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By N. Djilali

Many of the transport phenomena encountered in proton exchange membrane fuel cells occur intrinsically at the microscale level. Physically representative models that fully account for the salient physico-chemical and transport processes in PEM fuel cells are necessary to achieve truly predictive models that can be used with confidence to: (i) gain a better understanding of in-situ processes and couplings, (ii) explore new concepts, and (iii) support design and optimization. The development of more general, rationally based macroscale models requires use of knowledge on the microscale level to provide guidance, and to determine the required parameters and coefficients (model "constants"). In this paper we present a new membrane transport model, the binary friction membrane model (BFM2), recently developed to account for coupled protonic and water transport in polymer membranes. This general model is based on rational and physical consideration, removes several of the limitations of the empirical models used to date, and is formulated for all purfluoro-sulfonic acid membranes. The use of the BFM2 in a fuel cell model is illustrated highlighting significant performance predictions compared to existing empirical model. The second part of the paper addresses the fundamentals of two-phase transport in hydrophobic gad diffusion media. Computational and experimental visualizations resolving the microscale dynamics of water transport between the fibres of a GDL are presented, revealing transport mechanisms that are, contrary to assumptions used to date, dominated by fingering and channeling.

Jan 1, 2005

By S. Rajendran

Gas Hydrates (Methane Hydrates) are solid, ice-like substances composed of water and natural gas. They occur naturally in areas of the world where methane and water combine at appropriate conditions of temperature and pressure and are found in ocean bottom sediments and in some permafrost areas. Besides temperature and pressure, factors like bathymetry, sediment thickness, sedimentation rates, and total organic carbon content (TOC) also control gas hydrate formation in the ocean basins. The stability of gas hydrates depends on the critical combination of high pressure and low temperature (0 - 17 bars, 0 - 25°C), which in turn is dependent on the mix of gases from which the mineral is formed. As the critical parameters can be altered by deposition, erosion, slumping, formation or melting of ice cover, rise and fall of sea level, and sudden temperature changes induced by tectonic activities, current flow, or volcanisms, the gas hydrates tend to be very unstable. The Indian offshore is promising for the occurrence of gas hydrates in a total of about 80,000 km2 area in the bathymetry range of 700 to 3000 m as reported in earlier surveys. A gas hydrate stability zone thickness map was prepared using bathymetry and sea bottom temperatures along the continental margins of India. This map is expected to provide the depth window while searching for Bottom Simulating Reflectors (BSR). The study indicates that a minimum water depth of 750 m is required for the formation of gas hydrates, above which the chances for gas hydrate occurrence appear minimal despite other favorable conditions like organic-rich sediments, etc. Single-channel seismic analog records (Gupta et al., 1998) indicate that the Western Continental Margin of India (WCMI) offers a greater promise for gas hydrate occurrences, particularly with regard to the number of BSRs traced on the analog records as compared to earlier surveys.

Jan 1, 2005

By J A. Cowburn

The high intensity zone within the Jameson Cell is the downcomer. It is largely external and separated from the flotation tank. This, together with operation of the downcomer under vacuum, rather than at elevated pressure and the absence of moving parts, allows ready access to the high intensity zone for measurement and analysis. Experimentation was conducted allowing measurements of recovery for residence times of between 20 milliseconds and ten seconds within the downcomer of a Jameson Cell. The affect of aeration rate on the recovery of different particle sizes was also studied.

Jan 1, 2005

By Antonio Peralta, Guillermo Dante Ramírez-Rodríguez

Mining is generally considered a large-scale hightech industry. However, it has estimated that about 12 million people, about 30% of the world’s total mining workforce, relied on small-scale mining for their livelihoods. During the years, the large-scale mining industry has developed best practice environmental procedures, which have been applied in diverse settings through the world. In contrast, small-scale mining is better known for its high environmental impact and the lack of safe and healthy working conditions. This paper will discuss the environmental control strategies used by the large-scale mining industry, and its applicability to small-scale mining in developing countries.

Jan 1, 2005

By M. Greyling, C. Panaou, M. Bellino

Commonly the most frequent method of calculating the overall mass balance of a multi mineral platinum-group metal (PGM) concentrator circuit in Southern Africa has been through the use of spreadsheets, typically Microsoft EXCEL®. While there are some advantages in using spreadsheet based mass balances during the conceptual design phase of the project, their use becomes limited in the detailed design phase of the project. This paper discusses the successful application of METSIM® for mass balancing of a PGM concentrator and highlights the benefits gained during the conceptual and design phase of the project.

