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By E. Contestabile, B. von Rosen

Recently, the Canadian Explosives Research Laboratory (CERL) completed its investigation of a truck accident, which involved 18,000 kg of commercial explosives, 13,000 kg of which was ANFO. Over the three years of the investigation unconfined burns of piles of ANFO were performed. In its final phase of the investigation, two burn trials were performed in an attempt to recreate the accident and the ensuing fire, to identify probable mechanisms that led from burning to detonation. Two full-scale tests were performed using complete tractor-trailers. In each test, the trucks were placed in a jack-knifed position with the majority of the explosives located on the ground in front of the trailer. The explosives were placed in a manner to provide maximum confinement and to maximize the possibility of explosion/detonation while remaining as faithful as possible to the perceived accident geometry. The tests were instrumented using thermocouples and video cameras and observations were made on the burning characteristics of the explosives, tractor-trailer and tractor-trailer components. In each test the explosives burned calmly for approximately 80 minutes. There was no evidence of explosion or of unstable burning. The heat caused several truck components to rupture violently. These included the tires, some engine components, the spring brake chambers and possibly the fuel tanks. Of these, the most violent were the truck tires. Although no quantitative data was gathered on rupture violence or fragment velocity, it is speculated that several truck components might produce fragments with sufficient energy to initiate heat-sensitised explosives under favourable circumstances.

Jan 1, 2004

By Jeff Bird, Xijia Wu, Prakash C. Patnaik

"Prognosis and health management (PHM) is an evolving suite of technologies intended for application to the life cycle management (LCM) of mission/safety critical systems, with anticipated results, which will: - Reduce life cycle cost - Enhance operational safety and readiness - Assist in maintenance decision-making - Enable autonomic logistics While it is emphasized in the United States that future multi-mission fighter aircraft such as Joint Strike Fighter (JSF) must have PHM capabilities, Canadian initiatives also recognize the need to implement such schemes for future and legacy military and civil aerospace systems. With respect to four major technology areas of PHM, i.e., i) advanced sensors, ii) data analysis and fusion, iii) life consumption evaluation, and iv) predictions with reliability/risk assessment, there has been advanced technologies developed by NRC and others within Canada: - Aircraft/engine instrumentation and airborne data recording systems - Signal analysis and data fusion - On-line engine health monitoring - Physics based models for engine material failure modes and life prediction - Autonomic crack growth analysis for damage tolerance of engine components - Mission severity analysis algorithm - Probability, reliability and risk assessment This presentation reviews the above technologies in relevance to PHM, emphasizes the need to have physics based models and outlines the future R&D needs for integration and implementation of these technologies suitable for the advanced and legacy aircraft."

Jan 1, 2004

By F. Habashi

The first documentary evidence for the use of fire to extract a metal was furnished by the wall paintings of the ancient Egyptians showing workers using the blowpipe and bellows to increase the temperature to melt gold in a crucible. Furnaces grew in size and complexity, coke replaced charcoal in the blast furnace, and the Industrial Revolution took place in England that gradually spread worldwide. More metals became known and new techniques were introduced for their extraction. Among these, metallothermic reactions became prominent in the nineteenth century immediately after the discovery of the electric current and its use to liberate the alkali metals from their salts. Once these metals became available, they were used to produce aluminium from alumina that resisted all other methods of attack. Aluminium, now available on a large scale, was used to decompose the most stable compounds and liberate more metals that became the basis of modern civilization.

Jan 1, 2004

By Lewis A. Martin

Researchers from the Spokane Research Laboratory, National Institute for Occupational Safety and Health, in cooperation with engineers from the Department of Mining and Geological Engineering, Montana Tech, Butte, MT, conducted tests to evaluate the tensile strength, fiber count, and adhesion of shotcrete applied to panels at the Chief Joseph Mine, a research and training facility operated by Montana Tech. The tests were conducted in the mine ramp 45 m (150 ft) inward from the access portal at a 15.25-m- (50-ft) long test area divided into five 3-m- (10-ft) long sections. The shotcrete was applied with an Aliva 240.5 machine fitted with a predampener. Different amounts of fiber were entrained for each panel. Background data for the tests were obtained from earlier tests in Nevada, where the typical amount of fiber in the shotcrete is 6.54 kg/m3 (11 lb/yd3). All shotcrete was applied to a minimum thickness of 76 mm (3 in). Cylindrical cores were drilled at the wall-rock interface, and adhesion was tested after 28 days of curing. The goal of this research is to reduce the need to install multiple supports at the advancing face by creating a safer mining system that limits the time miners are exposed to unprotected roof.

