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By J. Hindman, E. Moeller

Vermiculite is currently mined from shallow (less than 25 m or 80 ft) surface deposits throughout the world. The largest producers are Palabora Mining of Phalabowra, South Africa (ore stock is a phlogopitemica), Xinjiang Yuli Xinlong Vermiculite of Korla, China, and W.R. Grace of Enoree, SC (ore stock is a biotite mica). Smaller operations are in Australia, Brazil, Russia and Zimbabwe. They also produce vermiculite on a continuous basis but do not export any significant amounts of product to North America. Intermittent and poorly documented production on a minor scale is reported from Argentina, Egypt, India and Uganda. Worldwide vermiculite production in 2004 increased1.7 percent to 432.8 kt (477,000 st). North American production declined, while African and Chinese production continued to increase.

Jan 1, 2005

By D. M. Mubita

Dilution reduction is one of the areas that offer metal mines an opportunity to increase revenue and reduce costs, resulting in enhanced profits. Effective dilution control programmes require interaction on a multi-disciplinary level. This paper outlines recent initiatives undertaken at Konkola Mine to reduce dilution and increase revenue. The increase in revenue arising from reduced dilution and high factors between in situ and delivered to mill grades were quantified and amount to close to U$ 1.0 million per one per cent improvement in grade factor at a 75c/lb copper price. Sources of dilution from open and in?stope mining methods practised at the mine were identified and a multi-disciplinary dilution control forum set up to control these. Among the major achievements were the introduction of low dilution in-stope mining methods; the introduction of Gemcom geological and mining planning software to replace traditional pencil and paper methods, leading to better in situ estimation and production planning; enhanced control in open stopes through dilution awareness among mining production personnel; location of critical secondary development ends in correct positions; enhanced blast hole control; tracking of development waste by metal tracers and monthly tally; implementation of a cavity monitoring system to check over-breaks in open stopes; and setting up of a stope history database. The results from the cavity monitoring system showed that stopes with over-breaks of 5 metres or less could be controlled to break along the hangingwall contact.

Jan 1, 2005

By John McDonald, Peter C. Raleigh, Christopher Dishlip

This paper will discuss how the construction management team and the contractor working together on the City of Los Angeles, North East Interceptor Sewer project, managed information on a daily basis. Data was synthesized from various sources including: inspection, survey, instrumentation, laboratory and the tunnel boring machine data logger systems to produce state-of-the-art reports and graphics which will become industry standard. Special emphasis is placed on how the data is managed and interpreted in a clear and objective manner, permitting the tunneling processes to be carefully monitored and suggesting appropriate action to be taken by the construction management team and contractor.

Jan 1, 2005

By Frank P. Frandina, Diane R. Hirsch, David P. Field, Colin R. Weeks

To accommodate growth in air service and to follow the Master Plan for long-term airport development, the Metropolitan Washington Airports Authority established thed2 Development Program at Washington Dulles International Airport. A sub-surface Automated People Mover (APM) System is under construction to replace the Mobile Lounges as the primary people mover system at Dulles. To minimize disruption to airport operations the majority of the APM System’s crossings of Taxi lanes will be undertaken using Tunnel Boring Machines (TBM) or the New Austrian Tunneling Method (NATM). This paper explores the planning and design of these shallow tunnel segments for future generation aircraft loads, within the constraints of minimal construction access under post 9/11 security requirements and the context of the overall airport expansion program.

Jan 1, 2005

By Y. Feng

Perovskite structured oxide 15% Y-doped BaCeO3 (BCY15) has been evaluated for use as proton conducting electrolyte in SOFC with propane as the fuel and Pt as both electrodes. Under the fuel cell conditions, BCY15 exhibited high proton conductivity and good cell performances. Propylene was detected as product at the anode outlet, and the product distribution suggests that propane dehydrogenation underwent competition with cracking to lighter hydrocarbons. Stability during cell performance tests showed that there was no obvious degradation for BCY15 electrolyte during operation of C3H8-O2 fuel cell.

Jan 1, 2005

By D. Limpitlaw, E. M. Hoadley

The minerals sector plays a significant role in the development of many Southern African economies. In the Southern Africa region, as in other developing regions, economic development is seen as the key contributor to poverty alleviation and social upliftment. The significant economic contribution of the minerals sector may be reduced by negative impacts on the biophysical environment and on the communities where mines operate. A critical variable in determining the net contribution of mining companies to SD is the degree of transparency with which the companies operate. Transparency is increasingly emphasised as an essential aspect of good governance and SD, but it is also difficult to establish, and is a sensitive issue for mining companies as they compete with each other for minerals sales. Transparent reporting could ensure that the interests of all stakeholders are addressed as company data is subject to informal ‘auditing’ by any interested party. This paper assesses published reports of five companies over a number of years to establish whether it is possible to make an assessment of the companies’ contribution to SD.