Jan 1, 2005

By Gift Makusha

Total extraction mining of coal is being undertaken on a small scale by Anglo Coal South Africa. Longwall mining has been done in the group at New Denmark colliery since the 80s and recently the company started experimenting with pillar mining at Goedehoop colliery. Total extraction mining methods result in caving of the overburden strata that is often accompanied by displacement of air causing wind blasts. The windblasts can cause injuries to underground mining personnel, damage to mining equipment, and ventilation disruptions. Some incidents of windblast damage and injuries have been recorded at both New Denmark and Goedehoop Colliery that prompted mine management to experiment with the goaf warning device, an instrument developed by CSIR mining technology to give early warning of impending god. The initial version of the Goafwarn was originally developed to operate as a stand-alone unit, with LED lights mounted on the device that would flash if the unit was triggered'. That set up would be effective in small working areas where the flashing lights are visible to all workers. This requirement is more difficult to satisfy in longwall application of the unit where mining activities are spread over large linear distances of up to 250 m and the flashing lights would not be visible to all workers in the longwall face. It was also found that the single unit had limitations in distinguishing between man made vibrations and cracking in rockmass leading to an unacceptably high incidence of false alarms. The case studies describe the experiments that were carried out to ameliorate the two issues mentioned above through networking more than one unit. This was achieved through the development of radio communication from the warning devices to a central control (Trollex Data Acquisition Unit) from which the alarms are issued once the prescribed triggers are satisfied. The operating system was made up of 4 Goafwarn units installed 30 m apart with 2 in the tailgate and other 2 in the main gate. The alarm state was defined where 3 or more units were triggered simultaneously. The concept was applied successfully in real time during longwall mining, and management procedures have been developed to achieve safety through the system including switching off the shearer, and flicking the lights to warn people.

Jan 1, 2005

By Andrea Gambi, Giancarlo Olivucci, Maurizio Lenzi

"In the paper a criterion for the evaluation of the sharing of the lateral loads in a piled foundation is presented. It relies on the the compatibility condition between the rotation of the rigid pile cap and the rotations of the pile heads, following in that the criterion suggested by the Eurocode 8 - Part 5. This assumption leads to an analytical solutions which allows to deal with the sharing of the lateral loads and moments by means of two main interaction parameters only. A sharing domain is also derived and it shows the role played by the eccentricity of the lateral load on the values of the axial forces and of the bending moments at the head of the piles.INTRODUCTIONIt is well known that the interaction among soil, piles and foundation is one of the most complex subject to deal with in Geotechnical Engineering. Its rigorous study needs to employ suitable finite element software nowadays available and able to take into account the non linear behavior of the soil as a continuum and the inelastic response of the structure. A deep insight to the topic of the sharing of the loads cannot obviously renounce to this approach.On the other hand it is a daily need of the designers to have at their disposal simple tools that allow to make preliminary evaluations of the basic equilibrium conditions. To this purpose many methods of analysis have been developed in the past to face the sharing of the loads in a simplified version. The present contribution follows this way trying however to introduce some improvements that leads to find a solution that satisfies both the equilibrium of the forces and the compatibility of the movements (Lenzi, Gambi, Olivucci, 2002). The proposed model allows to identify the basic parameters which govern the sharing of the lateral load and it allows to perform also parametric analysis and quick checks that may be useful in the design of the piles."

Jan 1, 2005

By S. S. Jenkins Jr.

While the method is seldom used anymore, coyote blasting is an historically interesting way to blast large quantities of rock. It was used extensively in the days before modern fast drills were available and can be very effective in some formations that have a natural breakage pattern. This paper will cover the general principles, some blast design factors and point out several actual blasts including some very large ones.

Jan 1, 2005

By A D. Ferreira, A E. C, A D. Padovezi

The increasing market requirements regarding the quality of products, the enhanced predictability from detailed mine planning, the need for process consolidation and upgrading require continuous investigation on the characteristics of different ore types to be concentrated. This paper addresses the mineralogical and technological characterisation of several itabirite iron ore types and the influence of the composition and mineralogical associations on desliming and flotation. Pellet feed quality and the influence on the major performance indicators, such as weight recovery of slimes, selectivity index, metallurgical recovery, flotation kinetics of iron minerals and gangue is also emphasised. The investigation resulted in a classification of iron ores according to their mineralogical composition, morphology of the crystals, and/or texture and microstructure of mineral particles with respect to desliming and flotation performances.

