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By L. Maday, V. J. Perrone, M. B. Gilbert

INTRODUCTION The Brightwater conveyance system project in King County, Washington consists of constructing about 21 km (13 mile) of effluent and combined influent and effluent tunnels. The influent tunnels will collect sanitary sewerage from the service area and convey it to the new wastewater treatment plant (WTP) site at Route 9 in Woodinville, Snohomish County, Washington. The effluent tunnels will convey treated effluent from the WTP to an outfall at Puget Sound. The tunnels will be constructed primarily under residential areas, busy suburban roads and state highways. This 21 Km (13-mile) soft ground tunneling project faced many design challenges because of the geologic and hydrostatic conditions, long tunnel reaches, and large overburden depths. Boring depths typically varied from 45.7 M (150 ft) to 114 M(375 ft) with a maximum depth of 185.6 M (566 ft) deep. Conventional empirical methods for non-mountain terrain based on a 1:1 ratio of drilled footage per foot of tunnel bore (National Research Council, 1984) for evenly spaced borings provided a good start for the Phase 1 explorations. However a continuation of this approach with closer spacing was deemed inadequate by the geotechnical team for efficiently allocating geotechnical exploration resources for the final design. This paper presents a rational approach that was used to evaluate the value of a particular geotechnical exploration boring, pump test or other in-situ test. The method of analysis, which was initially developed for rock tunnels (Einstein et al., 1978), was modified for the Brightwater project. The method considers the potential construction cost risks resulting from variable geologic conditions, the cost and reliability of the geotechnical exploration and the earned value (cost risk reduction) of performing the geotechnical exploration. PROJECT DESCRIPTION In total the land portion of the conveyance system will include approximately21 Km (13 miles) of tunnels ranging in size from 3.0 to 5.2 M (10 to 17 ft) minimum inside diameter with overburden depths of 30.0 to 168 M (100 to 550 ft) and

Jan 1, 2005

By Y. Qi

A cell-level nonlinear dynamic model of solid oxide fuel cell (SOFC) based on physical diffusion principles is built in this note. It demonstrates that reactant diffusion processes from gas flow bulks to triple phase boundaries (tpbs) play an important role in the dynamic behaviors of SOFC. The simulation shows that under certain condition, the effect of the double layer capacitance may be neglected. The phenomenon of slow rise of voltage in current interrupt experiment may be explained by the dynamic behaviors of partial pressures in the vicinity immediately above tpbs.

Jan 1, 2005

By A. Lam

The use of a liquid fed direct methanol fuel cell (DMFC) as a power source for micro and small portable applications is attractive due to its system simplicity, low temperature, etc. The aqueous methanol is directly oxidized and does not require additional fuel processing steps as in reformate based PEM fuel cells. In addition, the use of a liquid fuel is advantageous with respect to humidification, stack cooling and system energy density. The DMFC however, has technological issues that must be addressed before it can be widely adopted, particularly in larger applications such as small utility and transportation. At present, the crossover of methanol from the anode to the cathode is a major limitation on DMFC performance and fuel utilization efficiency. In this paper we discuss the influence of fuel modification on the control of crossover. This involves the use of different fuel additives and concentrations to minimize crossover. This appears to be the first reported case of the use of fuel modification (additives) to reduce methanol crossover. The rate of methanol permeation under passive conditions is discussed with respect to the different conditions.

Jan 1, 2005

By G. Barrasso, E. Nordheim

"The European aluminium industry, through its member organisation the European Aluminium Association (EAA), initiated a program on sustainable development for the aluminium industry in 2001. The first step involved the development of a set of sustainable development (SD) indicators for the industry, taking into account of the different interests involved and also the different existing conventions. The indicator set was developed during 2001 and 2002 with the assistance of recognised partners, including Wuppertal Institute from Germany and Versailles University from France. As well, both internal and external stakeholder groups were involved in order to validate the indicators. This has resulted in a set of thirty-four indicators used in the first survey exercise. In the survey the EAA, together with the national aluminium associations, attempted to cover all European plants producing alumina, primary aluminium, rolling ingots, extrusion ingots, foil and recycled aluminium -covering approximately 800 plants. The survey used two points in time, 1997 and 2002, in order to start developing a trend for the individual indicators and to measure progress over time. The industry response to the survey was very positive, with a total industry coverage based on tonnage reported of over 80% for 2002 data and 70% for 1997 data. The results also show a solid progress for most indicators and particularly for social indicators such as training performance, community involvement and employees health programmes. The EAA is committed to conducting this as a regular exercise and is engaged in a number of stakeholder workshops in order to present the survey results, to review the indicators used and to also consider adjustments of these based on feedback from stakeholders and experiences from the first data collection."

