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By N. N. Malila, N. R. Shoko

The ever-increasing pressure on the profit margins of ferro-chrome producers and the gradual depletion of deposits of rich hard lumpy chrome ores calls for the ferrochrome industry to maximise the use of fine fractions of concentrates and friable chromite ores. Zimbabwe is endowed with huge deposits of refractory and friable ores that occur on and off the Great Dyke complex. The conventional metallurgical process of smelting of chromite ores in submerged arc furnaces is favoured by the use of refractory hard lumpy ores. The requirement to use all lumpy ore has been circumvented to a large extent at Zimbabwe Alloys. The use of briquetted chrome ore fines in the production of Ferrosilicon Chrome and High Carbon Ferrochrome has yielded positive results over a period in excess of twenty-five years. Of the three industrially used methods of agglomeration of chromite ores; sintering, pelletisation and briquetting, briquetting is preferred because the other two are associated with higher capital and operational cost. Zimbabwe Alloys has developed operational and technical expertise on the briquetting and utilisation of chromite ore fines and concentrates. Variations in the quality of available chromite ore fines imply that their amenability to briquetting is a dynamic problem. Appropriate briquetting parameters to guarantee quality briquettes are essential to the successful use of briquetted chromite ore fines. In developing a technology for briquetting of chromite ores, it is important not only to study the mineralogical and grain-size characteristics of the chromite ore fines but also to make an informed choice of the type and quantity of the binder and the conditions for producing a physically and chemically competent green and cured briquette. This paper discusses Zimbabwe Alloys' experience on the briquetting process and the advantages derived in the smelting of the briquetted chromite ore fines in comparison to the use of conventional lumpy chromite ore with respect to improvements in chromium recovery and as a consequence related efficiencies and unit cost of production.

Jan 1, 2004

By Ashok D. Dalvi

Production of nickel from laterite ores has occurred for over 100 years beginning with processing of garnieritic ores from New Caledonia. However, until now the world nickel supply has been predominantly from sulfide sources. Going forward, the authors project that the production of nickel from sulfide ores will remain more or less constant. Most of the expansion in nickel production capacity over the next ten years will come from processing of laterite ores. Thus the capital and operating costs of new laterite projects will have significant impact on the nickel supply and therefore price. The authors have reviewed the history and capital and operating costs of various recent laterite projects and capital and operating costs of these projects and those "on the drawing board". The authors have also evaluated the risk associated with such projects. The paper will discuss the impact of this and the recent history on the future development of laterite nickel projects.

Jan 1, 2004

By Y. Kocaefe, S. Afshar, D. Kocaefe, Z. Kunt, C. Allaire

Interaction of aluminum with silica based ceramics Jose M. Soto, Jeffrey D. Smith, William G. Fahrenholtz. Department of Ceramic Engineering University of Missouri-Rolla Rolla, MO 65409-0330 USA ABSTRACT Interactions between A356 aluminum (Al-Si alloy) and dense fused silica (FS) riser tubes used for low-pressure casting of aluminum alloys were evaluated using a sessile drop approach. The tubes have a short service life, but cost and thermal shock resistance make them an effective solution. The main problem encountered during use is the reaction of aluminum with silica to form alumina and silicon, which causes failure. Tests have been conducted on as-fired (uncoated) and modified (coated) tubes. Experiments were carried out in a horizontal furnace at 1225°C under argon to minimize the effect of the aluminum oxide on the interactions at the alloy-silica interface. Images of the drop were acquired and contact angle values were estimated for uncoated and coated samples, but no significant differences in the contact angles were observed. Scanning electron microscopy revealed the presence of cracks at the interface between the reaction zone and the unreacted silica. The presence of reaction products (silicon in the reacting alloy and aluminum in a reaction zone between the alloy and the unaffected silica) has been confirmed using energy dispersive spectroscopy. A two layer coating system was found to be effective in reducing penetration of the aluminum alloy. The interactions between bed media and aluminum have been studied under static and dynamic flow conditions. An experimental system was set up simulating a small filter. Desired flow field can be created around alumina particles and velocities can be adjusted. A mathematical model was developed to predict the velocities, and this was validated using data from a visualization study. The interaction zone on the surface of the particles was analyzed with optical microscopy and SEM. This paper presents the study and compares the results under static and dynamic flow conditions.

