Search Documents

By J. F. Adams, V. G. Papangelakis

Chemical modelling is becoming increasingly useful in the development, analysis, design, and control of hydrometallurgical processes. The paper presents the development of reliable databases for chemical modelling of selected hydrometallurgical systems using state-of-the-art software, such as OLI. The modelling strategies are also demonstrated. The high pressure acid leaching (HP AL) of laterites, oxygen solubility in the oxidative leaching process of zinc sulfide, gypsum solubility and lead chemistry in mixed sulfate-chloride solutions are presented as case studies. This on-going work attempts to bridge the gap between theoretical research and industry needs. Computational Analysis in Hydrometallurgy 35th Annual Hydrometallurgy Meeting held in conjunction with the 44th Annual Conference of Metallurgists ofCIM Calgary, Alberta, Canada Edited by

Jan 1, 2005

By S. C. Livanou, S. P. Tampouris, E. N. Zevgolis

In ferronickel (Fe-Ni) production from oxidized nickeliferous ores, mechanical losses of ferronickel in the slag are reduced by magnetic separation. Slag from the electric furnaces (E/Fs) contains 0.16% Ni. Its magnetic separation gave a pre-concentrate with 0.76% Ni, weighing approximately 6.5% of the feed. Nickel recovery was 29.7%. This pre-concentrate was then treated in a second (concentration) plant. Concentration treatment involves screening, crushing and magnetic separation. A pre-concentrate with 0.76% Ni gave a magnetic concentrate with 2.58% Ni and a non¬magnetic part with 0.35% Ni. Smelting of the non-magnetic part without the addition of a reduction agent in a laboratory electric arc furnace, gave a ferronickel alloy with approximately 20% Ni and a slag with 0.16% Ni.

Jan 1, 2005

By Andrea Koschinsky

Numerous hydrothermal vents occur along the Earth?s oceanic spreading axes documenting the reaction of seawater with hot magmatic rocks. The circulation of seawater through the oceanic crust, the interaction with hot rocks in the crust, and the subsequent discharge of hot metal- and gas-rich fluids into the ocean have significant implications for the cycling of material and energy on Earth. Until recently, hydrothermal activity was unknown from the Mid-Atlantic Ridge (MAR) south of the Equator where the MAR is offset by about 1000 km at the St. Paul?s and Romanche fracture zones. During a British cruise in February/March 2005, the first active hydrothermal vent field was discovered on the southern MAR at 5°S. During our follow-up cruise M64/1 in April 2005, the first samples from this vent field were recovered with the ROV QUEST (Univ. Bremen) and analyzed onboard. The high-temperature vent field is situated in a water depth of 2990 m along a line of collapse pits within a large basaltic sheet flow. A diffuse, low-temperature field occurs in a jumbled sheet flow few hundred meters to the east with warm water streaming out of cavities between lava blocks. Here we show for the first time that boiling fluids of ~400°C are emanating from sulfide-bearing vents at a depth of about 3000 m at a slow-spreading Mid-Atlantic Ridge segment. Although this segment is composed of thick basaltic crust, these fluids are dominated by hydrogen relative to methane. Whereas the active chimneys consist of pyrrhotite, chalcopyrite, and isocubanite, the mineral association hematite-magnetite-pyrite occurs in the inactive chimneys suggesting that the fluids became more reducing in present times. The high hydrogen contents and the high temperature of the fluids as well as the change to more reducing conditions are most likely related to a young volcanic eruption event some 300 m east of the hydrothermal field. The presence of hematite and magnetite may indicate that the upflow zone or even the reaction zone at 5°S used to be more oxidized then at other MOR sites, where the hydrothermal fluids are commonly buffered by the pyrite-pyrrhotite-magnetite (PPM) buffer. Consequently, high iron contents and high hydrogen/methane ratios occur in high temperature fluids from basaltic host rocks rather than being restricted to ultramafic host rocks. Faunal communities at the South Atlantic vents largely resemble those from the North Atlantic vents implying that the large Equatorial fracture zones do not inhibit or obstruct faunal exchange along the Mid-Atlantic Ridge.

