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By Liangtian Liu, Tie Ou, Guangqiang Li, Chenghuan Yu

For stabilizing the production of containing nitrogen steels, a study on nitrogen absorption behavior of killed molten steel has been carried out by means of the RH vacuum device in which nitrogen was used as a driving gas. The results showed that there was an increase of nitrogen content in molten steel under vacuum processing but the rate of nitrogen absorption was slowed down by the surface active elements. Therefore, a kinetic equation for nitrogen absorption of molten steel with apparent first order reaction was derived by constructing a modified model in which the adsorption of closed surface site was taken into account. The experimental results confiimed that the calculated values agreed with the observed ones. This model is suitable for the prediction of nitrogen adsorption operation for containing nitrogen steels.

Jan 1, 2004

By A. Alfantazi

Recently, titanium and its alloys have been the materials of choice for the liner and internal components of autoclaves used to extract Ni and Co from laterite ores. There have been many corrosion incidents ranging from localized attacks due to scale formation or welding, to damage caused by pockets of concentrated acid. Most of the literature focuses on methods to avoid the corrosion altogether. Little has been published to increase awareness of the chemistry at these conditions. For this paper, a literature review of the thermodynamics of titanium was undertaken to decipher the slew of information available. E-pH diagrams were constructed from select data and compared with the results of electrochemical experiments. Since nickel laterite leaching takes place in sulphuric acid, and in many cases chloride concentrations are very high, the Ti-H2O, Ti-Cl--H2O and Ti-SO4---H2O systems were considered.

Jan 1, 2004

By F Jiao, J Wang

By the year 2000, China was the sixth largest gold producer in the world, with about one-quarter of total production being derived from refractory or semi-refractory deposits. Although bacterial oxidation plants had been previously tried in China using local technology, these plants had not been commercially successful. The Laizhou Gold Enterprise (Tarzan BioGold Co Ltd) located in Shandong Province, undertook to modernise their gold processing facility in 2000 with the introduction of Bacterial Oxidation (BACOX) Technology. In 1997 BacTech Australia and Mintek of South Africa had formed a technology partnership, combining forces in the provision of bioleach technology. Under a cooperation agreement, BacTech/Mintek were chosen as the preferred technology providers for this first application of commercially proven bacterial oxidation technology within China. The paper describes the successful operation of this plant over the last three years. The events of project implementation are described, from the metallurgical testing of concentrate; through to the commissioning at the design throughput of 100 tonnes per day resulting in 80 000 ounces (2.5 tonnes) per year of refined gold. Process aspects of the operation encountered over the last three years are discussed which illustrate the robustness of the operation. The success of the bioleach facility has led to an advancement of plans to double plant capacity and some of the innovations, which may be employed in this expansion phase, are discussed.

Jan 1, 2004

By Jonathan Tsang, Ali Merati, Jonathan Beddoes

Due to economic factors, many aircraft in service today have been operating for more than 30 years even though they were initially designed with a service life of 20 years. Improved damage management models are therefore needed for use in life prediction and management of the aging fleets of aircraft. Currently, the generally accepted procedure in fatigue life prediction methodologies is to back calculate the equivalent initial flaw size (EIFS) using established long crack growth data. However, it was observed from studies carried out at the National Research Council Canada that nucleation and short crack growth constitute up to -95% of the fatigue life. As a result, it seems that the significance of the short crack regime has been underestimated and must be further investigated and fully understood before an accurate holistic life prediction methodology can be realized. Unlike long cracks, local microstructural features such as grain boundary, grain size, inter-particle spacing, and texture play dominant roles in the behavior of short cracks. An extensive study has been carried out to evaluate different crack detection and monitoring techniques in the short crack regime for AA2024-T3. The results will be presented in detail.