Jan 1, 2005

By I Warren, M P. Simpson

Adularia-sericite epithermal ore deposits have well-documented alteration mineral zonation patterns with distinctive geochemical signatures. Proper use of whole-rock geochemistry can provide useful vectors for exploration and can enhance efforts to characterise and quantify the mineralogy and intensity of hydrothermal alteration.   Analyses of Au and Ag provide the most direct vectors to orebodies, and pathfinder elements such as As, Sb, Hg, Zn, Pb and Se are similarly zoned around at least some orebodies. However, the minerals that contain these elements occur almost exclusively in veins, and therefore identifying geochemical vectors related to wallrock alteration that is zoned outward from orebodies is crucial for effective exploration.   Distal alteration zones contain quartz-illite-chlorite-carbonate-pyrite, whereas samples proximal to veins contain quartz-adularia-pyrite, with lesser though variable illite-chlorite-carbonate. Therefore, adularia-sericite epithermal ore deposits show K alteration in their cores. The resulting K-metasomatism can be evaluated in several ways. Areas that have been most intensely altered are commonly characterised by highest K contents, but these results can be complicated by variations in rock type across the prospective area. Potassium mass balance results provide a robust and rigorous assessment of K-metasomatism, however, knowledge about the composition of fresh rocks and correct identification of fresh precursor compositions of altered rocks are required. Three alteration indices provide effective evaluation of K-metasomatism: 1.   the K number, which is the ratio K/(2Ca+K+Na) (molar); 2.   Barrie values [(K2O * 100) / Sr]; and 3.   the Rb/Sr ratio. In most places these provide similar vectors, although K numbers can be complicated by the appearance of hydrothermal calcite and/or albite.   Plots of K/Al vs (2 Ca + K + Na)/Al (molar) allow estimation of the intensity of K-metasomatism and its mineralogical products, thereby complementing traditional XRD and petrographic studies of alteration minerals.

Jan 1, 2005

By E. Sarris

Tailings dams are large-scale earth-fill embankments that are designed to contain mining wastes from ore dressing plants. Most commonly tailings dams are constructed in stages in order to keep up with the increasing volume of mine tailings. Staged construction using various methods (like up-stream, down-stream, and centerline) is generally considered as a very effective way to construct this kind of embankments. The present study is devoted to the investigation of the behavior and the stability of these geostructures under static conditions. In order to accomplish this task, elaborate two-dimensional numerical models are examined, utilizing the geotechnical finite-element code PLAXIS. Numerical analyses are conducted for all three types of tailings dams in order to obtain the potential modes of failure, while the corresponding factors of safety are determined by the shear strength reduction technique.

Jan 1, 2005

By C. Stoneback

The attapulgite industry saw a year of solid growth after a weaker 2003. Demand was up between 5 percent and 6 percent driven by almost all of the key markets. Construction continued to show record new housing demand, assisted by continued low interest rates. That drove strong growth in construction related markets like coatings, tape joint compounds and other construction materials applications. The agricultural markets rebounded modestly to increase sales for suspension fertilizers, animal feeds and pesticide carriers. Oil drilling also showed strong growth due to high oil and gas prices. Sales to molecular sieve applications grew due to petrochemical and construction demand. The export markets were assisted by further depreciation of the dollar. The only weak area was in nonagricultural granular sorbents, where other sorbent materials continued to dominate.

Jan 1, 2005

Two characteristics of the modern mining industry are that there is a skill shortage and that young professional people rise rapidly into highly responsible supervisory positions. With this responsibility comes the burden of identifying and managing health and safety risks. Without the benefit of a comprehensive health and safety training program, these young professionals may be putting both themselves and those under their supervision at risk. The Moura Mine explosions and the asbestos health disaster should not be just artifacts of history, but highly valued lessons that impress the need for comprehensive health and safety risk management strategies on young professionals. From the perspective of the former secretary of the Committee to implement the findings of the Moura (Disaster) Inquiry and as the former coordinator of the Coal Workers Health Scheme, key issues in occupational health and safety management systems are explored.

