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By Toru H. Okabe

As part of a systematic study on the thermodynamic properties of complex nitrides, phase equilibria of the system Li-M-N (M Mg, AI, Ga) at 900 K were investigated. An attempt to determine the thermodynamic properties of complex nitrides was made by using the galvanic cell method, which utilizes LiMgN as an electrolyte under nitrogen atmosphere. The electromotive force (Emf) of ilie cell at temperatures between 800 and 1100 K was measured. Whilc the Emf of the cell at 900 K was measured to be 0.137 V, data discrepancies of ±0.03V were found. It was difficult to determine temperature dependence of ilie Emf. The Gibbs energy change for the reaction, 113 LbN (s) + 1/3 Mg3N2 (s) = LiMgN (s), at 900 K was determined to be tJ.Gor (LiMgN) -13.2 (±2.9) kJ/mol. Using thermodynamic information on ilie binary nitride from literature, the standard Gibbs energy of LiMgN was derived to be AGO f (LiMgN)= - 121 kJ at 900 K. The thermodynamic stability range of nitride was discussed by constructing isothermal chemical potential diagrams that provide a better understanding of ilie stability region of the LiMgN phase. The diagram was found to be in good agreement with the isoiliermal phase diagram determined by ilie alloy equilibration meiliod. Although the obtained data includes large uncertainties, the results provide a better understanding of the iliermodynamic stability of nitrides. The potential application of this complex nitride to nitrogen chemical sensors or a medium for controlling nitrogen potential is also shown.

Jan 1, 2003

By Satoshi Itoh

Phase equilibria and activities of the components in the liquid lead-antimony-oxygen temary system, which is of fundamental importance for discussing the recovery of lead and antimony from a used lead-battery, have been investigated at 1173 and 1223 K. The two liquid phases of metal and oxide were observed at the temperatures studied, and the tie lines indicating isoactivities were determined. The activities of PbO, Sb015 and Sb203 in the PbO-SbOu and PbO-Sb203 pseudo-binary systems were then obtained by applying the Gibbs-Duhem equation to the phase relation of metal-oxide equilibrium. Both in the pseudo-binary systems the activities exhibit negative deviations from Raoult's law. The vapor pressures of lead, antimony and lead oxide, antimony oxide were calculated by using the activities of the components in the lead-antimony-oxygen ternary system. As a result, an oxidation of antimony concentrated in an anode slime followed by evaporation as antimony oxide Sb406 was found to be considerably effective for the recovery of lead and antimony from a used lead-battery.

Jan 1, 2003

An Environmental Impact Statement (EIS) for a major mining development typically has to address various aspects of surface water management, including some which generally tend to be the more contentious: the diversion of rivers and creeks from areas disturbed by mining, and their rehabilitation; the effective management of disturbed area run-off via the collection, containment and treatment of contaminated water on site in sedimentation dams; the collection, containment and treatment of mine pit water; the decommissioning of surface water storages; final void water quality; and water discharge criteria. Environmental Impact Assessment processes for proposed mining developments in Australia at the state and commonwealth level usually involve a form of Initial Advice Statement (or Notice of Intent), Terms of Reference, an EIS, and a Supplementary Report (or similar) which responds to agency and public comment on the EIS. The EIS is used by approval agencies to decide the acceptability of the Project, and to set the conditions of approval. The conditions are often in the form of a state-issued æOperational LicenceÆ or similar. With mining, the initial approval at the EIS stage is often just a pre-cursor to various other planning related approvals, including obtaining a mining lease. Afterwards, mine plans and plans of operations must be submitted to government at various stages of the mineÆs life, ostensibly to provide the detailed mine planning over periods of one û five years. Despite all this additional planning and documentation beyond the submission of the EIS, government approval agencies are increasingly not satisfied with conceptual water management designs and commitments to an outcome (such as meeting a specified water quality standard) in the EIS. Agencies are also requiring sufficient water management design information to be convinced that the outcomes are achievable. To assist proponents of major mining developments, the Queensland Government has published Technical Guidelines for water management, and Environment Australia has published a æBest Practice Environmental Management in MiningÆ booklet on water management. In addition, the Australian and New Zealand Environment and Conservation Council (ANZECC. 2000) has published Water Quality Guidelines which provide an approach to water management, and provide receiving water investigation trigger criteria. So, what are the water management issues that are likely to be the subject of comment, debate and negotiation prior to the EIS being approved? and what commitments may a mining proponent have to make in order to convince the approval agencies that sufficient investigation and design has been provided? This paper provides some answers to this question, by reference to recent major mining proposals which the author has managed through state and commonwealth Environmental Impact Assessment processes.

