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By M. Mirnezami, J. A. Finch, M. S. Hashemi A.

The surface of -30µm silica suspension (2% v/v) treated with 100 ppm Mg2+ at pH 11 was fully coated with Mg(OH)2. Under this condition, the silica is strongly positively charged (+30 mV) and the suspension is dispersed. Subsequent addition of Ca2+ promoted aggregation and reduced the surface charge. At this pH calcium is present as Ca2+ and CaOH+, i.e., positively charged ions interacted with the positive surface. Aggregation by a chemical bridging mechanism is proposed. The observation may be relevant to the widespread practice in mineral processing of adding lime to promote aggregation and settling in concentrate thickeners.

Jan 1, 2004

By H R. Watling, W van Bronswijk

Of the various copper sulfides in the EarthÆs crust, chalcopyrite is by far the most common. This mineral is also the most difficult to leach, with hydrometallurgical extraction processes characterised by prohibitively slow kinetics. While a number of processes, including leaching at atmospheric pressure and temperature, pressure leaching at higher temperature, and bioleaching of concentrates in stirred tanks and whole ores in heaps have been demonstrated to some extent, there is currently no full-scale unit process for the hydrometallurgical extraction of copper from chalcopyrite ores. Titan Resources NL operated a test bacterial heap leach at Radio Hill, Western Australia in 2001, to extract nickel and copper from a mixed sulfide ore that contained significant amounts of chalcopyrite, pentlandite and pyrrhotite. A proprietary mixed bacterial culture was used to inoculate the heap, and the nickel and copper were precipitated from the resultant solution as mixed hydroxides. Although 65 per cent of the copper from the Radio Hill heap was eventually recovered, the rate of extraction followed an unexpected trend, as the initial rates of copper recovery were much slower than column tests had suggested. It was postulated that this was due to dissolved copper precipitating as covellite or chalcocite in the most poorly aerated zones within the heap, ie furthest from the aeration pipes at the base. It was further hypothesised that the lack of oxidants (oxygen, ferric iron) and the likely inactivity of bacteria in these areas limited the re-dissolution of such secondary copper precipitates. In this study the above hypothesis was tested in column experiments using the same mixed sulfide ore and a synthetic leach solution. One set of columns was aerated and another set was operated without aeration. Results showed that precipitation of copper occurred regardless of whether the column was aerated or not. The results suggested that pH of the leach solution played a significant part in the precipitation of the copper. Further column tests revealed this to be the case. These results are described here in detail.

Jan 1, 2004

By J. Bakken, M. Th. Jonsson, G. Sævarsdottir

A typical three-phase submerged-arc furnace for production of silicon metal and ferrosilicon has arc currents ~100 kA, phase voltages ~100 V and total furnace power ~10 - 60 MW. The arcs burn in gas filled cavities or "craters", where the main atomic components of the plasma mixture are silicon, oxygen and carbon. Two quite different simulation models for high-current AC arcs have been developed: the simple Channel Arc Model (CAM), and the more sophisticated Magneto-Fluid-Dynamic Model (MFD). These models have been described extensively and results reported at INFACON-8 and INFACON-9, respectively. The coupling between the arcs and the AC power source is described by a complete three-phase Electric Circuit Model. Recent numerical modelling studies of industrial AC arcs show that the boundary conditions at the cathode and anode are critical for the simulation results. A novel Cathode/Anode Sub-Model for high-current AC arcs that treats both cathode and anode indicates a completely different cathode behaviour than previously assumed. A cathode spot which serves a high-current electric arc is shown to be dominated by the energy impact from the arc. This leads to lower cathode fall voltage than obtained from previously developed models. The anode fall voltage is negative, as the main function of the potential barrier is to repel plasma electrons. The cathode spot is diffuse in the sense that the arc in fact contracts away from the cathode. Simulation results are compared to measurements on both industrial furnaces and smaller scale pilot furnaces. An important conclusion, supported by our arc studies, is that the arc length in silicon metal and ferrosilicon furnaces does not exceed 15 cm and the arc may burn anywhere on the electrode, not necessarily beneath the electrode tip.

