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The aim of this investigation was to study the influence that varying production rates have on iron sinter quality. This was done by performing sinter pot tests at different pressure drops over the sinter bed, namely 11 kPa and 15 kPa (for 500 mm total bed depths). During each of the sintering processes temperature-time profiles were recorded of the top, middle and bottom layers of the sinter bed. On completion of the sinter process the sinter cakes were divided into top, middle and bottom layers. The physical properties of each layer were subsequently characterized by performing a tumbler test and a sieve analysis. A comprehensive mineralogical study was also conducted on each layer. This study revealed that sinters of similar cold strength could be produced under the examined production rates. However, a higher production rate was accompanied by an increased amount of fines. The cold strengths of both sinters significantly increased from the top layer to the bottom layer of the sinter bed. This strength variation is not related in any simple way to the phase composition. Keywords: Sinter, sinter bed, production rate, phase composition, cold strength, tumbler index, sieve analysis, temperature-time profile

Jan 1, 2003

By W. K. Collins, C. L. Dahlin, D. C. Dahlin, W. K. O’Connor, G. E. Rush

Direct mineral carbonation was investigated as a process to convert gaseous CO2, into a geologically stable final form. The process utilizes a slurry of water, with bicarbonate and salt additions, mixed with a mineral reactant, such as olivine (Mg2SiO4) or serpentine [Mg3Si2O5(OH)4]. Carbon dioxide is dissolved into this slurry, resulting in dissolution of the mineral and precipitation of magnesium carbonate (MgCO3). Optimum results were achieved using heat-pretreated serpentine feed material and a high partial pressure of CO2 (Pc02). Specific conditions include 155°C, PC02 = 185 atm and 15% solids. Under these conditions, a 78% conversion of the silicate to the carbonate was achieved in 30 minutes. Process mineralogy was utilized to investigate the appropriate feed characteristics, identify the process products and interpret the mineral dissolution and carbonate precipitation reaction paths. Key words: Mineral carbonation, Carbon dioxide sequestration, Carbonates

Jan 1, 2003

By G. A. Brooks

Reactive ball milling has been proposed as a new route for producing carbides from oxides through carbothcrmic reduction. It is claimed that through milling oxide and graphite powders to the nanoscale, amorphous materials with very high reactivity are formed, that allows for easy transformation of the starting material to another in a subsequent thermal process. Thermodynamic analysis of this proposed process suggests that unless particle sizes are reduced to below 10nm, then reduction in size alone cannot explain a change in the stability of oxides. Even with nanometer scale powders, the products formed need to have a lower total surface energy than the reactants before a chemical change will occur. A model developed by Bhattacharya and Arzt for predicting localized temperature changes based on milling conditions suggest that temperarure rises less than 400 K will be achieved in laboratory conditions. The present calculations suggest that nanometer scale powders formed through high speed ball milling (>10 mls) may have undergone a process analogous to melting and quenching. Further work is required to fully distinguish these features.

Jan 1, 2003

By Katsunori Yamaguchi

A new technique for the removal of tramp-elements from steel scrap has been required from the viewpoint of saving energy and protection of environment. In order to obtain fundamental information on the removal of copper, tin and zinc from molten iron, the extraction method by using of phase separation in the liquid Fe-Pb-C system was investigated at 1453K. A mixture of iron, lead and carbon melted in a carbon crucible separates into two phases of lead and iron containing carbon. The compositions on the miscibility gap in the Fe-Pb-C system are 95.4%Fe-4.5%C-0.1 %Pb and 99.9%Pb-0.I%Fe. The distribution ratios of copper, tin and zinc between the lead and the iron phases, Lx [mass%X in molten Pb]/(mass%X in molten Fe), are 2.2, 2.2 and 1.4, respectively. Seventy percent of copper and tin from iron scrap can be eliminated with comparable lead addition. Gold, silver and palladium are enriched in the lead rich phase, on the contrary platinum and rhodium are more distributed to the iron rich phase than to the lead phase.