Jan 1, 2003

By I D. Hair

A numerical groundwater model was used to predict the nature of interactions between heavy mineral sands mining operations and the groundwater regime at North Stradbroke Island, Southeast Queensland. North Stradbroke Island is formed mainly of massive vegetated Cainozoic aged dune sands. Since the 1950s, a number of operations have mined rutile, zircon and ilmenite on North Stradbroke Island. In such mining operations, a dredge and an associated processing plant are floated in a pond either above or below the prime groundwater table The numerical model was based on the North Stradbroke Island Groundwater Management Model, developed in 2001 by the Department of Natural Resources and Mines (NR&M). This model was constructed using the modular, cell-centred, finite-difference groundwater flow model, MODFLOW, developed by the United States Geological Survey (USGS). The NR&M model was refined to improve model resolution and detail for simulating dredge mine paths. Of particular interest were: water table fluctuations induced by mining for the identification of slope stability risk; the optimisation of sand spear arrays supplying mine make-up water requirements; inflow and outflow rates to the dredge pond for overall mine water balance; and interactions with Eighteen Mile Swamp and water supply bores controlled by the Redland Shire Council (RSC). Depending on the water level in the dredge pond compared with the surrounding groundwater table, water either flows out of the dredge pond into the groundwater regime or from the groundwater system into the dredge pond. The MODFLOW river package (RIV) was utilised for the modelling study. Dredge pond movement was simulated using specialised software developed by Watermark Numerical Computing (WNC) to interpolate pond positions and map the dredge path to the model grid both spatially and temporally. As tailings placement affects the groundwater system through increased recharge, the MODFLOW recharge package (RCH) was utilised to simulate different recharge efficiencies. Long-term model predictions were made for the period from July 2002 to May 2021. Results of the modelling showed that exchanges of flow between mining operations and the groundwater regime could be effectively managed. The study provided valuable information which was used to develop an appropriate mine water management plan.

Jan 1, 2003

By Levent Ozdemir, Charles Merguerian

Between 1996 and 1999, a high-performance Robbins TBM [235-282] excavated a 5 mile long, 23´2? wide, and ~700´ deep tunnel through the subsurface of southwestern Queens. Low penetration rates (~6´/hr [actual] vs. ~9´/hr [anticipated])resulted from changed rock mass conditions mostly attributable to high-grade metamorphism of the rocks. Over a three-year period, as-built circumferential geologic mapping (scale 1?=10´) and digital imagery of the tunnel, fracture and fault analysis, structural, lithologic, and petrographic studies have shown that the rocks of the Queens Tunnel consist of orthogneiss of mesocratic, leucocratic, and mafic composition. These metaigneous rocks developed coarse-grained fabrics during Grenvillian (~1.0 Ga) granulite facies metamorphism, and retained their nearly anhydrous, poorly foliated character during subsequent high-grade Ordoviciande formation. Lacking a penetrative foliation, the coarse granoblastic rock texture and extraordinary garnet content (up to 50% in some zones) together proved animpediment to efficient chip production and resulted in bimodal production of blocks and excessive fines. TBM excavation of the Queens Tunnel was also hindered by geological conditions that included unexpected lithology and rock fabric orientation, a zone of crosscutting hypabyssal rhyodacite dikes, and unanticipated extent of brittle faults. The dikes and brittle faults produced blocky ground conditions and a collapsing face condition that produced cutter damage and decreased utilization. Such fundamental textural, mineralogic, and lithologic control over hard-rock TBM penetration can be predicted by careful pre-bid geological analysis. To determine the causes of lower than anticipated TBM performance, a detailed investigation was carried out that included analysis of operational data from the TBM data logger and an extensive laboratory test program on cores retrieved from tunnel walls. Integrated laboratory testing included punch, point load, tensile strength, Cerchar abrasivity, and linear cutting tests, independent petrographic analysis and machine performance analysis. These allied investigations have provided quantification that the rock mass exhibited an unusually high degree of toughness and rock directional properties and established geological causes for decreased TBM penetration rates.

