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By Wilhelm Schwarz

Manganese nodules lay in vast areas of the deep sea floor. Ideal harvesting conditions for a manganese nodule field are dense nodule abundances of nodules between 20 and 60 mm diameter and a metal content as high as possible. With regard to the development of collector technology, the properties of the deep sea soil, in which the nodules are embedded and to which the nodules stick, are of major interest. The forces for loosening the nodules have to be provided by the collector. For this purpose water jets and/or mechanical devices can be employed. For the choice of the best collecting procedure, various criteria, such as collecting rate, energy consumption and the environmental impact on the eco system of the deep sea floor, have to be considered and weighted as to their importance. Nowadays, the concept of a mining system with a flexible transport hose and a self propelled collecting machine is increasingly accepted among the expert community. With regard to the trafficability of the deep sea soil with a self propelled mining machine, the mechanic properties of the soil and the morphology of the deep sea floor are of special importance. The manganese nodule fields, which are interesting with regard to their recoverability, are mostly in the areas of tectonic fracture zones, at which the morphology of the sea floor is formed by vulcanic activities. In these areas, deep sea mountains, pits and other obstacles exist that have to be driven around if not trafficable.

Jan 1, 2003

By G. van der Westhuizen, F. E. du Plessis

Ticor South Africa operates a dry mill at the town of Empangeni in the province of KwaZulu-Natal on the east coast of South Africa. The dry mill processes a non-magnetic mineral stream constituting rutile, leucoxene and zircon as major minerals, and minor quantities of ilmenite and other non-valuable minerals. For plant control and optimization, continuous ‘real time’ information about the mineral and chemical compositions in various plant streams is required. The current practice is to take samples at regular intervals and submit them for mineralogical(grain counting) and chemical analyses. However, these methods are time consuming, and in the case of manual grain counting, tedious and operator dependent. Until now an on-line or real-time instant mineral quantification system, which will be of great value in a plant operations environment, has not been available. Blue Cube Systems has developed a mineral quantification system using spectral mineral analysis. It measures and quantifies the composition of mineral samples instantly, providing consistent data in real time. A series of process stream samples from the dry mill mentioned above were used to evaluate the Blue Cube Systems instant mineral quantifier. This article will •describe the procedure of setting up and evaluating the Blue Cube Instant MineralQuantifier equipment •present its results, and •discuss the intended applications.

Jan 1, 2003

By D. Grgic, A. Giraud, F. Homand

RESUME : Le comportement mécanique partiellement saturé du minerai de fer a été étudié à partir d’essais de compression simple sur des éprouvettes à pression capillaire imposée par les solutions salines. Les échantillons restent peu saturés (32 %) même pour une humidité relative de 94 %, du fait de la présence de mésopores. Jusqu’à 90 % d’humidité relative la résistance diminue régulièrement. De 90 % à 94 % une forte chute est observée et pourrait être liée à la fois aux effets capillaires et à l’hydratation de certains minéraux. Le cycle hydrique subit par la roche dans la mine a été modélisé en 1D à l’aide d’un code de calcul entièrement couplé pour les milieux poreux partiellement saturés. Les calculs ont montré notamment une diminution importante en paroi des contraintes totales au cours de la phase de désaturation et une augmentation importante au cours de la phase de resaturation. Ces variations pourraient induire un endommagement du massif et être à l’origine d’instabilités, et soulignent l’intérêt d’une modélisation avec une géométrie plus adaptée. MOTS-CLEFS : mines de fer, partiellement saturé, pression capillaire, résistance, modélisation. ABSTRACT : The partially saturated mechanical behavior of iron ore has been studied from uniaxial compression tests on samples in which the suction is imposed with aqueous solutions. Samples are little saturated (32 %) even for a 94 % relative humidity because pores are too large. Up to 90 % relative humidity the strength decreases regularly. From 90 % to 94 % a great decrease is observed ; it could be explained by the capillary effects and the moisturizing of some minerals. The hydrous cycle imposed to the rocks in the mine has been modeled with an 1D fully coupled code for partially saturated porous media. The computations have shown an important decrease in the total stresses at the wall during the desaturation stage and an important increase during the re-saturation stage. These variations could induce a rock mass damage and instabilities, and highlight the necessity of a modeling with a well-adapted geometry. KEY-WORDS : iron mines, partially saturated, suction, strength, modeling. ZUSAMMENFASSUNG : Das mechanische Verhalten von teilweise gesättigten Eisenerz wird durch einachsige Druckversuche untergesucht. Die Prüfkörper haben einen durch Salzlösungen gestimmten kapillarischen Druck. Sie bleiben kaum gesättigt (32 %), sogar bei einer relativen Feuchtigkeit von 94 %, aufgrund der Anwesenheit von Mesoporen. Bis eine relative Feuchtigkeit von 90 % verringert sich gleichmässig die Druckfestigkeit und zwischen 90 % und 94 % merkt man eine starke Abnahme in Verbindung, möglicherweise, mit kapillarischen Effekten und Hydratation von bestimmten Mineralen. Die nümerische 1D Modellisierung des gezwungenen Wasserzyklus im Stein der Mine ist mit einem für porösen Medien ganz vernetzten Rechnungcode geführt. Sie zeigt besonders ein bedeutendes Sinken der Gesamtspannung während der Entwässerung und eine bedeutende Steigerung während der Sättigung. Diese Veränderungen könnten die Beschädigung des Gesteines herbeiführen und die Grundlage von Unstabilität sein. Sie unterstreichen die Wichtigkeit eine Modellisierung mit einer gut geeigneten Geometrie. STICHWÖRTER : Eisenminen, teilweise gesättigt, kapillarischer Druck, Druckfestigkeit, Modellisierung.