Jan 1, 2005

By S. A. Jacob

Magnesium sheet is notoriously difficult to form at low temperatures without initiating failure, In the present work cold rolling and annealing conditions are varied to produce samples of AZ3lB sheet with a range of grain sizes. The formability of these samples is investigated using tensile testing and forming limit diagrams (FLD's), The results are discussed in terms of twin types and frequencies.

Jan 1, 2005

By Yoshio Nakano

Keywords: Tannin gel, Palladium, Separation, Redox We have developed the novel recovery system of palladium from wastes, which is simple and generates little secondary waste in comparison with the conventional recovery processes, using tannin gel particles synthesized from condensed-tannin molecules. Pd is adsorbed onto the tannin gel particles through inner-sphere redox reaction mechanism: two-electron transfer from tannin gel to Pd(II) species, accompanied by ligand exchange between chloropalladium(II) complexes and tannin molecules. In addition, we propose the separation system of Pd and Au from Pd-Au mixture, which is feasible due to the difference in oxidization and reduction potential between Pd and Au species: PdCl3(H2O)? and PdCl42? are less adsorbable than Pd species containing fewer Cl, such as PdCl2(H2O)2 and PdCl (H2O)3+, while such a distinct difference between Au species is not observed.

Jan 1, 2005

By A. Plumtree

The morphology of environmentally assisted cracks in stressed pipeline steel has been investigated. For a dilute and neutral solution (NS4) simulating ground water in contact with the steel, semi-elliptical cracks grow faster on the surface (2c) than in the depth (a), hence, the aspect ratio (a/c) decreases. This is explained using a deterministic concept since corrosion is dominant and the primary constraint is the conservation of charge. By contrast, when mechanistic conditions prevail, significant growth occurs in the depth. When underloads are imposed in the loading history, temporary accelerations in crack growth occur because corrosion rather than mechanical effects become dominant.

Jan 1, 2005

By Vivian M. Troughton, Clifford J. Wren, Tony P. Suckling

"Secant pile walls are used for the construction of deep basement walls and earth retaining structures. Risk associated with secant pile walls is commonly perceived as being the safety of site personnel and the public during piling operations, or safety used in design. It is recognized that both of these are of paramount importance, but additional risks associated with the construction methods must also be considered to complete the risk management profile for any project. For the particular case of secant pile walls, if Clients take a ""back seat"" they may be unaware of the total risk package they are procuring. The authors argue that the piling contractor should be involved at the earliest stage giving input into the overall risk management process. Such early involvement within the professional team will maximise cost benefits to the Client and minimise the delays and cost increases sometimes associated with these works. A consistent methodology for identifying and then managing all the risks associated with secant pile walls is proposed. An example is used to demonstrate how this methodology should be employed. INTRODUCTIONThis paper discusses the value of a complete and integrated risk management process for structures with basements formed using a secant pile wall.The risk associated with any secant pile wall can be consicfered as comprising four components;1. Safety of people on site2. Safety of design or design methodology3. Construction risks4. Commercial risksAny risk management system needs to fully consider and integrate each of these four components to maximise the likelihood of a successful outcome for the basement.This paper concentrates on the construction risks for secant pile walls, as these are not often understood by the Client (in this paper the term ""Client"" also includes the main contractor, principal contractor, Engineer, Planning Supervisor, quantity surveyor and cost consultant)."

Jan 1, 2005

By B. Andreaus

In spite of tremendous efforts in research and development of polymer electrolyte fuel cells (PEFCs), essential properties of the actual catalyst material, supported Pt or Pt-alloy nanoparticles, are not yet well understood. Fundamental understanding of the catalyst structure and the prevailing kinetic mechanisms is, however, of utmost importance for further progress. In the present study, we investigate catalyst activity for CO oxidation from a theoretical point of view. Electrochemical CO oxidation serves as an important test reaction for the study of the fundamental properties of supported Pt nanoparticles. Recent experiments have revealed strong effects of catalyst particle size and supporting material on catalytic activity. It was found, that the activity towards CO oxidation decreases significantly when the particle diameter drops below 2.5 nm. We perform kinetic Monte Carlo simulations of CO oxidation on supported catalyst particles to elucidate this particle-size effect. The simulations are based on the active site concept, highlighting the role of active site formation and finite surface mobility of adsorbed electroactive species for catalyst activity. For comparison with experimental results, potential step experiments were simulated. The Monte Carlo simulations consistently reproduce effects of particle size and electrode potential found experimentally. In comparison with our simulations, analytical mean field models and nucleation and growth models exhibit inferior agreement with experimental data. In summary, our findings support an oxidation mechanism via active site formation. The reason for the slow reaction kinetics on catalyst particles with diameters below 2.5 nm is a rather low CO surface diffusivity. The rates of active site formation, diffusion and CO oxidation via recombination with adsorbed OH can be determined from the simulations.