Jan 1, 2003

By Rob D. Morrision, Paul W. Cleary

"The best accepted method for design of autogenous and semi-autogenous mills is to carry out pilot scale test work using a 1.8 m diameter by 0.6 m long pilot scale test mill. The load in such a mill typically contains 250,000-450,000 particles larger than 6 mm, allowing correct representation of more than 90% of the charge. This scale of DEM model is now within the practical range of standard workstations running an efficient DEM code.This paper describes various ways of extracting collision data from the DEM model and translating it into breakage and wear estimates. Account is taken of the different breakage mechanisms (impact and abrasion) and of the specific impact histories of the particles in order to assess the breakage rates for various size fractions in the mills. These impact histories have the potential to be directly related to breakage as they most resemble the single particle breakage tests which are used by the JKMRC to calibrate more traditional population balance models for variations in ore behaviour. However, the specific impact histories also show a background of many low energy collision events within the mill. This Background may constitute what is usually regarded as “abrasion” breakage. As might be expected, high impact events are concentrated in the toe of the charge and near to the mill shell where the forces associated with the load bearing on each particle is more concentrated."

Jan 1, 2003

By M Bezzina

In 1995 Standards Australia International Limited æSAIÆ published a risk management standard titled AS/NZS 4360 Risk Management. It was the first such standard published by a recognised formal standards body anywhere in the world and it put Australia at the leading edge of the risk management discipline. Many Australian and international organisations have utilised the risk management standard and it is one of SAIÆs most important and popular standards. Since its publication in 1995, the risk management standard has gone through a major revision in 1999 and is currently undergoing another such review, which is due for completion in 2004. This paper will chart the application of the standard within certain key organisations since its inception in 1995. A brief overview of the methodology behind AS/NZS 4360 will be presented as well as an overview of supporting and related standards. It is prudent to base risk management and other management system issues on existing and tested standards rather than creating new proprietary approaches. Examples of areas in which the risk management standard might be applied in the mining industry are given, subject to the specific operations of each company: technical, commercial, environmental, informational, and safety and regulatory.

Jan 1, 2003

By Chen Song

Cobalt basic carbonate particles were precipitated from 1.0mol cobalt nitrate or cobalt sulfate solution with ammonia carbonate. By controlling the zeta-potential of the particles and the ionic strength of the solution, the uniform particles with ellipsoid or rod shapes were obtained. During the precipitation process, the interface tension was diminished to the minimum and therefore the Ostwald ripening and secondary nucleation were both inhibited. The morphology and the size control by zeta-potential seem to be the result of thermodynamics rather than classical crystalline kinetics. The particle sizes were in the range of 0.4-0.6, 0.3-0.4 micrometer. After thermolysis, the spinel-type C0304 particles were produced. The morphologies of C0304 particles were similar to that of their precursors.

