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By Guy Chevalier, Jean-Guy Chartrand, Louis Barrette, Daniel Michaud, Michel Fortin

"COREM has developed, specifically for the mineral industry, a mobile laboratory using the Laser-Induced Breakdown Spectroscopy (LIBS) technique. It has been used to perform onstream analysis (OSA) of the chemical composition of slurries in both gold-ore and iron-ore processing plants. Industrial tests have been carried out respectively at La Mine Doyon (Cambior), a gold-ore processing plant near Rouyn-Noranda, Quebec, and at QCM's iron-ore pelletizing plant in Port-Cartier, Quebec. The aim was to demonstrate that the LIBS technique is capable of providing information that meets the needs for process control. C, Si, Ca, Mg, Mn and Al were the elements targeted on iron ore while Cu, Fe, Ag and Au were targeted for gold ore. The results obtained meet or exceed the requirements for process control and consequently clearly show that the LIBS technique is suitable for industrial applications.The feasibility of OSA, through in-plant validations using COREM’s LIBS mobile laboratory, has been demonstrated in four essential aspects: slurry sampling, LIBS chemical measurement, robustness for continuous operation, and functionality for industrial operators.INTRODUCTIONThere is a general need for optimization in the mineral industry. Process control is a favoured means to achieve this goal (McKee 1991). Real-time knowledge of process status is the key to effective control (Da Silva 1994). Only a few techniques, such as XRF, NMR and digital imaging, are currently amenable to chemically monitor industrial processes (Braden 2002). LIBS is an emerging technique with appealing characteristics for on-line and real-time measurement of bulk material (Lorenzen 1992, Palanco 2000). While our ultimate goal is to provide our industrial partners with performing monitoring tools, a shorter-viewed objective is to demonstrate the feasibility of developing a LIBS system for OSA. The LIBS technique has shown interesting capabilities for measuring solids, liquids, dusts and gases. Our work has focused on mineral slurries (Barrette 1999 and 2001, Turmel 1999). Special equipment is needed to perform in-plant validations. A mobile laboratory based on the LIBS technology has been assembled for this task."

Jan 1, 2004

By B. Tiryaki

Longwall shearers usually suffer from excessive pick and pickholder consumptions and severe wear of the back plate of the clearance ring section of shearer drums. In practice, most of the drums were seen to be withdrawn from the face due to the abovementioned problems, while vane picks and their holders were intact due to the improper lacing design of the clearance ring picks. However, few underground investigations and their results on the effect of lacing arrangement of clearance picks on the service life of shearer drums have been published. Nevertheless, the pick consumption characteristics of shearer drums were not investigated in detail, since these are fewer pick consumptions with shearers when compared to roadheaders. This paper is concerned with the comprehensive in situ trials on the effect of lacing of clearance ring picks on the lifespan of shearer drums, and the pick consumption characteristics of longwall shearers at Cayirhan Coal Mine in Turkey. The lifespan of shearer drums employed with shearers in this mine increased 70 per cent, while the consumption rate of clearance ring picks decreased threefold through using an alternative lacing for clearance picks, indicating the significance of utilizing proper design techniques for clearance ring picks for the service life of shearer drums. Statistical analyses carried out, using the raw pick consumption data, implied that the clearance ring picks experienced much higher loads than vane picks, revealing that special attention must be paid to designing clearance ring picks. An average maximum consumption value of 41 was determined for clearance ring picks, with corner-cutting picks having the most replacements, while it was 35 for vane picks, on three-day based pick replacements.

Jan 1, 2004

By J. Borlee, F. Sorrentino, A. Fleischanderl, M. Gimenez, W. Gebert, U. Gennari

Large quantities of solid by-products are generated by the steel industry and other important activity sectors in Europe (power plants, car dismantling companies, urban incinerators) with no or very limited potential for direct recovery. In the frame of a multi¬national project supported by the European Union, a consortium has been created to develop a treatment process able to turn these by-products into valuable metallic and mineral products. VAI has been responsible for the design, erection and start-up of the pilot plant for the new metallurgical process and for the execution of the test campaigns, with the targets defined together with the partners. Up to now, 9 campaigns comprising 60 heats have been performed successfully. By-products from C-Steel and stainless steel plants, as well as fly ash and auto shredder residues, have been used and defined products such as hydraulic binders for cement, metallurgical powders for De-S practice and recycled metal phase have been produced. The mineral products were positively assessed under industrial conditions. Results from cement tests and secondary metallurgy are reported, as well as a detailed characterization. The economic value of the products, credits from avoiding dumping and significant savings on CO2 emissions make the new process economically very attractive.

