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By L Singheiser, W. Willenborg, M. Mueller, K. Hilpert

The limitation of fossil fuel resources and the necessity of reducing CO2emission require an increase of the efficiency of power plants by using combined cycle power systems. Pressurized Pulverized Coal Combustion (PPCC) is a potential concept to realise these objectives. The direct use of hot flue gas for driving a gas turbine requires a hot gas cleanup to achieve corrosion prevention of the turbine blading. One of the main problems is the alkali release during the coal combustion process. Molten coal ash slag has a high potential for alkali retention which depend son the alkali oxide activity in the slag. Knudsen Effusion Mass Spectrometry (KEMS) was used to determine thermodynamic data of alkali gas species over molten coal ash slags and of alkali oxides in molten coal ash slags. The main interest of the investigations focused on the structural dependence of the thermodynamic properties of the alkalis. It was found that there is a strong correlation between the thermodynamic properties and the ratio of nonbridging oxygen to tetrahedral oxygen (NBO/T). An increase of the polymerization of the slag results in a decrease of the alkali oxide activity in the slag and thus a decrease of the alkali partial pressure over the slag. Keywords: coal ash slag, structure, alkali oxide activity, alkali vapour pressure, PPCC, KEMS.

Jan 1, 2004

By Y Hansen, J Petrie

Life Cycle Assessment (LCA) is increasingly being used as a decision-support tool within mining and minerals processing and metals production. However, a number of initiatives have highlighted the current limitations of LCA to accurately reflect the environmental performance of minerals and metals. These programs include:the Mining, Minerals and Sustainable development project (Stewart, 2001); the United Nations Environment Programmme/Society for Environmental Toxicology and Chemistry (UNEP/SETAC) workshop on LCA and metals (NRCan, 2002); the UNEP SETAC Life Cycle Initiative; and the review of the existing ISO 14 040 set of environmental management standards. Together, these initiatives highlighted concerns relating to the ability of LCA to engage with and support metals recycling, to adequately reflect the impacts associated with products from a multi-product orebody, the ability to adequately reflect the toxicity potential of metals in the natural environment and the fact that resource depletion focuses on mining (and not consumption) as the depleting activity in the life cycle of a metal. Additional impact categories to be included in LCA were also suggested. In this paper we demonstrate how existing initiatives are addressing LCA limitations. Finally we present the state of the art in Life Cycle Impact Assessment (LCIA) for two impact categories:resource depletion; and impacted land footprint for solid wastes.

Jan 1, 2004

By Roberto Folcht

The obligations of the European Directive 96/82/EC on the control of major accident hazards, the so-called Seveso II Directive, became mandatory within the E u ropean Member States February 3, 1999. Explosive products have been included within the Seveso II Directive, in the categories of substances capable of generating a major accident. In addition to taking “all measures necessary to prevent major accidents,” explosive manufacturers are also obliged “to limit their consequences for man and the environment.” However, for explosives in particular, no pro c e d u res, nor specific re f e rence values for damage calculation, are given either in the Directive or in the corresponding Italian Legislation, “Ministry of the Environment decree of 20 Oct. 1998.” This article presents a simplified but scientifically rigorous approach for the first approximation calculation of the effects on the surrounding area following an accidental explosion. As an example of the method of calculation, the damage areas in a hypothetical explosives manufacturing facility, as shown in F i g u re 1, will be anal y z e d . The method proposed in this article can also be used for the analysis of explosions of gas in tanks or pipelines,

Jan 1, 2004

By M Magee, D Way

The Mount Isa Copper Concentrator was commissioned in 1973. In 1991, two autogenous grinding mills were installed replacing two stages of crushing, one stage of rod milling and one stage of primary ball milling. The cyclone overflow P80 of the secondary ball milling circuit was reduced to 120 microns due to the increased operating power in the AG/SAG mill circuits. A study of the mineralogy of the milled products and the plant flotation recovery indicated that the installed secondary grinding energy was more than what was required for adequate liberation of the chalcopyrite and half of it had potential for more effective use elsewhere. Halving the secondary grinding energy meant only one of the two secondary ball mills would be needed. The predicted saving in operating cost of one less ball mill was more than two million dollars per annum. This paper summarises various plant trials that were conducted in the Copper Concentrator to decommission one of the two secondary ball mills.