Jan 1, 2004

By J. Swensen, R. Brandon, A. Wallstein, S. Bessinger, J. Pile

It is generally agreed that C.C. White was the first to describe and market coal mine roof trusses beginning as early as 1967. White was issued a patent in 1969 1. Coal mine roof trusses were extensively used in the 1970’s, and their use has proven valuable in many difficult conditions. Beginning in the mid 1990’s, several types of bar/cable trusses have been introduced. A new and innovative bar/cable truss recently introduced offers several advantages. By eliminating many small parts, and simplifying the installation, these new trusses are much easier and faster to install, thereby increasing operator safety.

Jan 1, 2004

By R. Bruce Patterson

The New Tacoma Narrows Bridge is a classic suspension bridge founded on concrete caissons. Caisson construction was complicated by the proximity of the existing bridge piers, only sixty feet away. High capacity plate anchors were used successfully to moor the new caissons in currents as strong as seven knots during construction.

Jan 1, 2004

By J. M. Johnson, J. Vialpando, C. Lee

Since 1951, Molycorp has operated the Mountain Pass Mine in San Bernardino County, California to extract fourteen lanthanide elements, or rare earths, from a carbonate ore body. Wastes generated by the open pit mining operation consist of overburden and 1800 tpd of tailings. The tailings are classified as Group B mining wastes by California regulators. Paste tailings is one of several alternatives being considered during the permitting process for future mine operations. This paper presents the findings of study to assess the feasibility of using paste tailings to develop an unsaturated tailings stack instead of dilute slurry discharge behind a tailings dam.

Jan 1, 2004

By S. Itoh, T. Nagasaka, J. Ono

With respect to the recycling of used lead-batteries, a pure lead is required to prepare a lead-calcium alloy electrode for a new maintenance-free battery. The pure lead can be obtained by means of electrolytic and/or pyrometallurgical refining. In the lead electrorefming, antimony is concentrated in anode slime. From the viewpoint of the recycling and recovery of metal values from used lead-batteries, especially from anode slime, oxidation experiments were conducted for pure liquid antimony in the temperature range between 973 and 1373 K to elucidate the oxidation kinetics and mechanism. Furthermore, since lead anode slime generally consists of antimony, lead and bismuth, experiments have been also carried out using antimony-lead-bismuth alloy. The equation relating to the mass transfer characteristics in the gas phase was then applied to analyze the oxidation kinetics. As a result, it was found that the anode slime treatment, that is, an oxidation of antimony concentrated in anode slime followed by vaporization as antimony oxide Sb406, should be operated with higher oxygen partial pressure and sufficient amount of gas flow rate at lower temperature around 1073 K. The feasibility of the oxidation treatment for anode slime has been also discussed.

Jan 1, 2004

By M. Sanchez, I. Imris, G. Achurra

The Smelting and Converting El Teniente Process for copper concentrates as well as Slag Cleaning Furnace Technologies to treat slags coming out from the El Teniente Furnaces are widely applied today in Chile and around the world. Several industrial applications of this process have shown their capability to treat copper concentrates in a wide range of chemical and mineralogical compositions. Main operational parameters determining performance of the process are: oxygen enriched air flow rate, degree of oxygen enrichment, moisture content of the solid materials processed, molten material levels inside the vessel, frequency of molten materials tapping, bath temperature and copper losses in slags. In this work, the copper losses in the slags from El Teniente pyrometallurgical process are predicted by calculation from thermodynamic data and compared with those determined by microscopic examination and slag industrial data. Results obtained show that the main part of copper losses in the slag from El Teniente Furnace are mechanically entrapped or floated unsettled droplets of the coexisting matte phase. by the contrary the very low copper losses in the slag from slag cleaning furnace are limited by the physico-chemical form.