Jan 1, 2005

By Marc Arl

Failures of the face and roof above longwall shields have caused days and sometimes weeks of lost production. A common recovery method for these failures has been to pump light weight cementitious grout into the roof and face cavity to stabilize the area This approach while effective is very time consuming and costly. Mines in several coal producing nations have over the past few years been applying phenolic foam grouts in these situations in lieu of cementitious materials. Phenolic foam is a two-component injection product intended for cavity filling, air and gas sealing and the consolidation of highly fractured strata. The properties of phenolic foam; rapid application, quick setting, high expansion rate, high compressive strength and excellent anti-static properties, produce a fast, safe and cost effective cavity filing solution. The product is also classified as fire resistant and so is also suitable for sealing off underground heatings and for aiding fire fighting operations in deep mines. This paper will discuss the application and use of phenolic foam in various underground coal mines in the world over the past few years.

Jan 1, 2005

By J P. van Dyk

The dramatic strengthening of the rand against the dollar as well as a decline in quantity and quality of locally available concentrates have had a dramatic impact on Zincor?s operations during the previous two years. Zincor has responded with the implementation of a number of technical improvements to the process to decrease cost and increase revenue and plant flexibility. Among the initiatives is the pre-leaching and pelletising of the zinc concentrate, de-bottlenecking and process improvements in the leach and purification circuits, the introduction of cathode washing and automated cathode stacking in the cell house and the installation of a new furnace to produce pre-alloyed jumbos. This paper will describe these initiatives and others that Zincor have recently taken to stay competitive in changing global base metals market.

Jan 1, 2005

By K-A. Adamson

If fuel cells and hydrogen are to become a mass market reality a substantial amount of further research and development needs to be undertaken. Work in hydrogen storage, production, the economics of all aspects of fuel cells and hydrogen, materials balances, and product integration are just a few of the areas that are under focus. Setting R&D targets, and providing R&D funding are therefore areas that are central to the long term development of the market, and areas in which a number of governments worldwide are highly active. Some governments, such as Japan and Korea, have set a number of very ambitious, highly focused, long term targets and are backing this up with substantial funding, others such as the EU are working on a more integrated approach, wrapping some fairly fundamental R&D into large integrated projects which run in combination with a number of other market aspects, such as public acceptance and roadmapping. The US is slightly different, in that although is has a number of long term programmes and targets, FreedomCar and SuperGen being just two, the levels of funding are set annually with the passing of each years Fiscal Budget. This paper takes three high profile regions and analyses the R&D targets and funding levels for fuel cells and hydrogen. Criteria that will be looked at include: Time frame of target(s), level of ambition, funding issues, including: Funding windows, levels available, funding barriers, overall programme goals. The added value to this paper is that it will provide a clearer picture of where each region is heading, what are its strengths and weaknesses, in terms of R&D and where there may be areas for potential international collaboration.

Jan 1, 2005

By Han-Tao Hu

Keywords: RH refining process, flow of molten steel, two-phase flow, gas holdup, circulation rate, mathematical modeling A three-dimensional mathematical model for the flow of the molten steel in the whole degasser during the RH refining process has been proposed and developed with considering the physical characteristics of the process, particularly the behaviors of gas-liquid two-phase flow in the up-snorkel and the momentum exchange between the two phases. The fluid flow fields and the gas holdups of liquid phases and others respectively in a 90 t RH degasser and its water model unit with a 1/5 linear scale have been computed using this model. The results showed that the flow pattern of molten steel in the whole RH degasser could be well modeled by the model. The liquid can be fully mixed during the refining process except the area close to the free surface of liquid and zone between the two snorkels in the ladle, but there is a boundary layer between the descending liquid stream from the down-snorkel and its surrounding liquid, which is a typical liquid-liquid two phase flow, and the molten steel in the ladle is not in a perfect mixing state. The lifting gas blown is rising mostly near the up-snorkel wall, which is more obvious under the conditions of a practical RH degasser, and the flow pattern of the bubbles and liquid in the up-snorkel is closer to an annular flow. The calculated circulation rates for the model unit at different lifting gas rates are in good agreement with the determined values.

Jan 1, 2005

By Anthony Leddin, Gillian Dooley

This paper is concerned with mineral policy in Ireland and how it might be improved to encourage more exploration and investment in mining in the country. The approach is to first outline the main desirable characteristics of a comprehensive national mineral policy document. This aspirational document is then used to assess the current regulatory, legislative and fiscal frameworks for mining in Ireland. The analysis also contains a brief account of the history, structure and characteristics of the mining industry in Ireland. The main focus of the paper is to identify those aspects of the existing framework that erode Ireland’s attractiveness to mineral investment and to suggest policy improvements.