Jan 1, 2004

By Alain Jardy, Thibaut Quatravaux, Denis Ablitzer

"A numerical model of the Vacuum Arc Remelting process has been developed and applied to simulate remelting of various metallic materials, such as specialty steels, titanium and zirconium alloys. In practice, electromagnetic stirring is sometimes used, resulting in a complex 3D molten metal flow. After having validated the numerical model for different remelting conditions, we can use it to study the effect of applying a constant or alternated magnetic field on the thermohydrodynamic behaviour of the melt pool. The intensity of flow turbulence, computed with a classical k-E model, is shown to depend strongly on the nature of electromagnetic stirring.IntroductionThe principle of the Vacuum Arc Remelting (VAR) process, illustrated in figure I, consists in melting a consumable metallic electrode of the required grade under a high vacuum, in order to obtain a sound ingot of good structural quality.During remelting, an electric arc is maintained between the tip of the electrode and the top of the secondary ingot, in order to ensure melting of the electrode. The metal droplets fall through the arc plasma and progressively buid up the ingot, which solidifies in contact with the walls of a water-cooled copper crucible. The secondary ingot formed in this way contains three distinct zones, corresponding to the liquid pool, fully solidified metal and intermediate mushy zone. In order to stabilize the arc, it can be confined with the aid of a magnetic field created by an external induction coil. This field can also be used to stir the liquid metal, the rotation induced being in the orthoradial direction. By reversing periodically the coil current, stirring can be alternated."

Jan 1, 2004

HoistEM is a helicopter-towed time domain electromagnetic system. This paper presents details of the towed array structure (the Hoist) as well as a description of the instrumentation. A comparison between HoistEM and ground TDEM (from which HoistEM was derived) is given. Over 50 000 line kilometres of HoistEM have been completed to date and datasets for structural mapping, nickel, base metals, manganese, ground water and bathymetry are presented and discussed.

Jan 1, 2004

By Walter S. Bergholz, Michael L. Schreder

"Since Escondida began operations in fiscal 1991, a series of aggressive expansion projects have enabled market share to be increased and ever larger profits to be realized. This was possible due to the very large size of the ore body and its high grade - averaging 2.7% copper from startup through fiscal 1997. The situation has now changed: ore grade is falling rapidly and is projected to be only 1.55% by 2003. Since revenue is directly proportional to ore grade, while costs are proportional to quantity of ore processed, profits will begin to fall dramatically. The Phase IV Expansion Project is intended to forestall this drop in profits by increasing ore processing capacity by over 85%.The Phase IV concentrator is designed for a nominal capacity of 110,000 MTPD and the key to achieving this value is through the proper design of the grinding circuit. This paper presents the general design criteria for the grinding circuit, as well as a description of the facility.INTRODUCTIONThe Phase IV Expansion Project consists of a new copper concentrator located 8.5 km south of the existing operations, a new tailings disposal and water reclaim system, a new concentrate slurry pipeline to the coast, and added concentrate handling capacity at the port of Coloso. The new concentrator has a nominal capacity of 110,000 tonnes per day (MTPD), compared to the existing concentrator’s capacity of 127,500 MTPD. The Laguna Seca concentrator is based on using the largest and most efficient ore grinding mills now available.The concentrator has been designed for a 110,000 MTPD nominal capacity. The process design criteria for the Phase IV project were established from in-house operating information and from test work. Unlike a green field project, Escondida already had an operating plant and it processes ore from the same pit that feeds the Phase IV plant. It is expected that the current mineralization will be similar for the first 6 years of operation of the new project. Therefore, some of the current plant operating conditions were incorporated directly into the design criteria."

