Search Documents

By M. Kreuh

Crystalline Mg(OH)Cl and amorphous Mg2(OH)3C1 were successfully isolated from a hydrolyzed molten salt electrolyte sample in this work, It was found that the chemical form and crystallinity of the hydroxylchloride were controlled by the cooling rate of the molten sample when it was taken. Crystalline Mg(OH)Cl could only be obtained by cooling the molten electrolyte sample at a rate not faster than 0.6 °C/min, Upon more rapid cooling, the hydroxylchloride species precipitated as Mg2(OH)3Cl, The behavior of these solid hydroxylchlorides when contacted with fresh and non-hydrolyzed molten electrolyte at 550°C was also examined, It was found that the Mg(OH)Cl rapidly dissolved in the hot electrolyte and did not decompose into MgO at that temperature as would be expected from the literature, The dissolution rate of solid Mg2(OH)3Cl was found to be so slow by comparison that it resulted in the complete decomposition into MgO which thereafter was incorporated into the electrolyte as a suspended solid phase rather than dissolution.

Jan 1, 2004

By Norman Paley, John Kells

The climate and location of the Red Dog Mine present several challenges to blasting operations. The mine is located north of 68º latitude, in an area of continuous permafrost. Ground temperatures are below freezing year-round and air temperatures range from -40 to 70°F (-40 to 20°C). Because there is no overland access to the mine, the entire year’s supply of bulk explosives, approximately 7,000,000lbs (3,175,000kg) is shipped in by barge during the 100 day shipping season when the port is ice-free. The first week in July is the earliest that new product arrives at the port. Emulsion usage is maximized from mid April through October when surface water fills the blastholes during drilling. This necessitates that a considerable portion of the bulk explosives are stored for 10 months or more before usage. The emulsion is routinely pumped from the ISO containers at temperatures of 20ºF (-7°C). The mine engineers conducted a testing program during the 2001-2 blasting season to identify the bulk explosives best suited for the conditions at the mine. A secondary goal was to decrease the usage of sensitized emulsion, as this is the most difficult portion of the explosives order to ship. To ensure repeatability when transferring the results to the day-to-day blasting operation, the majority of the testing was incorporated into normal blasting operations in the field. The mining methods used at Red Dog Mine make direct fragmentation analysis impractical and performance testing in the field relied primarily on VOD measurements. The products were also tested for their ability to be pumped in cold temperatures.

Jan 1, 2004

By Y. Shiraishi, Y. Sakurai

A new method, the gliding cylinder method, was proposed as a wide range viscometer for the measurements of molten salts, slags, and glasses. The method consists of two coaxial cylinders, cylindrical bob and a vessel containing a liquid sample. There is a narrow gap between bob and vessel. When the vessel moves against the bob, the generated force on the bob consists of three types of resistance: (1) Stokes’s resistance on the bob, (2) a capillary flow resistance though an annular gap between vessel and bob, and (3) lubricating resistance in a gap. The last two can be calculated on a theoretical basis but the first cannot be estimated by a simple calculation since a wall effect did not calculate easily. However, it can be assumed that the generated force depends on both the viscosity of a liquid and velocity of the vessel. Thus, the relation between viscosity and a force at desired velocity of the vessel was measured using several standard reference materials including glycerol aqueous solutions and standard reference oils. The results depended on the magnitude of the gap between the bob and the vessel. For the wider gap, it was shown that the viscosity is a linear function of a gradient of force with respect to a vessel velocity. In contrast, if the gap is small, the viscosity depends on the gradient (of force with respect to velocity). This implies that the non-linear phenomena would occur in Stokes resistance. Though detailed analysis is in a further investigation, a calibration method can be applied to determine the viscosity by this method, because good correlation was obtained among these quantities. Viscosity of molten salts, such as NaNO3and ZnCl2was measured by this method as high temperature demonstration. Keywords: viscometer, viscosity, sphere pull-up method, fused salts, molten slags, glass melts