Jan 1, 2005

By W. J. Birch, A. Wetherelt

The scaled-distance model for blast vibration analysis is the standard method employed throughout the surface mining and quarrying industries to model Peak Particle Velocity (PPV) data. Although empirical, the method is widely accepted and through the simplicity of its application and ease of graphical verification is set to remain a popular option. The validity of the technique relies principally on the fundamental parametric assumption that blasting data is normally distributed. Throughout the evolution of scaled-distance modelling, this is an issue that has most often been presumed rather than proven (most likely due to the tediousness of the calculations involved). In the few cases when normality has been given some degree of consideration, the result has been the product of a simple visual inspection of frequency distributions: clearly unsatisfactory. However recently the soundness of this assumption has been brought into question, with obvious connotations for blast modelling in general. This paper considers this fundamental issue and seeks to investigate the normality hypothesis within the blasting context through an in-depth statistical analysis of what possibly can be described as an ‘ideal’ blasting dataset. This being a rare case study concerning an opencast coal site in England, where for the entire life of the site every single blast was monitored and recorded through the use of permanent monitoring stations. This has provided a unique ‘total population’ dataset of considerable size from which the assumptions of normality are put to the test.

Jan 1, 2005

By B. A. Peppley

The current most common method of hydrogen production for fuel cell systems, including SOFC systems, is autothermal reforming. Autothermal reformers have a number of advantages including fast start up and load following and ease of control. However, there are a number of problems inherent with the addition of air into a system connected to the anode feed such as dilution of the fuel with nitrogen and the potential for oxygen to reach the anode chamber directly. Pure steam reforming, which does not involve air addition, provides a richer fuel mixture to the SOFC anode and is inherently safer than autothermal reforming. Although in theory pure steam reforming can be shown to provide these advantages, a number of technical problems need to be overcome before such a system can be practical. In particular, issues such as catalyst degradation due to poisoning and thermal sintering, coking, as well as fuel-steam mixing need to be addressed. Experimental results from a prototype reformer will be presented to illustrate a number of these points. This paper will compare differences in system efficiency, safety and complexity between autothermal/SOFC systems versus a steam reformer/SOFC system. A system simulation will be utilized that is able to account for material and energy balances for a SOFC power generator operating on diesel fuel. The requirements for improved catalysts will be discussed and an analysis of the potential benefits of sulfur tolerance and lower temperature activity will be considered.

Jan 1, 2005

By E. Asselin

Electrochemical polarization experiments were conducted on alloy 625 in ammonia solution between 25 and 225°C and the results were compared with those of an oxygen solubility model. Results confirm that corrosion is under oxygen control, Normalized corrosion rates are determined based on the rate of oxygen diffusion to the corroding surface, and the corrosion rate at 200°C (-9.7 µA.cm-2) is roughly 24 times higher than the corrosion rate at 25°C (0.4 nA,cm-2), An oxygen-solubility model for Supercritical Water Oxidation (SCWO) conditions was generated using the Redlich¬Kwong-Soave (RKS) equation of state, Results of the model confirm many of the experimental observations from SCWO reactors which suggest that corrosion is at a maximum at temperatures just short of the critical point, The RKS/oxygen diffusion model predicts that the corrosion rate at 365° C is ?85 times higher than the corrosion rate at 25' C. Given that a normalized corrosion rate is obtained, this type of model could be useful for selection of SCWO reactor materials.

Jan 1, 2005

By S. Solar, G. Tiess, K. Nielsen, H. Wagner

The paper summarises the results of a recent study of minerals planning policies of the Member States of the EU. The study has shown that contrary to the public opinion the production of industrial minerals and construction minerals is significant the former accounting for about 20 percent of global production, the latter amounting to about 3 billion tonnes per annum. In contrast the importance of metal ores has diminished although metal production in some European countries can still be significant. The study revealed that very few Member States have clearly defined mineral policies. Common to most mineral policies is the emphasis on reducing minerals consumption and recycling whereas the important aspect protecting access to minerals resources is not adequately addressed by most policies. Access to mineral deposits is regulated in most Member States by land use legislation and administration. Information on mineral deposits in land use planning data bases tends to be scarce. This together with the absence of formal mineral policies places minerals at a disadvantage in land use decision making. The emergence in the recent past of environmental legislation and in particular environmental impact assessments has had a crucial effect on the duration of the authorization process for new mineral projects. Examples are given how minerals planning is handled in some of the Member States.

