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By B. Fang

Electrochemical behavior of an X-80 pipeline steel, including frequency-sweep electrochemical-impedance spectroscopy (EIS), time-sweep EIS at a constant frequency and open-circuit potential (OCP) monitor, was investigated using four-point bending specimens subjected to a stress-corrosion cracking (SCC) test in a near-neutral pH environment, The capacitive loop became smaller with test duration, revealing an increase in the corrosion rate, The resistance obtained in the constant-frequency EIS test showed two regions, of which the region with a remarkable decrease in resistance transformed into a region of slow decrease, whereas the capacitance increased with test time indicating that iron dissolution was fast at first, and then a corrosion product or film formed and covered the surface, leading to the pitting formation.

Jan 1, 2005

By S. Svoronos, B. Moudgil, R. Stana, A. El-Midany

Due to their similar surface properties, it is not always easy to separate carbonate minerals from other salt type minerals by froth flotation. A particular example is the difficulty of separating dolomite impunities from phosphate minerals. Such challenging fundamental and practical problems have inspired several research efforts in various laboratories around the globe to find methods for economically removing the dolomite. However, a universal and cost effective process is not in commercial use. In this paper, a new process for separation of carbonate minerals (dolomite or calate) from other associated minerals is presented. Differential solubility of carbonates in slightly acidic solution is utilized to generate micro GO, bubbles at the carbonate mineral/ water interface. Particle (e.g., dolomite)/ bubble aggregates float to the surface leaving phosphate concentrate with low MgO content. Interestingly, up to 6.0 mm particles can be floated by such micro bubble/particle aggregates. Different sutface-active agents were tested to stabilize the bubbles. Results of these tests are presented and the mechanisms involved are discussed.

Jan 1, 2005

By Erwin Stötzer, Renato Fiorotto, Wolfgang G. Brunner, Manfred Schöpf

"Deep mixing methods can be used economically for the construction of cut-off or excavation support walls where other systems such as traditional soldier beams and lagging walls would yie ld unsatisfactory performance, where the installation of vibrated or driven sheet piles could cause vibration induced settlements and where concrete diaphragm walls would be time consuming and expensive. The new CSM method can largely replace the more conventional single or multiple auger methods of soil mixing or jet grouting. The cutter tool is similar to a cutter used in diaphragm walls or cut-off walls and is operated with a Kelly mounted on a drill rig. With this system much deeper walls can be installed and even hard soil layers can be penetrated. CONVENTIONAL SOIL MIXINGIn 1962 Norman Liver patented an auger-based soil mixing technique that has become the basis for the world's current technology.The deep mixing method (DMM), as it is known today, is an in situ soil treatment and improvement technology where the soil is blended with binders and/or other materials that are introduced in a slurry or dry form.Typically one or more hollow, rotating mixing shafts tipped with some type of cutting tool are mounted vertically to the mast of a base carrier and are driven into the ground by hydraulic or electrically powered rotary heads. The shafts above the cutting tool may be further equipped with discontinuous auger flights and/or mixing paddles. The binder is injected through the hollow shafts to nozzles located near the cutting tool where it is mixed with the ground to form columns of treated soil.Individual column diameters range from 0,6m to 1,5m and may extend to 40 m in depth. They can be arranged individually or in contiguous or secant patterns to produce a wide range of treated soil structures on both land and marine projects. Typical configurations are: Single elements, rows of overlapping (secant) elements, grids, lattices and blocks (Fig. 1 )."

Jan 1, 2005

By Yi Luo, Jeremy Slagley, Arunkumar Rai, Steve Guffey, Syd S. Peng

Research was conducted to study the characteristics of longwall mining machine noises and to develop engineering controls for the reduction of noise exposure at longwall faces. Time-motion noise dosimeter data was analyzed and compared with existing databases. Experiments were conducted above ground on a stage loader/crusher to explore the potential of using active noise control (noise cancellation) in reducing the noise levels. A 5-7 dBA reduction in recorded stage loader noise was achieved. This paper presents the equipment, procedure and results of the noise surveys, as well as the active noise control experiments.

Jan 1, 2005

Surface Plasmon Resonance (SPR) spectroscopy, combined with cyclovoltammetry, has been successfully used to study the interactions between ethyl xanthate, heptyl xanthate, dithio-phosphate and propyl trithiocarbonate flotation collectors and a gold surface. Large, easily measurable responses have been obtained in the potential areas where the thiol collectors are known to interact with gold. The four collector types lead to differing SPR maximum values, with longer alkyl chains resulting in higher SPR responses, and the trithiocarbonate leading to the highest response values. The SPR responses differ considerably from the current density response at very anodic and cathodic potentials. There are indications that thiols might still be adsorbed at potentials as low as-300 mV (vs SHE). Keywords: flotation collectors; thiol collectors; cyclovoltammetry; surface plasmon resonance spectroscopy.

