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By Benoit Bissonnette, David Gelderland

"The Campbell Mine Constructed Wetlands has been in full operation, processing effluent from the water treatment plant of the mill circuit for the last two years.The overall results are extremely positive with dramatic improvements for the originally targeted parameters – Ammonia, Copper and toxicity.• Ammonia concentrations were reduced from an average of 5 mg/L to an average of 0.43 mg/L which translates to an average reduction of 91%.• Copper concentrations were reduced from an average concentration of 0.054 mg/L to an average of 0.019 mg/L, which translates to an average reduction of 65%.• LC50 Acute toxicity testing revealed no impact.• IC25 Chronic toxicity tests revealed no impairment to growth or reproduction.As a result of the improvements in discharge water quality from the wetland, 100 percent compliance with respect to all Certificate of Approval, MISA and MMER regulations for effluent will be consistently achieved.The system has proven to be very easy to operate and maintain, with a minimum of care. Given some basic rules are followed, the construction of the wetlands was straightforward and relatively inexpensive compared to other treatment methods.The ecological benefits of the operation of the wetland are also quite substantial, as is the positive image of the corporation in environmental stewardship.INTRODUCTIONOver the last four years, Campbell Mine has adopted an aggressive schedule for the development of wetlands for use as the final stage of effluent treatment within the tailings management facility. The focus of this work has been to utilize natural biological systems to provide Campbell Mine with a 100 percent compliant water quality with respect to all MISA, MMER and COA discharge criteria at all times throughout the effluent discharge period."

Jan 1, 2003

By Nedam Abed

A fundamental study of the sonochemical leaching of chalcopyrite in ferric ion media has been performed to understand and quantify the effects of sonication and other parameters on leaching reactions. The study covers sulfate and chloride media. The main leaching reaction: CuFeS2(s) + 4Fe3+(aq) Cu2+(aq) + 5Fe2+(aq) + 2S(s) (1) was found to be dependent on temperature and initial particle size, but less dependent on ferric ion concentration. Leaching kinetics were not affected by ferrous ion concentration or the amount of chalcopyrite added. Leaching was performed under a variety of sonication and leaching conditions. Reaction stoichiometry was confirmed through detailed wet chemistry analysis and mass balance calculations. The use of ultrasound activation showed a clear improvement in leaching kinetics and amount of copper extracted, sonication having a catalytic-like effect on the leaching reaction. Compared to experiments without sonication, reaction rates were 2-3 times faster at the same temperature, and could be faster by a factor of 20 for the same initial particle size. Regardless of initial particle size, the amount of copper extracted was comparable under sonication, and could be twice that under chemical leaching, implying the avoidance of fine particle grinding. Sonochemical leaching was found to be only temperature dependent, where the best copper extraction was at 75C. Leaching was further enhanced by the use of a grinding aid. The leaching behavior of chalcopyrite particles remained similar with and without ultrasound activation, implying that the known passivation mechanism in the oxidative leaching was not eradicated. Sonication resulted in coarse particle breakage (ultrasonic milling). Sonication did not contribute to particle passivation, as affirmed from different leaching procedures and sonication in aqueous and organic media. Parabolic leaching kinetics were confirmed for leaching experiments.

Jan 1, 2003

Abstract A new approach is introduced for study of the behaviour of geotechnical strength parameter prior to slope analysis to ascertain whether strength parameters of slope materials are homogenous or heterogeneous at different mine depths. The strength parameters used for the study are uniaxial compressive strength, tensile strength and shear strength. The analysis is based on statistical analysis of variance technique for one-way classification. The application of the technique is given through a case study in an openpit mine. Auszug Eine neue Annäherung wird für Studie des Verhaltens des geotechnischen Stärke Parameters vor Steigunganalyse eingeführt, um zu ermitteln, ob Stärke Parameter der Steigungmaterialien homogenous oder an den unterschiedlichen Grube Tiefen heterogen sind. Die Stärke Parameter, die für die Studie verwendet werden, sind einachsige zusammenpressende Stärke, Dehnfestigkeit und Scherstärke. Die Analyse basiert auf statistischem varianzanalytische Technik für Einwegklassifikation. Die Anwendung der Technik wird durch eine Fallstudie in einer openpit Grube gegeben. Abstrait Une nouvelle approche est présentée pour l'étude du comportement du paramètre géotechnique de force avant l'analyse de pente pour établir si les paramètres de force des matériaux de pente sont homogenous ou hétérogènes à différentes profondeurs de mine. Les paramètres de force utilisés pour l'étude sont résistance à la pression uniaxiale, résistance à la traction et résistance au cisaillement. L'analyse est basée sur statistique la technique de l'analyse de variance pour la classification à sens unique. L'application de la technique est donnée par une étude de cas dans une mine à ciel ouvert.

