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By X. Xe, B. Myhre, N. Zhou, B. Sandberg, Z. Chen

Effects of microsilica and reactive alumina type on flowability, flow decay and working time of Al2O3-SiC-C castables for blast furnace trough were investigated. The results show that at a targeted self flow values of (80 ± 10)%, water demand markedly decreases with increased microsilica addition. The nature of reactive alumina has a strong influence on flowability of the castables. Higher microsilica content contributes to a longer working time. The flow decays gradually until the working time and then drops abruptly. In addition, microsilica have positive effect on both cold strength and hot strength.

Jan 1, 2004

By Steven A. Elmquist

INTRODUCTION R&D activities are needed, at a minimum, for a company's competitive survival followed in importance by the growth and diversification of the company. For most industrial companies, however, R&D is the business area that has been the most difficult relative to confident long-range financial commitments and effective control and relative to its value as a long-term investment. Investors look not only at the current profitability of the company but increasingly at the plans, actions, and quality of the personnel in position to improve the market position and profitability of an organization. "The strongest predictor of investment value is the degree of innovation of the 'company.' I believe this is true of both strategic planning and R&D activities." R&D is the lifeblood of a company's future. If this basic premise-R&D for survival and growth-is believed to be true, why is it necessary to "Sell R&D in your organization? My personal experience, in a number of organizations, is that R&D budget is perceived as a business element area that could be delayed or reduced to improve the bottom line during difficult business conditions. I believe the following quote speaks volumes about this subject-"There is only one thing I know for certain about research, and that is it costs money-lots of it." -Unnamed, Hard- headed Financial Executive. A business must make money and be profitable in order to maintain and create jobs, pay taxes, cover working capital and costs of goods sold, and most importantly, create value for its shareholders. The foremost element of selling R&D, therefore, is to consistently demonstrate the R&D group's contribution to the bottom line.

Jan 1, 2004

By D. X. Tang, G. Wilson, Y. Luo, S. S. Peng

Knowing the location of voids/fractures in roof rock will be greatly helpful for roof support design. The drilling parameters obtained during normal roof bolt installation cycle provide a fast and economic way for determining void location in roof rock. In this research, feed pressure and rotation torque are found to be good indicators for identifying the voids, based on the results of a series of laboratory experiments. A set of computational rules has been developed to locate voids in mine roof using the measured roof drilling parameters and implemented in MRGIS, a software package developed to allow mine engineers to make use of the large amount of roof drilling parameters for predicting roof geology properties automatically. Anew feature, 2D map+3D figure display, is also added to MRGIS.

Jan 1, 2004

By A. McLean, M. Iwase, K. Wakimoto, K. Katogi, Y. Kikuchi

One of the greatest obstacles to the application of physical chemistry principles to the elucidation of slag-metal reactions is a lack of knowledge of activities of the reacting species. To a large extent, oxygen potential of the slag phase governs iron and steelmaking practice. Without oxygen control by means of appropriate sensors, the behaviour of the other elements cannot be managed. In this paper, measurements of the FeO activity with various types of electrochemical FeO sensors will be described together with examples of their applications for improved strategies toward better practice for ladle metallurgy and sulphur and manganese distributions between slag and metal phases during steelmaking. Measurements of FeO activity have also been made in order to improve dephosphorization reactions. This type of work has led to significant reduction in volume of slag generated within the steelmaking vessel, which in turn has important implications for refractory wear, metal yield, alloy recovery and improved productivity. Finally, an on-line sensor is described that permits the oxygen potential to be determined for both the metal phase and the slag phase during steelmaking in the BOF.