Jan 1, 2004

By V. Brabie, S. Jansson, L. Bohlin

The rate of dissolution of solid MgO-C and doloma into liquid in CaO-Al2O3-SiO2-MgO slag at different temperatures was studied under conditions of forced convection by rotating cylindrical refractory specimens in a stationary crucible containing the molten slag. The corrosion rate was calculated from the change in diameter of the cylindrical specimens. Refractory specimens were 13 mm in diameter and 70 mm long. The specimens were rotated for15 to 120 minutes at speeds of 100 to 400 rpm in the molten slag. The rate of corrosion increased with temperature and with the rotating speed of the rod, and decreased when the slag was nearly saturated with MgO. The experimental results confirm the assumption that the diffusion of magnesium oxide through the slag phase boundary layer controls the corrosion process. The corrosion mechanism seems to be the dissolution of the refractory materials into the slag, followed by penetration of pores and grain boundaries and dispersion of the grains in the slag. Keywords: MgO-C refractory, doloma refractory, molten slag, corrosion rate, corrosion mechanism

Jan 1, 2004

By E Nik, A Manzoori, H Namavari, P Witt

The smelter building at Sarcheshmeh Copper Complex, Iran, houses two reverberatory furnaces and five Pierce-Smith converters. Under normal operating conditions SO2 emissions fill the building, posing a major health problem for all workers in the building, and reducing their ability to maintain the plant. The converter fume extraction system was analysed using plant measurements, engineering modelling of the entire system and CFD modelling of the extraction hoods. By applying fundamental engineering concepts, a user-interactive computer program was developed that enabled plant engineers and operators to gain a detailed understanding of the system. In conjunction with plant measurements, the model quantified the amount of inleakage throughout the system, identifying it as a significant contributor to the poor extraction performance. Furthermore, it enabled investigation of the effects of hood gates, converters on line, hood dampers, flue insulation, electrostatic precipitator (ESP) operation, and inclusion of an acid plant. The model gave unprecedented insight into the operation of a counterintuitive buoyancy-driven extraction system.

Jan 1, 2004

By J. Kunze, R. Degal

During the last 100 years, the submerged arc furnace has been one of the most amazing diversified melting units. These furnaces have found their application in more than 20 different main industrial areas such as iron, ferro alloy, chemical industry, lead, zinc, copper, refractory, titanium oxide, recycling, phosphorus etc. Such an evolution was only possible because of tremendous efforts in research and development and due to the large range of design solutions. The worldwide strong competition also forced the industry and plant suppliers to develop highly efficient, economically balanced units in optimized sizes and with long lifetimes, to adapt to the market conditions. Regarding the environment, the plants improved significantly in terms of water treatment plants and off-gas treatments as well as on site recycling units. This paper will give a short overview regarding the history of the furnace and the latest developments in today?s main application fields: ferro alloys, non-ferrous, special application and recycling. In addition new activities in research and developments are briefly discussed.

Jan 1, 2004

By Robin J. Batterham

We still need to innovate, but it is getting harder. The real price of metals is declining, return on shareholder value is lower than other industries, and there is a shorter-term focus on staying viable in a capital-intensive industry where timeframes for implementation of new technologies can be long (+I5 years). In this environment, the levels of R&D spent by major minerals companies are remaining steady at around 0.2%-0.5% of revenue. This is not large and to remain viable in the future, we need to be smarter about the way in which we do R&D. The mining industry is a knowledge-based industry. Driving down the cost curve demands innovation, which demands knowledge. To be smarter and more effective in our approach to innovation, a new paradigm is required Generating, capturing and using knowledge has evolved from Mode 1 (discipline based and clear distinction between basic and applied research) to Mode 2 (multidisciplinary, team-based approached with flow between basic and applied activities). Mode 2 is now seen to be much more efficient and to deliver better appropriability (Tegart 2003). To survive, we need to innovate, and the best way to do this is collaboratively. Some examples and pointers for the future will be given in this paper. THE CURRENT SITUATION The Rand report and other recent studies have painted a grim outlook for the mining industry. The real price of metals continues to decline (Figure 1) and profit margins remain thin. This is reflected in shareholder returnwhich are well below other industries (Figure 2)-and current management strategies-which reflect something of a "survival mode." The current focus for most mining companies is on short-term, incremental gains