Jan 1, 2003

Most processing plants use automatic samplers to extract ore aliquots along a producing shift. These aliquots are combined into a sample normally sent to lab analysis. The sampler used in the extraction of an aliquot from a continuous flow of ore, i.e. a belt conveyor is required to be both precise and accurate. Surprisingly, not all commercial automatic samplers exhibit these two mandatory properties. Consequently, it is recommended the development of a procedure able to check sample assays reproducibility obtained using a given sampling protocol. This paper uses the Gy’s sampling theory to evaluate coal quality control practices at a washing plant using an automatic sampler extracting coal increments from the ROM feeding belt conveyor. Gy’s theory provides the means to establish the precision limits for a given sampling protocol. Various ore properties are required to be determined in combination with sample mass and mass of the lot sampled. All this information leads to the definition of the precision limit. The precision limit obtained was checked via an experiment mimicking what happens in situations where both miner and consumer use the same and appropriate sampling practices. The experiment demonstrates that sampling theory precision limits were valid if unbiased samplers are used by both parties, i.e. miner and consumer. Keywords: sampling, quality control, coal

Jan 1, 2003

By Y. P. Shoupletsov

ABSTRACT. A retrospective analysis of some geomechanical classifications for rock masses is presented. It is shown that estimates of rock mass strength according to geomechanical classifications developed, e.g., for construction of tunnels and for ore mines can differ very much. Development of specifically oriented classifications for rock masses with certain geomechanical properties is required. ZUSAMMENFASSUNG. Es wurde eine retrospektive Analyse einiger geomechanoschen Klassifikationen von Gesteinsmassiven durchgefuhrt. Es idt aufgezeigt worden, dass die Bes-timmung der Festigkeit des Massivs nach geomechanischen Klassifikationen, die z.B. fur den Bau von Tunnelen und fur Erzbergwerke entwickelt wurden, sich um etliche Male unterscheiden kann. Es ist eine Entwicklung von spezialisierten Klassifikationen fur Gesteinsmassive mit bestimmten geomechanischen Eigenschaften erforderlich. RESUME. Il a ete fait l’analyse retrospective de certaines classifications geomecaniques des massifs de roche. Il a ete montre que les estimations de solidite du massif suivant les classifications geomecaniques etudiees, par exemple, pour la construction des tunnels et pour les puits de minerai peuvent differer en quelques fois. Il est donc necessaire d’etudier les classifications specialisees pour les massifs aux proprietes geomecaniques particulieres.

Jan 1, 2003

"In 2008, the Committee for Mineral Reserves and International Reporting Standards (CRIRSCO) and the Russian State Commission on Mineral Reserves (GKZ) entered into an agreement leading towards harmonization of Russian and international minerals reporting systems. The purpose of the protocol is to define an agreed method by which mineral resources and reserves, reported by companies in Russia according to the current Russian classification system, can be expressed in terms that are comparable to the CRIRSCO reporting codes in Russia and elsewhere."

Jan 1, 2003

The unpaved road network on a surface mine is extensive, comprising numerous roads of varying construction and material qualities with highly variable traffic volumes. Existing haul road maintenance management systems (MMS) work well for predictable traffic volumes, but for complex mine road networks, the MMS becomes onerous. This results in sub-optimal road maintenance strategies with the attendant increase in total road-user costs and reduction in service. A real-time maintenance management system was thus sought to overcome the deficiencies of existing MMS for mine roads. Since most large mines operate trucks with on-board diagnostic data collation, linked through a centralized communication and GPS backbone, it was proposed that road condition could be monitored on a real-time basis through on-board vibration signature analysis. The aim of this paper is to present the development of a real-time mine haul road maintenance management system. Following are view of mine road maintenance practices, the real-time system architecture is introduced and the results of a field trial of on-board vibration signature assessment is presented. The trial results are discussed in the light of road defect signature recognition, analysis, signature repeatability and system limitations. This approach has applicability to other situations such as a network of district roads, subject to an analysis of the economic feasibility. The paper concludes that modern technology has the potential to apply maintenance as and where needed with possible reductions in authority cost and an improvement in service provided for the road user.

Jan 1, 2003

By A. Valenzuela

During the last years, Chile has been the largest copper producer, either as concentrates or cathodes. Copper obtained via pyrometallurgy is produced by seven smelters, which have carried out modernization plans to increase smelting capacity or to achieve environmental regulations established in the Chilean legislation. Thus, the present work updates technological innovations in smelters, environmental regulations and presents solutions for S02 handling, particulate matter and arsenic. Also, the authors emphasize the important role of CODELCO Chile, the most important state-owned copper company, in developing technologies such as El Teniente Converter and El Teniente Slag Cleaning Furnace.