Jan 1, 2004

By R. T. Jones

Slags have been produced as by-products from pyrometallurgical processes for thousands of years, and have generally been regarded as waste. Many of these slags are no longer seen as residues merely to be discarded, but as potential economic sources of metals, or as useful by-products in their own right. Slag cleaning can enhance the recovery of valuable metals in existing pyrometallurgical processes, or can produce economic value from recycling old slag dumps. For example, a process has been developed and implemented industrially for recovering cobalt from copper smelting slag in a DC arc furnace. The relatively non-leachable behaviour of glassy slags allows them to be used as a very safe means of disposal of metallurgical waste streams, including many that are classified as hazardous. The high temperatures, reducing conditions, and good mixing that can be achieved in a DC arc furnace enable the effective functioning of this environmentally beneficial means of disposal. Lead blast furnace slag can be rendered safe for disposal by treating it using the Enviroplas process, which strips most of the hazardous lead from the slag (and traps the rest in an insoluble glassy slag) and recovers economic quantities of zinc by absorbing (in a lead splash condenser)the zinc vapour that is fumed off in the furnace. Another example can be seen in the recovery of a chromium- and nickel-containing alloy from stainless steel plant dust, while producing a disposable residual slag. The examples presented here illustrate that it is possible to develop processes that are both economic and environmentally beneficial. Keywords: DC arc furnace, plasma, slag cleaning, cobalt recovery, zinc fuming, Enviroplas, jigging, re-melting fines, environmental, economic

Jan 1, 2004

By S. J. Knoll, D. F. Scott, T. J. Williams

Highly stressed rock in stopes continues to be a primary safety risk for miners in underground mines because it can result in failures of ground that lead to both injuries and death. Spokane Research Laboratory personnel investigated electromagnetic (EM) emissions in a deep under-ground mine in an effort to determine if these emissions could be used as indicators of impending catastrophic ground failure. Results suggest that (1) there is no increase in the number of EM emissions prior to recorded seismic activity, (2) some EM signals are generated during blasting, (3) interference from mine electrical sources mask seismic-generated EM signals, (4) EM emissions do not give enough warning (compared to seismic monitoring) to permit miners to leave a stope, (5) the distance an EM signal can travel in the rock is between 17.7 and 39.6 m (58 and 130 ft), and (6) current data acquisition systems do not differentiate between EM signals generated from seismic activity and random mine electrical noise. These results preclude monitoring EM emissions as precursors of impending catastrophic ground failure.

Jan 1, 2004

By Craig Byington

The stress-field orientation mapping and analysis (SOMA) technique for determining the operative stress field near mine workings and its relationship to various fracture sets is described using Dickenson-Russell Coal Company's Laurel Mountain mine as an example. Carried to its practical application, this technique ultimately defines the optimal orientation for the mine workings wherein pillars, rather than rock bolts or other roof support methods, dominantly shoulder support of the highest-probability, potential, roof-fall blocks. It also provides a predictive tool describing local variability in rock deformation and in secondary roof support methods. Fracture discontinuities within a rock mass, either as pre¬existing natural fractures or as mining-induced fractures, are uniquely necessary for every brittle-deformation ground failure including roof falls. Prediction and mitigation of roof falls requires quantifying the interaction between the fracture sets and the operative principal-compressive¬ stress-axis orientation (olo). The SOMA technique utilizes the interaction between fractures and 61o, specifically their dilation or closure, to calculate the orientation of 610, and to estimate the orientations of 62o and o3o. A stereonet program is used to organize and statistically analyze the fracture data, and then to determine the optimal orientation for the mine workings. The final step in the SOMA technique involves modeling the Laurel Mountain mine using a 2-D, finite-element, modeling program. This assures that the interpretations regarding the optimal working orientation closely match the deformation features observed in the mine. It also provides a predictive tool describing highly variable stress and strain partitioning, seemingly erratic rock-bolt failures and the interactions between different sets of mine workings within different coal seams. The critical importance of including the fracture sets is well illustrated in the Laurel Mountain mine where the effects of earlier mining of an underlying seam is contrasted in both a fractured and otherwise identical non-fractured model to illustrate the consequences of ignoring fractures in a predictive roof-fall model.

