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By M. Makarenko

The sandstone type Devladivske uranium deposit is located within the limits of Eocene pale-ovalley filled with alluvial sediments. Mineralization with uranium content up to 0.1% forms several ore beds divided by redox barriers. In the period 1962-1983 the deposit has been exploited over an area of 918000m2 by in situ leaching (ISL) using drillholes with a depth between 35 and 100m. During mining operation about 200,000 t of H2SO4, 6,300 t of HNO3, and 15,000 t of NH4NO3, have been pumped in the ore body. In 1983, the groundwater pollution aureole had a length of 4.5 km and a width of 400-600 m. There is a hydraulic connection between the uranium-bearing aquifer and both the upper and lower ones. The technological solutions used for ISL caused partial contamination of these horizons. After mining completion, dilution of the residual technological solutions with "pure" natural waters took place through gaps in impermeable sediments between aquifer horizons. Calculation of self-purification process kinetics shows that the sulfate ion pollution aureole will disappear approximately after 120-150 years at a distance up to 2.0-2.5 km from the western margin of the deposit. This means that there is no risk for contamination of the river Saksagan? that flows at a distance of 17km from the deposit.

Jan 1, 2005

By Michael G. Nelson, Sekhar Bhattacharyya

Between 1974 and 1977, a detailed study of coal pillar strength was conducted by the University of Utah at the Beehive mine in southeastern Utah. This study was funded by the U.S. Bureau of Mines, and included laboratory testing of coal samples, extensive field instrumentation and measurements, and finite element analyses based on the laboratory results. Recently, a similar analysis of the laboratory results and mine design geometry was completed using the LAMODEL program developed by NIOSH. The results of this analysis were close to the data collected in the field. This study allows comparison with the earlier finite-element analysis, and illustrates the utility of the LAMODEL software suite.

Jan 1, 2005

By M. Cambridge

The extractive industries are currently, and will continue to be, major contributors to the world economy, particularly in the developing world where economic growth is dependent upon a sound supply of primary materials. However, tailings dam and other mine failures have been very much a feature of recent anti-mining publicity, particularly in Europe, and thus instrumental in inhibiting new mine developments. Although, superficially, the record of dangerous incidents might support the anti-mining position, closer inspection suggests otherwise. This paper reviews the failures which have occurred over the last 50 years and demonstrates that, though poor practice is an ongoing problem for the industry, the record is one of improvement in both design and practice. Examples are provided of significant events which have led to dramatic advances in design and operation. The paper assesses the improvements made in technology and practice, and concludes that historic events must continue to form the underlying basis for design and operation of future mining projects.

Jan 1, 2005

By M. Kozlowski, I. Candy, S. Kashani-Nejad

The production of ferronickel and matte from nickel laterite ores is dominated by the Rotary Kiln, Electric Furnace (RKEF) process. Over time, major improvements have been made to kiln operation. In particular, kilns are now required to perform substantial amounts of reduction of the metallic oxides, thereby reducing the load on the electric furnace and substituting less expensive fossil fuel for electrical energy. To the basic refractory lined cylinder have been added: internal features such as dams and lifters, aimed at changing residence times in different sections of the kiln and enhancing gas/solids interaction, on-board fans to introduce tertiary air and on-board scoop mechanisms to allow reductant coal additions to be made at advantageous locations along the kiln. Many of these advances in design have been made on a trial and error basis and by 'borrowing' technology from related kiln processes, supplemented by proprietary modeling to various levels of sophistication. This paper presents a conceptual review of modeling components for the development of a computational model for granular material flow, combustion and heat and mass transfer in a nickel laterite kiln. These components include: granular material flow and segregation models for the simulation of bed motion, heat transfer models that simulate heat transfer by turbulent diffusion and radiation and the distribution of this thermal energy within the bed, and fluid flow models for the prediction of combustion aerodynamics.

