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By Katarina Theander, Robert J. Pugh

In the flotation process, control of the stability of the froth is extremely critical. In the case where the froth is too stable then mechanical entrainment of particles can occur but in the opposite case, where the froth is too unstable and difficult to skimm-off, then a reduction in recovery can result. In minerals and deinking flotation, commercial fatty acids are used and may act as both both collectors and frothers. However, frequently the fatty acids are mixed with nonionic ethoxylated surfactants to give more effective froth control and increase the flotation performance. It is of interest to note from the surface chemistry literature, that such mixtures may cause synergistic effects in surface activity which may explain changes in bubble size, foaming and carry over of particles. In the present study, we have carried out foaming and drainage experiment with oleic acid and model nonionic surfactants; hexa(ethylene glycol) mono-dodecyl ether, C12E6 and tetra (ethylene glycol) mono-dodecyl ether, C12E4 both in separate and mixed systems. Frothing was carried out in a column, equipped with a series of conductivity electrodes which enabled the water content of the froth to be measured along the length of the column, during various stages of the drainage process. The variation in water content of the froth enabled the process to be characterised by distinct three stages; (a) an entrainment state where the water transfer from the bulk phase to the froth was dominant (b) a steady state when entrainment and drainage are balanced and no water is transferred to or from the froth and (c) the drainage step when drainage predominates and the volume of the bulk phase increases. We also carried out surface tension measurements on the oleic acid/ nonionic systems and related the results to the frothing and drainage performance. From the surface tension data, the adsorption interaction parameter of the mixed systems at the air/solution interface could be calculated and was found to depend on the oleate/ nonionic surfactant ratio. This value was related to the frothing performance and the results indicated a positive interaction parameter for the mixed surfactant systems which could explained the synergistic effects in frothing performance.

Jan 1, 2003

By C Fenton

The mining industry is a relatively minor user of water, which has historically been largely soured from private schemes. Frequently mines are often located in areas with limited available water resources. Water reform is increasingly affecting access to water for new mining projects and mining companies are being required to consider the value of water and the implications of reliability in their planning. This paper seeks to briefly review the water reform process in Australia and how it is affecting the mining industry with reference to some recent project experience.

Jan 1, 2003

By R. Kus´

The paper presents the comments on the advantages of implementing an integrated system of managing mining exploitation in hard coal mines, as well as the comprehensive integration of information on the process of deposit exploitation with economic data, so as to achieve an optimum technical and economic effects. The principles of constructing the production management system have been presented, thanks to which the management boards are provided with reliable technical and economic information on a mining company via information technology. The strategic direction of a company’s operation may currently be verified according to the external conditions that change over time (the information on the deposit, force majeure events, changing expectations of customers, etc.).

Jan 1, 2003

NIOSH is conducting research to reduce the silica dust exposure of workers at surface coal mines. One goal of this research is to evaluate the relationship between drilling parameters, rock strata and silica dust generation. This study involved measuring blast hole emission dust from a rotary drill rig which required sampling high concentration dust (>400 mg/m3) for silica content in a high velocity airstream. To measure dust initially, traditional sampling methods using personal sampling instruments were attempted in and around the shroud area of the drill with no success. Variations in the dust cloud concentrations under the shroud, the condition of the shroud and its orientation over the hole, and ambient air conditions prevented consistent and accurate dust measurements from being obtained. Amore consistent dust cloud is necessary for accurate measurements. An area of the drill’s dust collector system that consistently draws the emitted airborne dust from the hole is the collector tube. This tube connects the drill collector’s vacuum and dust filtration system to the shroud area. Assuming the collector system is working as designed, sampling from the collector tube would enable more consistent and accurate samples to be taken. However, current personal samplers are unable to sample in the concentrations and velocities experienced in the collector tube, so another method had to be devised. To achieve the desired results, an in-stack cascade cyclone was used. Preliminary field testing shows positive results.