Jan 1, 2005

By K. N. Panigrahi

India bestowed with 6000km of the coastal belt, contains some of the richest and largest placer deposits with a mixture of heavy minerals like ilmenite, rutile, leucoxene, zircon, monazite, sillimanite and garnet. Each of the minerals is having economic value due to its inherent characteristics for industrial use in fields of paints, metallurgy, refractory, abrasive and so on. The reserves of titanium bearing minerals (ilmenite, leucoxene, and rutile) in the country is around 378 million tonnes. More than 90% of the titanium based minerals produced worldwide are utilised for making value added products in the pigment industries. Approximately 8 million tonnes of monazite reserves are available in the country from which several rare earth elements like cerium, neodymium, lanthanum, yttrium etc. can be extracted for use in several industries. The country contains a deposit of about 20 million tonnes of zircon, which is used in foundries, refractories, ceramics and chemicals. India has a reserve of 107 million tonnes of garnet and 131 million tonnes of sillimanite required for the abrasive and refractory industries respectively. Keeping in view the multifarious uses, the beach sand minerals are being exploited to have the economic growth of the nation. Although the process adopted for the separations are simple, the equipment involved are specially designed because of the nature of the material of construction. Starting from the spirals to magnetic separators, all equipments are manufactured outside India, which is not only costly, but the availability also takes much time for fulfilling the import formalities. Unlike open cast mining, beach sand mining is a environment friendly mining because dredging is implemented to cut and pump the loose sand through a slurry pump causing less damage to the surface topography as both mining and backfilling takes place simultaneously. Therefore all out efforts are made to explore the beach sand placer deposits in an economic manner to emerge as a leader in the global mineral industries.

Jan 1, 2005

By M. M. Manamela

Paper written on project work carried out at the University of Pretoria in partial fulfilment of the requirements of the B Tech degree at the Tshwane University of Technology This work tested whether ore particle size affects the carbon-based pre-reduction of titaniferous magnetite. Pre-reduction is performed at a temperature of some 1100°C in a rotary kiln, in the Highveld Steel process. Laboratory isothermal reduction measurements were performed with ore-coal mixtures at this temperature, to test the effect of ore particle size. The results show that size does limit the degree of reduction for particles larger than 15 mm.

Jan 1, 2005

By Murali M. Gadde, Syd S. Peng, C. T. Holland

Cutter roof failure is one of the most common ground control problems affecting the safety and economy of an underground coal mine operation. Several attempts were made in the past to understand the processes responsible for cutter development and to devise mitigating measures. Yet, many cutter failures still happen and their advance prediction remains as elusive as before. One of the reasons for the impasse in predicting cutters lies in the limitations of the current numerical modeling technologies. The development and propagation of cutters is a progressive phenomenon and continuum models can only approximate this process. Since the discontinuum modeling is severely restricted by the lack of reliable input data, alternatives must be sought to better understand cutter failures using the continuum models. This paper proposes one approach using strain-softening material model to simulate the cutter initiation and propagation process. An attempt has also been made to provide some insights into the reasons for the change in cutter location at different parts of a development layout.

Jan 1, 2005

By J. O. Voigt

No major changes took place in the salt industry during 2004. No new uses of salt appeared and only localized supply disruptions occurred. Many salt producers reported slightly increased salt sales and profits for the year. In the United States, about half of the salt supply is produced as brine, by solution mining, and is used by the chemicals industry. One-third of U.S. salt is produced as rock salt by 14 underground mines. The remaining two production techniques, each with less than 10 percent of the total tonnage, are vacuum-pan-evaporation for refined, food-grade salt, and solar pond crystallized salt.