Jan 1, 2005

By S. Djaroudib

Keywords: iron recovery, hematite, hydrolysis, polyvinylpyridine The precipitation of hematite (Fe2O3) from ferric chloride media at ambient pressure and at temperatures below 100°C was studied as part of a program to recover a marketable iron product form metallurgical processing streams and effluents. Hematite was formed in preference to ferric oxyhydroxides (e.g. ß-FeO?OH) by controlling the precipitation conditions, especially by adding Fe2O3 seeds. The extent of the hydrolysis reaction was found to depend primarily on temperature and on the free-acid concentration. As to the latter, the controlled addition of an adsorbent of free acid, in our case the anionic resin polyvinylpyridine (PVP), was shown to allow for the nearly complete removal of iron as readily filterable Fe2O3. The hematite product typically contains = 63% Fe and = 1.5% Cl, and its composition does not change appreciably upon repeated cycling using regenerated PVP.

Jan 1, 2005

By Dennis Nottingham

"Increased interest in seismic soil liquefaction and preventative soil stabilization sets the stage for improved deep compaction methods using pile driving techniques. In 1971, L.B. Foster Company personnel patented a method of deep compaction using a vibratory pile hammer and pile probe. The technique had some success, but did not produce consistent results and thus found its way to obscurity. Other patents attempted to modify the technique by various probe modifications, but again without measurable improvement from a practical point of view. Solutions to economical deep compaction up to 100-foot depths particularly in saturated granular soils would have a great impact on the construction industry and new bulkhead structures being developed, thus PND was prompted into related research and development. The advent of higher horsepower vibratory hammers, coupled with PND engineers’ experiments, observations and measurements, led to an “H” pile probe design which has produced measured soil density improvements up to 250% using SPT “N60” values as a measure. Case histories of two projects involving extensive SPT soil sampling comparative measurements will be discussed along with findings that led to the compaction success. Applications to numerous modern “Open Cell” bulkhead projects will be presented and discussed.INTRODUCTIONNecessity often is the basis for innovation and such was the case for needed cost-effective deep soil fill compaction in Open Cell bulkheads where granular fill below water levels was often placed.Open Cell bulkheads were developed by PND Incorporated starting in 1980, for the express purpose of meeting client demands for an economical, easily constructed, extremely strong structure. Earth-filled structures historically have had a long history of problems with stability, scour and settlement.Open Cells are flexible steel sheet pile membranes supported by soil contact with embedded tail anchor walls.This concept creates an integral reinforced soil system. The result is a structure that can withstand large settlement and support a variety of very large loads. In effect, viewed from above the structure becomes a series of U-shaped horizontal membranes that require no toe embedment for stability. The Open Cell bulkhead is constructed of only three components: flat sheet piles, fabricated connector wyes and anchor piles. Compared to alternative structures, several cost savings are realized from this land based construction such as, reduced sheet pile area, greater construction tolerance, minimal pile penetration, and simplified backfilling procedures. In seismic regions or weak soils, the tail walls can be extended as required to guarantee fill mass stability."

Jan 1, 2005

By Leslie Taylor, R. Reed Skagga, William Gault

The ultimate aim of our overall task, of which the effort described in this paper is a part, is to be able to model the impulsive output of buried charges and the response of targets of interest. It is not practical or cost-effective to determine the response of all targets of interest to buried charges of all sizes by testing them. In order to have confidence in our models, however, they must be validated by a modest number of tests. A critical element in modeling the response of a target is the ability to model the loading function. The load a buried charge applies to a target above it when the charge detonates can be characterized in terms of the vertical impulse. The vertical impulse is a function of the size of the charge, its depth of burial, and the properties of the soil in which it is buried. The primary objective of the effort described in this paper is to determine the load a known charge places on a non-responding target so the data can be used to validate our models.

Jan 1, 2005

By Raphael Banda

1 Initiating Systems ? a definition An initiation system is a combination of explosive devices and component accessories specifically designed to convey a signal and initiate an explosive charge from a safe distance. In the use of explosives, the initiating system performs the functions of transmission and control of the firing signal to each explosive charge. As functional groups, initiating systems may be considered as: Starters Those which provide the initial signal to start the blasting process. Surface systems Products which provide transmission of the starter signal and delay timing (if any) across the surface of the blast outside the blast hole. In-hole systems Products which provide the signal transmission, delay timing (if any) and the initial explosives energy in the blast hole.1 2 Different types of Initiating Systems The initiation systems commonly used in Sub Saharan Africa are: ? Detonating cord and detonating relay systems ? Capped fuse and igniter cord systems ? Shock tube non electric systems ? Electric systems ? Electronic detonators 3 Overview of Electronic Delay Detonator Technology Conventional detonators use pyrotechnic delay elements and the variation of the actual delay periods is at best approximately 1% the nominal delay. The lack of guaranteed precision common to all pyrotechnic systems enhances the likelihood of negative environmental blasting effects.3 For example, take a 500 ms in hole delay. In conventional detonators this means that 95 % of shots fire within 10 ms of the mean. i.e. a window of 20 ms. Taking a fixed interval between shots of 25 ms, with a range of ± 3 ms, a very ragged firing pattern could be expected which in practice would result in non uniform fragmentation.