Jan 1, 2003

By X. Jay Gao

A fast high-temperature carburizing process integrated with materials design and optimization via a systems design approach was developed to significantly reduce process cycle time. Process experiments were focused on boost cycles to obtain a robust boost process and investigate surface reaction kinetics, primary carbide formation and dissolution. Weight gain and microhardness were measured, all showing evidence of non-monotonic time evolution for longer boost times at higher temperatures. Optical and electron microscopy and other techniques have been used to identify possible carbides, their location and types. These results assist the picking of first boost time with least variation rate in terms of content of case carbon and carbides, dissolvable in subsequent diffuse if any. The results also provide critical information to properly formulate surface reaction kinetics and diffusion and formation kinetics of carbides modeled using DICTRA. Keywords: high temperature vacuum carburizing, partial pressure carburizing, heat treatment, process development, carbide, case hardening, microstructural analysis, over carburizing

Jan 1, 2003

It is often assumed that geotechnical investigations or studies for open pit mines are confined to providing a slope design. However in an operating mine, the design is only one component of a mine geotechnical program. Reviews of slope designs are ongoing throughout the mine life. The concept of Pit Slope Management has been formulated because the design only entails one component of a total program that contributes to a safe, efficient mining operation. Risk is a normal part of mining. Effective management allows the risk to be contained or controlled. If the slopes are not effectively managed there will be increased risk for the operation. Experience has shown that utilisation of Pit Slope Management coupled with a broad base of experience to define the key controls on stability, provides a pro-active, objective approach. The reasoning is deductive and relies on the behaviour of the ærocksÆ. Once the key aspects are defined, studies are well focused, implemented as required and the risks can be effectively managed. When the key controls on stability are poorly understood reasoning is typically more ægut feelÆ. Under such circumstances studies, if carried out, may meet short-term objectives but often ignore the long-term objectives. Hence the risk to the project is greatly increased. This paper presents several case studies highlighting the above aspects and present elements of the Pit Slope Management Program approach which have been successfully utilised by the author to manage risk in mining projects.

Jan 1, 2003

By Katarina Theander, Robert J. Pugh

The generation of froth with a critical degree of stability and height is an important aspect of the froth flotation. In this paper we have studied the synergism and anti-synergism in frothing behaviour in a mixed flotation collector/frother mixture (a model fatty acid; sodium oleate and a model frother; nonionic (polyethyleneoxide alkyl C14E6). Values of the collector / frother molecular interaction parameters (the ß-parameters) were determined from the surface tension data using regular solution theory. The frothing characteristics of the system were evaluated using a glass column equipped with a series of conductivity electrodes, which enabled the water content of the froth to be determined. From these measurements, the dynamic frothability and static froth stability were determined. It was concluded that the synergism/anti-synergism in frothability was depended on the molecular composition of the surfactant system, the diffusion of monomer to the thin film interface and on the breakdown of the mixed nonionic/anionic micelles.