Jan 1, 2005

By Tetsuo Yamazaki

Manganese nodules, seafloor massive sulfides, and cobalt-rich manganese crusts in deep-sea areas have been considered as future metal sources (Mero, 1965; Halbach, 1982; Lenoble, 2000). Manganese nodules were the first recognized deep-sea mineral resource and many efforts concentrated on the R&D of mining systems (Welling, 1981; Herrouin et al., 1989; Yamada and Yamazaki, 1998) and assessment of environmental impacts (Burns et al., 1980; Foell et al., 1990; Yamazaki and Kajitani, 1999). No mining venture, however, has been active for this potential resource. The reason is that the rate of world economic growth has been slower than anticipated in 1960s. During the 10 year period of 1994-2003 (Fig. 1), on the other hand, there was about a 33% increase in the world copper demand. Of that increase, about 60% was consumed by China. Most of China?s increased copper demand took place over the final 4-5 years of that period. The growth is expected to continue for several years, and in 10 years or sooner the same situation is expected for India. Copper is the third metal in global demand, but its small abundance in the Earth?s crust is not well recognized (Table 1). From the production rate and the abundance, a copper shortage, or crisis, has a high probability than the other metals. Japan has no domestic copper resources and needs a counter measure for this potential coming copper shortage. Fortunately, Japan has a manganese nodule mining claim in the Clarion-Clipperton nodule field, Kuroko-type massive seafloor sulfide deposits in the Okinawa Trough and Izu-Ogasawara areas, and cobalt-rich manganese crusts around Okinotori-Shima and Marcus Islands. We need to re-evaluate their potential as copper resources and to realize their development.

Jan 1, 2005

BHP BillitonÆs Yandi channel iron deposit has a large resource of approximately 1.3 billion tonnes. This is a bulk mining operation with a high degree of selectivity not being practical. In contrast the deposit geology is a complex interrelationship of primary channel facies, secondary enrichment of iron and a secondary redistribution of the major contaminants. These variations in geology and alteration can occur over ranges of hundreds of metres down to knife edge contacts. In addition, differences in primary facies and mobility during alteration often result in the iron and contaminants having different patterns of enrichment and depletion. Despite the scale of these operations, if the geological domaining is not optimal, significant errors in the resource estimate of grades and tonnage will occur. Getting the geology right has become a common clichT among mining professionals. However, in many situations, obtaining optimal geological domains for resource modelling is best achieved when there is input from geology, statistics and geostatistics. In this paper, moving window statistics are utilised to see through locally high variability to identify trends that assist in locating difficult to identify geological boundaries. After the creation of geological domains, univariate and multivariate statistics and principal component analysis assist in validating and characterising geological domains. Finally, variography and domain contact analysis are used to analyse the nature of the boundaries between geological domains. At the Yandi channel iron deposit, the inter-relationship between geological and geostatistical analysis has resulted in significant improvements to geological domaining and the treatment of domain boundaries during estimation of iron and contaminates.

Jan 1, 2005

By H. Houali

Corrosion is an electrochemical process that causes degradation and deterioration of various steel works (pipelines, drains, cisterns) whether they are buried, immersed, or not. Worldwide, we estimate that corrosion destroys a quarter of the annual production of steel at a rate of 5 tons per second. Several techniques are used to protect against corrosion. Among these processes, Cathodic protection, which is regarded as the best technique to assure the protection of steel, works against this phenomenon. This is achieved either by a system of reactive anodes, or by the technique of impressed current protection or other techniques. Before any installation of cathodic protection, a preliminary study and pre-evaluation of certain parameters must be made. In the present work, we will present an example of dimensioning of an installation of cathodic protection by imposed current of a pipeline using solar energy, where we discuss the following items: ? Evolutions of the potential as well as current along the pipeline and their respective expressions deduced from the laws known as telegraphists; ? Range of protection (potential of protection along the pipeline); ? Influence of the isolation resistance of the coating on the range of protection; Effect of the aging of the coating and its influence on the current of protection

Jan 1, 2005

By N. Ahern, D. B. Dreisinger, G. Van Weert

In the thiosulfate leaching of gold, degradation of the thiosulfate reagent is a major cost. One of the intermediary degradation products is trithionate, which also inhibits gold recovery from solution by ion exchange. Little attention has been given to this species in the context of gold leaching - the limited information on trithionate and its solution chemistry available in the literature is seldom directly related to gold leaching conditions. This review is a compilation of the published knowledge on trithionate, with a specific focus on identifying the relevance of this information to gold leaching and the shortcomings in the knowledge base.

