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By R. Frim, S. D. Ukeles

The present U.S. production of bromine is from inland brines located in Arkansas and Michigan. The most concentrated domestic brines (up to 5,000 ppm bromide)are situated in Arkansas. Less concentrated brines(about 2,500 ppm bromide) are located in Michigan. The amount of bromine sold or used in the United States came from three companies operating in those two states. Its value was $191 million. In 2004, the estimated U.S. bromine production was 222 kt (244,000 st). That compared with 216 kt (238,000st) produced in 2003.

Jan 1, 2005

By WU Jian-hui

Keywords: metallic material; nickel powder; thermal decomposition; precursor; fibrillar powder; nanometer scale; passivation treatment The precursor thermal decomposition process of fibrillar nanometer scale nickel powder and passivation treatment of obtained powder are investigated, and the composition and morphology of the products are characterized by use of IR, TGA/DTA, XRD and SEM. The results show that the precursor morphology is a decisive factor to the product morphology of the nickel powder. The morphology of the product derived at low decomposing temperature is irregular. The nickel powders produced at the temperature higher than 480 coheres seriously. The product particles are reunited with the decomposition time prolong. The powder prepared under the optimal condition is fibrillar like woolen yarn; the grain diameter is less than 50nm.

Jan 1, 2005

By S K. Ray

Open fire in a mine gallery causes large-scale damage to property and sometimes precious lives. Such fires produce two distinct effects, the throttle effect and the buoyancy effect. These effects disturb the ventilation system of the mine. To understand the complex dynamic phenomenon of open fire and its effect on ventilation systems, a mine fire model gallery has been designed and constructed at Central Mining Research Institute, Dhanbad. Two sets of experiments at air velocities of 1 and 1.5 m/s were conducted in the gallery using coal samples from the Dobrana seam of the Raniganj coalfields. After about an hour of development of fully-fledged fire, heavy backlash, with smoke and fumes, was observed. At the time of backlash occurring the gallery was divided into two zones. In the region of the gallery from the base up to 1.4 m the airflow was normal, in the remaining upper portion the airflow was the reverse. Air quantity reduced substantially, while pressure dropped across the fire zone, the products of combustion (POC) and temperature increased during the period of the throttle effect. It has been revealed from these studies that with an increase in airflow, pressure drops across the fire zone, POC, temperature and reduction in airflow increases. This paper addresses the important design features of the gallery, the instrumentation system, the experimental procedure and assesses the effect of open fires on mine ventilation systems.

Jan 1, 2005

Aspiring to be excellent makes you a good leader as it shows a capability for strategic thought, defining and implementing a vision, making a job easier, more efficient and effective. Every great business leader can generate additional revenue or cost savings for their company. Becoming excellent requires the desire and action to follow it through. There are many established methods of excellence: benchmarking, target setting, supply chain and market analysis, employee suggestions and knowledge sharing forums. In BHP Billiton, practices benchmarking is a key tool in generating improvements for functional areas such as processing, mine operations and mine planning. Practices Benchmarking involves organisational and technical questions that allow the site to self-assess their maturity and generate a prioritised improvement path. Not only does it benchmark and identify gaps, but the approach also facilitates networking, education and team building. For new leaders it is important to remember that you are not alone. Chances are your problem has been solved before. Networks û internal, external, formal and informal can get you started and often save you time and effort. Any leader can achieve success in excellence through a proper process of problem formulation, data and analysis. Again, using key players can make the process more effective. It is important to remember that the people side of the solution is the key to success and that monitoring will ensure the solution will work. In the words of BHP BillitionÆs CEO, Chip Goodyear: Excellence is a mind set. ItÆs something that comes when people get rewarded forthinking outside the box and applying their skill and knowledge. It happens, not in$50 million chunks, but in hundred thousand and million and $2 million chunks.When you get 35 000 people thinking that way, then youÆve really got somethinggoing.