Jan 1, 2004

By N. R. Andrade-Gonzalez

The present work was performed on four alloys containing Al-6 2 wt pct Si-3 5 wt pet Cu, with magnesium in the range of 0.02-0 40 wt pct, and strontium in the range of 0-165 p p m Tensile bars were cast in a permanent mold (ASTM B108-160) and heat treated at 495°C for 4 hours, followed by quenching in hot water. Two different artificial aging temperatures were applied at 180 °C and 220 °C for times from 0 5 h up to 8 h Tests were conducted with the intent of determining how the mechanical properties of an aluminum-based 319 alloy are affected when aging time and temperatures are varied In general, it is seen that the alloy does not exhibit the common peak-overaged aging condition due to the presence of several coexisting phases, indicating that they form through complex eutectic reactions late in solidification.

Jan 1, 2004

By B. Anameric, S. K. Kawatra

Pig iron nuggets were produced in a laboratory scale furnace at Michigan Technological University. These nuggets are produced from pellets consisting of a mixture of iron oxide, coal, flux, and a binder, which are heated to 1450°C.These pellets then self-reduce to produce a solid, high-density, highly metallized (96.5% Fe) pig iron. During the nugget production process, a separate slag phase forms that cleanly separates from the metal. The physical and chemical properties of the pig iron nuggets are similar to pig iron produced by blast furnaces, which is distinct from Direct Reduced Iron (DRI).

Jan 1, 2004

The Mine Safety and Health Administration (MSHA) defines an independent contractor as "any person, partnership, corporation, subsidiary of a corporation, firm, association or other organization that contracts to perform services or construction at a mine." Contractors that perform specific types of work are required to report the number of employees who perform work at coal mines and at noncoal mines.

Jan 1, 2004

By S. H. Castro

Molybdenite depression by shear degraded polyacrylamide solutions has been investigated. Aqueous solutions of polyacrylamide-type flocculants were subjected to shear degradation under a range of high-speed stirring conditions. Settling tests, carried out with quartz slurries and sheared polyacrylamides, showed reduced flocculant performance with increased degradation. As the sedimentation rate is strongly dependent on the polymer's molecular weight, these results fit well with the shear degradation theory, which predicts the production of shorter chain segments due to breakage of the polymer macromolecules. Microflotation tests on natural molybdenite showed that the depressing ability of a commercial polyacrylamide flocculant remained unaltered after shear degradation, even when the flocculating ability was entirely lost. Practical implications of shear degradation on molybdenite flotation are discussed.

Jan 1, 2004

By Frank Mucciardi, Zhongsen Yuan

A new heat transfer technology --- termed Thermopump technology has been developed. This technology originates from conventional heat pipe configurations but has now evolved into its own class of heat transfer units, which we refer to as `Thermopumps (TP)'. A key feature is that Thermopump technology can be applied to high temperature / high heat flux environments where conventional heat pipe technology fails. Moreover, when implemented in less demanding applications where heat pipes appear to operate, Thermopump units have been found to function more smoothly and reliably. This paper will introduce Thermopump technology and several applications of this technology in steelmaking and refining will also be discussed. In addition, this paper will focus on three classes of applications: 1) waterless, non-consumable, high efficiency Thermopump oxygen lance and/or burner for EAF's, 2) Thermopump ladle lance for the desulfurization process, and 3) Thermopump cooling panels for furnace walls and roofs. Facilities equipped with Thermopump technology are expected to he better than the current corresponding ones in terms of increasing productivity and energy efficiency while at the same time lowering operating costs.

Jan 1, 2004

By Mark Svinkin

To save time for construction of coal pits, the contractor decided to combine erection of the tower pitheads with digging of skip shafts to the depth necessary for placing proper coal pit equipment. It was obvious that blasts used in shaft faces and lifting machines installed at a lower part of the pithead could excite vibrations of an upper part of the pithead with curing concrete. The contractor was concerned about vibrations of pithead concrete structures and the disturbance of freshly poured concrete in forms at a top of the pithead as a consequence of structure vibrations. The results of a study of the tower pithead structure vibrations from blasting and operating machinery, and effects of structural vibrations on curing concrete are presented. Structural vibrations were measured at the tower pitheads of two coal pits from twelve blasts. Records of horizontal and vertical displacements were superposition of harmonic low-frequency damped vibrations and sporadic high-frequency damped vibrations with a variable frequency. Low frequency vibrations attenuated during 8-13 s after the last delayed blast. Measured values of the natural frequencies of pithead horizontal vibrations coincided with the calculated frequencies of horizontal bend vibrations. An increase of a face depth from 18 to 50 m diminished 16 times horizontal bending vibration displacements of concrete structures. Measurements of vertical structural vibrations from blasting demonstrated increasing of vertical pithead displacements with the rising of structure elevations. This is evidence of the pithead longitudinal tension. The holes with charges were not properly condensed for one blast. As a result of incompact stemming, the blast substantially increased the energy of airborne pressure waves, which triggered natural vertical vibrations of the pithead with high displacements.