Jan 1, 2003

The Kelian gold mine which was developed in East Kalimantan Indonesia in 1990 - 1992 is scheduled to complete mining and processing operations in 2004. This will have a major impact on the neighbouring communities who have benefited from the jobs, economic activity and infrastructure development which has been generated by the mine. Currently, there are no formal regulations or standards specifying the procedures for relinquishment of mining leases in Indonesia. Furthermore, a move towards regional autonomy, providing greater authority and responsibility to local (regional) areas, has recently been implemented in Indonesia and limited capacity exists in the new regional governments. Consequently, in October 2000, Kelian Equatorial Mining (KEM) initiated a partnership with the local community and government to explore sustainable post-closure options for the mine site and community development programs. The Kelian mine closure strategy seeks full involvement of all stakeholders through the Kelian Mine Closure Steering Committee (MCSC) in the development of sustainable solutions which will enable communities to secure long-term benefits and minimise post-closure risks from the KEM operations. This organisation, jointly chaired by the Head (Bupati) of the regional West Kutai government and the KEM President Director, with representatives from the local communities, governments and NGOs, has developed a Charter, a website and evaluation criteria to ensure accountability and transparency. There are four technical working groups, consisting of representatives from the mine, local community leaders, NGOs, Universities, Local, Provincial and Central Government Departments, which report to the Steering Committee. These working groups have researched, developed and recommended sustainable options to the Steering Committee. The MCSC has met quarterly to examine options in accordance with the criteria set out in the Charter and has endorsed sustainable solutions which have support from Government, Community and the mine. This paper describes the closure risks, sustainable outcomes derived through the Kelian mine closure steering committee process and outlines the methodologies used to develop and endorse sustainable solutions in a society with limited capacity undergoing enormous change and uncertainty.

Jan 1, 2003

The quality of the external water source for a mineral processing plant may influence the extent to which the environmentally desirable practice of recycling of water from plant products is possible. This is particularly likely for froth flotation plants where the chemical quality of the water may affect the plantÆs performance. The quality of the external water source or the recycled water can be improved by a water treatment step, and in turn the extent of recycling which can be tolerated is able to be influenced. The quality of the external water can range from very high quality, soft water derived from melting snow, to poor quality, hard water (high levels of dissolved calcium and magnesium) from underground aquifers, and to even lower quality sea water (very high levels of dissolved species including sodium chloride). It can be noted that some underground water is more saline than ocean water as well as containing high levels of dissolved calcium and magnesium. Occasionally, a different source of water is utilised in the wet and the dry seasons. Increasingly, sewage water from cities is becoming a potential external water source with sustainability implications. If the initial quality of the external water is high, the scope for recycling of water from all the products is maximised. Such reuse or recycling of water from the products allows chemical species from oxidation of the ore and from other inputs to the process such as reagents to increase in concentration in the water returned to the plant. Such accumulation of species can have negative effects on the performance of a process such as froth flotation but instances of positive effects exist. Some reagents which are used in flotation plants such as lime or sodium carbonate also happen to be commonly used for independent water treatment plants. Hence, the flotation process may inadvertently provide some aspects of water processing. Where the quality of the water in the feed to a mineral processing plant (external water plus recycled water) is not an issue, more powerful solid-liquid separation processes can be considered to maximise the removal of water from the products and its reuse. Such processes may also have complementary benefits in a sustainable mineral industry by, for example, producing a tailing stream with a higher per cent solid value which is more suitable for safe storage on the surface or underground. This paper documents findings on the effect of water quality on the flotation process. It also considers current directions of change in the need for increased removal of water from plant products. It then considers the implications of these trends for maximisation of water recycling by such operations.