Jan 1, 2005

By Micheal Mitariten

The recovery of natural gas (primarily methane) from coalbed deposits is an established and growing source for the U.S and accounts for over 7% of its total production. The gas from on-purpose degassing is often pipeline quality and requires only compression and dehydration before being admitted to the pipeline grid. However, the raw gas is sometimes contaminated with nitrogen (N2) and/or carbon dioxide (CO2) that can make the gas inadmissible to the transportation pipeline. In general, the N2 must be 4% or less and the CO2 should be 2% or less. In treating gas produced from virgin coal bed or from degassing operations where CO2 is present, amine systems are traditionally used for its removal. Engelhard’s Molecular Gate® adsorption system offers an attractive alternative due to its skid-mounted equipment, low pressure and unattended operation, cost and high on-stream reliability. Natural gas can also be sourced from the residual coal, after the coal has been mined. This source can be the GOB or gas remaining in abandoned coal mines. This source is almost universally contaminated, often with a combination of CO2 and N2. If the source is from air intrusion, the source can also be contaminated with O2. In treating CO2 / N2 contaminated feeds, the Molecular Gate adsorption system removes both of the impurities along with a level of O2 within a single processing step. To date, ten Molecular Gate units are underway with three systems having been installed for upgrading gas from abandoned coal mines. The technology consists of specialty adsorbents and advanced PSA processes that are jointly offered as fabricated packaged equipment by Engelhard Corporation and Guild Associates, Inc. Upgrading requirements, project challenges and project arrangements are discussed in this paper.

Jan 1, 2005

By J. M. Shafer

Jan 1, 2005

By A. Moergeli

The Swiss are currently building the world’s longest tunnel, the 35-mile long Gotthard Base Tunnel. At Sedrun, for the first time in tunneling, four Roadway Support Machines will drive through most difficult ground, supporting variable diameters of up to 13 m. The machines are prepared for their first deployment. At Amsteg, two Hard Rock TBMs have successfully crossed a known fault zone by applying full circle steel arches and shotcrete immediately behind the cutter head. Comparisons between Drill& Blast and Hard Rock TBM are shown.

Jan 1, 2005

By P. Schmieder

"The close vicinity of mining companies to other sites that are used for commercial and residential purposes or to areas under conservation as well as the fact that the people become more and more sensitive to emissions have led to a negative attitude towards mining operations in the neighborhood. It is above all the use of drilling and blasting techniques that give rise to objections, in the course of which demands for more environmentally-friendly production methods have been voiced. It is in this context that production methods without the use of explosives are considered as an option. After all, the use of such production methods is the only alternative for some quarry operators. The question is what are the true benefits of these techniques and what is the relation between a possible improvement of the environmental effects on the one hand and the technological potential as well as the costs on the other. It is intended to assess the mining techniques for solid rock in their entirety. This paper will therefore look at the aspects for assessing mining techniques in the context of their environmental impact and the costs."

Jan 1, 2005

By Jacques F. Abrahamse, Kevin A. Bahe, T. Arthur Palm, Gregory E. McCluskey, Stephen L. Bessinger

Introduction Basis For System San Juan Coal Company (SJCC) is a subsidiary of BHP Billiton. Until recently, BHP Billiton operated three surface mines in northwestern New Mexico: Navajo, San Juan, and La Plata. The San Juan and La Plata Mines supplied the San Juan Generating Station operated by Public Service of New Mexico. Stripping ratios at those operations were increasing, and by 2000 a feasibility study was underway to develop SJCC’s vast underground reserves as a replacement. Early in the evaluation and planning phase for the San Juan Underground Mine, it was determined that the target seams (Fruitland #8 and #9) had a high propensity for spontaneous combustion. Spontaneous combustion was identified as a risk, both to personnel and equipment, and to the ability of SJCC to reliably fulfill its obligation to the power plant. In the last 20 years, several western US coal mines suffered underground spontaneous combustion events and/or mine fires. Included in this group were Colorado Westmoreland’s Orchard Valley Mine (1987), RAG’s Willow Creek Mine (1998 and 2000), Oxbow’s Sanborn Creek Mine (1999), the West Elk Mine of Arch Coal (2000), Arch’s Skyline Mine (2002), Western Fuels’ Deserado Mine (1996), and the West Ridge Mine of Andalex Resources (2003). The cause for the majority of these fires was spontaneous combustion. Fighting the fires required injection of an inert gas or foam. Nitrogen and carbon dioxide were the predominant choices of inert gas. In all cases, the gasses had to be trucked in from considerable distances. Before the inert gas could be used, injection holes had to be drilled into or near the suspected fire locations. This drilling and trucking caused costly delays in the timing of the fire fighting effort, and was not as precise as desirable. Emergency purchasing of gas and pumping services was extremely expensive, running as high as $70,000 per day at one mine. As a result of the experience of other western US coal operators, and the risk inherent with spontaneous combustion at SJCC, it was decided to pursue installation of a nitrogen delivery facility on-site at SJCC. This decision was later expanded to include a continuous supply of nitrogen.