Jan 1, 2005

By V. Prodanovic, M. Militzer

Production of advanced linepipe steels with strength levels of 685MPa (100ksi) and higher requires excellent control of runout table cooling to produce the desired final fine-grained microstructures, which may include acicular ferrite. Cooling is exerted on the runout table by applying water jets onto the hot surface of the strip and heat is removed from the steel by forced convective boiling. The associated boiling mechanisms are complex and include film, transition and nucleate boiling. A pilot-scale runout table test rig has been built to systematically study boiling heat transfer from a moving steel plate by employing industrial scale headers. Experiments were conducted using test plates moving at speeds between 0.3 m/s and 1.4 m/s. The plates were cooled down from 850°C to temperatures below saturation by a single water jet supplied through an industrial size circular nozzle. Based on these experiments heat fluxes were determined and further used to develop improved runout table cooling models.

Jan 1, 2005

By C. Caners

One of the main uses of fossil fuels is in the transportation sector, leading to environmental consequences such as climate change. In order to move towards a more sustainable energy infrastructure, a transition must begin from fossil fuels to renewable fuels, derived from e.g. biomass. One means of facilitating this transition is to develop reforming technology that can extract hydrogen from a suitable fuel that is either fossil fuel or renewable in origin. The hydrogen would be feed to a 'fuel cell' engine that would power the car, truck or bus. One reforming technology that is attractive for automotive applications is autothermal reforming (ATR). Autothermal reforming is the combination of steam reforming and partial oxidation, whereby a portion of the fuel is combusted using a sub-stoichiometric amount of air, and the resulting thermal energy drives the more desirable steam reforming reaction. ATR is attractive for fast start-up, rapid load following and ease of control. ATR also has the benefit of smaller volume and fewer peripheral requirements as compared to other reforming technologies. Recently, a bench-scale gasoline autothermal reformer (ATR) was constructed and tested. This ATR employs a novel design, consisting of three concentric annuli in order to promote heat transfer from the partial oxidation reaction to the steam reforming reaction. Concurrently, a CFD based model (FLUENT) of the ATR that considers the geometric complexity of the reformer was validated. In spite of the use of simplified kinetics, the model predicted well the observed trends in temperature and overall performance. This paper will discuss the use of the model to improve the design of the ATR. The impact of various system parameters upon performance will be investigated along with alterations in the geometry of the ATR. The various tradeoffs in performance and system volume/size will be highlighted in the context of a fuel cell power system.

Jan 1, 2005

By Yannick Bleuzen, Manuel Joao, Frederic Monath, Miguel Quaresma

The N1 Porto tunnel project is a 650m segment of large-scale civil engineering plan to improve traffic flow between Porto’s downtown district, the Santo Antonio hospital district and the highway access. The tunnel is being excavated into a massive “Granito do Porto” granite structure, 4 – 20m below a highly urbanized environment of Porto, Portugal. The project was originally started in 2000 and was stopped due to the inability to mechanically excavate the granite rock. The city of Porto engineers then turned to traditional drilling and blasting techniques. The use of pyrotechnical delay detonators did not easily comply with the specified environmental and safety requirements concerning blast charging, firing and vibration control resulting in the process taking far too much time. The introduction of digital blasting was proposed to overcome these concerns.

Jan 1, 2005

By U. Olsson, M. Ramström

"The IREDES1 Special Interest Group (SIG) for drill rigs has been active since its launch during MineExpo 2000 in Las Vegas, Nevada, United States. SIG for drill rigs is responsible for the development of an IREDES drill rig profile, including the exchange of production planning, performance, and quality reporting data between various kinds of drill rigs and the databases used by the operating mine. During 2001, a first draft of the drill rigs profile was jointly prepared by drill rig suppliers, mining companies, and third-party suppliers and reviewed during several SIG meetings. The profile for prototyping projects was released in mid-2002; the first official IREDES release was based on feedback received from these projects.In 2002, LKAB and Atlas Copco decided to carry out an IREDES prototyping project using the Simba L6C production drill rig. The goal was to verify the drill rig profile and identify potential problems prior to the official release. This was done by implementing the IREDES prototype version into LKAB’s production planning and Simba rig control systems. The Simba rig control system was designed to handle drill plan and logging information coming from the mine planning system. In parallel to this, the mine production system was adapted for drill plan export and logging data import in IREDES format.This paper presents the most recent results of the IREDES prototyping project. Results from late 2002 show that the basic architecture of the drill rig profile works and that a common language for data exchange, IREDES, will be a central requirement for future mine automation.As a result of the IREDES prototyping project, the IREDES standard was approved at the IREDES board meeting held at the 2003 CIM Annual Conference and Exhibition. Soon thereafter, IREDES compliant products, including drill rigs and mine production planning systems, were put on the market."

Jan 1, 2005