Jan 1, 2003

By Takashi Furuyama, Sukeyuki Mori, Abel Bissombolo

"In flotation practice, a good recovery of minerals largely depends on the degree to which the valuable minerals have been liberated from the associated gangue during the grinding process. Therefore, a regular measurement of the degree of liberation can provide data for the assessment of the quality of separation and predicts the effect of changes in the grinding-classifying circuit on flotation process. Generally, the standard procedure for measuring the degree of liberation requires the preparation of polished sections - a time consuming operation that also has the disadvantage of providing an overestimated number of free particles because of the stereological nature of produced samples.The present work is an alternative approach to avoid these miscalculations and establish a system of control for fluorite flotation plants. The system deals no only with the state of liberation but also the dynamic behavior of individuals particles and mineral components within the grinding-classifying and flotation circuits. It involves methods such as sieving, x-ray diffraction analysis, study of polished sections and microscopic counting of preliminarily sieved minerals particles from a fluorite processing plant, randomly dispersed on a glass slide, but not embedded in a resin mounting medium. If a complete information on the textural properties of minerals in the ore (including its mineral components distribution) can be obtained through x-ray diffraction analysis and study of polished sections, the microscopic counting is used to determinate with enough accuracy the mineral liberation, estimate the grade of fluorite ore and products, determinate the deportment and approximate recovery of individuals particles and mineral components within the investigated circuit. For a count of 100-1000 particles in each n-size range, the counting method was found to be a particularly reliable and less time consuming operation that could substitute the chemical analysis of fluorite ore for an estimate of the grade:"

Jan 1, 2003

By G Solly, P J. Leevers

Day-to-day operating practices at existing operations need provide high quality data for decisions that will impact directly on the potential value of the available resource, in addition to meeting standards of quality expected of data used in feasibility studies that will be completed to obtain additional capital required to finance operational improvements. Drill hole location, down hole survey and assay data standards of accuracy and precision have received considerable attention in recent years. The authors propose that geological descriptions of both cored and non-cored drilling warrant at least equal attention, considering their fundamental role in establishing the framework used for geological modeling and resource estimation. The iron ore deposits of the Middleback Ranges have been a major source of iron ore for almost a century. High-grade hematite-dominant ore is currently mined by OneSteel from three open pit operations supplying ore to the companyÆs integrated steelworks at Whyalla. A review of OneSteelÆs future iron ore resources, commenced in 2002, highlighted the need for more flexible and comprehensive management of all forms of geological data used in resource evaluation. Driving this program was the information needs of feasibility studies of the Iron Magnet deposit, located beneath the existing Iron Duke and Iron Duchess mines. Prior to the beginning of 2003, resource evaluation drilling data collected by OneSteel was managed using an in-house system based on industry standard relational database software. The system was demonstrably effective in ensuring the fundamental integrity of basic drilling data, but lacked necessary capabilities for the acquisition and management of geological descriptions, geotechnical and geophysical data obtained by down-hole logging. OneSteelÆs existing system for the management and interpretation of geological descriptions was restricted to storage of a single three digit code for each lithological description interval. The original logs for a large number of older drill holes could not be located, having been either poorly archived or culled from the database in the belief that they did not contribute to the understanding of the resources currently being mined. The three digit codes represented a combination of lithological and stratigraphic descriptions, including many subtle variations in iron ore colour and texture believed to be associated with variations in geochemistry, but subsequently demonstrated to be either incorrect or inconsistently applied. This resulted in the establishment of a plethora of codes for a relatively small number of distinct lithologies. Improvements implemented by OneSteel geologists addressed these shortcomings by ensuring the new data management system: facilitated the objective description of lithological characteristics; distinguished between obsevations and interpretations (eg lithology versus stratigraphy); promoted consistency between descriptions provided by different geologists; and helped to ensure data integrity by developing an audit trail for alterations made to data subsequent to its acquisition. The data used to develop interpretations of mineralisation distribution and characteristics are fundamental to the effective utilisation of a mineral resource: any mineÆs most important asset. Resource related risk is widely recognised as the principal source of technical risks affecting resource development projects, whether they are new mines or expansions of existing operations. A key lesson from this work is that most commercial or æin-houseÆ developed geological data management systems are able to handle basic data validation tasks effectively. Geologists, however, need to ensure that the data management system is appropriately structured to help promote the acquisition of objective and consistent data for interpretation.