Jan 1, 2005

By Daniel Journeaux

Introduction Daniel Journeaux is President of Janod Incorporated. Janod is a family owned and operated company that has been working in the field of slope stabilization since 1970. Daniel has worked in the rock stabilization industry for 25 years and has been President of Janod since 1992. Daniel has been an invited speaker for the Federal Highways Administration for the Northwest and Southwest divisions, Queens University in Kingston Ontario, The University of Laval, Vulcan Materials Company, CSX annual meeting for the Northeast Division. Daniel has written several articles and has been published in Pit and Quarry, World Tunneling, and American Shotcrete Association magazines. What is Required to Remediate Highwalls There are several techniques available to stabilize highwalls or temporary rock walls to allow for safe mining practices. The following are some of the techniques that can economically be used.

Jan 1, 2005

During the 20th century, the iron ore mining industries of Canada and the United States passed through several periods of transformation. The beginning of the 21st century has seen yet another period of transformation, with the economic failure of a number of steel companies, the acquisition of their facilities by more viable steelmakers, and the consolidation of control within the North American iron ore industry. Changes in Canadian and United States iron ore production and the market control structure involved are analysed. The consolidation of ownership, formation of foreign joint ventures within North America, planned divestitures of upstream activities by steelmakers, and industry changes made to ensure availability of feedstocks will be reviewed. The traditional isolation of the Canadian and United States iron ore operations and their strong linkage to downstream steel production will be discussed in the context of a changing global economy. Management-labour conflicts that have taken place and agreements made during 2000 through 2004 will be discussed in the context of the economic environment leading up to these agreements. Cooperative agreements between competing Canadian and United States companies to resolve client needs in processing and blending will be examined. A joint industry-government project designed to use new technology to produce direct reduced iron nuggets of 96 - 98 per cent iron content using non-coking coals will also be assessed. Changes in iron ore transportation methods, ownership and infrastructure will be reviewed for both rail and inland waterway transport between Canadian and United States companies. A brief analysis of social and environmental issues relating to sustainable development of the Canadian-United States iron ore industry will be included.

Jan 1, 2005

By A. Krishnan

Keywords: Tantalum extraction, SOM Technology, inert anode, membrane stability The Solid Oxide Oxygen Ion conducting Membrane (SOM) technology offers great potential for environment friendly and energy efficient extraction of high-energy content metals. This work was performed to demonstrate the technical and commercial viability of the technology to produce tantalum metal directly from tantalum oxide and ore concentrates using a solid-oxide, oxygen-ion-conducting membrane (SOM). The process can be used to efficiently produce tantalum metal without expensive pre-processing of raw materials and without harmful by products. The work reported in this paper is: the proof that high purity tantalum metal can be produced, study of the electrochemical behavior of the cell and the method to increase membrane stability.

Jan 1, 2005

? Develop a six year capital budget for future emission controls at Western Springfield Power Plant that would provide long-term operating certainty

Jan 1, 2005

By Rashi Tiwari, George Danko, Jeremy Knowles

A control technique is described for enhancing the efficiency of materials handling and other mining operations. The concept involves human-operator and robotics control interactions to assist in mining operations. Many mining tasks require a human operator to coordinate the motion of several machine links by simultaneously manipulating multiple joysticks or other control devices. The new control architecture allows for automatic coordination of multiple machine joints. The machine movement may follow a computer-optimized, learned coordination pattern, while the operator still retains the master control of the overall trajectory and velocity parameters. Examples are described for a surface mining front shovel.

Jan 1, 2005

By Michael R. King

The application and use of steel fibre reinforced concrete in precast tunnel lining design is a growing trend due to its advantages in performance over plain concrete, and ease of manufacture compared to traditionally reinforced concrete. However, the design process and performance characteristics of the material are poorly served by current codes and standards. This paper provides some basic design guidance for segmental linings, and compares the material properties for the different material options. A typical example is considered to compare the possible results of lining arrangement and thicknesses for a plain, reinforced, and fibre reinforced design solution.