Jan 1, 2005

By Donald Thompson, Jessie Bonner, Ileana Tibuleac

Predicting ground motion from complicated mining explosions is important for mines developing blasting programs in regions where vibrations must be kept below certain levels. Additionally, predicting ground motion from explosions in complex 3D media is important for source size estimation for nuclear treaty monitoring. Both problems have been addressed under the development of a new series of programs including: 1) Generalized Fourier Methods to generate synthetic seismograms (Green’s functions) in 3D media for a moment tensor source implementation and 2) MineSeis3D, a program that simulates seismograms for delay-fired mining explosions with a linear relationship between signals from small size individual shots. To test the programs, three-component seismic recordings of three production shots at an iron mine in northern Minnesota were compared to synthetic waveforms in 3D media. Comparison of the observed and synthetic waveforms shows promising results. The shape and arrival times of the normalized synthetic and observed waveforms are similar for most of the stations. The synthetic and observed waveform amplitude fit is best for the vertical components in the mean 3D model but not as promising for the transversal components. The observed effect of spall on the waveform spectra was weak in the case of fragmentation delay-fired mining explosions. Commercial applications of the code could provide data needed for designing explosions that do not exceed ground vibration requirements posed by the United States Department of Interior, Office of Surface Mining.

Jan 1, 2005

By E Yll÷, O HyvSrinen

Outokumpu has developed a new chloride leach process, called HydroCopper«, to treat copper concentrates. Chalcopyrite is quite refractory in leaching and in sulfate milieu an autoclave of high temperature and pressure is required. However, in the HydroCopper«-process copper sulfides can effectively be leached in atmospheric pressure using strong, aggressive chloride solution and copper (II) ions as oxidant. Copper is precipitated from the purified pregnant leach solution as copper (I) oxide, which is filtered and reduced by hydrogen gas to metallic copper powder, which is melted and cast into copper product. Sodium chloride formed in precipitation is decomposed in a chlor-alkali electrolyser, the products of which are circulated back to the process: sodium hydroxide to copper (I) oxide precipitation, chlorine gas to leaching and hydrogen gas to the reduction of copper (I) oxide. During 2003 - 2004 the performance of the HydroCopper«-process was confirmed in a demonstration plant processing one tonne of copper per day. It has been found to be applicable for different kinds of concentrates and can also tolerate a wide range of impurities. A significant advantage of the process is that gold can be leached as a chloro-complex and recovered with active carbon. HydroCopper« can economically recover copper from concentrates and process to a cast copper product. The best utilisation of the process is in most cases achieved when the plant is situated at the mine site. Higher recoveries are attained by the optimisation of the whole operation chain from the mine and the concentrator to the HydroCopper« plant.

Jan 1, 2005

By B Oostendorp, R van der Merwe, P

In order to assess whether polysaccharide depressants are strongly or weakly and reversibly bound to the surface of talc, a series of experiments was conducted on New York talc in which the floatability of the talc in a microflotation cell was determined. The talc was conditioned in solutions of carboxymethyl cellulose (CMC) or guar gum in 10-2 ionic strength Ca(NO3)2 or Mg(NO3)2. The talc was then washed with four successive aliquots of water, or cation solution, to try to remove the polymer and the flotation response of the talc was assessed. CMCs of different charge (DS) were used to assess the effect of charge on the strength of bonding. The results show that CMC and guar gum could be removed to a large extent from the talc surface by washing with water (the floatability was restored), however very little could be removed from the surface by washing with cation solution. The higher charge CMC was easier to remove from the talc planes in the absence of cations than the lower charge CMC. Thus CMC bonding to talc has been shown to be irreversible or very slowly reversible only if cations are present, implying that cations are necessary to keep the polymer bound to the surface of the planes to effect depression. The presence of ions in solution also had the effect of maintaining surface coverage of the talc by guar gum.