Jan 1, 2005

By AN. Kumar

Two fabrication stages in the manufacture of pipelines are identified as causing significant deterioration of the steel plates, namely cold bending and welding. The objectives of this work include quantitative assessment of the degradation of the quality of the steel plate by the loss of fracture toughness, and an estimation of the safe working pressure. The study was conducted on three API grade steels: X42, X46 and X60. After cold bending by the UO technique, various welding technique were employed for joining of the bend plates along the pipe length. A crack-tip opening displacement parameter (CTOD) was used at the onset of initiation and at the first load maxima as the criterion for assessing the toughness degradation under various fabrication stages and regime (such as WZ, HAZ and parent body). In addition, strength, hardness and impact energy values were determined to check the degree of degradation. Microstructural and microfractographic investigation of the fractured samples were also carried out in the scanning electron microscope (SEM). X60 grade steel plate suffers from CTOD toughness loss by around 38 and 55% after welding and cold bending, respectively, for the conditions studied. A combined effect of the two stages results in a loss in toughness by around 70% for the same steel. In X42 grade, the loss in impact energy ranges from 78 to 35 J due to electrical-resistance welding study (ERW). Crack resistance curves are also obtained for the steels to study the crack growth resistance behaviour and to supplement the information on crack initiation behaviour. The orientation of the pearlite banding, as observed on the fracture plane with respect to notch front and applied loading direction appears to have a strong influence on the microvoid-coalescence mechanism of fracture as well as the toughness values. An integrated analysis of the performance of pipelines, considering all these key factors, is discussed.

Jan 1, 2005

By Xiang-yang Zhou

Keywords: Low-Grade Dolomite, Low CaO Content, High Specific Surface Area, MgO. A low energy consumption preparation technology of magnesium oxide with low calcium oxide content and high specific surface area from low-grade dolomite has been investigated. The optimum technical conditions for the preparation of magnesium oxide are the followings: dolomite is partially calcined at 750-800° for 2 h; the optimum solid-liquid ratio range in calcined dolomite slurry is 20-30 g?l?1; carbonation temperature, carbon dioxide pressure and end point pH value of carbonation are less than 40°, 0.4-0.6 MPa and 7 respectively during carbonation process; decomposition temperature of Mg(HCO3)2 solution is near 100°; calcination temperature of the precursor (i.e. precipitated basic magnesium carbonate) is less than 850°. More than 90% of magnesium can be extracted by the technology. The MgO product (CaO < 0.38%) with a specific surface area of near 50 m2?g?1 also can be obtained by the technology.

Jan 1, 2005

By R. Krentz, P. D. Cordingley

The nickel-cobalt sulphides produced from limonitic laterite ores by Moa Nickel S.A. in Cuba are refined at the Corefco nickel-cobalt refinery in Canada. Major changes to the refining process were required when the Moa sulphide feed, with its unusually high cobalt content, was introduced in the early 1990&apos;s. In the period 1994 to 2005 the production capacity of the refinery has increased dramatically to match increases at Moa, and significant process improvements incorporated. The process flowsheet consists of the original ammonia leach process, optimized for cobalt chemistry and overall leaching capacity. Extraction of metal values is followed by the unique nickel-cobalt separation technology, in which most of the cobalt is separated from the ammoniacal nickel sulphate leach solution by precipitation as a nickel-cobalt hexammine salt. This salt is refined from a Co:Ni ratio of 1:1 to over 10,000:1 by selectively leaching nickel, redissolution and recrystallization in ammonium sulphate solution. Nickel and cobalt are recovered using the well-known Sherritt hydrogen reduction technology. This paper reviews the chemistry described above, examines some of the changes in operating conditions made over the years and highlights some of the recent physical changes made to the refinery.