Jan 1, 2003

By M. Barsky, E. Barsky

A study was conducted to elucidate the relationship between the hovering velocity and the particle settling velocity. The experiments were carried out in a water medium on five materials ranging in density from 1.070 to 4.000 kg/m3. Analysis of the results with allowance for the distribution of stream velocities over the cross section of the pipe revealed that the final settling velocity of the particles was equal to their local hovering velocity (on the stream axis), and not to the average velocity of vertical flow as is generally believed. It therefore follows that the kinetic structure of the stream must be taken into account when constructing theoretical models of the process for purposes of computation. In addition, the optimal stream velocity is not always equal to the hovering velocity and in fact is governed by other factors as well. Illustration is provided by the results of a study conducted in a vertical cascade classifier comprising eleven identical stages. The feed material was introduced at each stage successively beginning with the topmost (i* = 1 ) and ending with the lowermost (i* = 11). First, the stream velocity that yields optimum separation conditions at each stage of the cascade (i.e. k=50%, k being the yield of a given size class in the fines for a single stage) was sought. Subsequently the conditions of optimal separation for the instrument as a whole were determined (i.e. F(x) = 50%, F(x) being the yield of a given size class for the entire instrument). The results of the study are presented in the table.

Jan 1, 2003

By Dai Xi

In the present work, the viscosities of molten FenO-MgO-SiO2 and FenO-MgO-CaO-SiO2 semi-synthetic slags for nickel flash smelting were measured in the temperature range from 1473 to 1723K by a rotational viscometer. The ratio of Fe to Si02 was fixed at 1.2, calcium and magnesium oxide contents varied in the range from 2 to 8 mass% and 9 to 12 mass%, respectively. The results showed that silicate anions became smaller by increasing CaO content, which results in a decrease of the viscosity of the slag. In the case of MgO addition the viscosity behavior was complicated. At MgO content below II mass%, the viscosity increased with the increase of MgO at all temperatures tested. However, when the MgO content was above II mass%, the viscosity decreased slightly for FenO-MgO-CaO-SiO2 system. At higher MgO contents, low-viscosity slags can be obtained by adding CaO. At a given composition, .the viscosity decreased with increasing temperature. The higher the temperature, the more MgO can be added before saturation. The effect of Fe3O4 on the viscosity was quite significant. The viscosity of slag increased by 300mPa-s at 1573K when Fe3O4 content varied from 3 to 9 mass%. The viscosity values are presented as the functions of temperature and composition. A comparison between FenO-MgO-SiO2 and FenO-MgO-CaO-SiO2 systems is given in this study.

Jan 1, 2003

Water is a key resource input to copper heap leach operations in both quality and quantity. A number of recent developments in analysis of the technology have shown that water consumption can be optimised. The leach consumption has been generally considered in terms of minimisation of the evaporative loss by changing the application method (drippers or wobblers). Modelling of the irrigation effects on leach rate has shown that the poorer surface coverage from drippers has an adverse effect on the leach extraction rate. This is particularly evident in the early part of the leach. The use of different irrigation systems during alternate parts of the leach cycle can have benefits in minimising the water consumption without an unacceptable outcome from extended extraction times. By combining the leach rate effect with the evaporative loss estimates, an economic decision matrix can be generated to allow the operator to select an appropriate leach irrigation strategy, combining both irrigation delivery and irrigation rate. In the SX-EW plant, the total quantity of EW bleed and SX scrub stage bleed (both for iron control) can be reduced to an absolute minimum. The economic minimum may be different depending on the cost of producing the high-quality water used to replace the bleed streams. Adjustment of the SX process, in particular use of multiple entrainment control steps, can provide significant reductions in the total bleed and make up requirements.