Jan 1, 2005

By M. J. Nicol

The leaching of gold with thiosulfate solutions in the absence of ammonia and copper ions was investigated using electrochemical and kinetic methods. In sodium thiosulfate solutions, the electrochemical oxidation of gold was hindered and the leaching rate using pure oxygen as the oxidant was very slow. It was found that the addition of a small amount of thiourea or formamidine disulfide to the thiosulfate solution greatly enhanced the oxidation of gold. However, the enhancement to the overall dissolution of gold using dissolved oxygen as the oxidant was limited. This was attributed to the fact that the oxygen reduction process was unaffected by the additives and remained slow, which limited further improvement to the overall kinetics. An alternative oxidant, the ferric EDTA complex having a reduction potential of approximately 0.12 V, was found to be promising. The cathodic reduction of ferric EDTA was fast and reversible at neutral pH. While the ferric EDTA complex was effective in oxidizing gold, it did not appear to significantly oxidize thiosulfate. A thiosulfate solution containing thiourea and ferric EDTA has been shown to quickly dissolve gold in the form of a powder as well as from gold ores. In the leaching with the ores high gold recoveries of above 90% was achieved with the best performance obtained in neutral solutions (pH 6-7).

Jan 1, 2005

By V. G. Papangelakis, M. Cheung, M. Dry

The high pressure acid leaching of laterite was modelled and simulated using a combination of two commercially available software packages, namely Aspen Plus 11.1 and the OLI Stream Analyzer. New kinetic parameters for the acid-controlled metal dissolution and precipitation reactions at temperature were first determined from previous experimental data on the leaching of limonite. A grain model with cylindrical pellets was used to model the solid-liquid dissolution reactions. Precipitation reactions were modeled via aqueous equilibrium chemistry. A dedicated thermodynamic database previously developed at the University of Toronto was used in conjunction with the OLI software to model the solution chemistry and calculate the concentration of hydrogen ions in solution at the leaching temperature. Mass balances were handled by Aspen Plus. The simulation gave good predictions of nickel dissolution under industrial and laboratory conditions, for the dissolution of limonite and limonite/saprolite blends. Computational

Jan 1, 2005

By I. Koliabina

In this paper, the results of mathematical modeling of casing pipes decontamination from radio-active new mineral forms directly in boreholes using hydrochloric and hydro-silicic-fluoric acids are presented. Modeling for highly and low radioactive coatings on the walls of casing pipes of Anastasievka oil-and-gas deposit was performed using GEMS software, based on the method of Gibbs energy minimization. Calculations have shown that thorianite and goethite, that are present in low-active crusts, detected in casing pipes uplifted from comparatively low depths, are well dissolved in hydrochloric acid, but radiobarite is almost insoluble. For the same acid concentrations, almost all radiobarite of high-active coatings detected in pipes uplifted from considerable depth is dissolved. To evaluate the possibility of decontamination of pipes from radiobarite of low-active coatings, modeling of crust dissolution under the action of H2SiF6 has been performed. The results have shown that for acid concentrations of more than 13 % almost all Ra and Ba are dissolved while all iron and thorium remains in goethite-thorianite solid solution. For the same acid concentration, almost all radiobarite from high-active coatings is dissolved. Therefore, no reagent allows decontamination of pipes from coatings of both types. It seems that successive or simultaneous use of both reagents (HCl and H2SiF6) in certain ratio is required. To clarify this issue, further experimental and model investigations are necessary. The issue of decontamination of casing pipes from galena that is present in high-active crusts also needs to be clarified.

Jan 1, 2005

By M Miettinen

That microorganisms, both living and dead, and products derived from the organisms, can function as flotation agents and flocculation agents is abundantly clear. They can modify the surfaces of minerals. They can function as flotation collectors and as flotation depressants and activators. In many cases they or their products can function as specific flocculation agents. Problems that must be solved before such microorganisms or products from the organisms can be used in commercial operations include culturing the organisms at a cheap cost and reduction in dosages required for various separations. These tasks are formidable. However, the concept of using such natural materials in place of various chemical reagents that may be toxic is very attractive. An attempt is made to show some of the promise of microorganisms in mineral bioprocessing and to consider the problems that must be overcome before commercial application of the technology is realised.