Jan 1, 2004

By I B. Miller

Magnesium International Limited (MIL) has broken new ground in their desire to integrate their mineral development activities in the Southern Flinders Ranges of South Australia in to the communities of the region, despite there being no statutory requirement to do so. In their efforts to define a magnesite resource adjacent to the proposed site for a magnesium metal processing facility, MIL opened their exploration program up for public consultation. In conjunction with the Port Pirie Regional Development Board (PPRDB), a community group was formed to review the impact of exploration and mining on the ecologically sensitive Southern Flinders region. This voluntary move towards full community consultation for mineral exploration was a first in South Australia and probably in Australia. The Community Focus Group (CFG) worked closely with MIL, Primary Industries and Resources of South Australia (PIRSA) and the Department for Environment and Heritage (DEH) in the development of an exploration program and Declaration of Environmental Factors (DEF) acceptable to all stakeholders. Collaboratively, the community concerns were discussed and addressed, with the community gaining a very comprehensive understanding of the exploration process and possible future mine development. A balance of social, environmental and economic factors was developed that was accepted by all parties and encapsulated in the final DEF for approval by the regulatory authority. The consultation process was a new experience for all of the stakeholders, each of them effectively exploring new ground in addressing information dissemination, risk management and the social versus economic equation. MIL developed not only a viable and acceptable exploration program but also substantially reinforced its position as a responsible corporate citizen with the Southern Flinders communities.

Jan 1, 2004

By B. Q. Li, Y. Shu, K Lynn

"This paper discusses the effects of magnetic field and internal radiation on the melt flow and solidification morphology during solidification processing of oxide crystals for optoelectronic and remote sensing applications. The numerical solution of the integral differential equation characterizing the internal radiation and the magnetohydrodynamic equations describing the magnetic and transport phenomena is obtained by applying the combined discontinuous and continuous finite element method. The results show that both internal radiation and an externally applied magnetic field can have important effects on the melt flow and solidification behavior during the melt processing of oxide materials.IntroductionOptical single crystals are widely used in optical and electronic devices. These crystals are often grown from high temperature oxide melts under strictly controlled conditions. As in the well-known single crystal growth processes for semiconductor wafers, thermal gradient in the melt is a major contributing fuctor to the oxide melt pool. Unlike the semiconductor single crystal growth processes, however, the oxide melt is semitransparent and internal thermal radiation plays an important role in redistributing the thermal energy in the melt pool. Our recent experience with pilot-scale plant measurements also shows that the oxide melt is electrically conducting, although its electrical conductivity is considered much lower than the liquid metal or semiconductor melt.The fact that the oxide melt is absorbing and emitting in the thermal radiation frequency range makes it difficult to study the thermal energy transport in the melt pool. This is because thermal radiation is governed by a hyperbolic differential equation, which is different from those describing the transport processes in liquids. Also, our understanding of how thermal radiation interacts with other transport mechanisms such as convection and conduction is rather limited at point in time, in particular in high temperature oxide melts for optical single crystal processing."

Jan 1, 2004

By C. Lemire, A. Biscaro

Ferro-alloys are sold according to the size grading specifications of users. Fines are produced during crushing and the amount produced depends on the crushing process and the physical characteristics of the ferro-alloy. The market value of fines has declined. Market demand is very weak and in some extreme cases is nonexistent. An induction furnace melt process has been developed to solve this problem. The process feasibility has been demonstrated on a small scale with charges of approximately 2.5 kg. The piloting was carried out using a 100 kW furnace with a metal liquid capacity of 140 kg. The operating parameters were determined during the pilot process. The procedures were defined and the equipment required for melting fines produced at the client's site was sized. With the production of ingots, the client can now recover the full value of ferro-alloy fines.

Jan 1, 2004

By R. P. H. Willis, A. G. du Plessis, R. B. Wilson

This paper reviews issues to be considered in choosing primary access and transportation options for platinum and other mines. It proposes appropriate criteria and a methodology for deciding on the optimum primary access option for any particular orebody. Also included are generic parameters that can be used to facilitate the process of choosing the optimal access option.

Jan 1, 2004

By Sukumar Bandopadhyay

The Marine Mining Technology Center (MMTC) was authorized by an act of the United States Congress in 1996. The act established several marine minerals research centers in the U.S., including one at the University of Alaska Fairbanks. The Alaska MMTC is funded through the Minerals Management Service of the Department of the Interior and concentrates its research in the Artic seas region. Recent research projects at the MMTC include, among others, a geographic information system (GIS) application to the gold placer deposits offshore Nome, Alaska, a marine gold placer reserve definition model using a neural network, and development of an expert system model for submarine tailings disposal (STD) planning and decision-making. Although geostatistics remains the most prevalent method used today for ore grade estimation, researchers have made numerous improvements over the years for accurately predicting grades of ore using various other estimation techniques. As a result, the neural network has recently emerged as an alternative to geostatistics for grade estimation purposes. A neural network is a non-linear, model-free estimator that is well-suited for noisy and/or sparse data environments. Neural networks perform best with non-linear spatial data, contrary to the stationary assumption of ordinary Kriging techniques. In the marine placer ore reserve definition model, the neural network technique was used to estimate placer gold reserves offshore Nome. This study demonstrated the utility of neural network modeling over other traditional ore reserve estimation methods, especially for high cut-off grades. Some of the relevant issues of neural network modeling were also addressed in the study. In testing, the neural network produced results that were close to those from geostatistical techniques including Kriging, polygon, and inverse distance methods.