Jan 1, 2004

By Robert A. Creaser, Iain Mitchell, Robert L. Linnen

Abstract - The Bermuda Zn-Pb showing is hosted by dolomitized Blue Fiord Formation of Devonian age, located east of the Ensorcellement dome on the Grinnell Peninsula of Devon Island. Fluid inclusions in hydrothermal calcite indicate that the mineralization precipitated from low-temperature, highly saline brines. The ?34S compositions of sphalerite, galena, and marcasite range from 16.1‰ to 35.2‰. Consequently, the Bermuda showing is interpreted to be Mississippi Valley-type (MVT) mineralization. The apparent age of mineralization has been determined by the Rb-Sr method from sphalerite separates, and a Late Devonian age of 357 ± 50 Ma (MSWD=65), with an initial 87Sr/86Sr ratio of 0.7083 ± 0.0020 is indicated. This date, within error, is the same as the Polaris deposit. This suggests that the mineralization formed during the Ellesmerian Orogen, although it is also possible that mineralization is associated with extension, related to the opening of the Sverdrup basin. The strontium and sulfur isotopes and fluid inclusion analyses indicate the involvement of a brine that acquired its salinity from interaction with evaporites, lower in the stratigraphic succession. The Polaris mine is the type deposit in the Cornwallis Zn-Pb district and is hosted by the Thumb Mountain Formation. The results of this study are significant because they demonstrate that regional brine movement is more widespread than previously recognized, and that MVT mineralization in the Cornwallis Zn-Pb district is not restricted to the Thumb Mountain Formation.

Jan 1, 2004

By P. Cheung, J. Gulyas, R. Clary

Over the past 50 years, the use of autoclaves in the metallurgical industry has evolved from final metal recovery (hydrogen reduction) and purification (sulphide precipitate oxidation) to treating whole ores and concentrates. Recent process developments, such as the use of autoclaves for laterite leaching, have necessitated higher temperature and pressure operations, which in turn have seen marked advancements in technology and manufacturing capabilities to keep in step with process demands. This paper will discuss the advances in technology in terms of design, materials and construction of autoclaves and liners, typical dip tube design and geometric layout. This paper will also address specific auxiliary equipment, such as acid and steam injection systems, and components, such as agitator seal systems.

Jan 1, 2004

1. In 2002, a total of 7,125 sand and gravel mining operations reported employment to the Mine Safety and Health Administration (MSHA). The largest percentage of all mining sectors1 was sand and gravel mines (49.1%). Sand and gravel mines are found throughout all 50 states.

Jan 1, 2004

By B. Francis

Literature provides only limited information regarding the behaviour of laterally loaded piles socketed into weak rock masses. A laboratory program, comprising a number of tests of scaled models of the pile/rock mass system has been conducted. A synthetic rock, known as Johnstone was used to simulate a naturally weathered and fractured siltstone. The load-deflection behaviour of the test piles was measured, and strain gauges were fixed to the model piles to assess the bending moments. The laboratory results are compared with the results from several theoretical models, some of which are in the form of commercial software packages. This study highlights the inadequacy of existing methods to adequately model the influence of rock joint orientation in geotechnical design. Additionally, numerical modelling of the pile/rock mass system was carried out using the discrete element program UDEC. The importance in modelling the system using discontinuum mechanics is highlighted, particularly to capture the anisotropy of the rock mass.