Jan 1, 2004

By B A. Wake, G G. Lowder, M J. White

The Tooloom gold field is located within the New England Fold Belt in the far northeast of New South Wales, approximately 130 km south southwest of Brisbane. Gold was first discovered at Tooloom in 1857. Within a few years up to 10 000 people were mining placer gold deposits in the Tooloom valley and a few tried their hand at mining hard rock occurrences as well. Mining of alluvial gold continued in a small way at Tooloom until very recently, but only in the last few years, since Malachite Resources acquired its interest at Tooloom (now 100 per cent), has the full potential of this large, reduced intrusion-related gold field been appreciated. By the mid 1870s, once the alluvials were largely worked out, most of the early miners had made the 270 km trek north to the newly discovered Gympie gold field and Tooloom slipped into obscurity. Such was this obscurity that the Tooloom gold field was not recorded on published Government geological maps until 2001, four years after Malachite became involved. The many hard rock prospects that Malachite has identified in recent years were largely or completely unknown. Tooloom is a good example of blinkered thinking when it comes to modern mineral exploration. The New England province in NSW has long been the æpoor relationÆ to the much better known and more highly favoured Lachlan Fold Belt in NSW. It has also suffered serious neglect compared with the Queensland part of the New England Fold Belt that hosts such major gold deposits as Mt Morgan (>7 Moz), Gympie (>3 Moz) and Cracow (>1 Moz). Tooloom is proof that prospective geology does not stop at state borders.

Jan 1, 2004

By J. H. Zietsman

It has previously been observed that industrial high-titania slags display a compositional invariance, remaining close to stoichio-metric M3O5. The present study focuses on this invariance and the phenomena which may cause it. The invariance was studied using thermochemical calculations and a mechanism is proposed for the observed behaviour. The mechanism suggests that a combination of thermochemical equilibrium and transient slag solidification and melting results in the observed compositional invariance. The proposed mechanism provides new insights and prompts questions about other mechanisms in the smelting process.

Jan 1, 2004

By V. Prabhu, D. Mantha, R. Reddy

Secondary copper blast furnace slag was treated with carbon to derive the conditions for maximum recovery of copper with a minimum simultaneous reduction of iron oxide. Experiments were carried out to study the effect of temperature, carbon and CaO additions to the slag on the efficient recovery of copper. A two-stage reduction process was also employed to study the efficiency of copper recovery and the results were compared with those of single-stage reduction. The maximum recovery of copper in alloy phase was obtained with 5 % initial carbon in the slag, 2% CaO addition to the slag and at a reducing temperature of 1573 K. Higher grade of the alloy phase with respect to copper was obtained by employing a two-stage reduction process. The results obtained in this study are comparable to those of the earlier research on the recovery of copper from reverberatory furnace discard slags.