Jan 1, 2005

By Scott Dodds

"The Oxford Hydroelectric Station was a unique project that incorporated a variety of dam strengthening methods to stabilize the facility in order to meet the standards required by Federal Energy Regulatory Commission (FERC). The dam stability and Probable Maximum Flood (PMF) remediation work consisted of (1) construction of a new emergency spillway; (2) installation of 75 high capacity rock anchors; (3) construction of an anchored concrete powerhouse buttress; (4) construction of cast-in-place and sheetpile flood walls; and (5) design and construction of a permanent soil nail wall. INTRODUCTIONThe Oxford Hydroelectric Station is one of 11 hydroelectric facilities owned and operated by Duke Power along the Catawba/Wateree River. The Catawba River originates in the foothills of the Appalachian Mountains just west of Morganton, North Carolina. The river flows east out of the mountains and, at a point just below the Oxford Dam, the Catawba River turns and heads southeast. The Catawba River continues to flow southeast past Charlotte and into South Carolina where it eventually becomes the Wateree River. The Wateree River eventually flows in to the Atlantic Ocean.Located a few miles east of Hickory, North Carolina, the Oxford Dam and Hydroelectric facility is in the upper reach of the Catawba River. Oxford Dam creates the third impoundment along the river known as Lake Hickory. Lake Hickory is well known locally for providing many outdoor activities such as boating, jet skiing, canoeing and fishing. The dam and powerhouse were put into operation in the spring of 1928.Key features of the dam include a short embankment section on the south end of the structure, a 391-foot (119m) long south bulkhead and powerhouse, 540-foot (165m) long gated spillway section and a 235-foot (71.6m) long north bulkhead. The maximum height of the dam is approximately 100-feet (30m) from the crest to the dam/rock interface. (See Figure 1).The work associated with this project is the result of licensing requirements of the Federal Energy Regulatory Commission (FERC) which mandates that all hydroelectric facilities have the capacity to safely discharge runoff created by a critical rainfall event defined as the probable maximum flood (PMF). Duke Power, a division of Duke Energy (DUKE) submitted an initial PMF report in 1992 which indicated that at the Oxford Dam would be overtopped by approximately 10-feet of water during the modeled PMF event. Given the duration and depth of the overtopping, significant damage to the facility and a possible breach could result. Therefore, modifications to the existing facility were necessary to satisfy the report of the PMF model."

Jan 1, 2005

By B. Voyzelle

The deterioration of highway and bridge infrastructure has received considerable attention in recent years because of the billions of dollars needed for repair and rehabilitation. A major factor contributing to this problem is the corrosion of steel reinforcement. Reinforcing steels with good corrosion resistance and relatively low price are therefore essential for maintenance, cost reduction and service-life extension of the steel-reinforced structures. This article describes the development of low-alloying steels that offers good corrosion resistance with reasonably low cost. Topics include steel microstructures, mechanical properties, corrosion performance, industrial applications and economic aspects.

Jan 1, 2005

By W Lu, D Wang

Study of coal oxidation at low temperatures forms the basis of investigating the inherent properties of spontaneous combustion of coal. In general, the process of coal oxidation at low temperatures is very complex, involving many factors. Experiments examining the properties of oxidation and ignition of coal have been carried out. Based upon the results of these experiments, the catastrophe properties in the process of coal oxidation are analysed and the mechanism of catastrophe is proved for the ignition of coal. A folding catastrophe model is also established for the process of coal oxidation. Results obtained show that the process of coal oxidation to ignition is discontinuous, where the coal-environment system yields structure destabilisation. The system can jump from one stable attractor to another. The research results presented in this paper help to show the irregularities of coal oxidation at low temperatures and how to pursue effective control measures.

Jan 1, 2005

By Simon Mundike, Muwindwa Lipalile

A scraper based block cave method has been successfully applied to extract the Lower Ore Body at Nchanga since the 1950?s. Since inception, scraper drifts and service ways have been supported using steel arch sets fabricated to a specific design from high strength manganese steel To reduce costs and to improve productivity, trials commenced in 2002 using fibre reinforced shotcrete as an alternative support method. One of the areas; the 2420 8E 1C trial drift was subjected to abutment loading for several months prior to undercutting and cave mining. Shotcrete installed exhibited minor cracking shortly after application but very little deterioration thereafter. Following the success of the trial, the application of fibre reinforced shotcrete was extended to other drifts. This paper describes the application of fibre reinforced shotcrete at Nchanga and outlines design and quality assurance methods employed.