Jan 1, 2003

By G. Hilson

The exact application of sustainable development in the mining and minerals industry has precipitated considerable debate in recent years. Since the publication of the Brundtland Commission?s Report, Our Common Future, numerous attempts have been made to define sustainable development in the mining context. The inability of the Brundtland Report to outline an effective sustainability framework, combined with its contention that no single blueprint for sustainable development exists, has prompted many academics and practitioners to provide viewpoints on the application of sustainable development in the mining and minerals industry. This paper provides an overview of the many groups of assessments made of sustainable development in the mining industry. Sustainability assessment and reporting for this industry sector using indicators are also addressed.

Jan 1, 2003

By Lætitia H. Delmau

SXFIT is the latest in a series of programs developed in our group to model solvent extraction systems of increasing complexity. SXFIT permits the user complete freedom to define the constituents from which the composition of each phase is to be specified in the data and from which all species of a model for a system are assumed to be formed. Activity coefficients in the nonaqueous and aqueous phases, water activity, apparent molar volumes of aqueous species, and solution density needed for the conversion of concentration from the molarity to the molarity scale are all taken into account by the program. Several extraction systems relevant to nuclear-waste treatment were modeled successfully using this program. As an example, the cesium extraction efficiency of the CSSX process chosen by the USDOE for cesium removal from high-level waste stored at the Savannah River Site can be predicted correctly for varying feed composition.

Jan 1, 2003

By Matti Hämäläinen

Outokumpu has developed a new chloride leaching process, HydroCopper?, for copper concentrates. The process utilizes the cupric ion as oxidant, which is able to dissolve chalcopyrite. After solution purification monovalent copper is precipitated as cuprous oxide, Cu2O, using sodium hydroxide. Copper product is produced from Cu2O by reduction, melting and casting. An essential part of the new process is chlor-alkali electrolysis, which regenerates the reagents used. All impurity metals are removed before Cu2O precipitation, because otherwise they would report to the copper product, impairing its quality. A multistage solution purification scheme has been developed consisting of firstly, chemical precipitation of impurity metals by pH increase, secondly, cementation of silver and thirdly, removal of trace multivalent ions using ion exchange. This paper describes the characteristics of solution purification in the HydroCopper? process based on the laboratory tests and pilot runs made by Outokumpu Research Oy.

Jan 1, 2003

By Sung-Hyun Park

Core sediment samples collected from the KODOS area of the Clarion-Clipperton Fracture Zone in the NE Equatorial Pacific were analyzed for chemical and mineralogical compositions to investigate the depth- and time-related variation of paleoenvironmental and paleoceanographic conditions during their deposition. These core sediments are divided into three layers from top to bottom by its color; 1) brown layer (Unit I), 2) pale brown layer (Unit II), and 3) black brown layer (Unit III). Geochronology of 10Be indicated the depositional age of Quaternary for Units I and II and of late Pliocene for Unit III with a potential short hiatus between them. Analyses of interelemental correlation identified three major groups of elemental groups that show moderate-to-strong correlations: 1) Al, Ti, K, and Fe representing for terrestrial alumino-silicate fraction of sediments, 2) Ca, P, REEs, Cu, and Zn for biogenic apatite, and 3) Mn, Ni, and Co for hydrogenous Mn-oxide. With an exception, Fe content was very high and showed fair correlations with Mn, Ni, and Co in Unit III. Unit III shows high smectite but low quartz and illite contents compared to the overlying two units, indicative of reduced supply of terrestrial materials. In a meanwhile, major elements (Fe2O3, CaO, P2O5), minor elements (Cu, Zn) and REEs are highly enriched in Unit III compared to the upper two units. All these elements other than Fe reflect the fraction of biogenic apatite, which indicates higher fraction of biogenic components in Unit III. This is also supported by higher amount of smectite formed by the consumption of siliceous biogenic components. The reduced supply of terrestrial material and/or increased productivity of surface water at the time of Unit III deposition are attributed to Pliocene warming preceding Northern-pole glaciation during Quaternary. Unit III also includes clinoptilolite and unidentified 8Å mineral, likely amphibole, that are absent in Units I and II, suggestive of the possibility of different source region and/or materials during Pliocene. Higher contents of Mn and Fe in Unit III are likely due to the high fraction of Mn-oxide that was formed by diagenetic process after deposition.

Jan 1, 2003

By S J. Woods

As a part of Solid Energy's progressive rehabilitation of the Stockton Mine, it was determined that significant rehabilitation of the existing Mt Frederick Sidecast would be required to ensure the long-term stability of the sidecast. The goal of this rehabilitation is to reshape the existing stockpile into a more stable slope configuration, and the construction of a comprehensive stormwater collection and discharge system. The reconfigured slopes will facilitate the final revegetation of the exposed surfaces and the management of surface and groundwater discharges from the area. This paper briefly describes the specific details of the project and the significance of seismic conditions on the long-term stability of the reconfigured stockpile.