Jan 1, 2005

By G. T. Lapidus, J. Trejo-Gallardo

A phenomenological model is presented for leaching silver from silver sulfide contained in mineral particles with ammoniacal thiosulfate solutions of copper in stirred reactors. Experimental results were used to adjust the kinetic parameters of the model, such as the reaction order and velocity. The incorporation of the cuprous sulfide-silver sulfide equilibrium at the reaction interface allowed the prediction of the conversion limits for different reagent concentrations. The information obtained from the reactor model was later integrated into a heap leaching simulation, whose results adequately describe tendencies observed in column tests, with respect to variations in copper and thiosulfate concentrations. Comp

Jan 1, 2005

By J. B. Pateiro Fernandez, S. Möllerherm, E. Drüppel

"Since 1997 the Institute of Mining Engineering 1 at the Aachen University is dealing with the concept of sustainable development in the mineral industries. During this time it has conducted several research projects in this field. Its latest project is on the development of sustainability indicators for the German mineral industry. This paper describes some results of this project. A process chain analyses have been carried out identifying economic, social and environmental effects of the minerals extraction. Thirty indicators reflecting the particular conditions in the mineral industry have been designed. One important challenge was the design of quantifiable indicators taking into account the life cycle of a mining operation as well as mineral beneficiation and enrichment of the raw material."

Jan 1, 2005

By W. H. Van Niekerk

The metal zinc has been around since only about 1400 AD. This may sound like a long time, but when compared to fellow base metals copper and lead, which were discovered in 5000 and 4000 BC respectively, it is evident that zinc is a fairly new kid on the block. This may also be the reason why many new facts and benefits of zinc are still being discovered. For instance, it has been discovered only in the last few decades that virtually no life on earth is possible without zinc. In this address it will be shown that zinc is not only very useful to mankind, but is in fact vitally important for all forms of life. It will be shown that zinc is natural, zinc is essential for life, zinc protects, zinc contributes to the well-being of society and that zinc is fully recyclable. It is therefore hoped, that by the end of this address, zinc will no longer be viewed only as the metal that is responsible for the nice colour of roofing sheets and steel buckets, but may indeed be man?s best friend.

Jan 1, 2005

By D. Fleury

"This paper describes the challenges of mining a sill pillar under various types of paste backfill quality. From 1994 to 2002, Louvicourt mine produced approximately 12,600,000 t grading 3.5% Cu, 1.5% Zn, 27 g/mt Ag, and 0.85 g/mt Au. The mining method is transverse blasthole stoping, mining primary and secondary stopes. The production of this 4,300 t/d operation was accomplished using two mining horizons; from the 655 m level to the 415 m level and from the 860 m level to the 680 m level. The main sill pillar is between the 680 m level and the 655 m level. The second sill pillar is between the 885 m level and the 860 m level representing a quarter of the main sill pillar in size. Since 2002, production has gradually decreased and mining activities are expected to end in mid-2005. The sill pillar production will represent almost 25% of the total mine production. The overall recovery of the sill pillars stopes will be discussed in this paper. To recover the sill pillars, more than 1,500 m of development was planned in or under paste backfill. The first sill pillar stopes under paste backfill were mined out in 2002 with excellent results."

Jan 1, 2005

By C Mroczek, B Mitchell

Perilya Broken Hill, from its inception, has budgeted for more than 2.0 million tonnes per year from the Southern Operations. This tonnage was planned to come from in excess of 100 stopes per year in a remnant mining environment with numerous mined voids and consequent mining challenges. To mine an average of two stopes per week requires patience, flexibility and detailed knowledge to best manage the potential risks and hazards. The evolution of the Perilya Broken Hill Mine Planning Process has necessitated the establishment of a process to identify and manage these risks during the planning stage in a reliable but efficient manner. This process is to ensure that vital steps for each stope are not missed, and that each personÆs work can be tracked by other members of the team. This paper outlines the planning process from resource to stope closure.

Jan 1, 2005

By Reginald N. Boryor, Steven D. Woods

1.0 Introduction ?Low grade, high tonnage, open pit gold mine. ?Gold bearing Tarkwaian conglomerates. ?Reverse Circulation percussion drilling (25m X 25m grid). ?Composite 1m intervals, logged and split in the field to provide±2Kg samples. ?Samples used to build grade control block models using SURPAC. ?Approximately 100,000-130,000 meters drilled per year. ?RC samples are assayed using Rapid Cyanide Leach (RCL). ?Check assays are done using Fire Assay