Jan 1, 2003

By Wolfgang Schott

The propagation velocity of in-seam seismic (ISS ) waves depends on frequency which is also known as dispersion. This dispersion is not only determined by the thickness of the coal seam and its dirt hand content (i.e. thickness and position), but also by the rock type and its condition (soft or compact) above and below the coal. A coal panel completely surrounded by roadways was investigated using the in-seam seismic transmission survey technique. Along the roadways the immediate roof was either sandstone and shale- The seam thickness varied between 1.20 m (sandstone in the roof) and 1.40 m (shale in the roof) and a fault system (normal faults) crossed the panel with a total throw of about the seam thickness. Below this coal seam another coal scam with a thickness of about 80 cm exists. Its interval shown by exploratory drilling changes from about 60 cm to more than 6 m (scam splitting). Tomographic inversion was applied to the dispersion of the measured ISS waves and velocity distributions were calculated at frequencies found to he most sensitive to changes in the seam thickness and the distance to the coal seam below. By correlating the velocity distributions with known values along the roadways approximate distributions of the coal seam thickness and the seam splitting within the panel were produced. The mining of the coal panel had already been finished and comparison was made between the survey results and the actual situation as far as it was documented. Prediction by the seismic survey was partly in good agreement with the actual held conditions or showed at least the same trends.

Jan 1, 2003

The advantages of quantitative environmental risk assessment techniques over the more commonly used qualitative approach is widely accepted. One important parameter related to the level of risk is the extent and geographic spread of pollutants. Geographic Information Systems (GIS) provide a powerful and highly flexible tool that increases the sophistication of the risk assessment methodology. Through spatial representation, the estimated risk becomes more comprehensive, thus facilitating the decision making process. In addition, valuable qualitative information can be incorporated into the risk assessment procedure with the help of GIS. This paper illustrates a methodology for quantifying risks posed to human health, by exposure to contaminated land, in a manner, which gives a measure of the uncertainty in the assessment and preserves the spatial distribution of the risks. The case study utilised to illustrate the methodology is a large industrial area around a number of decommissioned minerals production and processing sites with known high heavy metal loads at Lavrio, Greece. The spatial distribution of Pb concentration in soils was derived from 425 soil samples collected over a total area of 120 km2. Indicator kriging was used to quantify the spatial distribution of the risk and related uncertainty and the results displayed in map form using GIS.

Jan 1, 2003

By Steve Kral

Borates are minerals that contain boron. Trace amounts exist in rocks, soil, water and people. Boron-containing ores are rare and U.S. Borax, a subsidiary of Rio Tinto Borax, controls one of the world’s two world-class borate deposits. Through its global systems of mines, refineries, ports, sales offices and distribution centers, the company supplies nearly 45 percent of the world’s demand for borates. Borax has been mining borates in California for more than a century. This year the company celebrated 131 years of continuous business in the Golden State and 76 years at its operations in Boron, the site of California’s largest openpit mine. It also has mines and refineries in Argentina, refineries and ship-ping facilities in Europe and technical staff in the United States, North and South America, Europe and Asia Pacific. So, with the 130±years of borate mining and processing experience behind it as well as its global marketing and distribution centers, there is very little that Borax does not know about borates.

Jan 1, 2003

By R. Katzenbach, M. Vogler, U. Adamietz

Abstract The design of deep excavation pits in rock mass is dependent as well on the mechanical properties of the rock mass as for example the orientation and the type of discontinuities like bedding planes, joints and fissures, the length of the discontinuities (persistence), the grade of weathering, the strength of rock mass, and the shear strength in the discontinuities, etc., and also on the respective boundary conditions specific for the project, and here especially the geometrical boundary conditions. The basic mutual influences and interactions between these boundary conditions are explained and exemplary presented at an excavation pit with a depth of 18,5 m, situated at a slope with a surface near groundwater table. Résumé La planification des excavations profondes dépend aussi bien de la qualité mécanique du roc, par exemple la location de la texture de la surface de moindre résistance, le degré de rupture, le degré de décomposition, la dureté du roc et la résistance limitée au cisaillement de la texture de la surface de moindre résistance que des conditions limitées spécifiques pour le projet, ici en particulier des conditions limitées géométriques. Les influences et interactions essentielles et mutuelles entre les conditions limitées isolées seront expliquées et présentées à l’aide d’une excavation 18,5 m de profondeur, située sur une pente où le niveau des eaux souterraines est près de la surface. Kurzfassung Die Planung tiefer Baugruben im Fels hängt sowohl von den mechanischen Eigenschaften des Fels wie z.B. der räumlichen Lage des Trennflächengefüges, dem Durchtrennungsgrad, dem Verwitterungsgrad, der Gesteinsfestigkeit sowie der Scherfestigkeit des Trennflächengefüges als auch von den projektspezifischen Randbedingungen hier insbesondere von den geometrischen Randbedingungen ab. Die wesentlichen gegenseitigen Einflüsse und Interaktionen zwischen den einzelnen Randbedingungen werden aufgezeigt und an einer 18,5 m tiefen Baugrube in Hanglage mit oberflächennahem Grundwasser vorgestellt.