Jan 1, 2004

By H. Saroglou

Anisotropy is a characteristic of intact foliated metamorphic rocks (slates, gneisses, phyllites, schists). Testing was used to establish the anisotropic behaviour of selected gneissic rocks. The effect of anisotropy on various mechanical properties (strength, deformation) and dynamic properties (wave velocity) was examined. The rock samples were also tested at successively higher confining pressures in order to evaluate the effect of anisotropic behaviour at high overburden pressures.

Jan 1, 2004

For too long we, as an industry, have borne the brunt of irrational claims, poor science and even worse, journalism with regards to our affect on the environment. To some of us, the overwhelming media attention on greenhouse warming, the polluting outputs of mineral processing or unthinkable depletion of natural resources has left us embarrassed and more unfortunately has turned bright young people away from a career in the minerals industry.This paper shows the hypocrisy associated with an element of the green movement and dispels some general myths on mining disseminated by radical environmentalists.The fallacy of the greenhouse warming effect will be scrutinised by common sense and the mining industryÆs use of land will be discussed and put in proper perspective.Problems associated with safety and emissions and the means to overcome such are discussed briefly.

Jan 1, 2004

By M. E. Holuszko

Although there is no widely accepted rigorous definition of handleability, the handling coal characteristics often referred to as handleability define whether a coal has the ability to flow unhindered through the processing and transportation systems. The handleability may be severely affected if fine coal particles tend to aggregate. In the pelletization process, the rolling action of the drum is applied to bring the individual particles into proximity with each other so that they can aggregate and form pellets. Because of apparent similarities between these two processes, the pelletization tests are carried out in parallel to the handleability tests in this project, and the pelletization results are used to explain coal handleability properties.

Jan 1, 2004

Geological models for the exploration and evaluation of epithermal Au and porphyry Cu-Au deposits rely upon a classification of different deposit styles and an understanding of the evolutionary processes of deposit formation. These models guide the interpretation of subsurface deposit anatomy in order to target drill testing and assist the explorationist to focus on the more prospective projects. It is important for the explorationist to distinguish between different styles of magmatic arc Au deposits as each style displays distinctive characteristics with exploration implications. Magmatic arc Au deposits are distinguished as porphyry Cu-Au formed at depths of 1 - 2 km at the apophysis to larger, buried, magmatic sources which are also the ultimate metal sources for the varying styles of shallower level epithermal Au deposits. Low sulfidation epithermal Au deposits characteristically develop from dilute circulating meteoric waters and are distinguished as the group with a closer relationship to intrusive source rocks, and slightly higher sulfide contents (still generally

Jan 1, 2004

By T. Weimer

Gasification of carbonaceous energy carriers with simultaneousCO2 removal is a new and interesting alternative e.g. ZECA [1],HyPr-Ring [2], AER [3]. In the ZECA process lime supported Hydrogen generation from Methane is a basic process unit and the Hypr-RING process investigates Hydrogen generation from hard coal with addition of lime. Here the main objective is a further development of the AER process. High energetic efficiencies for gasification in the range of 90 % can be achieved if the humidity of the energy carrier is already sufficient for steam reforming reaction. The aim of the overall process is upgrading coals and biomass yielding into three valuable products: • A fuel gas ready for power generation • A CO2gas stream containing >95%, ready for transportation to disposal or chemical fixation • A pre-calcined feed for cement clinkering consisting ofCaO and coal ash Thus power generation and gasification are independent. A promising industrial application is the combination of gasification and cement production. Then only one additional reactor is required and the precalcination mass flows have to be increased.