Jan 1, 2003

By P Hanna

In an effort to improve returns to shareholders, the Australian Mining Industry has consolidated considerably over the past decade or so. Technical services at mines have been re-structured, whilst those at corporate offices have been all but eliminated. A recent study of the role of the geologist in BM Alliance Coal Operations Pty Ltd (BMA), showed the adverse impact on the companyÆs performance due to a lack of geologists. With an education campaign, to demonstrate the contribution of geologists to the æbottom lineÆ and in increasing the options available to the company, the value of the geology role became better understood. The implications of the loss of invaluable corporate knowledge, when long serving geologists left the company, also became clear. Steps have since been taken to increase the numbers of company geologists, particularly on mine sites. In common with other sectors of the mining industry, the Australian coal industry is experiencing a critical shortage of experienced coal geologists, as companies have found in recent recruitment efforts. This is further evidence that the recommendations from the recent study by World Competitive Practices, commissioned by The Australasian Institute of Mining and Metallurgy, æRising to the ChallengeÆ have not been adopted. People, and the mineral resource base, are the assets from which mining companies gain a sustainable competitive advantage. Geologists, as the nexus between the resource base and people, are in a unique position to enhance the profitability of their companies. To maximise their contribution to the industry, and ensure that they receive due recognition, geologists must adopt a more commercial approach in their work and take a front foot stance in promoting their value to management. Geology is a core competency for all mining companies. The tendency for companies to outsource this function, to the detriment of the company geologist role, is not sustainable in the longer term. TodayÆs geologists need to work closely with management, technical and human resource professionals, universities and schools to ensure their significant value is well understood, and that the industry can attract, train and retain new recruits through the implementation of graduate programs and company career paths.

Jan 1, 2003

By Robert van Hille, Alison Lewis

The precipitation of a selection of metals from both a synthetic and an actual metal-rich effluent was investigated. The experimental aspects of this study were carried out in a two-stage process consisting of a pre-treatment clarifier and a fluidised bed (pellet) reactor. Each unit operation in the two-stage process was investigated separately. The pre-treatment clarification stage at pH ˜ 5 resulted in a 99.9% removal of iron and 97.3% removal of aluminium. The pellet reactor was used to precipitate nickel as nickel carbonate from a pure stream and a removal efficiency of 99.6% was achieved. The high local supersaturation at the reagent inlet points caused the formation of a large amount of fines, but these agglomerated onto the pellets up the length of the bed. For copper precipitated as copper sulphide from a pure stream, a maximum removal efficiency of 92% was achieved. The high local supersaturation at the reagent inlets also caused the formation of a large amount of fines, but the extremely sparingly soluble nature of copper sulphide meant that the fines were not agglomerated up the length of the bed. For removal of cobalt as cobalt carbonate from an actual stream, a stable cobalt removal of only 60% was achieved. This was found to be due to the presence of magnesium, which reduced the cobalt precipitation efficiency through the formation of the magnesium bicarbonate ion.

Jan 1, 2003

By Travis Davidsavor, Stanley: Dong Vitton

Concrete is a common construction material used throughout the world, and with increasing demand of fast-track construction, blasting and concrete casting are occurring simultaneously at many sites where rock is being excavated for concrete placement. However, there has been significant disagreement in the construction industry as to what intensity of shock vibrations green, or fresh concrete can tolerate. Peak particle velocities are often arbitrarily chosen, or are simply based on materials such as plaster and drywall that have been more thoroughly studied in relation to damage. Previous research on green concrete has used the concrete’s static strength subjected to shockwaves at different ages as the primary damage criteria. In addition, the static strength tests have been based on curing time. However, changes in temperature or humidity can dramatically alter the hydration rate, which affects strength development of different cements. To account for temperature changes and humidity the concept of concrete maturity is commonly used and allows the researcher to see where the concrete was in terms of hydration progress. In general, static testing determines the failure stress that the concrete’s macrostructure can handle, and often failure occurs in the natural materials first or along large defects in casting techniques. Dynamic testing or high strain rate testing, on the other hand, loads materials at such a high rate that larger defects do not have time to react and instead the microstructure is more highly stressed leading to higher strength and stiffness values. This is known as the material’s strain rate sensitivity. Since dynamic testing better tests the microstructural strength, it is believed that it may provide a better way to assess damage to green concrete. Testing includes both static and dynamic compression as well as static and dynamic splitting tensile strength to assess whether damaged has occurred to the concrete. No significant statistical evidence was discovered that damage to the concrete occurred at five different “green” maturities from peak resultant velocities ranging from 10.66 in/s (271mm/s) to 4.40 in/s (112 mm/s) with average intensity of 6.7 in/s (170mm/s).