Jan 1, 2004

By R. Loots

High temperature creep resistant alloys are used in power plants as steam pipes and headers where they have to withstand super heated steam temperatures of up to 600ºC for the lifetime of the plant. Frequently certain portions of pipes may be subjected to excessive temperatures and consequently suffer from creep damage. Damaged portions then have to be replaced by welding new steel to the service exposed steel. Such welds will have to be subjected to a post weld heat treatment (PWHT) to relieve residual stress. During such a PWHT it is then possible for the steel to crack in the heat affected zone (HAZ) by what is known as Reheat Cracking (RHC), also known as stress relief cracking. For the present purpose the RHC susceptibility of service exposed steel was compared with that of new steel by reproducing the temperature cycle to which the HAZ will be subjected during welding in a weld simulator. This was followed by PWHT where the influence of residual stress was studied by applying a constant stress to such a weld-simulated specimen in a creep testing machine. A sharp spiral was machined along the length of the cylindrical specimen to simulate the presence of a possible weld defect. In this way it is possible to subject all portions of the simulated HAZ to the same stress intensity. For the purpose of the investigation 1/2Cr-1/2Mo-1/4V steel known to be susceptible to RHC was chosen. During testing a constant tensile stress was maintained while the temperature was increased to follow the thermal cycle prescribed for PWHT. It was found that the new steel in all instances failed by RHC along the grain boundaries in the high temperature heat affected zone. In the case of the service exposed steel the creep strength of parent metal was lower than that of new steel as a result of exposure to a steam temperature of 540°C for about 15 years. Consequently, all of the failures during testing occurred in a ductile manner by necking outside the HAZ rather than by RHC. When service exposed steel is welded to new material, it is expected that the creep strain associated with stress relaxation will mostly be concentrated in the parent steel outside the HAZ. Accordingly, it should probably not be necessary to make any extra allowance for reheat cracking during repair of steam pipes manufactured from 1/2Cr-1/2Mo-1/4V steel other than that applicable for welding new steel.

Jan 1, 2004

By V Rajakumar, S Trang

Titanium has the potential to become the third wave of light metals used in high volume applications, following on from aluminium and magnesium. These light metals have functional attributes that can meet many of the goals needed for societyÆs transition to sustainable development. CSIRO has initiated a Light Metals Flagship to focus additional R&D efforts in support of the light metals industry. The vision of the Light Metal Flagship is for Australia to lead the Light Metals Age by reducing the costs and environmental impacts through innovative technologies for these metals. Life cycle principles will be used to identify novel technology pathways for metal production and product manufacture that are more energy efficient, less capital intensive and incorporating eco-efficient material flow chains.Under the auspices of the Light Metal Flagship, a Life Cycle Assessment (LCA) of titanium metal production was carried out with mineral sands mining of ilmenite as the starting point. Upgrading of the ilmenite to synthetic rutile by the Becher process and titanium metal production by the conventional Kroll process were the processing routes considered. Two alternative processes for titanium metal production, the FFC Cambridge process involving direct electrochemical deoxygenation of titanium dioxide, and a plasma process for producing titanium powder from titanium tetrachloride were also examined using LCA methodology and compared to the Kroll process. The environmental impacts included in the LCA were greenhouse gas emissions (Global Warming Potential, GWP) and acid rain gas emissions (Acidification Potential, AP). The Gross Energy Requirement (GER) of each process was also determined.These results for titanium, along with those from previous LCA studies by CSIRO on aluminium, magnesium, steel and stainless steel production, were used to show that despite the relatively large amounts of primary energy required for the production of these light metals, their special properties (eg corrosion resistance, strength and light weight) mean that these metals offer potential GER and GWP reductions compared to other competing materials in a number of applications, when viewed on a life cycle basis. Two applications considered in the paper are the lightweighting of motor vehicles and chemical plant equipment manufacture.

Jan 1, 2004

By K. D. Peaslee

Slag splashing is an important development that has dramatically improved BOF vessel campaign life and reduced operating costs. This paper highlights research from physical modeling work using a 1/8-scale room temperature model BOF and slag characterization studies from several plants in North America and China. In the model studies, gas flow rate during blow and viscosity of the liquid were found to be two of the most important factors to changing the overall rate of liquid splashed onto the vessel sidewalls. When the flow rate was increased or viscosity decreased, the lower regions of the walls were splashed at a much greater rate. It was also shown that by changing the lance height, more liquid was deposited in the upper regions of the vessel at the expense of lower regions. Reducing the number of nozzles was found to be the most effective method of selectively coating a particular vertical section of the wall. Studies of BOF's using slag splashing in North America and China showed a difference in the melting characteristics of the final slag. Generally, slag splashing is successful when the melting point of the slag is 220-270°C below the tap temperature to maintain a balance between fluidity and refractoriness.