Jan 1, 2005

By Yi Luo

The efforts to mitigate longwall subsidence influences on various residential and farming structures by many coal mining companies have been successful in the recent years (Luo, et al, 2003). The successes were largely dependent on the accurate subsidence predictions, correct assessments of potential influences, appropriate design and implementation of the mitigation measures. However, such efforts for protecting large industrial structures are still very rare. In this paper, the successful assessment and mitigation of the subsidence influences associated with a very intensive dynamic longwall subsidence process on a large workshop are presented.

Jan 1, 2005

By Malcolm Scoble

This contribution examines the motivation and prospects for mining companies to become Learning Organizations and integrate Lifelong Learning into their culture. Mining Schools have a potentially central role to play in developing Learning systems for access by industry. Reference is made to initiatives to develop a system that is based on collaboration between UBC, Edumine and the Canadian Institute of Mining, Metallurgy and Petroleum. Recent experiences with this model are reviewed.

Jan 1, 2005

By J-P Franzidis, E V. Manlap

Froth transportation characteristics have a significant impact on the flotation recovery especially in large flotation cells. The probability of an attached particle being recovered into the concentrate depends strongly on the location where it enters the froth phase. A mathematical model for froth transportation in industrial flotation cells was proposed (Zheng et al, 2004). The model has been tested on the experimental data obtained from testwork conducted at the Western Metals Hellyer lead/zinc concentrator. The results show that the model fits the experimental data well, especially when the froth is well developed (ie for a deep froth). The model fitting can be significantly improved by incorporating an air dispersion factor. However, the models encounter some limitation, ie inconsistent prediction at different froth heights, due to change in froth viscosity which cannot be modelled at the present time.

Jan 1, 2005

By C. A. Young, H-H. Huang, L. G. Twidwell

Solid particles, especially oxides/hydroxides, develop an electrical charge on their surface when submerged in aqueous solution. Parks was able to relate PZC (point of zero charge) of an oxide to its minimum solubility and isoelectric point. Dzombak has compiled an extensive database for adsorption reactions on ferrihydrite surfaces using the double layer theory. The equilibrium calculational program, STABCAL has been used to extend the considerations of Parks and Stumm. The PZC for many hydroxides, complex oxides, and non-oxides have been investigated and the results are reported in the literature. Removal of arsenic and metals by adsorption on ferrihydrite as the substrate has been computed using ST ABCAL and the computational results are compared to experimental data. Absorbents other than ferrihydrite such as aluminum hydroxide are also discussed.

Jan 1, 2005

By M van Kampen

The Resource Management Act 1991 has been amended on a number of separate occasions since its enactment in 1991, and has recently be subject to further amendment by way of the Resource Management Amendment Act 2005. The amendments as proposed in the Resource Management and Electricity Legislation Bill would have had revolutionary and far-reaching consequences. However, as finally enacted, the amendments are a greatly watered down version of what was initially proposed.   Nonetheless, the Resource Management Amendment Act 2005 has provided for a number of amendments that will impact on the minerals industry to varying degrees. This paper discusses in particular the changes and impact of the changes to the definition of æcontaminated landÆ, clarification with respect to the duty to consult, amendments to the provisions relating to National Environmental Standards, and to the council and Environment Court hearing process.

Jan 1, 2005

By J J. Cilliers, K Hadler, A W. Stra

This paper examines the use of the FrothSim flotation simulator to improve the performance of an industrial column flotation cell. The performance of an industrial retreat column cell is simulated, and, from the discrepancies between the simulated and experimental results, a problem with the wash water distribution is postulated. The scientific reason for the reduced performance with uneven wash water addition is described in detail. Further simulations indicated the potential for improvement with an even wash water distribution, resulting in both improved performance and reduced wash water usage. The simulated uneven wash water distribution was confirmed industrially, and the headers were redesigned and installed. A sampling campaign to compare the performance before and after the modifications showed that the flotation performance was improved dramatically, with a statistically significant decrease in gangue recovery, without a commensurate reduction in valuable mineral recovery.