Jan 1, 2004

By N Ozawa, R Kaneko, M Arimit

The Mitsubishi Higashitani limestone mine is a ten million tonne per annum operation located near the city of Kitakyushu on JapanÆs western island of Kyushu. Higashitani is one of the largest limestone mines in Japan and accounts for about five per cent of national production. Blasting practices at the Higashitani mine involve the use of bagged ANFO, dynamite primers and non-electric detonators. Regulations in Japan prohibit the use of site mixed bulk explosives. Blast size is usually around 17 000 tonnes with 20 holes in a single row, two or three blasts are fired per day at a powder factor of between 0.25 and 0.32 kg/m3. As part of a program looking at oversize reduction Mitsubishi, Asahi and Orica agreed to conduct a joint project at the Higashitani mine to investigate the relationship between the powder factor and fragmentation. The first stage of the project was to benchmark the current blasting performance. Five blasts were monitored in each of the 210 (hard rock) and 220 (soft rock) areas of the mine. OricaÆs Powersieve« software was used to measure fragmentation and total rock breaker hours were also recorded for each blast. OricaÆs computer blasting simulation model Sabrex« was used to prepare revised blast designs with a higher powder factor and predict their performance. The performance of these blasts was monitored using the same methods.

Jan 1, 2004

By M. Ramulu, A. K. Chakraborty, P. B. Sahu, C. Bandopadhyay, P. B. Choudhury

Human response to blast induced vibration and air overpressure is an unsolved problem that accompanies excavation process in mining. Pre-assessment and understanding of annoyance due to production blasting is probably one of the most important aspects of a successful mining operation. Complaints arising due to unoptimised blasts lead to various critical situations that hamper production. Inspite, this important aspect has been covered by a limited number of researchers in the world and probably least in Indian context. Human response is a complex phenomenon and the sensitivity of individual also vary from person to person depending on various factors like age, sex, literacy, health and exposure to mining. With ever increasing demand of minerals, opencast mines are expected to approach habitats and thus mine management may witness increased response to blasting. Many developed countries have their own guidelines based on scientific analysis, addressing such environmental problems, where as there are a few studies available in India. This study introspects above phenomenon in tune with mining requirements by analysing direct human response. This paper is based on a case study regarding the human response to blast induced hazards in a Manganese mine situated in central India. Advanced techniques of Critical Path Method and Multiple Response Analyses have been used to unearth important inferences on the response of different crosssections of population residing about the mine to blast induced noise, ground vibration and air overpressure. Various inferences drawn may provide guidelines to the planners, environment or safety departments and blasting official for safe and environment friendly blast design.

Jan 1, 2004

By K. Saito, Y. Miyauchi, T. Nishi, Y. Kizu

At Tokushima Plant of Nippon Denko Co., Ltd. high-carbon ferromanganese is produced by the electric furnace method using lump manganese ores and sintered manganese ores manufactured from fine manganese ores. However, the distribution of manganese ores is significantly uneven on earth, and their characteristics considerably vary by ore type. It is known from experience that the production of high-carbon ferromanganese by the electric furnace method depends greatly on material ores. Therefore, to maintain stable operation in the electric furnace-smelting field, it is important to identify the characteristics of each type of material ores in advance. Thus, we evaluated the high-temperature electric characteristics of manganese ores using the electrical conductivity measuring system developed by ourselves and provided the standards for determining ores and blending ratio necessary for stable operation of the electric furnace based on the evaluation results. This time we worked for optimisation of the high-temperature electric characteristics of sintered manganese ores through modification of the characteristics because the blending ratio of sintered manganese ores in the electric furnace is high. The electrical conductivity of sintered ores having various chemical components in a high-temperature region (up to 1 550°C) was measured using our electrical conductivity measuring system and high-temperature electric characteristics evaluating method reported at INFACON 9. As the result of the measurement, we revealed that the high-temperature electric characteristics of the sintered ores depend on their chemical contents and the sintered ores can be modified to those having excellent high-temperature electric characteristics by controlling their chemical contents, so that the resources can be effectively used.