Jan 1, 2004

By Jane Spooner

"The papers presented in this edition of the Bulletin cover some of the business issues that face mining companies exploring or operating in jurisdictions outside Canada. While technical innovations may, generally, be seen as fast-moving and farreaching, these papers also show that changes in approach and thinking continue to be evaluated and implemented.The Forum paper co-authored by Roger Taplin of McCarthy Tétrault LLP and Marchand Snyman of Muratie Investments Pty Ltd. highlights the quite radical changes that have taken place in South Africa’s mining industry with the introduction of the Mineral and Petroleum Resources Development Act, 2002, in October of that year, together with the Broad-based Socio-Economic Empowerment Charter for the South African Mining Industry and the Mineral and Petroleum Royalty Bill of March 2003."

Jan 1, 2004

By Kia Riihioja, Mike Higgins

A major difference between electronic and pyrotechnic detonators is that, in almost all but the simplest of blast layouts, computer software is required to plan a blast using electronic detonators. While it may be possible to program delay times without software, using only the manufacturer’s control hardware, the full potential of electronic detonators can only be realized through software. Until recently, the only software available has been provided by the suppliers of the electronic detonators. These usually have just enough features to create a hole layout and to assign times to the detonators in the holes. The software is also able to communicate only with the manufacturer’s detonators. This means that the client may be compelled to change several parts of the blasting process when a different delay system is adopted, from design through to implementation and reporting, even though these may be sub-optimal at the client’s mine. While many authors have demonstrated improvements in blasting outcomes using electronic detonators, very few have discussed how the delay times were calculated. Where the calculations are discussed, it is also obvious that the delay times must be monitored and re-evaluated as conditions in the mine change. For example, the principles of superposition and scaled distance, burden relief and energy cooperation between holes should be checked constantly for different locations within the mine, changes in rock properties, or even for differences between design and actual hole positions. The most common methods in blast design software to calculate delay times are inter-hole interval, relief contour and direct editing. Although they are simple in concept, they can result in fundamental errors if they are not applied correctly. The software for electronic blast designs should be capable of not just a timing calculation, but also of showing, to some degree, the impact and interaction of the calculated times.

Jan 1, 2004

By Keith Pucalik

Understanding Vibrations fr om Blasting focuses on explaining blast vibrations and their effects on people and homes while keeping an eye on the importance of the use and significance of explosives in our daily lives. Unlike many predecessors, this film will help blasting pro f e s s i o nals explain blast vibrations and address many of the layman’s most fre q u e n t l y asked questions. The film can be used in pubic hearings, given to homeowners during preblast surveys, or played at educational seminars for professionals. The film can also be used after blasting has begun and residents have already experienced vibration events.

Jan 1, 2004

By Muhammad Tawalbeh

The calculated temperature history of a single particle of MgCl2 hydrates when it came in contact with fused salt electrolyte at 650 °C was determined using the measured heat transfer coefficient for the molten salt bath at 650 °C. The calculations revealed that the entire interior of the particle reached the temperature required for the formation of MgOHCI from hydrated MgCl2 in less than 2 seconds. This was much less than the time required for dissolution of the prills as observed in experiments. It is very likely that the formation of MgOHCI during prill dehydration and dissolution is a result of hydrolysis in the interior of the prills.

Jan 1, 2004

By Z. -G. Ren, J. -S. Qian, Y. -G. Yang

The waste slags from chemical and metallurgical plants contain approximately wt 1% water soluble Cr6+. This hexavalent chromium is very harmful to human health, and the treatment of the slags has concerned metallurgists for many years. A sintering method was developed to treat the waste slag. In this process, sinter was made from a mixture of the waste slag containing hexavalent chromium, iron concentrate and coke breezes. During sintering, hexavalent chromium was reduced to trivalent chromium. The latter is known as a non-harmful material and can be used as chromium resource for the production of ferrochromium or chromium-containing cast iron. After sintering the hexavalent chromium in the sinter could be reduced to less than 0.0008%. It was found that the waste slag with fine particles was favourable to the Cr6+ removal. An increase of carbon content in the sintering mixture could increase the rate of Cr6+ removal and the strength of the sinter produced. The rate of Cr6+ removal increased with increasing basicity of the sintering materials with basicity less than B=1.8, above which it decreased with increasing basicity. Blast furnace was found to operate smoothly when using the sinter made from the waste slag containing chromium. However the productivity of sintering machine was slightly low compared to the sintering operation using ordinary raw materials.