Jan 1, 2004

By David A. Staab

Numerical modeling was used to investigate the feasibility of using two geophysical imaging techniques, cross-borehole ground penetrating radar (XBGPR) tomography and electrical resistivity (ER) tomography, for detecting and characterizing defects in deep-mixed soil columns. XBGPR modeling was accomplished with a three-dimensional numerical forward modeling code and a two-dimensional inversion routine. Spatial variations in apparent dielectric constant (Ka) and attenuation (a) were mapped. Electrical resistivity modeling was accomplished with a three-dimensional numerical forward modeling code and a three-dimensional inversion routine. Spatial changes in electrical resistivity were then mapped. Three different types of defects were simulated, in addition to a defect-free column. The computer simulations suggest that XBGPR tomography and ER tomography might be useful, non-destructive methods for detecting and estimating the extent of defects in deep-mixed soil columns. The results show that small, isolated defects might be difficult to detect, but defects approximately equal to or larger than the sampling interval (for XBGPR) or vertical electrode spacing (for ERT) should be detectable.

Jan 1, 2004

By G Chitombo, G Lewis

The knowledge of the expected run of mine (ROM) fragmentation during the feasibility study of a green field site is essential for the design of downstream crushing and milling processes. However,the prediction of blast fragmentation can be a challenging process due to the uncertainty related to the blast design and rock mass parameters. In general,a number of possible blast designs are considered in a feasibility study,with factors such as bench height and blasthole diameter influencing the design. Rock mass parameters are normally derived from a limited number of geotechnical diamond drill cores. Although diamond drill core can provide detailed information concerning intact rock strength (unconfined compressive strength and point load),it provides limited structural information to predict the in situ block size distribution of the rock mass. The in situ block size is an essential input to the prediction of the fragmentation distribution, in particular the coarse end. This paper outlines the methodology of blast fragmentation modeling undertaken for a green field feasibility study at the Riska gold deposit in Indonesia. The favoured milling process for the feasibility study was dump leaching,with no crushing of the ore material extracted from the pit. For this reason,blast fragmentation was a critical issue to be addressed by the study. A range of blast designs were considered with bench heights and blasthole diameters ranging from 4 m to 7 m and 76 mm to 102 mm respectively. Rock mass data was obtained from 19 diamond drill cores across the deposit (total drill length approximately 2200 m). Intact rock strength was estimated from qualitative strength descriptors,while the in situ block size distribution of the rock mass was estimated from the Rock Quality Designation (RQD) of the core. The methodology of fragmentation prediction involved a number of steps including the estimation of rock mass parameters from diamond drillhole data including the estimation of the in situ block size, delineation of blast domains within the deposit,and the assessment of the impact of various blast design parameters and rock mass variation on the predicted fragmentation distribution. The modelling process for the Riska green field site highlighted the need for additional rock mass data to be collected post feasibility stage and once the development of the mine commenced.

Jan 1, 2004

Two examples of risk assessment and risk management in action are discussed. The first is in a management context in relation to Kingsgate Consolidated LtdÆs Chatree operation in Thailand. Kingsgate has conducted an over-riding risk management program to assess and manage risk across its complete business from the Sydney and Bangkok offices through to the Chatree Mine and the companyÆs exploration group. This example addresses how Kingsgate has applied risk management, particularly to the process operation, and the benefits that have been gained. The second is in an operational context in relation to Minara Resources LtdÆs Murrin Murrin operation in Western Australia. The subject is the methodology and outcomes of a risk assessment across the Murrin Murrin operation specifically to identify and assess risks with potential impacts from $1 M to $7 M. This section of the paper then shows how the outcomes of the risk assessment were integrated into MinaraÆs strategic plan to debottleneck the plant and increase nickel production.