Jan 1, 2004

By J van Niekerk

The BIOX« process for the treatment of refractory gold ores and concentrates has been commercially in operation for 18 years. A total of six BIOX« operations have been successfully commissioned since the commercialisation of the process. Four of these BIOX« plants are still in operation today. There has been a renewed interest in the process the past few years with two BIOX« plants, the Suzdal plant in Kazakhstan and the Fosterville plant in Australia, scheduled for commissioning during 2004. Four new projects are also in various stages of development and are currently scheduled to be commissioned during 2005 and 2006. Research into the process are currently focussed on the two highest operating cost items for the commercial operations, namely power for agitation and air dispersion and cyanide consumption during leaching. Laboratory aeration and agitation testwork using the A340 up-pumping agitation system has shown that similar mass transfer rates can be achieved at slightly higher agitator power. The up-pumping system, however, eliminates the need for a separate blower and sparger system as air is introduced into the slurry from the slurry surface. The use of the thermophile bacteria as the final oxidation step during biooxidation has shown great promise. Reductions in cyanide consumption of up to 50 per cent were achieved when using the combination mesophile and thermophile process compared to standard BIOX« product solids. The combined process takes advantage of the milder oxidising conditions of the well known BIOX« process for the bulk of the oxidation and then uses the high temperature thermophile bacteria to complete the oxidation. The ASTERÖ process for the biological degradation of cyanide and thiocyanate containing effluent solutions has been proven to be efficient and stable. The process uses an activated sludge system with a residence time of approximately six hours in the sludge reactor. Heavy metals and metal cyanide species have also been shown to be removed successfully from solution.

Jan 1, 2004

By R. Carpenter, H. Muntanion, P. Kleespies, E. Flood, M. Tansey

Abstract - BHP Minerals discovered the Archean lode gold ULU deposit on the western margin of the High Lake Volcanic Belt in 1989. The greenschist to amphibolite facies mafic volcanic and sedimentary rocks on the property are folded into a 5 km-long anticline. There is a close spatial association of Au-As zones to the trace of this F2 ULU anticline. The largest of these auriferous zones, the Flood zone, is localized at the core of the fold. The southeast-trending Flood zone consists of several anastomosing lenses that have been traced for 435 m on surface. Overall, it dips steeply (70° to 80°) to the southwest and has been intersected to depths below 600 m. The hosting high-iron tholeitic basalt displays a lower amphibolite mineral assemblage of ferrohornblende + plagioclase + ilmenite with accessory quartz and epidote. Alteration minerals include biotite, chlorite, hornblende, actinolite-tremolite, and potassium feldspar (microcline) with minor calcite, epidote, tourmaline, and titanite. The highest gold values occur where brecciated basaltic wall-rock clasts are replaced by acicular arsenopyrite + quartz + K-feldspar. BHP Minerals completed 54,783 m of both exploration and resource development drilling before selling the ULU property to Echo Bay Mines in 1995. Development of ULU as a satellite deposit to Echo Bay’s Lupin mine began in 1996. A -15% ramp was extended to the 155-meter level, and 16,011 m of underground drilling were completed before the decline in gold prices forced a suspension of activities at ULU in August 1997. The current owners, Wolfden Resources Inc., drilled 18,569 m in 2004 to increase confidence in the resource blocks. Following this drill program, a revised resource calculated by an independent consultant determined that the ULU deposit contains an inferred/indicated mineral resource of 1,130,000 t grading 11.34 g/t gold (373,748 oz) to the 360-m level. The portal was re-opened in 2005 and a prefeasibility study is underway.

Jan 1, 2004

Existing processes for the recovery of platinum group metals (PGM) from UG-2 ores place stringent requirements with regard to chromite content upon feed material to the plant. An alternative hydrometallurgical process for which this is not an issue is proposed that involves reductive roasting of the ore followed by leaching with HCl/chlorine, ion exchange, and recovery of PGM from the ion exchange eluate by reduction. Problems associated with leaching of PGM are discussed and results of laboratory testwork for each of the process steps are given.