Jan 1, 2003

By Thomas A. Post

The methodology of determining the optimum SX pumper-mixer system based on bench top, pilot, or small-scale solvent extraction systems, is demonstrated. The design of small-scale SX-plants is different than a full-scale plant. The difference is explained here. The use of dimensionless parameters Nh, Nq, and Np that describe the head, flow and power of the pumper is shown and how to use them for the scale-up. Additional data is required to determine the optimum operating range. Applications of this methodology were used to design well known currently operating SX plants. The emphasis on the optimization of hydraulic efficiency will be shown on examples, including how the hydraulic efficiency is affected when the throughput of the system goes beyond the design. Designs of all sizes of equipment will be shown which optimize the hydraulic efficiency.

Jan 1, 2003

By P. Johnson, G. E. Jones, G. K. Hoffman, C. B. Krueger, J. S. Raugust, M. Wilks, V. T. McLemore

The NMBGMR is slowly converting historical data into a relational database using Microsoft Access 97. The purpose of this database is to provide data on districts, mines, and mills in New Mexico to government agencies, public organizations, industry, and citizens to make informed decisions about resource development, resource management, water supplies, environmental impacts, hazard assessment, and waste disposal. Once the data are entered into the database with locations, the data can easily be converted to GIS format for displaying as different map layers.

Jan 1, 2003

By L Smith, R Beckie

An intermediate scale (8 m + 8 m + 5 m high) constructed waste rock pile experiment was built upon a contiguous grid of 16 gravity drainage lysimeters to investigate the flow of water in unsaturated waste rock. Average net infiltration to the uncovered waste rock pile is 55 per cent of precipitation. Large rainfall events have net infiltration of 55 per cent to 85 per cent. Net infiltration estimates range from 23 to 120 per cent of precipitation between lysimeters. Small-scale lysimeters of less than 4 m2 area are shown to be poor predictors of net infiltration for uncovered waste rock. The appropriate size for lysimeters increases with increasing flow rate. The residence time distribution has an estimated median value of 3.0 to 3.9 years under average infiltration conditions. Water flows within the fine grained matrix, within larger pores (macropores), and in matrix free areas of the pile. In situ tracer concentrations vary between pore sizes, and between spatially distinct areas of the pile, indicating water geochemistry may also be variable. Water samples collected from in situ soil water samplers are dominated by the most mobile water fractions. In situ measurements of water content and matric suction are compared to the measured outflow. The data indicate the focusing of flow in spatially distinct areas can make in situ instrumentation a poor (non-conservative) predictor of volumetric water flow.

Jan 1, 2003

By Michael Deutscher, Jozef F. Zurawski

Part of Capital Improvement Project SE-754 tendered by New York City Department of Design and Construction included installation of a 96-in. (2.47 m)diameter sewer by pipe jacking methods. The pipe selected by the Contractor, EIC Associates, Newark, New Jersey, was a glass-fiber-reinforced thermosetting resin pipe installed in two reaches: 72 m (235-ft.) and 222 m (728-ft.). The machine selected for the excavation was an open face shield. This paper describes the set up of the tunneling operations, subsurface conditions, progress of excavation, pipe performance and other details of the project including unexpected difficult ground conditions that were encountered during excavation and how these conditions were overcome.

Jan 1, 2003

By Richard A. Shulkosky

The American Iron and Steel Institute (AlSO, in conjunction with the U.S. Department of Energy (DOE) jointly funded the development of a mechanical properties model for Hot Strip Mills. INTEG process group, inc. validated an enhanced version of the model under a project funded by the AlSI/DOE Technology Roadmap Program (fRP). The Hot Strip Mill Model (HSMM) version 6.0 allows users to easily set-up their mill configuration, simulate a rolling mill schedule and calibrate the model for a variety of grades of steel. Starting from reheat furnace drop out, the model simulates roughing mill stands (reversing and continuous), heat retention equipment (coil box and covers), finishing mill stands (tandem and Steckel mills), the run out table and the mill exit area. The HSMM uses a series of physical models to calculate both the thermo-mechanical and the microstructure evolution of steel being processed in a hot mill to predict its final mechanical properties. The enhanced HSMM was validated using a multitude of samples from several steel companies. Excellent agreement was obtained for tensile strength. The supporting steel companies have utilized the model for a variety of practical applications. Keywords: Process Modeling, Microstructure Evolution, Mechanical Properties

Jan 1, 2003

By Steven W. Hunt, Steven B. Fradkin, Roger J. Maurer

During the 1980s and 1990s, twenty deep shafts were constructed in Milwaukee to depths from 85 to 91 m (280 to 300 feet) through soil and weak rock thicknesses ranging from 37 to 69 m (122 to 227 ft). Adjacent compressible soils, settlement sensitive structures and high groundwater levels required that shafts be constructed without dewatering. Contractors attempted several methods of ground support and groundwater cutoff. Significant problems developed during construction of 11 of the 20shafts. One shaft collapsed; groundwater blow-ins occurred at five of the shafts; and seepage caused unfrozen windows at three of the freezewalls. Ultimately, combinations of grouting and ground freezing were utilized to complete all of the shafts into bedrock. This paper discusses the main design and construction challenges experienced and the lessons learned.