Jan 1, 2003

MULSIM/NL and La Model are displacement-discontinuity programs which have been used quite successfully in the past to provide detailed structural models of various single and multiple-seam mining situations. However, both of these programs required fairly complex details of the mine plan and topography to be manually input into the program, often taking several days of work. Recently, automatic mine and topographic grid generation capabilities have been added to the MULSIM/NL and La Model programs, reducing the input time requirements from days to hours. This paper discusses the algorithms used for the automatic grid generation and demonstrates the utility of the new capabilities with a case study.

Jan 1, 2003

By A. R. Miller, G. Desrivières, M. C. Bétournay, D. L. Barnes, P. Laliberté

"Over the last four years, an international initiative, championed by Vehicle Projects LLC, the Fuelcell Propulsion Institute and Natural Resources Canada, has been active in carrying out research projects to prove out the concept of applying fuel cell technology to underground mining vehicles. These have been carried out by a consortium consisting of mining companies, equipment manufacturers, technology developers, national laboratories and consultants, with the participation of Canadian and U.S. mine regulatory agencies.This clean technology, which produces only water and electricity, would allow several advantages to be obtained, in the health area (by eliminating diesel emissions and reducing noise generation), in lowering production costs (such as reducing ventilation required) and lowering greenhouse gas emissions.This paper outlines the results obtained in several key areas, such as, the operation of fuel cells in underground conditions, risk issues related to underground and surface operation of hydrogen vehicles and hydrogen production and delivery systems, and the design and mining performance of the world’s first hydrogen mining vehicle, a mine production locomotive. The work to date on the fuel cell loader, designing the power plant and power transmission systems, operational requirements, and operating cost reductions is also presented."

Jan 1, 2003

By Slobodan B. Vujic

"Some twenty years ago, during construction of flotation in the “Veliki Krivelj” copper and non-metallic mine Bor, a computer supported system for remote controle of technological process was installed. Nowadays, the major part of equipment of this system is worn-out and technically old-fashioned. Having this in mind a decision was made to design a new computer supported information-management system for Flotation. The paper presents a concept and features of project solutions.For the requirements of remote monitoring and management of technological process in Flotation of “Veliki Krivelj”, Copper and non-metallic minerals mine in Bor, Yugoslavia (hereinafter: CNM Bor), a measuring-regulation equipment was implemented and a computer control system, adjusted for that time, built some twenty years ago. The major part of this equipment is today worn out and technically out of date.Having estimated that production and business activities could hardly be more efficient, operative and successful on one hand, and available mineral and other resources rationally exploited, the CNM Bor made a decision in 1999 to improve information-management function of Flotation. The idea was that the set task be realized through development and introduction into practice up-to-date integrated and computer-supported production-business information-management system. The first logic step in completion of this task refers to engineering-creative determination of information management system (hereinafter: IMS), namely to project elaboration.When considering the real system from technical, technological, organization, monitoring-management, logistic and business aspects, the Project on IMS of Flotation, should provide a rational, modern and, for the real system conditions, complete solution. The Project solutions should be based on the most recent knowledge from computer and measuring-regulation technics as well as from CIM concept (Computer Integrated Manufacturing)."

Jan 1, 2003

By Patrick R. Taylor

A kinetic study of the fluosilicic acid leaching of galena was performed under the presence of different oxidants. Fluosilicic acid concentration, agitation speed, concentration of solids and particle size, type and concentration of oxidant, and temperature were the variables studied. Hydrogen peroxide was found to be the most effective oxidant, its effectiveness being proportional to its concentration. As expected, an increase of leaching temperature increased the overall extraction and extraction rate. The same was found by decreasing the galena particle size. It is thought that leaching using hydrogen peroxide is controlled by fluid film mass transfer due to the calculated apparent activation energy. Reaction by-products such as sulfur and sulfur compounds retard the leaching rate. A mathematical model is proposed and compared to experimental results.