Jan 1, 2003

By Dingwu Feng, Jannie S. J. van Devente

"The effect of ultrasonication on reactions at solid/liquid interfaces was investigated in two slurry systems, i.e. gold cyanidation and geopolymerisation. The kinetics of gold extraction were significantly enhanced and the cyanide consumption was reduced in the cyanidation of a pyrite concentrate using ultrasonication, probably due to the prevention of leaching passivation, the improvement of the dissolution of the gold host sulphides and the oxidation of soluble sulphides to sulphate. The effectiveness for ultrasonication was improved with the injection of oxygen and the addition of dithiophosphate through enhancing the formation of the oxidation radicals and selectively inducing cavitation bubbles directly at the sulphide interfaces. Ultrasonically enhanced cyanidation could render currently uneconomic deposits viable for extraction by improved cavitation efficiency with the aid of surfactants.Ultrasonication increased the compressive strength of the formed geopolymers through accelerating the dissolution of the Al-Si materials, strengthening the bonds at the solid particle/gel phase interfaces, enhancing the polycondensation process and improving the formation of semi-crystalline to crystalline phases. The use of power ultrasound will yield high-performance geopolymer materials."

Jan 1, 2003

By Takaaki Ishikawa

The distribution equilibria of lead, zinc and copper between CaO-Si02-Ah03 melts and liquid copper were measured at 1623K under a controlled H2-C02 atmosphere. The distribution ratios were plotted against the oxygen partial pressure, and reasonable oxide forms dissolved in the melts were estimated from the slopes of the plots. The activity coefficients of zinc oxide (ZnO), lead oxide (PbO) and cuprous oxide (CuOQs) increased with increasing slag basicity, defined by Xcao /XSiO, The temperature dependence of the activity coefficients was also measured.

Jan 1, 2003

The quality of the rock mass in which an excavation is being driven has a strong influence on the level of dynamic forces to which the excavation can be subjected and sustain damage. Though each specific rock mass occurrence is unique yet there are common rock mass features which influence the outcome of controlled blasting in a similar way. A field study was conducted which involved assessment of blast damage at several operating mines and the blasting of small-scale models. The effects of block size and strength, joint parameters, ground water, weathering of rocks and rock mass rating on the results of controlled blasting have been investigated and discussed in this study.

Jan 1, 2003

By Klaus Opolony

The world's most popular method of longwall mining requires multiple entry systems for the panels. In contrast to this mine layout the roadways in German coal mining are used for advanced mining from the rock mechanic point of view or are even re-used by a second panel. This procedure of roadway use is presented within this paper using a 3D visualisation software tool. In the previous conferences in Morgantown several papas had addressed the basics of rock mechanic background, planning tools and variants. This paper gives a practical case study for reuse of a roadway in a German coal mine. The heading and the use of various alternatives are compared under the aspect of efficiency and costs. Within the comparison the specific requirements and benchmarks of German coal mines are taken into consideration. The costs for a multiple entry system and first of all the development rates that can be achieved with common road heading systems are compared with international layout alternatives. A prospect includes a discussion of pro and con for various development methods. Devices are given due to this prospect if and how multiple entry systems are applicable to German coal mines. The paper gives an initial point for international comparison and is a base for further discussion.