Jan 1, 2003

By J. P. Josien, J. F. Noirel, F. Lahaie, P. Bigarre, M. Al Heib

ABSTRACT: In June 2001, a fatal rockburst affected a longwall face in the Houillères du Bassin de Lorraine (HBL), France. Subsequently, a large operation of in situ stress measurements by overcoring was carried out with two main objectives: providing input data for the back analysis of the dynamic event and characterising the stress field in the next panels to be mined for identifying other potential high-risk zones. This paper makes a synthesis of the results of the overcoring tests performed and discusses those results in connection with the mining context, numerical model predictions, laboratory rock test results and microseismic activity. KEY WORDS: Mine, rockburst, stress, overcoring, measurement. ZUSAMMENFASSUNG: Im Juni 2001 hat ein Bergschlag eine Kohlengrube des Houillères du Bassin de Lorraine (HBL, Lothringen, Frankreich) schwer beschädigt. Nach diesem Unfall sind Spannungsmessugen durch Überborung durchegeführt worden, mit zwei Hauptziele : 1/ Daten zu liefern für die Retro-analyse des dynamischen Gebirgsschlag und 2/ die Spannungen in den zukünftigen Ausbauen so gut wie möglich zu charakterisieren, um eventuele andere Risikozonen festzustellen. Dieser Artikel stellt eine Synthese der erzielten Ergebnisse vor. Er diskutiert diese Ergebnisse in Verbindung mit dem gesamten Kohlengruben Zusammenhang, mit den Ergebnissen von numerischen Modellierungen, mit der Labor-Charakterisierung und mit der microsismische Überwachung. SCHLÜSSEL-WÖRTER: Kohlengruben, Bergschlag, Spannung, Überborung, Messung. RESUME: En Juin 2001, un coup de terrain a gravement affecté une longue taille aux Houillères du Bassin de Lorraine (HBL) en France. A la suite de cet accident, une importante campagne de mesures de contraintes par surcarottage a été réalisée, avec deux objectifs majeurs : fournir des données d’entrée permettant la rétroanalyse du phénomène dynamique et caractériser au mieux le champ de contraintes dans les futurs panneaux exploités afin de détecter d’éventuelles autres zones à risque. Cet article présente une synthèse des résultats obtenus, et discute ces résultats en liaison avec le contexte d’exploitation, les résultats de modélisation numérique, de caractérisation en laboratoire et de surveillance microsismique. MOTS CLES: Mine, coup de terrain, contrainte, surcarottage, mesure.

Jan 1, 2003

By Ralph J. Holmes, Victor Sharp, Steven J. Spencer, Kevin J. Davey, Jonathan J. Campbell, Peter L. Phillips, David G. Barker

"Improved measurement tools for monitoring and control of AG/SAG mill performance have a high level of interest in industry. Historically, acoustic emission monitoring has been widely used on SAG/AG/ball mills and hydrocyclones to provide new information on the conditions inside these devices affecting their performance. The current work was focused on a new technique using surface vibration monitoring of a number of pilot-scale and production-scale AG/SAG mills to yield insights into the events occurring in the mills. The development of relationships between signal analysis outputs and mill operating conditions can be used for soft-sensor measurement of mill process variables. The technique used an array of accelerometers mounted on the mill lifter bolts linked to a fast data acquisition system which monitored the surface waves generated during operation. Details of the system are presented. Mill operating variables were adjusted systematically to provide a wide range of operating conditions for surface vibration signal collection. The experimental approach is discussed.The signals acquired during the experiments were analysed using a range of techniques. The results show that strong relationships exist between measured vibration power (both total power and within certain frequency bands) and mill load level/power and mill speed. A new method for extraction of power spectral density and band power information on features of interest in a mill rotation cycle is also presented.These results show that single sensor analysis information from the surface vibration system can be used as soft sensor inputs for monitoring process variables such as mill load that until now, have not been reliably measured. System outputs also show considerable promise in the area of condition monitoring. An example of the signal analysis output is presented showing elevated vibration levels in an area with higher resultant wear. Eventually, it is considered that outputs from this system for process variable and wear condition monitoring will be key new inputs to an online AG/SAG mill monitoring and control system."

Jan 1, 2003

By Shijie Wang

In pressure oxidation leaching of copper anode slimes, than 65% of the tellurium is m' cxtraoted during decopperizing. About l0- 15% of the selenium is also dissolved simultane¬ously by severe leach conditions. Current operation for the treatment of the leachate is to constantly recirculate the leach solution through a bed of copper turnings. The tellurium and sele¬nium are precipitated from the leach liquor as copper telluride and copper selenide and sepa¬rated from the solution by filtration. In order to improve the reaction efficiency and reduce the process cost, viz, minimize the copper addition, cut retention time, and reduce the energy consumption; a chemical reducing agent is studied and the cementation process tested in the laboratory. In this paper, the test results are presented and the process chemistry is discussed.