Jan 1, 2003

By M E. Malmstr÷m

Quantification of site-specific sulfide oxidation rates is crucial to accuracy of prediction of, for example, the environmental impact of a mine site. Sulfide oxidation reactions are reportedly increased by bacterial mediation; determination of abiotic and biotic weathering rates thus requires the establishment of sterile control samples. However, sterilisation often involves exposure of samples to extreme conditions that may alter the physical, chemical, or mineralogical characteristics of the tailings and hence affect element release rates. The impact of various sterilisation techniques, common and novel, on the element release rates from tailings from the Kristineberg site, northern Sweden, has been investigated. Batch weathering experiments indicated that the different methods of sterilisation (autoclaving, heat treatment, ethanol/heat treatment, application of antibiotics, rinsing with distilled water, and γ-radiation) did not greatly affect long-term element release rates. Long-term experiments (>30 days) are thus to be recommended for establishment of weathering rates. Sterilised and untreated control samples showed similar element release rates after ~100 days of experiments; possible explanations include that microbial oxidation is not important under our experimental conditions (Po2 = 0.2 atm, pH ~2.3, 22¦C, 0.01 M HNO3, no additional nutrients).

Jan 1, 2003

By Shize Jin

Effect of four polyols, namely ethylene glycol (EGL), glycerol (GCL), propanediol (PDL), butanediol (BDL) and three organic acids, namely oxalic acid (OA), malonic acid (MA) and succinic acid (SA) on the current efficiency (CE) and the cell voltage during zinc electrowinning was studied. Galvanostatic polarization was conducted in a supporting electrolyte (SE) containing 180 g dm-³ H2SO4, 60 g dm-³ Zn2+ and 8 g dm-³ Mn2+ at 38°C with magnetic stirring. The imposed current density was 50 mA cm-². The anodes were made of a Pb-Ag alloy and the cathodes were made of an aluminum alloy. The results showed that all the polyols tested in this study decreased the current efficiency and the cell voltage, but the decrease of the cell voltage was not important. Oxalic and succinic acids decreased the current efficiency to a less extent than the polyols, but did not decrease the cell voltage much. The only compound that increased the current efficiency was malonic acid, and its capacity of decreasing the cell voltage was the highest within the seven tested organic compounds.

Jan 1, 2003

By N. Raeis Hosseiny, S. H. Bassir

"Chador-Malu iron ore is one of the most important iron mines of Iran.About 98 percent of Fe in the ore is in shape of Magnetite, Hematite, Martite, aqua oxide of Iron and the other irons are with ferrous silicates, actinolite, cholorite and ferrous dolomites. 1% of Fe has replaced in pyrite. The phosphor distribution in the ore is non-hemogenous and its average in the whole of the deposit is 94%. It is in shape of Apatite.This mine contains considerable phosphor, which makes it useless for metallurgical uses. At this mine the phosphor is reduced in the iron ore at two steps. At the first step, magnetic part of the ore is separated from the gangues and phosphors by magnetic separator. At the second step, the ore is enriched by the flotation methods. Experimental flotation methods to obtain the optimum conditions are as follows:• Effect of Starch as Hematite depressant with ATRAC as Apatite collector• Effect of Sodium silicate as Hematite depressant with ATRAC as Apatite collector• Effect of ASAM as Apatite collector with Sodium silicate as Hematite depressant• Effect of ATRAC (BEROL) as Apatite collector with Sodium silicate as Hematite depressant• Effect of ASAM & ATRAC mixture as Apatite collector with Sodium silicate as Hematite depressant• Effect of Kcarbonate as pH-modifier• Final test to Optimize pH, Collector, DepressantAt this research we have found the optimum circumstance of the flotation of Chador-Malu iron ore in order to decreasing phosphors of iron oxide and floating of Apatite to make pure Hematite.To reach the optimum conditions, some tests were done with different amounts of pH, collector and depressant. The results are as follows:"

Jan 1, 2003

By Jack Curran

KANSAS CITY, MO - Performing one of the most impressive urban building-implosion projects in recent memory, Tulsa, Oklahoma-based Dykon Explosive Demolition Corp. and Omaha, Nebraska-based Anderson Excavating recently felled the landmark Columbia Bank Building in downtown Kansas City, Missouri, USA. Although every structural blasting project presents special challenges, this undertaking was most notable for its unusually unique structural design, tight clearances, and high risk to adjacent structures.