Jan 1, 2003

By Richard L. Patterson, Alan P. Finch

Twenty years ago, when tunnel projects in the UK were generally procured by the public sector, many were completed late and over budget. Now a significant proportion of new infrastructure is developed by the private sector. Seeking more certainty in cost and programme, promoters have tried new and radically different methods of procurement and contract forms. The paper will review these developments, then examine the approach adopted for some of the largest current UK tunnelling projects (both in the public and private sectors) including the Channel Tunnel Rail Link, the Heathrow Terminal 5 Development and new highway tunnels.

Jan 1, 2003

By Michael J. Sapko, Eric S. Weiss, Kenneth L. Cashdollar

A fundamental safety research area for the National Institute for Occupational Safety and Health (NIOSH) is to eliminate the occurrence of coal mine explosions or to mitigate their effects. One approach is to develop and evaluate new and innovative seal designs that provide increased explosion protection for mining personnel. The NIOSH Pittsburgh Research Laboratory (PRL) cooperated with HeiTech Corp. of Virginia, Barclay Mowlem Construction Ltd. of Queensland, Australia, and the Mine Safety and Health Administration (MSHA) in three separate research programs to evaluate the strength characteristics and air leakage resistance of numerous innovative seal designs and ventilation control structures for use in underground coal mines. For each phase of the program, various full-scale seals, stoppings, and an overcast design were constructed in PRL's Lake Lynn Experimental Mine near Fairchance, Fayette County, PA. The seals and stoppings were built in crosscuts and were subjected to explosions to evaluate their strengths. Four pumpable cementitious seal designs ranging in thickness from 610 to 915 mm (24 to 36 in) were evaluated in the first cost-reimbursable research program with HeiTech Corp. A simple wooden framework with brattice liner was used as a form to contain the cementitious slurry during the curing period. As the seal designs decreased in thickness, higher compressive strength cementitious grout was used. All four seals withstood an explosion pressure pulse of at least 138 kPa (20 psi) while maintaining acceptable air leakage resistance. In the second cost-reimbursable research program with Barclay Mowlem Construction Ltd. of Australia, several innovative seal and stopping designs and an overcast design were evaluated. Each of the seal designs and the overcast side and wing walls used one or more air-inflated vinyl bladder assemblies anchored to the mine roof and hitched into the ribs and floor. The air within these bladders was displaced with a high-strength cementitious grout. The overcast deck consisted of a 200-mm ('7.8-in) thick reinforced cementitious slab. This was the first time that an overcast structure had been explosion tested under full-scale conditions. All of the seals, stoppings, and overcast design passed the air leakage tests before being subjected to a series of explosions with static pressure pulses ranging from 14 to 475 kPa (2 tab 69 psi). Instrumentation measured seal and overcast wall displacement as a function of time. The 450-mm (1 7.7-in) thick seal in the 2.8-m(9-ft) high third crosscut withstood an explosion pressure of 170 kPa (25 psi), but failed during a later test, which generated a peak static pressure of 475 kPa (69 psi) at the seal location. A similar 450-mm-thick seal in the 2.1-m (7-ft) high second crosscut withstood three explosion tests, which generated peak static pressures of 195, 205, and 370 kPa (28, 30, and 54 psi) at the seal location. Next, the overcast design withstood four explosions, which generated static overpressures ranging from 16 to 47 kPa (2.3 to 6.8 psi). A third program at the request of MSHA evaluated the effectiveness of using pressurized grout bags (Packsetter bags) along the mine roof and ribs in lieu of floor and rib hitching for a standard-type solid- concrete-block seal. This program was initiated to address an urlusual geological mining condition encountered when building seals in entries where required rib hitching is not a viable option due to soft friable coal. Results showed that the use of these quick-setting grout-filled Packsetter bags pressurized internally to 300 kPa (44 psi) not only provides a seal that can withstand a 138-kPa static pressure explosion, but also provides a sealing option where rib hitching is not possible.