Jan 1, 2004

By Maria I. De Rosa

Table 10 and figure 4 show the number of fires and fire injuries occurring at the surface of underground metal/nonmetal and stone mines by state during 1990-2001. Table 10 also shows the injury risk rates, employees' working hours, and lost workdays. A total of 12 fires occurred in 11 states; 5 of the fires caused 5 injuries. The yearly average was one fire and 0.42 injury. Five fires with two injuries occurred at metal mines, five fires with two injuries occurred at nonmetal mines, and two fires with one injury occurred at stone mines. None of the fires involved contractors. The Ewhr value was 58 x 106 hr (Irr = 0.017), and the LWD value was 75. Nevada had the most fires (two fires and no injuries). Ohio, New Mexico, Missouri, South Dakota, and Idaho each had one fire with one injury. Of these states, Missouri had the highest injury risk rate value (In = 0.25). Table 11, partly illustrated in figure 5, shows the number of fires, fire injuries, risk rates, employees' working hours, and lost workdays by time period. The number of fires decreased during most of the six time periods. The number of fire injuries and employees' working hours decreased during all of the periods. The Irr values follow patterns similar to those shown by the injury values. Tables 12-17 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 6 shows the major variables related to fires for 1990-2001. Table 18 shows the number of fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By M. Xian, M. Jahazi, Y. L. Lin

The 2-mm butt joints of ZE41A-T5 sand castings were laser welded at different defocusing distances on two surface conditions (as-cast or machined) using a continuous wave 4 kW Nd:YAG laser system at a power of 2.5 kW and a welding speed of 6.0 m/min. Two welding modes (conduction or keyhole) have been observed. The adjustment of defocusing distance can greatly influence the establishment of conduction or keyhole modes. On the machined surface conditions conduction welding is obtained at a power density of 4.0 x 105 W/cm2. In contrast, keyhole welding is reached at a threshold irradiance of 1.5 x 106 W/cm2. Neither conduction nor stable keyhole modes have been established at a range of power density from 7.7 x 105 to 1.2 x 106 W/cm2 on the machined surface conditions. On the as-cast surface conditions keyhole is obtained at a power density as low as 4.0 x 105 W/cm2 but good surface quality is obtained at a defocusing of +2 mm. The as-cast surfaces require lower power irradiance for the formation of keyholes indicating that they have higher energy absorptivity for Nd:YAG laser beams probably due to coarse surface morphology.

Jan 1, 2004

By J Boland

Polycrystalline diamond compacts (PDC) have been widely used as cutting elements in the drilling tools for the oil, gas, civil and mining industries because of their faster penetration rates and longer bit life. US Department of Energy reports that PDC bits account for more than one-third of the total footage drilled worldwide (US Department of Energy, 2004). However, non-thermally-stable diamond composites (NTSDC) have seldom been applied to geothermal drilling, since premature failures of such PDC cutters have been observed in hard rock formations. Several factors need to be considered to prevent premature failure of cutters and improve cutting performance when using PDC-based bits and other rock cutting tools. The first set of factors consists of the strength, density, stiffness, toughness and thermal resistance of the PDC and the rock. A second set relates to the complex behaviour of the bonding between the PDC cutter and the bit matrix, or the pick and the pick holder, which is vital in maintaining stable, reliable and durable adhesion of the cutters to their hubs. Finally, based on a better understanding of the cutting processes, the formulation of a predictive model would assist in further development of cutter design.