Jan 1, 2005

By L. Mead

Dimension stone is a natural stone (granite, marble, limestone, sandstone and slate) that can be quarried, cut and shaped to conform to acceptable industry standards for size, consistency and durability. There are numerous outlets for the finished product in exterior and interior architectural and design applications. A continued growth market is with residential usage— particularly in new, upscale construction. This has become a competitive market between domestic producers and lower cost imported products. These imported products have become available at many of the building supply retail outlets and have increased the use of stone in residential construction and renovation. The traditional architectural application of dimension stone is tied to commercial and institutional building construction trends and market. There has been a noticeable increased usage of stone in the Sun Belt. This stone is usually supplied by local fabricating shops. It is used in the exterior and interior of shopping malls. This market generally uses local stone sources. It has increased the demand for sandstone, limestone and quartzite in this region of the country.

Jan 1, 2005

By G. A. Hope, K. Watling, R. Woods, I. Chandra, I. M. Ritchie

This paper presents two aspects of gold leaching research and development. The first section of the paper covers the development of innovative gold leaching processes. The research in this area has concentrated on the development of new thiosulfate leaching systems which use Fe(III) stabilized by ligands as the oxidant in place of copper(II)+ammonia. The second section will cover the development of innovative techniques such as surface enhanced Raman scattering (SERS) to study the leaching of gold in cyanide solutions. It will be shown that the use of in-situ SERS yields information which cannot be obtained using other methodologies.

Jan 1, 2005

By E Kunz

Decreasing the gas content in the worked seam by degassing before the start of winning has proven its worth in some areas of German hard coal mines. On the one hand, it removes the risk of gas/coal outbursts and on the other hand it reduces the gas inflow into the longwall. The underground experiences of the last 30 years have led to a æhit listÆ of coal seams with respect to their suitability to predegassing. Trials in the DMT laboratory and also results gained in the deposit show that the suitability of a seam for predegassing depends on its rank. In seams with volatile matter of 20 - 30 per cent, high efficiency ratings are achieved as a rule, with lower ratings both in seams with lower and with higher content of volatile matter.If the rock pressure is unusually high, the efficiency rating of the predegassing is lower, even in seams which would normally be suitable for this process. Under unfavourable conditions, for example below or above residual pillars, in-seam boreholes cannot be drilled successfully and the method is not practical. But if the worked seam was already stress relieved, the predegassing has an optimal efficiency. Latest investigations show that the distance between the in-seam boreholes can be extended. But in that case, the time necessary to reach the same reduction of the gas content increases considerably.

Jan 1, 2005

By R. Browner, J. Collard, D. Ibana

The extraction of cobalt from synthetic pressure acid leach solutions of nickel laterite ores by the direct solvent extraction route using ESPLIM is reported. It first explored the use of gaseous ammonia as pH modifier and then the variables that affect the dispersion of the aqueous phase in the organic phase such as ionic strength, viscosity of the phases, initial droplet size, etc. were explored so that phase hold-up and thus extraction can be effectively controlled. The results show that the technique allows better control of phase dispersion circumventing one of the main weaknesses of conventional solvent extraction.

Jan 1, 2005

By S. Möllerherm

"Since the adoption of the Rio-Declaration in 1992 the concept of sustainable development is raising more and more awareness in public perception. The World Commission on Economic Development WCED has defined sustainable development as the concept that "meets the needs of the present without compromising the ability of the future generations to meet their own needs". The concept requires the integration of economic, environmental and social considerations into all decision making, fostering intra-generational equity through the alleviation of poverty by concentrating the benefits of development in lesser developed areas; and considering the needs of future generations to ensure that inter-generation equity exists. This paper is devoted to give a review of the current status quo of the discussion. It describes the achievements of the mineral industries on their progress towards sustainable development since the Milos Conference (SDIMI 2003), but also discusses future challenges and obstacles."

Jan 1, 2005