Jan 1, 2004

By K. Ding

The thermodynamic activity of MnO was measured in MnO-CaO-MgO-SiO2slags that are typically encountered in the production of manganese containing stainless steels. Gas equilibration-quenching technique was employed in measuring the activities. Activity of Mn in Pt-Mn alloys were redetermined at 1600°C which reconfirmed earlier results of strong negative deviations. MnO activities were then measured by equilibrating slags of various compositions based on a statistical experimental design procedure with Pt-Mn alloys under controlled partial pressure of oxygen in MnO saturated platinum crucibles at 1600°C. Activities of MnO were found to increase with increasing concentration of MnO, basicity and CaO to MgO ratio. Two multi-coefficient repression models were developed to predict the activities and activity coefficients of MnO in slags at 1600°C. Keywords: activity, MnO, slag.

Jan 1, 2004

By M. Pearson, J. Irvine, L. Mercer, P. Lauzon

Severe service ball valve performance has a direct impact on the mechanical availability of high pressure oxidation and leach plants. The primary function of these valves is to isolate the autoclave for maintenance. Valve failure has historically contributed significantly to the maintenance downtime of these process plants. An understanding of the root causes of valve failures is the first step in increasing the reliability of the severe service ball valves. A rigorous failure analysis practice has been developed by Hatch for investigating refractory failures in furnaces and kilns based on Kepner-Tregoe methodology. The method has also been modified for valve failure analysis. From a root-cause failure tree analysis of each of the valve components, a list of all potential valve failure mechanisms was developed for ranking and evaluation, along with recommendations for further valve development. The purpose of this paper is to present the reader with the modified Kepner-Tregoe method and examples of this analysis.

Jan 1, 2004

By D. Zhou, T. Hamano, Tsukihashi. F., W. -G. Seo

The thermodynamic properties for the CaO-CaF2and CaO-BaO systems were calculated by molecular dynamics (MD) simulation using Born-Mayer-Huggins type pair potential. The parameters of interatomic potential were obtained by fitting the thermodynamics properties of CaO, CaF2and BaO with the experimental data. The phase diagrams for the CaO-CaF2 and CaO-BaO systems were calculated by the thermodynamic properties obtained by MD simulation. The eutectic composition and temperature of the CaO-CaF2system calculated by MD simulation were about 28 mole per cent CaO and 1575K, respectively. The calculated eutectic point agrees very well with experimental data, which are about 22 mole per cent CaO and 1633K, respectively. Keywords: molecular dynamics simulation, thermodynamics, phase diagram, calcium oxide, calcium fluoride, barium oxide.

Jan 1, 2004

By A. D. Pelton

The evolution of thermodynamic models of molten salts and slags, starting with Temkin in 1948, has culminated in today?s sublattice models. These modern models have permitted the development of large thermodynamic databases of model parameters, which can be used to calculate and predict accurately the properties of multicomponent solutions. The model parameters are mainly obtained by the critical evaluation and optimization of available thermodynamic and phase equilibrium data for binary and ternary subsystems. The models are then used to estimate the properties of multi component slags and salts from these assessed binary and ternary parameters. When used in conjunction with thermodynamic databases for solids and solid solutions (salts, oxides, sulphides, metals, etc.), other liquid solutions (such as liquid metals),and gases, these databases permit the calculation of complex multiphase equilibria in multicomponent systems, with applications in a wide variety of industries. These calculations can be performed with general commercial software for Gibbs energy minimization, which can also be incorporated into process simulation software packages. Keywords: slags, salts, solution models, thermodynamics, phase diagrams, oxide systems, molten salts

Jan 1, 2004

By Scott Orenstein

Construction blasting has allegedly been the cause of property damage in the following situations: (1) When the detonation of the shot hurls rock and debris into the air that causes property damage upon impact; and (2) When property owners notice cracks in their walls and foundations after they experience the momentary vibrations that coincide with the detonation of the shot. The current state of the law for both these situations is firmly established. Blasting is classified as an abnormally dangerous activity, for which the blaster is held strictly liable, whether the damage is the result of flying debris or vibrations and concussions generated by the blast. It is when the alleged blasting damage is supposedly from concussions and vibrations, however, that the courts usually reach the wrong result. The typical scenario involves property owners that thoroughly investigate their property after feeling blast generated vibrations, and find cracks that they believe did not exist beforehand. Most often the truth is that the property owners have never noticed these cracks before because they have never looked that closely before. Any structure has a certain number of cracks due to a variety of causes, such as settlement overtime and temperature and humidity changes.

Jan 1, 2004