Jan 1, 2005

By D. Ortiz, J. R. Frias, E. D. Mast, J. J. Fañas

Falconbridge Dominicana (Falcondo) has operated an integrated tpy nickel laterite mine and ferro-nickel processing plant since 1972 in the Dominican Republic. The operation includes mining, a processing plant, an oil refinery, and a power plant. Falcondo has improved process efficiency over the years via modernisation and better understanding of the process. The present business environment of high fuel prices and high nickel prices present a challenge and an opportunity to Falcondo's operation. This paper gives an update of Falcondo's process, improvements in energy consumption, factors affecting energy consumption and how Falcondo is facing up to the current business environment.

Jan 1, 2005

By M DellÆAmico, K Vining

The iron blast furnace is the most widely used and efficient producer of liquid iron; however, emissions from sintering and coking cause environmental pressure for the integrated steel works. The combustion of coke fines (breeze) during sintering contributes to greenhouse gases (GHG) (eg carbon dioxide) and is a source of SOx and NOx emissions. Coking capacity is also constrained by environmental concerns and economic factors, such as increased coke consumption, and short supply is leading to high prices. Improved coking practices, which result in reduced production of fines, are also contributing to the tight availability of breeze for sintering. This combination of factors presents an opportunity to consider alternatives to coke as a fuel for sintering. CSIRO Minerals has been investigating the use of wood biomass/char as a substitute for coke during sintering. Wood biomass, or char produced from it, is an attractive carbon source as carbon dioxide liberated during combustion can be sequestered back into growing biomass. It has great potential to reduce the emissions from integrated steelworks and improve their environmental acceptability. Harvested biomass/char is also a renewable and sustainable resource and can be integrated with good land management practices such as remediation of salinity affected land. Weeds, especially woody weeds, can also be used as a source of biomass for charcoal, and integrating char production with weed management can help address a pressing environmental issue in Australia. Previous reported preliminary testwork indicated that the use of Red Gum char as a replacement for coke resulted in a product sinter of comparable quality, improvements in productivity and significant reductions in SOx and NOx emissions. In the latest testwork, CSIRO has examined the properties of a range of potential charcoals, and has conducted a further series of granulation and small-scale sintering trials with them in simulated Japanese Steel Mill iron ore blends. Sinter fuels characterised and evaluated include industry sourced coke breeze, commercially available wood char and a charcoal from prickly acacia (acacia nilotica). Prickly acacia has been declared a noxious weed, is widespread in Australia, and is classified as a æWeed of National SignificanceÆ. The results presented in this paper support the notion that charcoal outperforms coke in many aspects of iron ore sintering and factoring in environmental considerations makes the switch to charcoal even more favourable.

Jan 1, 2005

By Charlie Li

A cut-and-fill mine stope, located at a depth of about 1000 m in a lead-and-zinc mine, was closed down because of large roof convergence and fractures appearing on the hanging wall. The instability problem was owing to the relatively low strength of the rock subjected to high in-situ stresses. Extra reinforcement was required to secure the stope so that the remaining ores in the stope could be mined. Assessment of the fracture mode in the country rock surrounding the stope was carried out and then the reinforcement de- sign was worked out. It was proposed that the unstable section of the stope would be reinforced by bolt-shotcrete ribs as well as selective long bolts. The philosophy of the design was to hold up the fractured country rock by bolts and shotcrete so that a load-bearing arch could be formed in the roof and in the hanging wall. Six shot- Crete ribs were set up in the unstable section of the stope. Displacement measurements showed that the roof convergence reduced from about 2 &day to the ordinary creeping level, about 0.25 &day, immediately after the reinforcement operation. Six month later, the hanging wall collapsed into the stope in a place just outside the reinforced section, which indirectly proved the effectiveness of the bolt-shotcrete ribs in reinforcing the fractured country rock. This case showed that an appropriate rock mechanics assessment would form a solid base for reinforcement/support design. It also provided an evidence for the philosophy of the reinforcement by bolt-shotcrete ribs - establish a load-bearing arch in the rock.