Jan 1, 2003

Kosaka Smelter & Refinery has a history of more than a century as a metallurgical department belonging to Kosaka mine. It has treated for a long time the "Black Ore" or the complicated concentrates dressed from it. The "Black Ore" is composed of black sulfides. It contains not only valuable metals such as gold, silver, copper, lead and zinc but also some impurities like arsenic, antimony and bismuth. With the development of Kosaka's floatation technology, five kinds of concentrates (copper, zinc, lead, pyrite and barite) have been separated from the "Black Ore" but the separation was not complete and each concentrate contained some unfavorable impuritie. In 1980s the highly appreciated yen and the drop of the metals priees forced many domestic mines to close their operations. Since then Kosaka Smelter has changed its way of operation to a custom smelter. Now more than 95% of copper concentrates are imported to take advantage of this technology of "Black Ore" treatment. It mainly treats the raw materials that contain high gold and silver like the "Black Ore". Recently, Kosaka has been working on the recycling of the metals from the printed circuit board scraps and sludge which contain some precious metals. The volume of the recycled metal is continuously increasing.

Jan 1, 2003

By H. P. Ehrlinger

The Illinois State Geological Survey added Minerals Processing to its capabilities in 1966. Subsequently, the Minerals Processing Team and several Geologists collectively thought what neither would have thought of separately. The results included a number of projects. discussed here are: 1) The Utilization of the Fines from Kitty Litter as a Bonding Agent for Iron Ore Pellets; 2) Separating Plant Waste from a Commercial Silica Sand Producer into two marketable products, including a closely sized Silica Sand; 3) Marketable Feldspar Sand and Silica Sand from Dune Sands near the Kankakee River; and 4) A Method for Making Metallurgical Grade Fluorspar more desirable as Blast Furnace (Steel) Feed.

Jan 1, 2003

By Francesco Vegliò, Luigi Toro, Francesca Pagnanelli

"Different hydrometallurgical processes have been studied in order to recover manganese(II) from oxidised minerals such as MnO2 (Vegliò and Toro, 1994). An innovative acid reductive leaching carried out in soft experimental conditions was here considered using agro-industrial wastes containing carbohydrates as reducing agents (Vegliò et al., 1998).The leaching process was investigated from a kinetic and equilibrium point of view in order to optimize the experimental conditions and obtain high purity and concentrated MnSO4 solutions.The overall leaching process (not considering the complex network of intermediate oxidation reactions of the carbohydrates in hot sulphuric acid medium (Vegliò and Toro, 1994)) can be described by the following reaction:24 MnO2 + C12H22O11 + 48 H 24 Mn2+ + 12 CO2 + 35 H2O (1)A Shrinking Core Model (SCM) was modified by a variable activation energy term to take into account both the variable reagent concentrations and the reaction rate change with respect to the manganese dioxide conversion. The influence of the particle size in the kinetic model is discussed with the support of SEM analysis and BET surface measurements before and after leaching.Manganese extraction yield was maximised (170-190 g/L) using appropriate carbohydrates and acid excesses, while impurity concentrations were kept low (Fe<10ppm and Ca<300ppm) pre-treating the ores, using hydroalcoholic leaching medium and different combinations of down-stream processes. In particular precipitation, solvent extraction and adsorption onto active carbon were tested to eliminate Fe and Ca from MnSO4 solutions."

Jan 1, 2003

By B. J. Jody

This paper describes a one-step thennal-treatment process, developed at Argonne National Laboratory, to remove all organic contaminants from the glass-fiber waste that is generated during the glass-fonning process. The recovcred glass fibers can then be recycled into new glass fibers or new glass products without adversely impacting the operations of the glass industry or the quality of its products. Our process involves shredding the waste to a manageable size and then processing it at temperatures below its melting point to remove the polymeric-coating layer. The glass industry generates more than 60,000 tons of glass-manufacturing waste annually in the glass-forming process alone. Recycling of this waste stream can keep this non-biodegradable waste out of the landfills. In addition, use of recycled glass lowers energy costs, by an average of about $5 per ton as compared to using virgin raw materials to make virgin glass fibers. This process will also reduce the emission of C02 by 17,400 tons a year and it will also reduce the emission of nitrogen oxides. Economic analysis of our process shows a potential payback of less than 2 years.

Jan 1, 2003