Jan 1, 2003

Financial theory often takes some time to penetrate industry and when it does it can result in a paradigm shift in valuations and mental models. The Black Scholes option valuation was first published in 1973, although the authors were only awarded a Nobel Prize in 1997. The valuation of real options has been applied to the oil and gas industry for some time, however it has only recently been more widely applied to the non-oil, mineral resource sector. The use of real option valuation (ROV) for the valuation of marginal and short mine life resource projects is a more useful valuation tool than the conventional DCF, NPV valuation tool. The application of ROV has major implications for corporate strategy. It generally favours equity over debt funding and non-hedging over hedging. A retrospective assessment of the successful development of the Lennard Shelf Operations demonstrates the concepts of implementing real options and the value destruction of limiting operational flexibility through debt and hedging activities.

Jan 1, 2003

By Steven R. Izatt

IBC Advanced Technologies, Inc. (IBC) has developed a mercury selective product, which can be used by sulfuric acid producers as either a polisher, or as the primary technology for mercury removal from sulfuric acid. The Molecular Recognition Technology (MRT) separations material selectively binds Hg2+, and to a lesser extent Hg+, out of concentrated sulfuric acid. Mercury output levels of less than 0.1 ppm can be attained by the MRT system. Pilot plant tests have been successfully conducted at base metal smelting operations. A large-scale commercial plant is due for commissioning in 2003. Results from these projects will be discussed.

Jan 1, 2003

By J. Tian

"BHP Billiton carried out a pre-feasibility study on the LanPing zinc deposit to evaluate the possibility to jointly develop the zinc deposit into a large-scale zinc project with their Chinese partner. The unique characteristics of the complex LanPing zinc orebody and ore are 1) smithsonite (ZnCO3) as one of major zinc bearing mineral besides sphalerite, 2) varying and irregular oxidation degree of zinc (0 ~ +90%) in the different zone and depth of the deposit, and 3) varying host gangue from limestone/calcite dominant to quartz dominant, which requires a robust and flexible flotation process to recovery zinc from both sulphide and oxide efficiently.The conventional mineral processing flowsheets have been tested on the LanPing samples taken from the various orebodies by various parties during the past 20 years that includes a sequential flotation flowsheet that was tested in a demonstration plant using the mixed ore. The results of the demonstration plant runs show that the conventional oxide flotation using Na2S and amine collectors could achieve 50 ~ 75% of oxide zinc recovery at very high sulphidiser consumption for the mixed ore but the highly oxidised ore did not satisfactorily respond to the flowsheet in terms of performance consistency and efficiency of oxide zinc recovery, which is very crucial to the overall economics of the project."

Jan 1, 2003

By Bowen Li

Copper vermiculite is a special nanomaterial with excellent antibacterial and antifungal performance. By means of ion exchange, copper vermiculite containing up to 5.8wt% copper was prepared. The chemical and mineralogical characterization of the material was investigated in this study based on the XRD, AAS, TEM and EDS analysis, as well as the calculation of crystalline parameters and crystal chemical formula. Cu2+ and Mg2+ have similar atom radius and same electrovalence. Correspondingly, the structure character of copper vermiculite is very close to that of standard Mg-vermiculite. Most of the CU21 may have occupied the interlayer cationic positions in the form of hydrate in vermiculite. However, some may have entered into octahedral coordinate positions. The values of au and bo of the copper vermiculite crystal cell have no obvious change compared to that of original vermiculite micropowder, but the Co value decreased slightly, which is desirable for the stabilization of the Cu2+ in copper vermiculite.