Jan 1, 2004

By B. T. Lu, J. L. Luo, J. F. Lu

The present paper investigates the chemo-mechanical effect in slurry-erosion corrosion process of carbon steel to understand the synergistic mechanism due to interaction of chemical and mechanical factors. The erosion-corrosion tests were conducted with A1045 steel in slurries comprising tap water and silica sand. Various heat treatments were adopted to achieve different hardness in the test material. The chemo-mechanical effect is evaluated in line with the correlation between the degradation of hardness in the surface layer and anodic current density. During the erosion-corrosion tests, various anodic currents were applied to find the relation between the anodic dissolution rate and erosion rate. The experimental results indicate that the hardness decreased with increasing anodic dissolution. Based on the fact that pure mechanical erosion rate increased with decreasing hardness, this result suggests that the corrosion-induced degradation of mechanical property is a mechanism of corrosion-enhanced erosion. This theoretical prediction is verified by erosion-corrosion experimental results.

Jan 1, 2004

By J. Beddoes

The various microstructural factors that influence the creep resistance of y-titanium aluminides are presented and discussed. Titanium aluminides have potential for a variety of intermediate temperature applications in both gas turbine and reciprocating engines. While it is well established that the 'fully lamellar' titanium aluminide microstructure offers superior creep properties, the particular influence of lamellar morphology, third phase precipitation, and grain boundary structure in controlling both the primary and tertiary creep behaviour is presented. The results are primarily based on tensile creep experiments undertaken using several titanium aluminide intermetallic compositions processed via powder metallurgical techniques, investment casting and Bridgman directional solidification. The results indicate that lamellar structure and precipitate formation have a major impact on primary creep, while microstructural degradation through both lamellar and precipitate coarsening influence on the onset of tertiary creep leading to fracture. The results are used to design a creep resistant microstructure produced by directional solidification and the effectiveness of this designed microstructure is demonstrated through 10,000 hour creep tests.

Jan 1, 2004

By D. A. Harman

The U.S. Environmental Protection Agency recently recognized Newmont and other mining companies, along with the Nevada Division of Environmental Protection for their voluntary work in reducing mercury air emissions. One example of this voluntary effort is the installation of a reactive scrubber to capture mercury vapor from the exhaust of a carbon regeneration kiln at Newmont’s Twin Creeks Mine. After considering the available technologies, a proprietary reactive scrubber, developed by ADA Technologies, Inc., was selected and is currently being commissioned. Mercury removal rates greater than 90% have been documented.

Jan 1, 2004

By S. E. Boyd

Studies of benthic recolonization following the cessation of dredging in U.K. waters and elsewhere are limited, and are largely confined to experimental circumstances. Investigations of the physical and biological status of licensed areas in the U.K. at various times following cessation of commercial dredging are very limited and so judgments as to the likely progress towards environmental restoration and the time-scales are often based on predictions rather than real data. This study was established to address this deficiency by assessing the status of seabed substrata and associated benthic fauna within and outside areas where dredging had ceased and to conduct follow up sampling to monitor progress towards full recolonization.

Jan 1, 2004

By A. Haile, A. Poole

During 2001-2002, the Granny Smith Mine of Western Australia undertook the development of a planned circular failure. Excavation took place in an interim pit wall that intersected the transported sediments, lake clays, and palaeo channel sands that overlay the deposit. The purpose of the study was to refine feasibility level slope parameters used for the initial design of the Wallaby pit, with the intent of increasing the overall slope when excavating the ultimate pit limits. During excavation, the geological and hydrogeological characteristics were studied in detail and data was collected using area-specific instrumentation and monitoring. Failure occurred in mid February 2002, at which time a detailed survey of the excavated slope using laser technology was conducted to provide geometric information suitable for back analysis of the material shear strength. The slope failure and associated information was analysed by geotechnical consultants. The revised shear strength and hydrogeological parameters were then applied to design the final pit walls. The slope redesign provided a cost saving of approximately seven hundred thousand US dollars. Design, slope formation, back analysis, the geology of the clay units, the hydrological environment, planned infrastructure, management and safety issues, and the on-going slope performance of the final slope are discussed.

Jan 1, 2004