Jan 1, 2004

By R. Q. Honaker

It has been shown that naturally hydrophobic carbonaceous materials such as coal and graphite can be selectively coagulated and separated from hydrophilic impurities without using oily agglomerants, flocculants or electrolytes. The coagulation occurs at C-potentials significantly higher than those predicted by the classical DLVO theory, suggesting that it is driven by the hydrophobic interaction. In the present work, the energy barriers for the coagulation of a hydrophobic coal sample have been calculated using the extended DLVO theory which incorporates the hydrophobic interaction energy in addition to the dispersion and the electrostatic energies. For the coagulation of minerals present in the coal, the classical DLVO theory has been used for the energy barrier calculation. The results of these calculations provide an excellent correlation with the results of a series of Selective Hydrophobic Coagulation (SHC) tests conducted with run-of-mine coal and graphite samples.

Jan 1, 2004

By K. E. Livo, D. H. Knepper

Modern remote sensing provides a means for locating and characterizing exposed mineralized systems in many parts of the world. These capabilities are non-invasive and help target specific areas for more detailed exploration. An example of how remote sensing technology can be used is evident from a study of the Questa Mining District, New Mexico. Analysis of low spectral resolution data from the Landsat Thematic Mapper satellite system clearly shows the region-al distribution of two broad mineral groups often associated with mineralized systems: clay-carbonate-sulfate and iron oxides-iron hydroxides. Analysis of high spectral resolution data from the Airborne Visible and Infrared Imaging System (AVIRIS) shows the occurrence and distribution of many individual mineral species that characterize the pattern of hydrothermally altered rocks in the district.

Jan 1, 2004

By John Hoffert, Darren Colwell, Greg Tucker, Jeremy Kinch, Greg Rasmussen

"The Kemess Mine, a major producer of gold and copper, is located in north-central British Columbia. Kemess was brought into production in May 1998 by Royal Oak Mines. On February 11, 2000 Northgate Exploration Limited acquired Kemess Mine from receivership. Since acquisition in 2000 Kemess has seen many accomplishments, including the reduction of costs by 40%.One of the largest site capital costs was the construction of the tailings storage facility dam, which when finished will be one of the largest earth filled dam structures of its type. The existing construction design by AMEC called for a kilometer wide rock dam to be built from the 1350 M elevation to the 1504 M elevation at a 5.5:1 slope by hauling over 30 million tonnes of non-acid generating waste rock 7-kilometers from the open pit to the tailings dam, which was highly expensive.Kemess realized an opportunity for cost reduction was possible if the dam could be built from suitable quality tailings sand; however the sand did not meet the neutralizing potential ratio specifications. It was determined that cycloning combined with flotation to reduce pyrite concentration in the sand would produce a non-acid generating product for dam construction. The sand plant design challenges were to remove the sulphides from the tailings to obtain an NPR greater than 2:1 and provide a consistent sand product for the construction with a fines content of less than 15% passing 200 mesh. After a 2-year testing design and construction period, the sand plant was successfully started at the end 2002 resulting in higher than expected sand quality and production rates.This paper describes the plant design phase, commissioning, and operation of the tailings sand plant for construction of the tailing storage facility dam to enable us to meet all the engineering and regulatory requirements. The many challenges faced were successfully met using several innovative designs. The operational, economic, and environmental benefits are detailed."

Jan 1, 2004

By L Torckler, J Hobbins

Favona is a blind low-sulfidation epithermal vein deposit in the Waihi Vein System approximately two kilometres east of the world class Martha Hill deposit that has produced nearly 6.8 M oz Au to date. The Favona epithermal system has surface expression in variously altered and mineralised hydrothermal eruption breccias forming a series of low hills that are windows through post mineral dacites and ignimbrites. The tip line of the Favona vein is about 50 û 100 m below surface with a steeply east dipping principal vein structure carrying numerous hanging wall splays in the upper flatter section and thickening down dip where the vein steepens. Host rocks comprise feldspar phyric andesite flows with minor pyroclastics. Although Favona has a strike length in excess of 1000 m and vein widths up to 25 m over a vertical range in excess of 400 m it was only recently discovered after nearly thirty years of exploration by various companies involved in the Martha Hill joint venture that operates the Martha Mine. Since discovery in 2001 a feasibility study based on 27.5 km of diamond drilling in 83 holes has been completed reporting a reserve of 1 Mt @ 10 g/t Au against a resource of 1.8 Mt @ 10.3 g/t Au. Exploration is continuing with a further 20.5km of diamond drilling completed to date on nearby prospects.

