE imaging and chemical analysis are not always sufficient for identification."

Jan 1, 2003

By B. Dias, P. C. Schutte

Work-related musculoskeletal disorders (WMSDs) affect the wellbeing of workers and result in poor quality work, lower work performance and decreased motivation. In contrast to ‘occupational’ diseases where there is a direct cause-and-effect relationship between hazard and disease (e.g., asbestos and asbestosis, lead and lead poisoning), ‘work-related’ diseases are multifactorial, where the work environment and the type of work that is performed contribute significantly to musculoskeletal disorders. WMSD is the term used to describe disorders and diseases of the musculoskeletal system (i.e. muscles, joints, ligaments, tendons and nerves). WMSDs are by definition a work-related phenomenon. The literature shows inarguably that certain jobs and certain work-related factors are associated with a significant risk of contracting a WMSD. It is assumed that repeated movements and postures, static work, continuous loading of the tissue structures or lack of recovery time, trigger or cause a pathological process that then manifests itself as a WMSD. This paper looks at the prevalence of the WMSD condition at three mines in South Africa: a coal, a gold and a platinum mine. Predisposing factors that include work factors, presentation of symptoms and psychological factors will be discussed in the paper.

Jan 1, 2003

By Fabio Amaya, Andrés Marulanda, Ramiro Gutiérrez, Alberto Marulanda

The behavior of a salt rock mass is strongly related to a creep phenomenon. The amount of creep depends on the level of stress generated in the underground excavation. Additionally, security conditions and the lifespan of an underground cavern excavated under this geological conditions depend on the evolution of creep. Based on the experience of the failure of the Old Underground Salt Cathedral of Zipaquirá(Colombia) and the construction of the new one, the theoretical framework to predict the creep behavior of a salt rock mass is explained. The theoretical formulations are calibrated based on actual observations of the material behavior to predict the lifespan of this striking structure.

Jan 1, 2003

By H. J. Glass

Collection, preparation, and analysis of blasthole chippings is expensive. Frequently, interpolation of grades at unsampled locations is considered using techniques like kriging. A pre-requisite for kriging is that an experimental variogram is established. In order to assess the quality of the experimental variogram, a measure is developed in this paper. The measure is derived from analysis of the time-honoured expression relating the variance, semivariance, and covariance. It reflects the weighted average deviation of the summed semivariance and covariance from the biased variance. The proposed measure allows assessment of the influence of key variables on the quality of the variogram. Using simulated data, it follows that the quality improves with an increasing number of samples, increasing density of the sampled locations, increasing regularity of the sampling pattern, and increasing uniformity of grades in the absence of correlation. Application to real data shows that the minimum number of samples could coincide with a marked decrease in the value of the measure. Establishing a threshold value is subject to further research. Keywords: variogram, variance, covariance, semivariance, minimization, sampling.

Jan 1, 2003

By Kazuteru Tozawa

Surface tension, density and viscosity coefficient of acidic copper sulfate solutions simulating electrolyte solution for electrolytic production of copper have been measured and are summarized as a function of the solution composition and temperature. Nickel sulfatc is taken to be a representative coexisting sulfate that affects the physical properties of the copper sulfate electrolyte solution. The sulfates in the solutions, including sulfuric acid, increase the physical properties under consideration. Gelatin, representing organic additives for electrolyte solution, was found to sensitively affect the surface tension of the solution at low concentration of up to 200mgIL. The surface tension was markedly lowered by the addition of gelatin and the increasing concentration of gelatin led to a more pronounced decrease in the observed values. The surface tension gradually increases with time after addition of gelatin and the increase is enhanced by higher acid concentration and higher temperature. The observed change in the surface tension is considered to reflect the preferential adsorption of gelatin to the bubble-solution interface and the decomposition of gelatin due to hydrolysis to form various molecules having smaller molecular weights.

Jan 1, 2003

By Jay Black

In the thiosulfate gold leaching process gold is oxidized to Au+ by a copper(II) ammine catalyst and complexed by thiosulfate. Copper(I) complexes, formed during gold oxidation, are reoxidised to Cu(II) complexes by oxygen. In this study, we present the results of a spectrophotometric study of the Cu(I)-NH3-Cl system, which follows on from our recent investigations of speciation in the Cu(I)-Cl and Cu(I)-S2O3-Cl systems and is part of a detailed study of copper(I) speciation associated with the gold leaching process. Formation constants for Cu(I)-NH3-Cl complexes have been determined by modeling the systematic changes in the UV spectra that occur as the concentration of the components is varied. The analysis of the data indicates that three Cu(I)-ammonia complexes are present, i.e., [Cu(NH3)2]+, [Cu(NH3)Cl2]- and [Cu(NH3)2Cl] and their respective log Kf values are 11.13, 8.33 and 10.79 at 25°C. Investigations of the oxidation of Cu(I)-NH3-Cl solutions by oxygen in the atmosphere are also presented. These experiments indicate that the reaction of copper(I) complexes progresses through various intermediates. The presence of many copper(I) and copper(II) complexes in ammonia thiosulfate solutions complicates the task of determining optimal conditions for gold leaching. Further studies are needed to identify the complexes and chemical processes that are important in the Cu(I)-NH3-S2O3-Cl system.