Jan 1, 2004

By T. Hall, R. Ferris

Waterjets and diamond wire saws have raised the productivity and lowered the cost in dimensional granite quarries. While the cost of diamond wire sawing is substantially lower than waterjet, the judicial use of the waterjet can simplify and improve the overall operating efficiency and predictability. Granite is the hardest commercial stone and only the gem-stones garnet and diamonds are harder. The introduction of industrial diamonds has made it possible to quarry and process granite at costs equal to or less than other natural stones – making granite, with its superior properties, the best value available.

Jan 1, 2004

By H. Krogerus, P. Niemelä, P. Oikarinen

High carbon ferrochromium is produced by carbon reduction. No replacement for carbon as reductant has yet been developed. The reduction creates a considerable amount of CO-gas. In open and semi-closed furnaces the gas is burned when leaving the burden. In closed furnaces the formed gas is sucked out by a fan, washed and utilised as fuel. The formation of carbon monoxide is presented briefly starting from thermodynamic considerations up to solid and liquid state reduction. The volume, composition and energy content of the furnace gas are discussed, focusing on the raw materials and pre-treatment processes of the furnace feed as well as on the process equipment and control. Outokumpu has been using closed and sealed furnaces and utilising the CO-gas in its Tornio Ferrochrome Works since 1968. Today in Tornio with an annual ferrochromium production of 260 000 t CO-gas production is 186 million m3, representing 68 MWh an hour. At the same time the furnace power input is 95MW. About 98 % of the CO-gas is utilised, whereof 30% in the ferrochrome production itself. This paper focuses on the characteristics and utilisation of CO-gas. CO-gas is secondary energy, which on one hand saves primary electric and fossil fuel energy in ferrochromium production and, on the other, replaces other fossil fuels at the adjacent steel works. The characteristics of the fuel, requirements for utilisation as well as health and safety aspects are discussed. Utilisation of the gas has a high impact on the total dust and gaseous emissions and on the energy optimisation at the ferrochromium and steel works.

Jan 1, 2004

By A. W. F. Smith, P. B. Prangnell, D. N. Crowther, P. J. Apps

It is well known that the refinement of grain size in metals leads to a significant improvement in important mechanical properties. As part of a European collaborative project, processing schedules have been investigated aimed at producing a homogeneous ultra-fine ferrite and spheroidised carbide aggregate microstructure structure in high carbon (CMn) steels (0.6-1.2wt%C), via conventional 'warm' rolling and innovative Equal Channel Angular Extrusion (ECAE). Suitable deformation schedules were determined from dilatometry and thermo-mechanical Gleeble simulations. Evidence of an ultra-fine ferrite and carbide aggregate microstructure following 'warm' rolling is given. A significant improvement in tensile strength, particularly proof stress (0.2%) was also noted in comparison to material deformed at higher temperatures. Concurrent Equal Channel Angular Extrusion (ECAE) experiments investigated microstructural evolution with incremental strain. Extensive analysis was carried out using various techniques, including high resolution Electron Back Scattered Diffraction (EBSD). Evidence of ferrite grain refinement was noted in a eutectoid composition steel. A sub-micron ferrite structure was observed following high strains (E-3.33) and the mechanical properties exhibit a marked increase in tensile strength.

Jan 1, 2004

By G. Van Weert, J. F. Breedveld

Both regular and Silver Impregnated Activated Carbon (SIAC) were studied for their effectiveness in removing WAD (Weak Acid Dissociated) cyanides from solutions at pH = 10. SIAC has already been shown to be effective in the removal of free cyanide down to 30 ppb or less. The present work deals with complexed cyanides. Zinc cyanide was used to represent the WAD component. At pH=10, in either batch or column tests it was not possible to lower the total cyanide in solution from either 30 or 8 ppm to less than 1 ppm, using SIAC, regular activated carbon as received, or after grinding. Silver (metal) impregnation of the carbon was not beneficial in the removal of WAD cyanide. However, when silver is added as silver ions (nitrate), the cyanide is adsorbed as silver cyanide in preference to zinc cyanide. The latter compound converts to zinc (hydr) oxide. This way, the cyanide concentration in solution can be lowered below 1 ppm, even when zinc cyanide is already adsorbed on the carbon used. A single exploratory test with added copper ions indicated a similar effect for that system.

Jan 1, 2004