Jan 1, 2004

By Frank J. Arland

Augered-Cast-in-Place piles have been used successfully for many deep foundation applications. The four case studies discussed herein describe ACIP pile projects where problems developed during ACIP pile installation requiring changes to the method or sequence of installation. The case studies illustrate the importance of understanding existing subsurface conditions and project constraints when considering the use of this pile type. Ground loosening and over-excavation of soil during the augering process, a significant concern for fine to medium sands and non-plastic silts below the water table, can significantly impact adjacent structures. This risk needs to be evaluated during the pile selection process and generally can be mitigated, but not eliminated, by requiring the use of piling equipment with high torque and slow auger rotation speed to advance the auger with minimum amount of rotation. In some applications where high lateral stresses in the soil are present such as at the base of retaining structures, the use of ACIP piles may not be appropriate if structure movement is unacceptable. On the other hand, ACIP piles have been successfully used to support deep foundations in preconsolidated varved deposits where the new structure was designed to accommodate recompression settlement.

Jan 1, 2004

By S. Xu, A. Ramesh, F El-dabbagh, Z. Fang, A. Sobhy, J. A. Kozinski

Waste remediation is a goal that will be driven forward by economic conditions. As the cost of waste disposal increases, new methods of waste reduction will become economically attractive, and will be implemented. It is difficult to imagine, however, a time when there will be no waste generation. For the foreseeable future, despite effective reduction practices, there will still be hundreds of millions of tons of waste that must be destroyed or controlled to protect the public health and the sanctity of the environment. To remain faithful to environmental covenants, the mineral and metallurgical industries will face these new challenges. This paper discusses novel waste remediation approaches and techniques focusing on hazardous wastes and thermal remediation. Aspects concerning technological and environmental importance are examined. Solutions for neutralization of environmentally hazardous compounds are proposed.

Jan 1, 2004

By J. H. Potgieter

This paper describes two cases of corrosion that occurred in dry-process, rotary, cement-clinker kilns. In the case of the kiln with five pre-heater stages, the attack occurred primarily from sulphates that probably originated in the raw feed and fuel being used in the plant and that penetrated the refractory lining. The corrosion was similar to ash-deposit corrosion often observed in steam boilers. In the second case the plant consisted of a long dry kiln with a single pre-heater fitted to the feed-end. In this case the corrosion could be ascribed to alkali chloride penetration through the refractory-brick lining and subsequent hot corrosion of the kiln shell.

Jan 1, 2004

By A. V. Pavlov, V. A. Grygorian, Kossyrev, A. E. Semin, A. Korostylev

A new way of producing low-silicon ferrosilicon from iron-ore materials in a new type of aggregate-oxygen reactor is presented. The oxygen reactor process is based on using the calorific combustibility and reducibility of carbon materials inside the aggregate. The key to the process is successful post-combustion of carbon monoxide above a layer of a solid coke bed. Initially the possibility of production of grades of ferrosilicon containing 20 to 25% Si (FeSi20-FeSi25) was studied on a laboratory model of the oxygen reactor. Quartz sand and iron ore concentrates (from Russia and India) were used in the laboratory tests. This test work demonstrated that a ferrosilicon grade FeSi15 could be obtained directly from raw iron ore (containing 75.9 % Fe2O3 and a maximum of 23.8 % SiO2) without using rich iron-ore concentrates. The process was successfully tested on a pilot furnace at Serovsky metallurgical plant. Very promising results and efficiency parameters were achieved. The consumption of materials for 1t of ferrosilicon (15 % Si) production was as follows: 1567 kg raw iron ore, 591 kg of coal (in a composition of ore-coal briquettes), 299 kg of coke (for coke bed formation), and 815 m3 of oxygen.

Jan 1, 2004

By Craig Wilbour, John Stimberis, Rob Gibson, Lee Redden

An avalanche is a snow slide. A simple explanation is that the snow on a slope will slide (avalanche) when the snow strength can no longer support its own weight. Snow avalanches happen when the load from snowfall or ram on a snow slope increases faster than the stre n g t h of the bonds between snow crystals. Avalanches can also happen when the strength of a buried layer decre a s e s . Active avalanche control is the intentional triggering of slides. Washington State Department of Tr a n s p o r t a t i o n (WSDOT), does avalanche control to minimize the chance of natural avalanches into traffic. Avalanche control work is done all over the world by: highway departments, ski resorts, railroads, mining operations, utility companies, and other activities threatened by avalanches. The majority of active avalanche control is done with skis, by explosives, or exploding projectiles. Blasting techniques and practices have evolved to fit the specific needs of avalanche contro l . Passive avalanche control is the use of engineered s t r u c t u res such as snow sheds, bridges, or snow supporting devices, to permanently protect a specific location from avalanches. The problem is that these struct u res are extremely expensive. There are a variety of passive avalanche control measures as well as the active m e a s u res used to protect the highway over Snoqualmie Pass. As traffic volume and use expectations incre a s e , m o re extensive passive measures will be needed to keep avalanches from affecting the highway.