Jan 1, 2003

The placer gold industry has experienced a roller-coaster history incorporating four major boom eras. The first, 'hand-methods' boom arose in the mid-19th Century from application of an old idea in new places around the globe. The subsequent hydraulic mining, bucket dredging, and 'hydraulic excavator-portable plant' booms each arose from application of new ideas in old places around the globe, ie in places where gold had been found during earlier booms. The new ideas that heralded the second, third and fourth booms were all significant advances in excavation technology. These enabled the industry to target the known deposits that were too deep, too wet, too small, or too low-grade for recovery by earlier boom methods. Relatively few new deposits or new deposit styles arose from the 'history book' exploration approach, so the number of known deposits to which each of the boom methods were applicable was limited. Consequently, the first three booms were each followed by significant periods of industry decline, and the fourth boom is currently waning inNew Zealand. Further decline is not inevitable and can be avoided by changing to a knowledge-based exploration approach similar to that adopted by the hard rock gold industry in the 1970s. Such an approach could easily herald the next placer gold boom.   Most of the relatively coarse, easily won alluvial gold in proximal and medial reaches of the active placer systems is gone. However, a substantial alluvial gold resource remains in the distal reaches of active systems, and in ancient placers formed onshore and on the continental shelf during previous sedimentary cycles. The resource in these deposits probably exceeds the total New Zealand placer production to date. Successful development of these placers requires application of robust geologic models for the formation and distribution of the placers through time, and advanced exploration technology that has not been used before in New Zealand. Nevertheless, the knowledge and technology required to explore and mine these deposits is available now. Many of these deposits contain a large proportion of problematic gold types that are difficult to recover with the commonly used gravity technology without sustaining significant losses. Despite advances in recovery technology in last few years, too much emphasis is placed on the incorrect assumption that gold size is the primary control on recovery efficiency. Other gold particle parameters, especially particle shape, exert a much greater control on whether gold will be saved or lost to the tails, and must be considered in the design of recovery technology and configuration of recovery circuits.

Jan 1, 2003

By Florian Kongoli

The production of a homogeneous self-fluxing sinter is an important step in iron making processes. A good sinter should have good permeability and reducibility and has to keep those characteristics for a certain time. An early melt down of the sinter in the blast furnace, where its solid state reduction is essential, would cause many problems such as low permeability and reductibility. Nevertheless, the important factors that influence these characteristics, such as the chemistry of the sinter and the fluxing effect during sintering and sinter reduction conditions have not yet been clarified. In today's new reality where many new minor components such as Al2O3 and MgO enter to the sinter through raw materials, the quantification of the fluxing effects during sintering becomes even more important. In this work, the liquidus surface and phase relations of the sinter primary melts in the CaO-FeO-Fe203-Si02 system at sintering conditions have been quantified. The fluxing effect of oxygen potential, Al2O3 and MgO has also been quantified by the means of some practical diagrams that can directly help the optimization of the sintering processes.

Jan 1, 2003

By H. Y. Sohn, R. D. Hagni, M. K. Kojo

Reflected light microscopy was used to study the mineralogy and textures of experimental reactions of a nickel concentrate with a slag. Such an interaction is an important step in the bath smelting of nickel sulphide concentrate. Concentrate particles in the central portions of the pellets are rounded and develop vermicular S02 gas porosity. In the outer portions of the pellets, the original minerals of the concentrate, i.e., pyrrhotite, pentlandite, pyrite, chalcopyrite and violarite, have agglomerated and reacted to form two intergrown phases: pyrrhotite solid solution (FeO.75Ni0.18Cu0.01S) and pentlandite solid solution (Fe0.58Ni0.51Cu 0.03S). Magnetite formed euhedral crystals, skeletal crystals and dendrites at the margins of the matte. Prismatic, ferrohypersthene and octahedral Mg-Al-Fe spinet crystals and dendrites are present in the glassy slag. Key words: Nickel sulfide concentrate, Iron silicate slag, Bath smelting, Mineralogy, Microscopy

Jan 1, 2003

By E. Turner

In a joint exercise, the European Commission, (led by DG Enterprise), the EU Member States, the various sectors of the Extractive Industry, and WWF have developed a set of Sustainable Development Indicators specific to the non-energy extractive industries. Of equal significance, a Voluntary Scheme for publicly reporting the data has been created. This paper presents these indicators at the company level and explains the role of companies and trade federations in establishing the reporting process. This has been achieved in just 18 months and the paper identifies 6 Success Factors, which have made this possible. It is believed this is the first Scheme of its kind to be put into place and to have begun operation. It is a model for co-operation between government, the NGO sector and industry. The first set of data, based on the reference year 2001, has been gathered. The SD performances of the European Minerals Industry will be publicly reported on for the first time, on the basis of these 2001 data by industry sub-sector. The Member State level Indicators will follow to complete the picture.