Jan 1, 2004

By Vladimiros G. Papangelakis

During the past five years, chemical modelling work at the University of Toronto has elucidated the role of soluble magnesium on the autoclave acidity and has demonstrated why feeds rich in magnesium, and other divalent metals, require more than the stoichiometric requirements in acid to produce a leaching performance comparable to that of low magnesium feeds. This understanding has allowed the calculation of acid additions to the pressure acid leach (PAL) on a less empirical basis. Optimizing acid additions to the PAL confers savings in neutralization costs, ensures high productivity and minimises corrosion problems. Hence, our picture of the solution chemistry inside the autoclave during the PAL process has been substantially improved and is reviewed here. Experimental techniques based on solubility and direct acidity measurements that support the theoretical predictions are presented. Concepts of chemical modelling of electrolyte systems at high temperature and software issues are also discussed. Finally, a better understanding of the solution chemistry at temperature has led to better kinetics models because all metal dissolution and precipitation reactions are acid driven and controlled. . Therefore, reactor modelling efforts by our group are also presented and a reactor model with very good performance, as compared to pilot-plant data, is also made here. Finally, in spite of the above success in PAL solution chemistry and reactor modelling, significant challenges lie ahead in theoretical data gaps and instrumentation; these are also discussed in this paper. Keywords: Laterites, process modelling, pressure acid leach, solution chemistry, chemical modelling, reactor simulation

Jan 1, 2004

By M. S. Miller

With prevailing assumptions that plentiful domestic coal reserves will be available for meeting our Nation’s expectations for on future low emission, coal-fired power plants, major government funding in Clean Coal Technology, and Carbon Sequestration Programs continues to be aggressive. However, after more than a decade of cutbacks in funding for domestic coal-related programs and personnel, there is a growing concern that adequate quantification and qualification of our Nation’s coal reserves is increasingly being compromised. This paper will define the growing concerns and dichotomies that continue to increase, and address the decreasing number of fossil fuel mapping and assessment programs by Federal and State programs.

Jan 1, 2004

By M. Timmins

Campbell Mine operates a 100 tpd gold autoclave that treats sulphide concentrates at 305 psi and 200 °C. Autoclave feed consists of fresh pretreated concentrate, an acidic oxide slurry recycle as well as other high arsenic sources. The brickwork that is used to construct the five compartments of the vessel must be inspected and repaired periodically. Shutdowns are scheduled to inspect this brickwork and at times replace entire sections of the brick walls or lining. It also provides an opportunity to repair or replace other internal features such as agitator blades or oxygen spargers. Mechanics and contractors are scheduled around the clock to perform the maintenance requirements. There are many safety considerations and precautions that must be taken in order to protect the well-being of the workers and minimize damage to sensitive pieces of equipment. Heat, arsenic and lead contamination and confined space issues are just a few of the hazards involved. The following paper will describe how these safety concerns are addressed and will serve as a guide for future autoclave shutdowns.

Jan 1, 2004

By K. Potluri, S. Akella, S. Bhansali

"This paper presents the design and angular strength analysis of microneedles for use as a transdermal interface for drug delivery, fluid analysis and sampling etc. Microneedles of different dimensions were designed and fabricated using various materials viz. Si02, OxideNitride- Oxide (O-N-0). The design, modeling and analysis was done using the Finite Element Analysis (FEA) software ANSYS™ 6.1. Angular strength analysis of the microneedles was done using angular loading in ANSYS™, with the corresponding inaterial property settings. Using the force-displacement settings, forces of magnitudes in the range of 10 mN - 25 mN were applied on the microneedles at loading angles ranging from 30° to 90° was applied on needles. Square and circular shaped microneedles were modeled and the displacements and stresses generated were studied to characterize the angular strength of the microneedles. The buckling and force-displacement analyses show that O-N-O microneedles are more strong and robust as compared to needles of other materials. The analysis shows that while circular microneedles have uniform stress distribution, square microneedles have low stresses concentrated along the edges.INTRODUCTIONIn modem clinical and biomedical applications, drug delivery is done either by oral administration or by hypodermic injection. Hypodermic injection of drugs using needles is often painful. Hence, transdermal drug delivery techniques are increasingly being sought out as an alternative. In transdermal drug delivery the needles puncture the Stratum comeurn - the outermost layer of the human skin. The advantage of transdermal drug delivery (or transdermal measurement) technique, is that it reduces pain and tissue trauma."