Jan 1, 2005

By H. R. Oliveira, C. R. Aragonez de Vasconcellos

Pipeline operation and maintenance necessarily involves geotechnical studies at points and areas with deflagrated instabilities or still to map and monitor areas prone to geotechnical problems. Landslides, erosions and debris flows are some examples of natural hazards, that not rarely, can bring high consequences to pipelines, sometimes leading them to high stresses levels and ruptures. Bolivia-Brazil Natural Gas Pipeline has 2.593 kilometers since Rio Grande City in Bolivia until Canoas City, in south Brazil. The pipeline crosses a lot of types of geological fields and difficult topography. The south spread of the pipeline has the most prone areas to geotechnical hazards because of its hard topography combined with the variety of geological materials, such as, colluvium deposits and debris flow areas. The aim of this paper is to present the right-of-way geotechnical risks that affect pipelines, presenting some practical remedial works done by TBG at Bolivia-Brazil Natural Gas Pipeline as well as the integrity plan and the adopted actions in way to prevent geotechnical accidents.

Jan 1, 2005

By Darren Thorton, David Sprott, Ian Brunton

Blasting causes movement of the rock and can be detrimental to the accurate delineation of the ore and waste regions within the resulting muck pile. The consequences can be ore loss and dilution. However, ore loss and dilution can be minimized and significant increases in profit can be realized if the movement can be accurately measured. Various methods have been used to measure muck pile movement including poly-pipe, chain and sandbags but these have been either inaccurate or impractical. The Julius Kruttschnitt Mineral Research Centre, JKMRC, has developed an electronic blast movement monitor that provides accurate three-dimensional movement vectors following a production blast. From this information, the ore block boundaries in the blasted bench can be adjusted to compensate for the measured movement and then ore recovery can be optimised. Following initial development of the prototype technology, the JKMRC further developed and demonstrated the system in actual production blasts at an open pit gold mine operated by Placer Dome Inc.

Jan 1, 2005

By Jae R. Lee

Keywords: Self-propagating high temperature synthesis, AlN, Powder synthesis The particle size and shape effects of starting raw powders on the synthesis of aluminum nitride by self-propagating high temperature technique under high nitrogen pressure were investigated with various AlN diluents and Al reactants. It was found that the structure of beds of the starting raw particles largely affected the pore channels for nitrogen gas infiltration as well as the passages for combustion propagation before and during the reaction, resulting in the morphology and purity changes of the synthesized products. The AlN product of purity over 98% with about 30 microns was obtained.

Jan 1, 2005

By Rudrajit Mitra, Wesley B. Johnson, Erik C. Westman

The ability to understand stress redistribution within a mine allows greater extraction efficiency with reduced safety concerns. Stress redistribution has been examined at the laboratory scale using ultrasonic tomography and numerical modeling using PFC3D. A data acquisition system was built to obtain tomograms as samples are loaded in uniaxial compression. Limestone samples were loaded to failure. Three-dimensional tomograms of the samples correlate to various stress distributions. The tomograms are compared to analytical and PFC3D results.

Jan 1, 2005

By M Stevens, M P. Simpson, J L. Mauk

The Karangahake deposit was the second largest producer of gold-silver bullion in the Hauraki Goldfield, New Zealand. New mapping of a 2 + 3 km (6 km2) area demonstrates that hydrothermal alteration surrounds productive veins. Wallrocks proximal to veins are intensely altered and alteration decreases toward the margin of the system.   At Karangahake, distinct zonation of adularia, calcite, epidote, illite and illite-smectite surrounds gold-bearing lodes with unaltered rocks containing magnetite and plagioclase occurring on the margins. Adularia, illite, illite-smectite, and calcite zonation defines hydrothermal alteration extending 2 km to the east of productive lodes. Epidote and adularia zonation occurs proximal to veins. The adularia zone compares well to potassium/thorium studies conducted in the area. Illite zonation is well developed to the east of the veins grading into interstratified illite-smectite containing 5 to 40 per cent smectite 1.5 km from the Maria Lode. Calcite is restricted to the east of the study area occurring in 18 per cent off surface samples. Less altered rocks containing plagioclase and magnetite occur distal to veins. The magnetite occurrence compares well to aeromagnetic studies conducted in the area.   Adularia and coexisting adularia and albite indicate the host rocks were highly permeable. Epidote, illite, illite-smectite and previous fluid inclusion evidence implies temperatures graded from >240¦C in the core of the system to approximately 150¦C on the periphery. The alteration association of quartz, adularia, calcite, pyrite, chlorite, illite and illite-smectite reflects a near-neutral to weakly alkaline water. Calcite occurrence and the absence of zeolite imply the fluid contained significant dissolved CO2.

Jan 1, 2005