Jan 1, 2003

By R. M. Imhof, M. J. G. Battersby, J. V. Brown

There is a plethora of former industrial sites where coal mining operations have left large slurry impoundments. These contain raw washed fines, which have previously been too expensive to process to requisite grades for commercial use. New technology has been developed for fine material processing, namely the Imhoflot pneumatic flotation G-Cell. This froth flotation technique is a highly efficient means of concentrating coal and is particularly appropriate to the nature of materials encountered in tailings ponds. The high volumetric throughput resulting from the vastly reduced residence time in the cell allows for drastically reduced equipment sizes when compared to conventional flotation cells. This means the process, when combined with innovative pre treatment and filtration equipment can be developed as a mobile plant concept. This is seen as a minimum requirement when re-treating and rehabilitating fine coal ponds.

Jan 1, 2003

By S. K. Kawatra, S. J. Ripke, T. C. Eisele

"An estimated 600,000 tons of bentonite clay are used annually in the U. S. as binder for production of iron ore concentrate pellets. Since this is a significant cost item for the plants, and the addition of bentonite to the pellets contributes undesirable silica into the finished pellets, there is considerable incentive for finding methods to reduce bentonite use. One way to reduce bentonite levels is to selectively use those bentonites that are most effective in this application, so that a lower dosage will still produce a sufficiently strong pellet. Unfortunately, there are no satisfactory methods available for accurately predicting which bentonites are actually most effective, short of using them to actually make pellets. One of the popular methods for attempting to evaluate bentonites is the “Plate Water Absorption” (PWA) test. While some plant operators accept the PWA results as indicating the relative quality of bentonites, others disagree and claim that, over a fairly broad range of values, PWA does not correlate with bentonite performance.Since both Ca+2 and Mg+2 ions are known to reduce the swelling and water absorption capacity of bentonite, it was believed that the presence of these ions in plant recycle water could be changing the bentonite performance. Since the standard PWA test uses only distilled water for its measurements, it could not detect these effects. Experiments were therefore carried out on a number of different bentonites using a modified PWA tests, with plant recycle water replacing the distilled water. These experiments showed little effect of the plant water on the PWA value, and chemical analysis of the water showed that the levels of dissolved salts were quite low.Water and accompanying salts were then extracted from a magnetite concentrate filter cake by rinsing with distilled water. Analysis of this water showed an extremely high level of dissolved salts, particularly salts of calcium and magnesium. When concentrations were compared with the recycle water from the plant filters, it was determined that levels of Ca+2 and Mg+2 retained in the filter cake were over 500 times higher than levels in the recycle water. This extreme elevation of soluble salts in the filter cake is believed to be due to adsorption of these ions into the electrical double layer of the magnetite particles."

Jan 1, 2003

By Katsuyoshi Kondoh

The synthesis processing of Mg2Si or Mg2SiIMgO at lower temperature from the elemental magnesium alloy powder/chips and Si or SiO2 powder mixture was established via the repeated plastic working (RPW) based on Powder Metallurgy (PIM) process. RPW is much effective on the mechanical breakage of MgO surface films, which prevent from the solid-state reaction between Mg and Si powder. The solid-state synthesized Mg2Si particle of 200nm-2um is extremely fine, compared to that via the conventional casting process, causing the coarse one of 50-100um. This is because of not coarsening during the solid-state synthesis of Mg2Si. By using in-situ fonning process of Mg2Si via RPW and pre-heating before hot working such as extrusion and forging, the magnesium composite material with Mg2Si or Mg2Si/MgO dispersions was developed in employing Si or SiO2 particles, respectively. For example, when employing AZ31 chips as raw materials of the matrix, it has low density of 1.85g/cm3 and extremely superior mechanical properties, such as tensile strength over 350MPa with 5-10% elongation and Young's modulus of 47-50GPa, to the conventional Mg-Al-Zn alloys. The Mg composite alloy wires and pipes were produced via the hot extrusion process in the manufacturing plant, and also showed excellent mechanical properties.

Jan 1, 2003

By J O. Okonkwo

AngloGold operates various gold mines in South Africa, the largest of which are situated in the North West province. The impact of AngloGold Vaal River mining operations on the environment and, specifically, on aquifers and groundwater is assessed. The location of such aquifers and plumes is determined by remote-sensing and ground-sensing operations, followed up with the correct placement of monitoring boreholes from which information such as water rest levels, chemistry and geological data is gathered. This study utilises an integrated approach consisting of the following mutually reinforcing phases: Phase 1: Airborne multi spectral scanning; Phase 2: Airborne thermal remote sensing; Phase 3: Ground resistivity survey; Phase 4: Borehole placement; and Phase 5: Sampling and monitoring. The integration of the investigation tools and phases in use at AngloGold Vaal River has been found to be very useful in determining the exact sources of contamination, the direction of flow of such contamination, the positioning of interceptive measures and the analysis of such contamination. This adopted approach will enable the development of flow transport models that will further enhance our knowledge of contaminants in aquifers at the mine and enable management to conduct educated interventions.

Jan 1, 2003