Jan 1, 2005

By J. H. Canterford

The nickel industry in Australia has followed the general pattern apparent in many other regions - lots of ups and downs, successes and failures, but always plenty of challenges. Some of these can be attributed to local geographical and infrastructure factors, others to a healthy mix of corporate good luck and management countered by decisions that, in retrospect, were less than optimum. The roles of several entrepreneurs have certainly added plenty of spice! In terms of processing technologies, there was an initial heavy reliance on the use of "off the shelf' commercially proven processes such as ammonia leaching of concentrates and mattes, and flash smelting. Over the past decade there has been an increasing dominance of plant modifications and process technologies that have been developed "in house" in order to enhance project economics and exploit lower grade and more complex resources. This presentation provides an overview of the past 40 years of the major developments in the Australian nickel industry and concludes with some guesses as to where we will be in another decade or so.

Jan 1, 2005

By P Hulteberg

In this article, an integrated catalytic reactor design approach to produce PEMFC-quality hydrogen is evaluated. The design is based on a high level of heat exchanging perfonned internally, highly active noble metal catalysts and a woven wire mesh catalyst support system. It consists of an integrated steam refonner and a catalytic burner section, a water gas shift section and a preferential carbon monoxide oxidation section. The reactor design is described and experiments perfonned to evaluate the two reactors built are reported. The two reactors have a maximum output of 3 Nm and 10 Nm3 hydrogen/h respectively. In the larger unit, a total of six fuels, three gaseous (methane, natural gas and liquid propane gas) and three liquid (naphtha, ethanol and methanol), were evaluated. The larger unit was also used to investigate how variations of parameters such as steam-to-carbon ratio in the steam reforming part of the system and the relation between oxygen and carbon monoxide in the preferential carbon monoxide oxidation affect the reactor perfonnance. The smaller unit was used, after implementing automatic control, to run a system life time test for 480 h. The refonner system perfonned according to specifications on almost every aspect.

Jan 1, 2005

By Keith E. Meyers

Condition monitoring is a viable troubleshooting practice among many industries to extend equipment performance, minimize unplanned downtime, reduce maintenance and repair time and costs, and increase related aspects of plant safety. But obstacles abound for mining, mineral-processing and cement operations striving to implement the technologies. Harsh machine environments can muddy efforts. High vibration in machinery can interfere with wide-spread rollout. Staff expertise or skills may be lacking. And costs may be prohibitive. Fault detection has emerged as a practical and cost-effective solution to identify process and machinery faults before failure interrupts productivity or jeopardizes worker safety. Fault detection can be a stand-alone system or connected to plant automation.

Jan 1, 2005

By Didem Maral

Olivine is a name of a mineral group that has a chemical formula of: (Mg, Fe), SiO4. The most important rock for the olivine group minerals is dunite, which can contain olivine up to 95-99%. Dunite can be obtained from chrome enrichment as a by-product. As a result of alteration of the olivine group minerals, several kinds of different minerals can occur. Main consumption areas of olivine are steel and iron industry. Also olivine is used in not only casting and refractory industries but also production of radiator, ballast material and abrasive. North of Bursa-Orhaneli has got more than 5 billion tons reserves in ultrabasic massifs. M.T.A found that olivine has got high quality of using in refractory and casting industry.

Jan 1, 2005

By P. Rice, A. Photolo, A. C. Barnard

Introduction -Sampling Tool Project (STP) -History -Results to date -Costs -Questions

Jan 1, 2005

By Ryan Walton

The Flash Converting Furnace at Kennecott Utah Copper converted over 465kmt of high-grade matte in 2002 but was restricted due to low matte production to 395kmt in 2003. This paper presents updated operational performance data and describes improvements implemented since the mid 2001 rebuild. Matte burner feed distribution, silica and arsenic impacts on settler lime-based slag operability, blister laundering, uptake/boiler accretion control, and dust sulfation will be discussed, as well as current development requirements dictated by operational imperatives and furnace modification plans.

Jan 1, 2005