Jan 1, 2004

By M J. Sale

The Epithermal and Mesothermal Gold Prospectivity Modelling Projects recently completed by Crown Minerals provided explorers in New Zealand with a new compilation of historical exploration data combined with new geological information from the GNS QMap 1:250 000 scale mapping project. These data were used to produce predictive mineral potential maps for gold mineralisation in New Zealand. The aim of these projects, which was to stimulate mineral exploration and investment in exploration, has been successful with new companies acquiring new tenements and committing significant exploration expenditure to exploring in New Zealand in the coming years. The projects were undertaken at a national scale and consequently not all exploration data were compiled into the prospectivity models. HPD New Zealand Ltd recognised the value of the prospectivity modeling work and committed exploration funds to continue the modelling process started by the projects. They recognised the need to compile the remaining data and run the models again to allow detailed exploration targeting.

Jan 1, 2004

By Scott Samson, Weidong Wang, Shekhar Bhansali, Vandana Upadhyay

"We present an improved design for the two-arm polysilicon thermal actuator. The classic thermal actuator design produces a localized hot spot at approximately the center of the thin actuator arm. This phenomenon limits the actuator efficiency, lifetime, and reliability. Since the actuator deflection is based on thermal expansion of the material, advantage may be gained by making the temperature profile more uniform along the hot-arm length. In our design, the geometry of the thin arm is modified by forming a nonlinear structure near the approximate location of the original hot spot. Electromechanical simulations of this design show an increase in deflection, due to a flattening of the temperature profile along the hot arm. The solid model generation, finite element analysis and simulations are carried out using PEA software. Experimental devices are in the process of being fabricated by using a polysilicon rnicromachining process.1. IntroductionMost active MEMS devices employ some kind of actuating mechanism to increase functionality. Various actuating mechanisms like magnetic, electrostatic, thermal, magnetostatic and piezoelectric have been investigated and incorporated for actuating microstructures. The primary features required from many on-chip actuating mechanisms are large deflection (>10 µm), low actuation voltage, low power.consumption, reliability, fast response, ease of design and fabrication, and small size. Thermal actuation is an attractive mechanism for rnicromechanical devices requiring high actuation forces, large deflections, good linearity and low actuation voltage. Thermal actuators, also known as ""electrothermal actuators"", ""heatuators"" or ""U-shaped thermal actuators"", have been largely used in MEMS based devices to provide both in-plane and out-of-plane actuation [l] .Thermal actuators are also easily compatible with standard CMOS circuitry due to their low driving voltage. However, high power consumption remains a major drawback of the thermal actuation mechanism."

Jan 1, 2004

By Q. Dong, S. A. Nightingale

An investigation has been carried out to assess the effects of an applied voltage on the dissolution rate of MgO refractory in a steelmaking like slag. In this study corrosion results obtained from dip tests using a dense direct bonded MgO refractory in a CaO-SiO2-Fe2O3-FeO-MgO slag are presented. These results demonstrate that the application of a voltage across a dense MgO refractory-slag interface can change the rate of refractory dissolution. For the slag composition used and the voltage range tested, it was found that a maximum corrosion rate was obtained at a voltage setting of -0.45V. The results of this investigation have been explained in terms of voltage affects on Marangoni (interfacial tension induced) stirring and its effect on the MgO dissolution reaction that is at least partly controlled by mass transfer in the slag.

Jan 1, 2004

By M. X. Yao, C. D. Opris, P. C. Patnaik, R. Liu, X. J. Wu

Two cobalt-based superalloys, Stellite 694 and Stellite 712, were functionally graded with reinforcement of titanium-carbide particle for high-temperature wear/corrosion applications. The designed composite specimens were fabricated using powder metallurgy (P/M) technique, combined with hot isostatic pressing (HIP). Calorimetric effects of the alloy powders were investigated using the differential scanning calorimetry (DSC) technique, which provided the basis of the sintering cycles designed. The phases present in the microstructures of the materials were analyzed using SEM and X-ray diffraction. The wear resistance of the materials was evaluated on a pin-on-disc tribometer. It was demonstrated that adding titanium-carbide particles to the alloys has increased significantly their wear resistance. It was also found that the HIP process had improved the density of the sintered specimens and thus enhanced their wear resistance.