Jan 1, 2005

By J E. (Boet) Coetzee

SAFEX International, as the name suggests, is a global organisation, which has the fundamental objective of improving the safety of operations concerned with the manufacture, storage, transport, and use of commercial and military explosives and pyrotechnic products throughout the world. It is a nonprofit making organisation of manufacturers of explosives from all parts of the world, founded in 1954 with the aim of exchanging experiences within the explosives industry. Every third year SAFEX organises a Congress during which members present papers on selected themes and discuss reports of significant incidents that occurred since the previous Congress. Admission is for SAFEX members only, thereby creating a safe environment for discussing problems “within the family”. The XV Congress will celebrate the Association’s 50th anniversary in Geneva where it was founded. An overview of the Congress indicates its structure and covers aspects such as the training event, technical seminars and the themes for the plenary sessions and associated workshops. The paper also highlights the special event for the chief executives of member companies and the review of incidents that occurred in the industry since the last Congress. The Congress concludes with a social programme for delegates and their partners on the last day.

Jan 1, 2005

By H. J. Le Roux, W. B. Drummond

1. INTRODUCTION We have a moral responsibility towards the world to reduce the harmful deposits we emit into the environment arising from beneficiation technologies. Industry has not willingly spent money to limit these emissions because it affected their profit margin with the end result of emitting harmful elements into the environment. Governments have thus rightly stepped in and enforced systematic reduction of these emissions through legislation. In the past beneficiation of sulphur bearing ores was typically done through hydro-metallurgical concentration, smelting, followed by Sulphur removal by converting processes like the Pierce Smith converter. The latter two processes emitted substantial quantities of Sulphur into the atmosphere. Spiralling costs and legislation have resulted in the quest to develop more efficient and environmentally friendly processes to achieve the same end results. New hydro-metallurgical processes like the ActiVox process has completely eliminated the pyro-metallurgical processes. Kansanshi are also operating a similar process. It however elicits other ground water and spillage pollution hazards and problems of it?s own. Various improvements has also been made to the pyro-metallurgical stages, examples being combined smelting and converting with the Noranda reactor, the Codelco CMT furnace, one step flash smelting/converting or the Mitsubishi continuous smelting, converting and slag cleaning process. The new converting processes are also normally enhanced using oxygen leading to higher SO2 gas strength with only a marginal increase in off-gas volume. These processes have led to better efficiencies and a more controlled environment that reduces pollution, but does not eliminate it completely. The fact that there are still more than 70 existing Pierce Smith converter plants throughout the world that needs to be replaced or upgraded at tremendous capital cost, means that we will have the environmental problems for some time to come. The need thus exists to cost effectively get these existing plants into a state where they meet the new environmental regulations, community and safety requirements. This paper will concentrate on just one aspect of this quest, i.e. reduction/removal of off-gasses emanating from the converting of non ferrous sulphur mattes to achieve higher or specialised grades of refined metals.

Jan 1, 2005

By H. Lachmund, R. Bruckhaus

At Dillinger Hüttenwerke/Germany steel production of grades for linepipe applications especially for sour service has a long tradition. The BOF process after replacement of the vessels is optimized by a newly developed lime addition model and variations in lance tip geometry. Equipped with three state-of-the-art VOD tank degassers metallurgical requirements of lowest contents of e. g. sulphur, nitrogen and hydrogen can be achieved. Three continuous casting machines of vertical bending type with solid core even improve already high levels of cleanliness. The vertical part corresponds to the metallurgical length of 12 to 15 m and therefore assures a maximum of cleanliness after solidification before bending. Slab thickness up to 400 mm can be produced with model controlled dynamic soft reduction. The accurate alignments of the casters assure minimized segregation and microporosity. Surface and internal cracks can be avoided by special cooling, bending and straightening strategies.

Jan 1, 2005

There are many ways to classify structural slurry wall elements, but the DFI committee chooses to limit these descriptions to three functional requirements, namely: design function, plan configuration and type of panel reinforcement. (See Figure 1 in Part IV for panel classification). Slurry walls can function as: 1. Curvilinear or linear elements for temporary and/or permanent structures to resist lateral forces transferred from the ground, water, earthquakes and various surcharge loads. 2. Load bearing elements in various plan shapes to resist vertical forces. 3. Combination Elements to resist combined forces under conditions 1 and/or 2. For example, elliptical shafts with various openings for tunnels and conduits have been commonly used for deep excavations.

Jan 1, 2005

By I Ross

The ground handling system needed for the second lift of the underground block caving operation at Northparkes Mines had to link into the existing infrastructure. Production requirements indicated that an annual output of 5 Mtpa was necessary from a depth of approximately 850 m. The shaft that serviced the first lift stopped at a depth of 520 m. This paper covers the selection of the design for the system and the factors that were taken into consideration in making the decision. It will describe the installation program and methodology and highlight areas of significance and then detail some of the issues concerning commissioning of the ground handling system.

Jan 1, 2005