Jan 1, 2004

By S. M. Taghavi, M. Halali

This paper investigates the possibility of zinc oxide production from zinc ore concentration residues, and also the effect of temperature, time and depth of bed on waste materials reduction percents. The results obtained show a significant increase of the reduction percent as a function of time and temperature. With increasing in depth of bed, reduction percent will decrease. Maximum zinc oxide percent in products was 93.5%.

Jan 1, 2004

Attractive geology does not guarantee mining investment if a region’s policies are bad, according to mining executives surveyed in the Fraser Institute’s seventh Annual Survey of Mining Companies. Companies responsible for a combined US$642.4 million in international exploration (during 2002) rated the policy attractiveness and mineral attractiveness of mining jurisdictions around the world. Jurisdictions like Chile, Australia, Quebec and Nevada bolster their attractive geology with mining-friendly policies, the report said. These locations do well on the overall investment attractiveness index. On the other hand, jurisdictions like British Columbia and Indonesia, each with excellent geology, are hurt by their policies, which have lowered their score.

Jan 1, 2004

By William James Middleton

The life-cycle assessment (LCA) approach can be an important tool for the quantification and evaluation of environmental impacts associated with metal production systems. At the conceptual phase of a new metals development project, LCA can: ? Aid project decision making by evaluating the environmental consequences of design decisions ? Support project permitting and reinforce site/process environmental impact assessment ? Allow environmental impact comparisons between alternate flow sheets For existing metals production systems, LCA has been used to aid targeted process improvements by monitoring recent historical trends in environmental performance, either through local or external (externalities) process improvements. This paper discusses the life- cycle assessment methodology, and its application as a supportive tool for environmental decision-making in process design and operation, and for site environmental impact assessment and permitting. Selected examples from a recent LCA performed on the Pressure Acid Leach Process for treating nickel Laterite ores are employed to demonstrate the usefulness of the tool.

Jan 1, 2004

By J. Daavittila, P. Jokinen, M. Honkaniemi

In the latter part of the 1980?s Outokumpu Chrome in Tornio, Finland, was in a situation when its twenty-year-old ferrochrome plant was becoming inefficient to sustain economically sound production. The company made extensive studies on the then available processing methods to find out the best possible processing route. As a result the whole plant was practically rebuilt and expanded. When equipment was proven in practical operation an application for FeMn production was developed. Now when Tornio FeCr-plant is considering the expansion the same type of exercise is to be performed with today?s challenges, which will be discussed in the paper. These challenges include increasing costs or decreasing quality of raw materials, increasing energy costs, stricter environmental regulations and demand of better working conditions. The possibilities to respond to these challenges will be discussed in the paper. The future and continuing development with FeCr includes the better utilization of process dusts and a lower consumption of energy. By adapting the latest automation tools to better control of the process even higher efficiencies can be achieved with present technology. New processes are considered for development in the future and some possible technologies will be described.

Jan 1, 2004

By F. C. Robles Hernandez

This paper presents the results of the electromagnetic semi-solid treatment of the 319 aluminum foundry alloy, Various levels of structure modification were achieved controlling the AC current used to create the Electromagnetic Field, thus manipulating the intensity of the field, The level of grain refinement, partial modification of the Al-Si eutectic, as well as cellular dendrites were observed, A quantitative analysis of the structure was performed using Image Analysis (IA) techniques. In addition a novel Thermal Analysis methodology was developed for the on-line determination of the microstructure modification level.

Jan 1, 2004

By X. Zhong

Thermal shock resistant properties of reaction sintered bauxite-based ß -Sialon bonded corundum have been investigated, and the results are compared with those of Al2O3 based counterpart. It is found they all have very good thermal shock resistance. Their residual strength ratios after one thermal shock cycle at ? T=1200°C and A T=1350°C are 61-73% and 53-65% respectively. TSR parameters are calculated based on thermal expansion, modulus of elasticity, and fracture toughness determined. The reasons for improved TSR of these composite materials are discussed.