Jan 1, 2004

By John Stubbles

Data are presented on the global warming issue to reinforce the decision by the U.S to reject the Kyoto protocol. The evidence that CO2 is a problem rather than a benefit is inconclusive and will be discussed in this paper. Nevertheless, for economic reasons alone, the US steel industry will continue to minimize CO2 emissions (and the release of real pollutants) per ton of steel through energy reduction programs. However, relative to inevitable increases in absolute CO2 emissions from the utility industry and the transportation sector, future reductions by the steel industry will be inconsequential in the "big picture."

Jan 1, 2004

By G. Avramovic-Cingara

Grain boundary characteristics and microstructural evolution are analyzed in a comparative study using orientation imaging microscopy (OIM/SEM) and transmission electron microscopy (TEM/SAD). The subgrain sizes and misorientations were determined by the OIM for aluminum deformed in torsion to equivalent strains between 0.2 and 4 over the temperature ranges of300-600°C and strain rates 0.01-1 s". The OIM gives clearer evidence of boundaries with high misorientation than does TEM, but it overestimates their frequency b y missing boundaries less than 1 0. T EM more clearly reveals low-angle arrays of widely spaced dislocations resulting in finer subgrain sizes than those indicated by OIM. The evidence supports a mechanism combining dynamic recovery (DRY), deformation band formation with permanent boundaries and geometric dynamic recrystallization (gDRX) in contrast to the hypothesis known as continuous dynamic recrystallization (cDRX).

Jan 1, 2004

By L B. Sukla, V N. Misra

Microbial desulfurisation of coal has significant advantages over physicochemical desulfurisation processes since the former process selectively removes the inorganic sulfur compounds and heavy metals without significant carbon loss. The purpose of this study was to improve the desulfurisation yield of a coal sample from northeastern coalfields, Assam, India using microbial technique. The coal sample contained 2.13 per cent of total sulfur and 2.59 per cent of ash. Stirred tank reactors of 40 L capacity were operated in batch mode. Initially, the reactor was fed with 40 L of slurry containing ten per cent (w/v) coal, ten per cent (v/v) inoculum of mixed culture of mesophilic acidophiles, native to coal itself and the requisite amounts of constituents for 9K medium without added ferrous sulfate. The percolate of the reactor was then used to seed the medium for the next experiment. The purpose was to obtain a better adapted and more active biomass which would give a better desulfurisation yield for coal. Further studies were conducted in the bioreactor, fed with 40 L of slurry containing ten per cent (w/v) pulp density of coal, ten per cent inoculum (derived from previous studies) and the medium, supplemented with ferrous sulfate. Results showed an increased total desulfurisation yield of 43 per cent in the latter treatment in comparison to the previous one, where the desulfurisation yield was only 23 per cent. The findings also demonstrated the convenience of using inocula derived from coal, where 50 - 60 per cent of pyritic sulfur was removed, while chemical desulfurisation is of little significance with the majority of coal types. The ash content was also reduced to 1.74 per cent as the low pH of the process caused dissolution of a number of common minerals present in the coal.