Jan 1, 2004

By T. C. Cheng, G. P. Demopoulos

It is the object of this paper to discuss various options for improving the hematite process in terms of increased throughput hence lower capital cost and production of saleable quality hematite. With reference to increasing the throughput of the process, it has now been determined via the analysis of Akita Zinc Co's continuous industrial autoclave performance data that the process kinetics is limited by the rate of the hydrolytic precipitation reaction. By correlating the hydrolytic precipitation rate to supersaturation ratio, it is shown that accelerated kinetics can be achieved via the following measures: (1) in-situ neutralization with addition of zinc calcine; (2) elevation of temperature; and (3) dilution of feed; of which, the first one was retained for further evaluation. According to presented estimates, addition of calcine, amounting to only 2.6% of the total zinc calcine processed, can allow for shortening the retention time by at least 50%. Such drastic shortening of retention time may be either used to increase the throughput of a given autoclave circuit or alternatively to release autoclave capacity for clean hematite production. Hydrothermal treatment of the crude hematite product proved effective in producing clean hematite as according to laboratory tests, hence allowing the sulphur content of hematite to be reduced from around 4% to less than 1%. A conceptual flowsheet incorporating in-situ neutralization for accelerated kinetics with hydrothermal upgrading of crude hematite without sacrificing production capacity and with minimum upset of the plant's water balance is described.

Jan 1, 2004

The unique chemical and physical properties that can be displayed by polypropylene and its copolymer derivatives are enabling its development as a truly versatile material for water filtration. Well known applications include spiral wound cartridge filters commonly used for household water or the office drinking fountain, to pressure membranes that provide micro, ultra or nano size filtration barriers, whilst needle-felt or woven cloth filter belts or inline pressure bag cloths are well known to the hydro metallurgist and process engineer. A relatively new filtration concept that is generating interest and applications across all industries including the mining sector involves use of a unique fabric type filtering media made from polypropylene fibres. This technology not only has a vastly wider window for potential applications, it delivers an attractive cost saving alternative to the traditional sand media or diatomaceous earth type filters, along with potential benefits for integrated filtration units. This paper discusses the proven potential of the fabric media technology with examples of performance comparisons and confidence gained from full scale operating installations at mine sites and other locations.

Jan 1, 2004

By Xiao Huang, Jean-Francois Thibault, Ali Merati, Prakash C. Patnaik

Single-crystal nickel-based superalloys are the current state-of-the-art technology for the manufacture of turbine blades. This technological improvement of the turbine blade has brought a considerable increase in its cost. Repair and overhaul of service stressed single crystal turbine components is an economic necessity for life cycle cost reduction of engines since the cost associated with replacement is significantly higher than its counterpart polycrystalline component. This paper will first review the recently reported research in developing repair technologies used for DS and SX components. These techniques repair the crack or defect while at the same time ensuring that the mechanical properties do not deteriorate and, more importantly, that the single-crystal microstructure is not jeopardized. It will then be followed by a brief overview of the research conducted and initiated by the authors with regards to the repair of single crystal alloys.

Jan 1, 2004

By A. More, J. Bullón

Metal casting is one of the most important operations in ferroalloys factories. After the tapping of the furnace and the depuration of the metal, the preparation for customers with cooling, crushing and sizing begins. In total production costs, this contains around 8 % of the total cost of the metal, depending on the value of the fines and other important parameters. From an investment point of view, this represents around 20% of the total capital for a new furnace. Casting onto a water-refrigerated copper plate is not new for molten metals. In steel, continuous casting machines are normal in every factory. Water granulation casting exists at some ferroalloys plants. However, the majority of plants and production technology still use the technology of lumping, crushing and sizing. This technology is time consuming, produces fines and requires a relatively large work force. In 2001, Ferroatlantica put into operation a new water-cooled copper casting-machine, which seems to be a very convenient solution to solve all these problems. It is in operation at a silicon factory; the same place where the new ELSA electrode was developed for silicon metal production. This paper describes our experiences using it.