Jan 1, 2004

Sampling and analysis of mineral deposits need to be executed without fear or favour of financial or personal impacts. Examples are given to illustrate the effects of departures, witting and unwitting, from correct use of appropriate techniques and/or equipment with emphasis on exploration and mining of porphyry copper deposits of the Pacific Rim. Some of the results of errors on the low and high sides of true value in exploration, resource or reserve estimations and in production caused by sampling and/or sample preparation mistakes, faulty practices, equipment and/or analysis are considered.

Jan 1, 2004

A blast is designed to completely break competent rock such that it can be economically extracted, and efficiently handled or processed. Efficient breakage of the rock is critical to the success of an operation, and in many operations blast design is optimised to achieve fragmentation, muckpile profiles, and material that is easily excavated. There are inevitably other issues, such as damage to adjacent rock, that should be taken into account when designing a blast to achieve overall optimisation. Some of the key issues with respect to the integrity of the in situ materials adjacent to a blast are identified and briefly discussed in this paper. The potential for damage and the effects of a blast will be strongly influenced by the rock mass properties. This makes it important that site specific conditions and their response to blasting are known. Practical techniques that allow the disturbance adjacent to a blast to be measured with minimum disturbance to operations are described in the paper. Experience shows that, during the blasting process, there is considerable potential to disturb the in situ rock mass adjacent to the blast. In some circumstances a very important objective must be to minimise disturbance outside of the immediate blast area. Measured and observed disturbances caused by blasting to adjacent rock, for various common types of blasting, are discussed in this paper. Blast induced disturbances to the rock mass have been observed in both the near and far fields. These disturbances have the potential to impact on geotechnical design. The geotechnical significance of blast disturbance on a rock mass that is to remain in situ is explored and suggestions with respect to design are given.

Jan 1, 2004

By R. Grimard, M. Gamache, L. -P. Bigras, P. Cohen

This paper describes a real-time fleet management system for an undergroun mine. Dispatching, routing and scheduling are handled simultaneously, taking into account the mine status, operational constraints and vehicle location information. Each assignment decision takes into account the traffic on the road segments of the mine network, whether road segments are bi-directional or uni-directional, and ensures that each LHD (load-haul-dump) vehicle arrives at loading and dumping points with the correct orientation. Such a system can be used either as a simulation tool for strategic planning or as a real-time managing and optimizing system for operations. In the simulation mode, the system can accurately estimate the impact on productivity of decisions such as the development of waiting areas (bays, sidings), or the addition (elimination) of vehicles to the fleet in operation. When used for real-time dispatching, routing and scheduling of vehicles, the system can optimize production with respect to various assignment criteria such as cycle-time minimization or deviation from a target production plan.

Jan 1, 2004

By R. A. Hodge

Over the past decade, there has been a significant increase in effort put to tracking progress toward sustainability. Many aspects of society are participating in this “movement” including mining. The drivers are diverse and include evolving ideas in business and public administration as well as concerns for human well-being, community robustness, environmental integrity, and overall social and ethical responsibility. The scale in question varies greatly from local to global. For the most part, there has been a pre-occupation with developing discrete measurable signals. This paper argues that the overwhelming focus on the quantitative is ill-advised and that a more effective approach is to bring together the best of both quantitative and qualitative. The mining industry in particular is well-placed to affect this shift and reap the associated benefits.

Jan 1, 2004

By Frank Baczek, R. Q. Honaker, D. P. Patil, B. K. Parekh

Fine refuse slurry impoundment is a requirement for the coal industry to dispose the fines. Impoundment maintenance is an on going problem for the coal industry and its breakage creates environmental as well as financial problems. Deep Cone thickener technology which has been successfully applied in the alumina industry to dewater red mud was evaluated for fine refuse slurry. Preliminary obtained in a pilot-plant test showed that properly flocculated conventional thickener underflow slurry could be thickened to about 52.5 wt % solids and could replace belt filter press. The Deep Cone thickener was also found to dewater clean coal slurry to about 70 wt % solids. Further testing of the unit at other coal preparation plant is in progress.

Jan 1, 2004