Jan 1, 2004

The effect of composition on electrical conductivity (resistivity), viscosity and liquidus temperature of the slags encountered in electric smelting of PGM containing suphide concentrates is reviewed, along with the relationsip between slag composition, slag-matte separation and metal losses to slag. Optimization of slag composition at furnace temperature is attempted on the basis of opposite and parabolic trends of the viscosity-conductivity relationships of the slags. The importance of surface tension of slags is emphasized using available and estimated information which are grouped into a useful correlation. These values are coupled with or incorporated into slag viscosity plots to illustrate the correlation between the two factors, which influence slag-matte separation as well as refractory attack. The electrode in the slag-resistance furnace is the central factor in the design and operation of the furnace by its role of conveying the smelting power. The obvious parameters are the size and positioning in the slag bath, which are defined by slag resistively, furnace resistance, cell constant and power input. The flow of heat generated by the electrode current determines the energy distribution and furnace dimensions creating viscosity profiles, which in turn affect flow conditions. Thus the flow of slag and matte are discussed in conjunction with the furnace geometry, stirring action of the electrodes, buoyancy and electromagnetic effects. The action of the electric furnace as a settler is discussed. The rectangular furnace is considered as a channel reactor in this analysis, and the action of the electrodes is described to indicate a balanced settling rate in the area of electrode action. Discussion of the design and production capacity of the electric furnace, with reference too perating current, power input, furnace dimensions and electrode size, are based on considerations derived mainly from slag properties such as its resistively, viscosity and liquidus temperature.

Jan 1, 2004

By Kot Unrug

The selection of tensioned versus non-tensioned roof bolts, for primary coal mine roof support, has been debated for well over 25 years. The wide spread use of fully grouted rebar marked the beginning of the discussion of the relative importance of bolt tension and the resultant immediate roof compression. The focus is on roof conditions encountered in coal mines however the discussion may be extended to hard rock mines as well. The theoretical bases for both systems are presented, with the analysis focused on the bolt's ability to actually fulfill the theoretical assumptions. Of specific concern are assumptions about bolt tension upon installation and the likelihood of maintaining useful bolt tension over time. The usefulness of tension roof bolting is limited by the mechanical interaction of roof bolt assembly and the rock, which may be valid at the time of installation only. Ambient mine atmosphere and fluctuation in moisture content changes the physical condition of rock, which may have a significant impact on the effectiveness and longevity of bolt tension. Changes in the material properties of the surface of the immediate roof can invalidate the assumptions, which were made in the design stage of roof support system. This means that the roof support in the long term excavations may be inadequate requiring costly rehabilitation. The presented arguments are illustrated with the examples of some relevant experimental data. Tension primary roof bolting is recommended where the immediate roof is: ? Stiff with a high modulus of elasticity ? Surface layers are continuous and fairly thin ? Not easily weathered

Jan 1, 2004

By N Patzelt, T C. Logan, I B. Klymowsky

In 2003, NEWMONT MINING CORPORATION, the worldÆs largest gold producer, set out to prove that High Pressure Grinding Roll (HPGR) technology is sufficiently robust and reliable to be considered for the treatment of hard rock gold ores. In collaboration with POLYSIUS, a significant trial was conducted and 127 600 tonnes processed, successfully proving the HPGR capabilities on the Lone Tree Mine, Nevada ore û one of the most competent and abrasive ores in the industry. The success has led a number of mining companies to consider HPGRs for the comminution of gold and copper ores.

Jan 1, 2004

By Hae-Moon Choi, Sang-Don Lee, Hee Soon Shin, Choon Sunwo, Chang-Ha Ryu, Hyun-Koo Lee

Building tunnels means dealing with what rock is encountered. Relocation of the site of the underground structure is rarely possible. Tunneling engineers and miners have to cope with the quality of the rock mass as it is. Different tunneling philosophies and different rock classification methods have been developed in various countries. Most of the rock classification methods are based on the response of the rock mass to the excavation. Tunnel support requirements could be assessed analytically, supplemented by rock mass classification predictions, and verified by measurements during construction. Rock mass classifications on their own should only be used for preliminary, planning purposes and not for final tunnel support. Design of blast pattern in tunneling projects in Korea is also for the most part prepared according to the general rock classification methods such as RMR or Q. It, however, does not take into account the blast performance, and as a consequence, produce poor blasting results. In this paper, the methods of general rock classification and blast design for tunnel excavation in Korea are reviewed, and efforts to develop a new classification method, reflecting the blasting performance, are presented. Copyright ©