Jan 1, 2004

Jan 1, 2004

By B. Friedrich

In a German governmental funded three-year research project, a closed loop recycling process for Nickel-Metalhydride-Batteries (NiMH) is under development. Today the discarded batteries are used in the steel industry as a cheap nickel source. Cobalt and rare earth (RE) are slagged and lost for reuse. The entire value of the metals in discarded Ni-MH is estimated to be 4?-4.5 ?/kg. Spent NiMH-batteries containing 36?42 per cent Ni, 3?4 per cent Co and 8?10 per cent rare rarth (Ce,La, Pr, Nd). The dismantled and processed NiMH-batteries are melted in a DC electric arc furnace producing a nickel-cobalt alloy and a slag phase highly enriched with RE-oxides. The key to success in this process is to find a suitable slag system, which ensures best separation of NiCo-alloy from the rare earth oxides and high concentration of RE in the slag. Different oxidic and halogenic slag systems are investigated in the melting process. So far a slag system based on 65per cent CaF2 and 35 per cent CaO delivers the best separation of the two phases and metal yields. A slag with a composition of 20?25 per cent La, 13-16 per cent Ce, 1.5?2.5 Pr, 4.5?6.5 per cent Nd is obtained and further treated to misch metal hydro-/electrometallurgically. The first results of the influence of rare earth oxides on the density of CaO-CaF2slag system are shown at 1600°C. Keywords: battery recycling, CaF2, CaO, rare earth oxides, slag characterization, density measurement

Jan 1, 2004

By D. M. Sloan

While surety capacity for the mining industry continues to shrink, States are demanding greater financial certainty for closure/post closure obligations. To combat these demands, larger mining companies are pursuing a Mining Surety Reinsurance Program that requires a significant up front capital contribution. This paper outlines an alter-native program for middle market mining organizations. The program utilizes a “Blended Finite Risk” environmental insurance solution with surety acting as the “front” in states where insurance is not an acceptable form of collateral. Marsh proposes creating separate programs for each State requiring surety. The reason for separate programs stems from each states’ different surety rules. Insurance companies typically require at least $5 million in future value remediation liabilities for finite risk programs. Since most middle market mining companies have obligations that fall below this threshold, the Blended Finite Risk Program contemplates combining several companies closure/post closure liabilities to accomplish the minimum amount required by the insurance company. Why use a Blended Finite Risk Program? One of the primary benefits is the financial assurance that funds will be available for planned remediation. For example, the financial assurance may be required by a government agency. The certainty may help facilitate a merger or acquisition. Additionally, the funds may be part of a CER-CLA PRP settlement. In all cases, the insurer providing coverage would be a secure independent 3rd party. A Blended Finite Risk Program also provides a long-term solution – up to 30 years and in some select cases longer. The benefit to a state or the BLM is the removal of financial uncertainty. An insurance company writing the policy would have an AA or AAA balance sheet. The hardening of surety markets coupled with the tightening of financial assurance requirements in many states have necessitated the posting of 100% collateral. This program substantially reduces these collateral requirements.

Jan 1, 2004

By J. Nell

An overview is given of the matte melting process used for the beneficiation of South African Platinum Group Metal (PGM) ores. Most producers use six-electrode furnaces to melt the concentrate and Pierce Smith converters to oxidize excess iron sulphide from the furnace matte. Concentrates from two reef-types (the so-called Merensky and UG-2 reefs) dominate the feedstock supply. Concentrate from the Merensky reef is low in chromium and do not pose significant melting problems. Concentrates from the UG-2 reef contain much higher levels of chromium, which results in the formation of chromium-rich spinels during melting. This is attributed to the low solubility of chromium in furnace slag under typical operating conditions (an oxygen partial pressure of 10-8-10-9bar at temperatures of 1550°C to 1600°C). During the converting process care is needed to avoid excessively oxidizing conditions, which result in cobalt, nickel and copper losses to the slag. High nickel losses result in the formation ofFe2NiO4(trevorite), which often forms solid solutions with FeCr2O4and Fe3O4. In future, the main challenge in the processing of South African PGM ores will be to cope with ever increasing levels of chromium in the concentrate. A short-term solution to the problem would be to melt the concentrate under slightly reducing conditions to promote the formation of CrO, which is more soluble in the slag than Cr2O3. A longer-term solution to the problem would be to abandon the current matte-smelting process in favour of an alloy-based process, which would offer total flexibility with respect to the amount of chromium that can be tolerated in the feed. Key words: Merensky, UG-2, furnace, slag, matte, converting, spinel, chromium.

Jan 1, 2004