Jan 1, 2004

By J. Björkvall, S. Ångström, L. Kallin

In this paper results from industrial trials of CaC2 injection during stainless steel production in an electric arc furnace at Sandvik Steel is presented. The main purpose of the investigation was to analyse the effect of the injection on slag foaming and final chromium oxide concentration in slag. The results show that both an increase in slag foaming and a decrease of the final chromium oxide could be obtained during the charges with CaC2injection. On the basis of the results, the economical requirements are also discussed. Both the technical and economical requirements could be achieved for steels alloyed with Mo. In order to secure the economical requirements for all steel grades of interest, the injection technology must be further developed. It would also be important to utilize the positive effect of the slag foaming on the electric energy consumption. The work has been performed as a part of MEFOS frame research programme with participants from Sandvik Steel, AKZO Nobel and Avesta Polarit. Keywords: stainless steel, EAF, slag foaming, injection, CaC2

Jan 1, 2004

By M. Laframboise, M. Buarzaiga

High-pressure acid leaching (HPAL) of nickel laterites has received considerable attention in recent years. High paymetals extraction, good selectivity, and advances in pressure hydrometallurgical technology are some of the reasons for this interest. Falconbridge Limited (Sudbury. Ontario) investigated the HPAL process using both fresh water and seawater for ore processing. The use of seawater resulted in a chloride concentration of 7.8 g/L in the autoclave feed. A test program was developed to study the effect of process water and leach temperature on the leaching behaviour of different ore compositions from the Koniambo deposit in New Caledonia. The work showed that salinity has a major effect on autoclave chemistry. This paper explores the results.

Jan 1, 2004

By F. -Z. Ji, G. A. Irons, M. Barati, K. Coley

The use of oxygen in electric arc furnace steelmaking is tied to the use of fossil fuels, and slag foaming. The current work examines the kinetics of carbon injection into EAF slags especially the saturation injection rate and available reaction area in the slag foam. Based on individual rate data and experimental gasification rates of carbon in the slags, the available reaction surface area in the gas bubbles was found to be around 1900¬4700 cm2.kg-slg-1 for carbon injection into EAF like slags at appropriate injection rates and steel making temperatures. The ratio of number of bubbles to number of particles is 1 to 17 and the weights of carbon per unit reaction area are 0.001-0.008 gC-cm-2. Using the relationship between active reaction area and x supplied in this study, the gasification rates of carbon in slags can be estimated with gas-slag interfacial reaction rates.

Jan 1, 2004

By W. D. Gould, A. Kapoor

Acid mine drainage (AMD) is characterized by low pH and high concentrations of sulfate and dissolved metals such as iron, manganese, aluminum, zinc, and copper. Chemical treatment of AMD achieves pH neutralization and toxic metal removal but also produces large quantities of bulky sludge that requires long-term storage facilities and monitoring. Chemical treatment of AMD achieves only partial removal of sulfate (SO4) and total dissolved solids. Sulfate reducing bacteria (SRB) have been used for the removal of sulfate from industrial process wastewaters. The biological sulfate reduction process generates sulfide and alkalinity. The sulfide produced in the biological sulfate reduction process is used to precipitate metals present in AMD as their respective sulfides and the alkalinity generated is used to neutralize the AMD. This review article will present an overview of biological sulfate reduction processes using SRB, bioreactor configurations, AMD treatment studies, and full-scale systems in operation for the treatment of acid mine drainage.