Jan 1, 2003

By G. du T. Judeel

An investigation was carried out to determine whether a numerical model could be constructed that would produce results that realistically represent actual ground deformations in and around a vertical shaft. The ground deformation was brought about by the partial extraction of the shaft pillar. A special characteristic of the rock masses, affected by the shaft pillar extraction, was that the shaft was located in poor quality rock masses. After the extraction of a portion of the shaft pillar, excessive deformations occurred at the shaft/reef intersection. Therefore, a decision was taken to extract the entire shaft pillar protecting the shaft by a proposed waste-cut across the shaft. The effects of stress and displacement on the shaft were investigated by using inelastic numerical modelling in different stages. A calibrated numerical model was constructed producing modelled results comparable to the actual displacements along the shaft. Des recherches ont été poursuivies pour déterminer si on pouvait construire un modèle numérique qui donnerait des résultats représentant avec réalisme les déformations réelles du terrain à l’intérieur et autour d’un puits vertical. La déformation du terrain était entraînée par l’extraction partielle du massif de protection. Une caractéristique spéciale des masses rocheuses, affectées par l’extraction du massif de protection, était que le puits était situé dans des masses rocheuses de qualité inférieure. Après l’extraction d’une portion du massif de protection, des déformations excessives se sont produites à l’intersection du puits avec le filon. Par conséquent, la décision a été prise d’extraire le massif de protection en entier par une coupe de déblais à travers le puits. Les effets de contraintes et décalage furent étudiés en utilisant une modélisation numérique inélastique à des stages différents. Un modèle numérique calibré fut construit, donnant des résultats modelés comparables aux décalages réels le long du puits. Eine Untersuchung wurde durchgeführt um festzustellen, ob ein numerisches Modell konstruiert werden könnte, das Resultate produzieren würde, welche realistisch aktuelle Bodendeformationen in und um einen vertikale Schacht darstellen. Die Bodendeformation resultierte teilweise aus der Extraktion des Schachtpfeiler. Eine spezielle Eigenschaft der Gesteinsmassen, beeinflußt durch die Schachtpfeilerextraktion, war, daß der Schacht in Gesteinsmassen geringer Qualität situiert war. Nach der Extraktion eines Teils der Schachtpfeiler, traten übermäßige Deformationen am Schacht/Riff Kreuzungspunkt auf. Folglich wurde die Entscheidung getroffen, die gesamten Schachtpfosten zu extrahieren und den Schacht mittels eines geplanten Verlustschnittes quer zum Schacht zu schützen. Die Auswirkungen des Druckes und der Versetzung auf den Schacht wurden unter Anwendung unelastischer numerischer Modelle in unterschiedlichen Stadien untersucht. Ein kalibriertes numerisches Modell wurde konstruiert, welches berechenete Ergebnisse mit den tatsächlichen Versetzungen entlang des Schachtes vergleicht.

Jan 1, 2003

By A E. Annels, M D. Raine, I M. Platten

Lode-gold systems are often characterised by a high to extreme nugget effect (>50 per cent), and the presence of coarse gold particles (>100 ¦m in size). They rank amongst the most difficult of ore deposits types, in terms of producing an accurate and precise resource estimate. Their effective sampling is generally difficult because of the relatively low concentrations involved and erratic nature of the gold particles. Grade continuity is usually less consistent than gross geological continuity, and is typified by the localisation of grades within discrete oreshoots. In most cases drilling, particularly diamond drilling is an effective measure of global geological continuity, whereas grade can only be reliably resolved from underground development. Depending upon drill density and geology, it is unlikely that anything above an Inferred Mineral Resource can be estimated from surface drilling alone. Underground development, in-fill drilling and, potentially, bulk sampling or trial mining will be required to delineate Indicated and Measured Mineral Resources and subsequent Ore Reserves. Grade estimation will have to account for highly skewed and often multi-modal populations, extreme values, a high nugget effect and low geostatistical ranges. A clear geological model that honours both geological and grade continuity must drive the resource estimation process.