Jan 1, 2003

By K. Cybulski

In 2002 a coal dust explosions occurred in the Polish collieries “Jas-Mos” and “Rydultowy” in the Upper Silesia coal basin. In the “Jas-Mos” colliery the coal dust explosion was initiated in the face of gallery by explosives and causing ten death. The stone dust barrier extinguished the flame, stopped the explosion development and saved forty nine miners working in that area. In the “Rydultowy” colliery methane inflammation caused three deaths and seven serious burns and ignited the coal dust explosion. The coal dust explosion was stopped by stone dust barrier and did not cause any victims itself. This paper presents the investigation carried out by the Central Mining Institute Experimental Mine “Barbara” and shows that the stone dust barriers remain still a basic mean for suppression of coal dust explosion in mines. The investigation were aimed at determining the cause of explosion and circumstances that led to their propagation. The evaluation of the state of dust explosion hazard in the areas of accidents have been performed, and the range of flame estimated.

Jan 1, 2003

By H. S. Rathor

In a major hydropower project in the Himalayas, during excavation of tunnel, hydrothermal gradient line appeared and caused extremely unfavorable conditions with rock and water temperature varying between 55°–66°C and nearly 100% humidity. Major changes in method of excavation, schedule of works, deployment of additional equipments and acclimatization of personnel were made to complete this unfavorable stretch of world’s longest Head Race Tunnel. The case study covers the various aspects of tunneling in geothermal rocks, inhuman working conditions, loss of production, cost overrun, contractual claims and strategy to manage such unfavorable working conditions.

Jan 1, 2003

By F. Chase, D. Pappas

Pillar recovery has been associated with nearly one third of roof fall fatalities in underground coal mines during the past decade. Safe pillar recovery requires global stability and local stability. Global stability is addressed primarily through pillar design. The local stability risk factors include cut sequence, the final pillar stump, supplemental supports (timbers vs. Mobile Roof Supports (MRS)), roof bolting, and many others. The National Institute for Occupational Safety and Health (NIOSH) has evaluated each of these factors through field research and analysis of accident statistics. The paper discusses design methods and technologies that have been transferred to the mining community and implemented.

Jan 1, 2003

By Corby G. Anderson

Over the past 15 years, numerous pressure oxidation plants for pretreatment of gold ores and concentrates have been installed throughout the world. While this technology is now established, it suffers in terms of the complex engineering and operational characteristics inherent in utilization of high temperatures (i.e. up to 225oC) and high pressures (i.e. > 3000 kPag). This paper outlines the application of an industrially proven pressure leaching methodology utilizing nitrogen species catalyzed pressure leaching and alkaline sulfide gold leaching. As such, it stands as an economic and engineering advancement in pressure leaching and non-cyanide treatment of gold ores and concentrates. In particular, the technology offers significant technical and economic advantages over traditional pressure oxidation and cyanide gold recovery in the treatment of gold bearing chalcopyrite ores and concentrates. An example of this will application will be delineated in this paper.

Jan 1, 2003

By Edward Barrody

There are wide variations in the values of heats of explosion and detonation as reported in literature. These values are not “stand-alone” or sole properties of the explosives. Specifications of the conditions under which they were determined are necessary to characterize these values. This paper proposes that these values are dependent on their oxygen content and the surroundings their products “work against” upon expansion. Also, the heats of explosion and detonation values can have the same values, but different products, showing that the products can take “independent paths” but have the same values.

Jan 1, 2003

By J. Drzewiecki, J. Kabiesz

Coal mining using longwall methods of mining can lead to intense disturbances of undermined roof strata. The disturbances may extend beyond the extraction area and the resulted rock mass deformations will appear differentiated. In the case of stiff and undermined roof strata, the energy stored in these rock masses may be frequently dissipated in the form of high-energy seismic tremors. Such events can occur if these strata should fail or „free themselves” either from the constrainment of rock environment or from adjacent strata. It has also been found that the amount of the stored energy closely depends on the size and/or slenderness of these strata. Thus, it would be possible to apply specific preventive measures to reduce the energy of mining – induced seismic tremors. The methods are based on artificial disintegration of the structure of energy – storing strata. One of the most efficient methods is a method of directional hydraulic fracturing, which is regarded as an alternative solution from the traditional blasting and hydraulic methods.

Jan 1, 2003