Jan 1, 2005

By Melissa L. Trapani

Keywords: Copper, Taphole, Flow Instability. ?Blister spitting? is a flow irregularity where the molten blister copper stream ? or part thereof ? sprays from the taphole exit rather than following a regular flow profile to the collection box. As well as being a general ?housekeeping? issue, the unpredictable nature of the flow is a threat to operator safety. Also, the aggressive flow pattern may contribute to the mechanical wear of the taphole refractory, compromising the integrity of the taphole. This paper brings together a collection of first-hand observations and reports from process personnel, and suggests some theories as to the causes of blister spitting.

Jan 1, 2005

By R Espinosa-G=mez

Industrias Pe±oles, S A de C V (Pe±oles) in Mexico, is a major silver producer. The Pe±oles mining division has eight operations and the flotation process in seven of them to concentrate the metal and mineral values. Common metal and mineral values are: metallic gold and silver; gold-silver alloy (electrum); silver sulfide minerals (acanthite, pyrargyrite, freibergite, proustite); lead sulfide (galena); zinc sulfide (sphalerite); and copper sulfides (chalcopyrite and bornite). This paper aims to share Pe±olesÆs mineralogical and metallurgical information on the seven operations where the flotation process is used. Some basic conclusions are drawn from this analysis. Some of the information presented includes: types of orebodies, concentration processes, concentrator throughputs, head grades, concentrate grades and recoveries. Importantly, grind size and liberation values for the main mineral species are presented along with the relationships between sphalerite liberation and its recovery, and galena liberation and its recovery. Also included are three mineralogical case studies: maximisation of silver recovery at the Fresnillo mine producing a silver-zinc concentrate; options to improve gold recovery at the Tizapa mine; and sphalerite iron content for the different orebodies.

Jan 1, 2005

By E. Steiakakis

This paper presents in detail the procedures followed and the results obtained in order to determine the stiffness parameters of the calcareous marls found in the lignite mines in Ptolemais, Northern Greece. Triaxial tests were performed on representative samples of the inner burden marl and the marl which underlies the lignite bearing series of the region. The tests were conducted under drained conditions, with controlled loading (including an unloading-reloading loop), while the axial strain was measured externally as well as with displacement transducers mounted directly on the specimen (Hall Effect sensors). The geotechnical parameters obtained (i.e., cohesion, angle of friction, stiffness modulus, stress-strain relationship), were subsequently used for simulating the triaxial testing with the Plaxis finite element software. Simulation results are in good agreement with the experimental results. The resulting material model can then be applied to modeling the mobility that is expressed during the excavation of the open pit mines.

Jan 1, 2005

By Rob Farnfield, Charlie Adhock

The measurement of near-field shock has always been an attractive proposition for those working in the field of explosive and blast performance. The most commonly employed technique involves the use of piezoelectric accelerometers. Although highly effective, these complicated devices are relatively expensive and are often destroyed in the blast event. This paper describes the development and field-testing of a shock sensor of sufficiently low cost to enable it to be routinely used in product blasting. This new device is based on piezoelectric wafer technology and does not require any external signal conditioning. The device is housed in a small cylindrical package with approximate dimensions of 30mm (1.2”) length and 5mm (0.2”) diameter. It has been determined that the most effective way of fixing the device to rock is in a small diameter hole with epoxy glue. Alternatively the sensor can be simply placed in holes filled with either water or bulk emulsion explosive.

Jan 1, 2005

The fire started in the development section from methane released into the mine through a roof-bolt hole. The date was 8 May 1998. The flames spread quickly as the coal was ignited. After eight hours the Safety Department decided to seal the vertical ventilation shafts and the slopes. The quality of coal in the Esmeralda Mine is very high quality, and Minerales Monclova (MIMOSA) decided to recover the facilities, however, the Esmeralda Mine coals have a very high gas content of 12 m3/t. Immediately after the mine was sealed, MIMOSA staff implemented a plan to monitor the gas levels underground and contacted specialists for assistance in bringing the mine back on-line. During the next 2.5 months, MIMOSA staff and the specialists observed and analysed the gas behaviour supported by a chromatograph. With the results of the observations and analyses, MIMOSA in consultation with the specialists developed a recovery plan based on flooding the area in which fire might have propagated and in which rekindling was highly probable. Those results were analysed by the command centre (Mexican engineers responsible for mine recovery). At the same time MIMOSA trained rescue teams which included miners who had no previous experience in mine recovery operations. By 20 August 1998, the mine command centre had re-opened the slopes seal. Using a æStep-by-StepÆ system, the rescue team began the recovery process by employing cross-cuts and using an auxiliary fan to establish the ventilation circuit. The MIMOSA team advanced into the mine as far as allowed by the water level and was able to recover the main fan. The official mine recovery date was 30 November 1998.

Jan 1, 2005