Jan 1, 2004

"After the non-destructive testing is completed, the data must be compiled, evaluated, and interpreted. During this process, the data may indicate that there is an anomaly warranting further investigation, which may eventually be determined to be a flaw or defect. The definitions of an anomaly, flaw, and defect can be described as follows (after Amir, 2002):Anomaly - Any irregular feature identified in the NDT graphic results. An anomaly may be due to the testing instrumentation (such as noise), to the means used to perform the test (e.g. access tube debonding in CSL) or to the shaft itself. It is the responsibility of the NDT practitioner to gather and analyze all relevant data and try to resolve every anomaly before it is declared a flaw or defect.Flaw - Any deviation from the planned shape, size and/or material of the shaft.Defect - A flaw that, because of either size or location, may detract from the shaft’s intended performance or durability. The geotechnical engineer and the structural engineer are jointly responsible to decide which flaw comprises a defect.This section describes the process of evaluating the data, determining if an anomaly exists, and if so, deciding whether the anomaly is actually a flaw or a defect. If the anomaly is determined to be a defect, its effect on the performance of the shaft must be evaluated, and if necessary, the can be re-engineered, repaired, or replaced."

Jan 1, 2004

By Jon Machin

?ORE? is defined as ?mineral/s that can be mined at a profit?. So, what is ORE at 2,000 m water depth? Is it 5% Copper or 1.8% Nickel/Cobalt? One of the key factors that determine what is ORE, profitable or not, is the cost of mining and extraction. Therefore a determination of ORE requires a commercial and technical appreciation of both sea bed mining equipment and mining options. Perry Slingsby Systems (PSS) have built more remotely operated submarine work vehicles, including 900HP trenching machines, than any other company. With Nautilus Minerals, PSS have been studying a range of deep ocean mining solutions. This paper discusses the commercial and technical issues of various extraction techniques applicable to deep ocean mining from 1,500 m to 5,000 m water depth. Issues such as the rate of extraction, (i.e. tons per hour) is a key economic component and is often constrained by the design and horsepower of the miner. Likewise the design itself of the mining machine and cutting heads can determine the size of material produced which impacts on methods of lifting the ore to surface. Issues such as overburden, sea floor conditions, style of mineralization and physical properties of the ore, obviously affect the selection of appropriate mining machine configuration.

Jan 1, 2004

By K. S. Coley, M. A. Rhamdhani, G. A. Brooks

Interfacial phenomena in high temperature reactions such as between iron alloy and slag is well documented but not fully understood. It is believed that a gradient of oxygen concentration plays an important role to the occurrence of such phenomena. This article describes the results from the continuation of the study of interfacial phenomena between Fe-Al alloy droplets and CaO-SiO2-Al2O3 slag. Materials characterization techniques involving microscopic observations, depth profiling, bulk, point analysis and were carried out. The roles of oxygen as well as other factors that contribute to the interfacial phenomena were evaluated. The results and their implications to steelmaking will be discussed.

Jan 1, 2004

By Detnet Solutions

1. “Daisy-Chain” concept The term “daisy-chain” stems from the fact that when the HotShot? detonators are connected there is a chain or electrical path for electrical current to flow from detonator A to detonator B, detonator B to detonator C etc until the path is terminated by an electrical means. The “daisy-chain” concept has long been used in electronic detonator systems, historically used in Expert Explosives’ ExEx 1000 5/6 wire system and currently in use in African Explosives Limited (AEL’s) Electrodet? electronic detonator system and has been adopted as the basis upon which the “auto-programmability” of the HotShot? electronic detonator system functions. HotShot? Detonators are connected to each other in a string, completing a “daisy chain”, and during the auto-detection mode of the control equipment, it is possible for the equipment to determine the order of hookup of the detonators as well as map the entire blast layout. The auxiliary components (Row Controllers & Branch Controllers) assist the control equipment in mapping the entire blast by indicating different points on the blast, i.e. The inflection point of a row of blast holes on a closed chevron timing pattern, the beginning of row of blast holes on open chevron timing pattern and extra blast holes or extra blast rows.

Jan 1, 2004