Jan 1, 2005

By Janice Reed

The first seismograph was developed around 132 AD. Much has happened since then. The “modern” seismograph (> 1920) has seen a lot of changes. From falling pin seismographs to magnetic tape units to today’s Z-curve analysis models, the blasting seismograph remains a necessary and useful tool to the blasting community. But why so many changes? What forces drive the advancement of the seismograph? There are many answers and aspects to this question. Research, regulation, and technological advances are the primary forces behind innovation in our industry. But these three forces also drive each other. Research drove our industry from displacement seismographs to particle velocity seismographs. Technology took us from 80 pound seismographs to units weighing less than 5 pounds. Regulation (and litigation) - the driving forces behind the Z-curve analysis units. How have these innovations helped today’s blaster? Have there been any negatives? It is important for today’s blaster to understand how we got here and why.

Jan 1, 2005

By Leslie C. Taylor, Anthony L. Kee

Computational modeling of explosively loaded saturated sand on a suspended plate is an inherently complex problem. In this study a computational method is used to predict the dynamic pressure load/impulse from a buried charge. A fully coupled code modeling the explosive charge, sand and air with a Eulerian mesh and the plate structure with Lagrange elements, such as Gemini-Dyna, is an appropriate computational tool. In water-saturated sand, the loadings are soil and water-transmitted shock and bubble or blast effects depending on the depth and the charge size. The computations provide the capability to determine the total impulse load placed on a horizontal plate on or above the soil due to an explosion in the saturated sand for different burial depths in saturated sand and different plate stand off distances. The following test case will be presented: (a) 4.5 Kg (10 lbs) TNT, 10.16 cm (4 in) depth of burial to top of charge, and 20.32 cm (8 inch) stand off distance (Test 4).

Jan 1, 2005

By Bruno Bussière, Michel Aubertin, Anne-Marie Dagenais, Johanne Cyr

A five steps remediation program was commissioned in 1998 for the acid generating Lorraine mine site, located in the Témiscamingue region, Quebec, Canada. It included, as the main expenditure, a cover with capillary barrier effects (CCBE) used to limit oxygen migration. After construction of the cover, instruments were installed on site to monitor the CCBE performance. Modified oxygen consumption tests were also done to measure the oxygen flux through the cover. Results from water content and suction data, measured from 1999 to 2003, show that the capillary barriers effects are effective and that the water retention layer stays near saturation throughout the years. Oxygen fluxes estimated from monthly water content measures are generally below 10 g/m2/year. Results from modified oxygen consumption tests made on the site give almost similar oxygen fluxes. A two dimension numerical model of the Lorraine mine site was also constructed to verify that mathematical models could predict realistically the in situ conditions on such a large scale site. Numerical results obtained for three years show a good concordance between measured and calculated values. The results obtained form these different evaluation methods for the performance of a CCBE concur and confirm the efficiency of this cover in limiting acid mine generation.

Jan 1, 2005

By Augustine O. Orumwense

Ball mills are commonly used for regrinding operations in the mineral processing industry. But, in recent times, efforts are being made at the introduction of stirred mills particularly for those instances where very fine grinding is required. Media type (steel shot, glass beads, alumina balls and crushed quartz), media size, mill speed and the number of passes required to obtained the target product size are studied. The product size and energy consumption are used in the evaluation of the test results. The grinding media size, shape, density, filling ratio, mill circumferential speed and grinding time play a distinct role in product size fineness.

Jan 1, 2005

Strips of AA6111 automotive alloy were cast on a horizontal single belt strip casting simulator, Pure copper and carbon steels substrates plasma sprayed with different coatings for improving the strip surface quality, were used as chill moulds, Experimental studies revealed that a graphite coating provided the greatest benefit in achieving good surface quality. The interfacial heat fluxes during solidification of AA6111 strip were calculated by the IHCP method (Inverse Heat Conduction Problem). Temperature variations and cooling rates within the strips were then calculated through numerical simulations based on the time-dependent heat fluxes obtained by IHCP, The effects of casting parameters, including casting temperature and strip thickness, on interfacial heat fluxes, cooling rates and microstructures, were investigated, Although the maximum interfacial heat fluxes on the chill copper substrate were much higher than the results obtained from the steel substrates, the solidification times of the melts were mainly determined by strip thickness. Very fine equi-axed grains were obtained for both 1.2mm and 2.5mm thick strips thanks to the rapid extraction of heat, and effective grain refinement.

Jan 1, 2005