Jan 1, 2003

By L. du Plessis

The name FISH (Fully Integrated Sort House) refers to a class of technology deployed at Jwaneng Mine final diamond recovery. The FISH concept is based on three pillars, namely: ?Improved sorting efficiency FISH is based on laser technology, which is more efficient than hand sorting for certain product categories. Laser sorting is based on measuring in-elastically scattered light from molecules and this is referred to as Raman spectroscopy. The Raman scattered light occurs at wavelengths that are shifted from the incident light by the energies of molecular vibrations ?Availability of production information Roller gap diamond size distribution information is generated on line for upstream process optimization ?Improved product security A ?hands-off? philosophy reduces security risk during operation and maintenance of the plant. In addition, a number of lessons were learnt about the application of new technologies in the industry: ?The required human competency profile demanded by new technology should match the available competencies of the operational staff ?An integrated information management system should be fully functional for both production management and diamond control purposes ?Operational feedback must be correctly evaluated to identify design, maintenance, training and operational issues so as to accelerate the maturity of the new technology within the time span of the sustainable operations project ?Project execution and technology maturity risks have to be evaluated and married to ensure risk mitigation by means of suitable project resource and contracting model selection.

Jan 1, 2003

Brand se Baai, on the North-Western Cape Coastline of Southern Africa, is the site of the Namakwa Sands Limited Heavy Mineral Sands Mining Operation. The mine is a 14 000 000 tonnes per annum open-cast strip-style mining operation using truck and excavators to mine the sand. The orebody consists of relatively unconsolidated sands reworked by fluvial, marine and aeolian mechanisms. The total orebody includes three primary ore types, namely the Red Aeolian Sands, the Dorbank (a hardcap layer) and the Orange Feldspathic Sands, which forms the bulk of the resource. Mine planning and scheduling is done using a 50 m + 50 m variable bench height system with three primary bench heights. The Aeolian and Dorbank each have a bench that varies with their thickness of up to a maximum eight metres and the Orange feldspathic sand, a standard bench height of eight metres. For a number of years Namakwa Sands used a complex 2D, Datamine Based, macro system to perform the resource evaluation and mine design. As the mining operations expanded it became clear that a complete system redesign was required to cope with the increasing operational pressures coming to bear on the old system. The biggest challenges facing any replacement system are the sheer scale of the mining operation (16 km long and 7 km wide resulting in a minimum of 30 000 individual 50 m + 50 m mining blocks), the size of the geological data files (up to one gigabyte) and representing the benching system accurately (as the benches follow the topography and are not horizontal). In addition to these large-scale issues, the ability to run multiple mine design scenarios was required, an aspect which the old system was unable to perform adequately. Based upon these primary difficulties, a new business process was developed which required a complete rethink of the mine design methodology as well as the creation of a new system to deplete the resource model, produce monthly reconciliation evaluations and create a ultimate pit limit based on the operations mining cost model. Using a system based on the Earthworks Mine2-4D Mine Design and Scheduling System (with its mine design and scheduling specific tools), as well as a small, customised program, massive time-savings have been made. It is now possible to run several life of mine scenarios in the same timeframe that a single life of mine run took under the old system. This paper will present the methodology and business decisions behind the new Namakwa Sands system, and detail the restructuring and development used to deal with the large data set sizes and long processing times inherent in the old system. Future enhancements to the system that will make it more generically applicable to open-cast mining scenarios will also be dealt with.

Jan 1, 2003

By V. P. Kolosyuk, A. M. Bryukhanov

Occurrences of hazardous events (explosions of methane or coal dust, fires, outbursts) have been investigated and presented as a flow of events in time. It has been shown that flows of hazardous events in a long time span are homogeneous, stationary and no-after effect flows and can be considered as stationary Poisson flows. A flow of CH4/coal dust explosions that had happened for the last 27 years in Ukraine was analyzed. The explosions have been statistically processed. Practicability of agreement of statistical and theoretical data on mathematical expectation and mean square deviation of time interval between explosion and the explosion intensity has been stated. Probability of an emergency event in time is expressed through an exponential function, while mathematical expectation of an accident and mean square deviation of time interval between successive explosions are in inverse proportion to the accident intensity. Accident probability for practical purposes can be determined as a product of accident intensity by calculated time interval.

Jan 1, 2003