Jan 1, 2004

By S. J. Frank

The development of feedforward semi-empirical control models for furnaces and the evaluation of mass balances are based on plant data. The models can only be as good as the data and it is therefore required to know the inherent uncertainty associated with the plant data. This uncertainty stems mainly from the fact that the slag, alloy or dust, have a distributed nature that depends on the degree of mixedness. It is commonly accepted that melts from open bath furnaces are well-mixed, and submerged arc furnaces less so. The impact of this assumption is significant, as a reasonably homogeneous melt could be represented by one sample only. As so much of metallurgical control depends on the assay information of the alloy and slag melts from furnaces, it was decided to characterise the possible variation in melt chemistry and temperature. Sampling campaigns and continuous temperature measurement of the melts were performed for different alloy and slag taps at a major ferrochrome producer. Both a submerged arc furnace and open arc furnace are evaluated in this way, by way of comparison. The slags of both open arc and submerged arc furnaces were found to be of similar degrees of homogeneity, with much spatial variance in the reducible iron and chromium oxides. However, it was found that the alloy melts deriving from open arc furnaces were significantly less homogeneous than the alloy derived from submerged arc furnace alloy production. The compositional variance could be related to the furnace operating conditions and it affects both metallurgical accounting and process control. In all cases it was found that the variance in melt solute components are larger than can be ascribed to analysis instrument error. It will be shown how this predetermined variance in melt composition could be included in process modelling and control.

Jan 1, 2004

By C. Anim-Sackey, R. K. Amankwah

Some large-scale mining companies in Ghana have adopted proactive management strategies in dealing with small-scale (galamsey) miners who have encroached on their concessions. This has been mainly achieved by ceding portions of the concessions held by the companies to the Minerals Commission of Ghana for licensing to the small-scale miners. This development has created an amicable relationship between the mining companies concerned and the galamsey miners in their host community. Ghana’s small-scale gold and diamond industry The small-scale gold and diamond mining industry in Ghana has existed for many centuries as an informal sector. Since the regularization of the activities of small-scale mining in 1989, two types of small-scale miners have emerged — legal and illegal.

Jan 1, 2004

By L C. Thompson

BioLix is the term for a new class of biologically-derived lixiviants for precious metals (gold and silver) recovery. BioLix can be used as an alternative to cyanide on virgin and spent ores. The BioLix process is based on inducing microbial enzymatic reactions that generate organo-lixiviant chemicals. The bioprocess involves a two-stage culture strategy. First, specialty microorganisms are cultured to generate a high biomass. Then, a food-grade quality amendment is introduced that forces the microorganisms to produce the organo-lixiviant. The second-stage culture is applied to the ore where the microbial/lixiviant system acts on mineral surfaces to extract precious metals. The process operates at ambient temperatures and near neutral pH. This paper will examine the BioLix process through an extensive laboratory development and demonstration project. Laboratory development consisted of identifying and isolating specialty microorganisms and inducing agents for the production of the organo-lixiviant solutions. A demonstration was performed on low-grade and high-grade oxidised ore from the Buffalo Valley mine in Nevada, USA. Results indicate that the BioLix process was comparable to cyanide in terms of gold recovery and operated at near neutral pH and ambient temperatures. Applications for the BioLix process will be discussed including spent-ore re-leaching, cyanide replacement for virgin ore, and in situ mining.

Jan 1, 2004

By W. M. Silva, PAP. Miotto, M. A. P. Silva, V. P. Ramos, L. R. M. Bittencourt

The major cause of breakdown of anode baking furnace fluewalls is chemical corrosion, which leads to deterioration of the properties of the bricks. Subsequent deformation of the fluewalls occurs, and also extensive cracking of the lining is observed. The present work studies the major changes of the brick during the operation of the furnace, after 22, 60 and 90 cycles of baking; in two different regions: upper and lower. Due to excellent cleaning conditions of the butts, negligible amounts of fluorine were found in the bricks. The major contaminants found were carbon, sulfur and alkali compounds, all of them present in the anode baked during the process.

Jan 1, 2004

By D. C. Van Aken, O. J. Rajtora

A research effort sponsored by the Department of Energy (DOE) and several steel producers, is investigating the benefits of coating steelcasting nozzles with various materials. Coatings were applied to casting simulation nozzles made from industrial tundish nozzles (primarily of magnesia) and industrial submerged entry nozzles (SEN's) (primarily of alumina-graphite) in order to extend casting time prior to nozzle clogging. Nozzles were coated by air plasma spray (APS) using a 9M series APS system from Sulzer-Metco. The ability of these coatings to provide protection from clogging was evaluated using a steel casting simulation. Substrate-coating compatibility was characterized using optical and SEM microscopy.

Jan 1, 2004