Jan 1, 2003

By A. V. Tarasov

Investigations of thermodynamic properties of Cu-Ni and Cu-Ni-S systems and mattes have been conducted with the aid of a MC-1301 mass-spectrometer designed for studies-of processes of vapor formation of hardly volatile substances. The instrument comprised a combination of an evaporator of Knudsen chamber type with a mass-spectrometer for analysis of the vapor phase, In the process of studies of molten Cu-Ni-S systems and commercial-grade mattes within a temperature interval of 1400-1800 K the partial pressure of sulfur was measured by means of complete isothermal evaporation and the partial pressure of copper and nickel by comparison of ionic currents. The partial pressure values of the components above the molten Cu-Ni-S were used for calculation of activities of the respective components in the melt. The copper and nickel activity data obtained was used for assessing the amount of dissolved losses of these metals in autogenous smelting slags.

Jan 1, 2003

By B McCreath

Industrial process water for the Commodore Coal Mine and the adjoining Millmerran Power Station is provided by pumping secondary treated sewage effluent 100 km from the Wetalla Sewage Treatment Plant near Toowoomba. (A separate source is used for potable water.) The effluent is not of sufficient quality for discharge to a watercourse, but it is suitable, with further treatment, for the mine and power station. In designing and constructing the pipeline, special emphasis was placed on preventing accidental spills or planned releases to the environment. The pipeline and associated works can transfer 1000 ML/annum for reuse in the coal mine and power station.

Jan 1, 2003

By Hideki Yamamoto

A new technology to convert fluoride gas (C2H2F4 ; R-134a) contained in the exhaust gases from semiconductor manufacturing plants and refrigerators directly into a harmless substance have been established, thus, presenting a new concept for the disposal of fluoride gases such as CFCs that are associated with the global warming. Experimental results verify that chemical reactions with metal compounds can take place at substantially lower temperatures of 700- 800K as compared with combustion. treatment temperatures of 1200-1500K. The reaction product is mainly metal fluoride, which chemically is a harmless material. Furthermore, this process is compact, easily controlled, safe and has low running costs. This paper deals with a new chemical reaction method for the harmless disposal of gases effecting the global warming.

Jan 1, 2003

By S. K. Kawatra, S. J. Ripke

Iron ore concentrates pellets are currently in duration heat hardened (sintered) under oxidizing conditions. Pellets produced from magnetite ore concentrate are completely oxidized during induration and finish as hematite pellets. These pellets then require a blast furnace to reduce the hematite to metallic pig iron. Partially reduced pellets would save energy and fuel during transportation and further reduction. It has been stated in the literature “the most important single factor responsible for the development of strength in fired magnetite pellets containing no additive is the oxidation of the magnetite to hematite and the subsequent recrystallization and grain growth of this constituent.” However experiments shown in this paper reveal that oxidation is not necessary to produce high-strength pellets. Magnetite concentrate pellets developed similar strength when indurated at 1350°C under either oxidizing (air) or inert (argon) atmosphere; the pellets sintered under argon remained magnetite. In addition, magnetite concentrate pellets indurated under reducing (CO) atmosphere also remained as magnetite, but required induration temperature of approximately 150°C less than the other pellets.

Jan 1, 2003

By C M. Hall

We report 40Ar/39Ar ages for adularia and illite from veins and wall rocks at the Waihi and Favona deposits, in the Waihi district. One sample of vein adularia from the Favona deposit yielded a plateau age of 6.04 ¦ 0.06 (la) Ma, and two samples of vein adularia from the Waihi deposit yielded plateau ages of 6.17 ¦ 0.03 and 6.17 ¦ 0.09 Ma. Two samples of wall rock adularia from the Waihi deposit yielded plateau ages of 6.07 ¦ 0.06 and 6.08 ¦ 0.03 Ma. Adularia ages overlap at the 2s level, and we do not consider them to be significantly different. Two samples of illite from wall rocks at Favona have total gas ages of 5.66 ¦ 0.04 and 5.65 ¦ 0.04 Ma, and retention ages of 6.57 ¦ 0.04 and 6.61 ¦ 0.04 Ma, whereas one sample of vein illite yielded a total gas age of 5.29 ¦ 0.17 Ma, and a retention age of 6.26 ¦ 0.19 Ma. The total gas ages of illite are minimum ages that are equivalent to conventional K/Ar analyses, whereas retention ages of illite are maximum ages. Although interpretation of the illite data is complicated, the adularia results strongly suggest that the Waihi and Favona deposits formed contemporaneously in the same fossil geothermal system at 6.0 to 6.1 Ma.

Jan 1, 2003