Jan 1, 2004

This paper reviews recent advances in geophysical tools for mineral exploration. It does not restrict comments to methods which are usually applied in the tectonically active belt surrounding the Pacific Ocean, where geophysics has often been secondary to geological prospecting (eg visual recognition of surface alteration) and drainage geochemistry; but considers geophysical tools applied to a broader range of both deposits and terrains. For example, the subdued topography of much of Australia and Canada has lent itself to the development and extensive application of airborne methods. In Australia, deep weathering and transported cover have necessitated the use of geophysical methods to not only detect anomalies but also to map and understand basement geology. This same weathering has caused specific problems, particularly for electrical methods, but recent improvements in instrumentation, processing and visualisation have largely overcome them. A great deal of geophysical data is now being collected by government agencies, often from the air, and made readily available to explorers. In several Australian states it is free, often on line, and in almost all cases it is relatively cheap. These regional data sets are often augmented by more detailed local surveys in areas of interest. Although æanomaliesÆ are still important much more is being done with the high quality data which is now available The results are used for geological mapping, to test geological hypotheses, to construct detailed 3D geological models and, together with fluid flow modeling, to predict optimum locations for mineralisation.

Jan 1, 2004

By T Leach, F Kaiqiang

The Jianchaling gold deposit is located about 1200 km south west of Beijing in central China. The deposit was discovered in 1988 by the Northwestern Geological Exploration Bureau (711 Exploration Team). Sino Gold Limited, an Australian based company, developed the mine in 1998 and is currently operating a 1000 t per day underground mine, producing about 80 000 ounces of gold per year. The pre-mine resource for Jianchaling was 1.6 million tonnes at 9.85 g/t gold. The deposit occurs within the east-west trending Mesozoic Qinling-Dabie orogenic belt formed during the Yanshanian Orogeny. In the Jianchaling region, gold mineralisation is primarily hosted by regional west-northwest to east-southeast striking faults, the most important of which, the reverse sinistral F145 fault, hosts the larger gold deposits including Jianchaling. At the mine scale, the most important zone of mineralisation is localised within a shallowly north dipping dilation on the F145 fault. Proterozoic dolomite forms the hangingwall and serpentinite and talc schist the footwall to the fault. Within the footwall, serpentinite is the most important host rock to mineralisation. Initial alteration involves replacement of serpentine to dolomite ¦ pyrite, talc to ankerite ¦ pyrite, and magnetite and chromite to pyrite, the latter locally through a transitional hematite phase. Proximal to feeder structures, the carbonate minerals have undergone partial dissolution and replacement to quartz. Gold is related to arsenean pyrite and marcasite rimming and replacement of early-formed pyrite, and associated with iron release during the processes of dolomitisation, silicification and carbonate dissolution.

Jan 1, 2004

By B. T. Mirabile, D. Tang, Y. Luo, S. S. Peng, C. T. Holland

Knowledge of local coal mine roof geology is critical to the design of a safe and suitable mine structure. An automated drill control and data collection system has been designed for a J.H. Fletcher twin-head roof bolter. Drilling parameters collected during the drilling process can be used to interpret geologic features intercepted in the mine roof. The drill and data collection system have been tested in both laboratory and underground settings. Visualization of certain drilling data has shown good correlation with geology drilled. A quantitative prediction model was developed using drilling parameters examined with data visualization. The quantitative model was tested using laboratory drilling data.

Jan 1, 2004

This paper introduces a new, safer bulk emulsion loading system for underground mining operations. The features and benefits of the equipment, along with the use of Dyno Nobel Inc patented gassed emulsion technology, is summarised in the application of a stope blast with very difficult and complex ground conditions. The paper describes methods used to optimise the amount of energy required to break the ore while protecting the integrity of the surrounding backfilled pillar.

Jan 1, 2004