Jan 1, 2003

By E. V. Manlapig

"Some researchers postulate that the floatability of a particle in the streams of an industrial flotation circuit is a function of only its size and liberation properties. They do not discount the importance of reagent or surface contamination on particle floatability but assume that the reagent coverage or surface contamination of the particle surfaces is essentially uniform for particles of similar size and mineralogical properties when subjected to a particular chemical regime.In this paper, samples collected from laboratory batch flotation tests performed on different streams of Cominco Teck’s Red Dog lead cleaning circuit have been characterised with respect to their size, mineral association and mineral surface exposure. An analysis of this data set indicates that the flotation rate of a particle in an industrial flotation environment is a strong function of its size and also of the mineral composition of its surface (Figure 1). It is a function not only of the proportion of the most floatable mineral on its surface but of the floatability of the other minerals on its surface as well.Nodal analysis is a technique developed by the authors that can be used to determine if the ore floatability of a particle class is changing within an industrial flotation circuit. This technique is used within the paper to show that the floatability of all the different types of particle classes studied within the Red Dog circuit did not change significantly during the lead cleaning stage. However, it was also concluded that particles with the same size and mineral composition did not all float with the same rate in the individual streams of the flotation circuit, but with a distribution of rates. It is suspected that the particles within a size mineralogical class in this study have varying degrees of surface oxidation and that this results in varying particle flotation rates. Thus basing particle floatability on size and mineralogical effects, alone, in a flotation model is not always valid."

Jan 1, 2003

By G. C. Yao

Branch and needle-shaped intermctallic compounds of iron, silicon and aluminum normally exist in the molten aluminum. If a suitable amount of manganese metal is added into molten aluminum, the shape of the intermallie compound particlcs may become lumpish and spherical. According to the difference in electric and magnetic properties of these impurity particles and molten aluminum, these impurity intermctallie compound particles can be separated by applying an alternating magnetic field. In this experiment the alternating magnetic field was formed by a "C" type loop with AC (50Hz) current. The inner vacuum of the fireclay refractory separator is 25>< 15" 130mm3 with a lateral baffle inside. The separator was put into the interspace of the "C" type loop. It was found that the longer the separation time, the larger the amount transferred of impurities. The amount of transferred impurities increases with the increase of separation time and intensity of magnetic field. The addition of manganese metal enhanees signifieantly the efficiency of impurity separation.

Jan 1, 2003

By Mônica Suede Santos Silva

This work describes characterization of the performance of the tundish of a six strand continuous casting unit of the Companhia Siderurgica Belgo Mineira, Joao Monlevade, Brazil using physical modeling. Permanent and transient conditions, due to ladle metal composition changes are considered. Pulse and step tracer addition techniques are employed to assess the control variables. For transient conditions the degree of inter-mixing and the minimum residence time are determined with a view to optimize the process especially during the grade changes of steel.

Jan 1, 2003

By Jean-Michel Rendu

On April 30, 2003, representatives of the Society for Mining, Metallurgy and Exploration, Inc.(SME) met with the staff of the Division of Corporation Finance of the U.S. Securities and Exchange Commission (SEC). The meeting was held to discuss issues related to the estimation and publication of mineral resources and ore reserves. It took place in the Washington, D.C. offices of the SEC. SEC staff members included Roger Schwall, assistant director, Division of Corporation Finance; Jill Davis, senior accountant; Roger Baer, senior mining engineer; Carl Chavez, chief mining engineer; Ron Winfrey, senior petroleum engineer; and John Murphy, senior petroleum engineer. SME committee members included JM Rendu, independent consultant and chairman of the SME Committee on Resources and Reserves; Ian Douglas, manager of deposit modeling and reserve estimation with Newmont Mining; Art Graham, director and mining engineer with Deutsche Bank Trust Company Americas; Larry Smith, chief geologist with AMEC Mining and Metals Consulting; and George MacDonald, vice president of exploration with Freeport-McMoRan Copper and Gold.

Jan 1, 2003