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By V. Saltas

The present work investigates whether dielectric spectroscopy can be used to detect contamination, which may appear in a natural porous material, due to the spreading of pollution. For this purpose, dielectric and conductivity measurements, in the frequency range of 10mHz to 1MHz, were carried out in sandstone samples, partially filled or saturated with solutions of leachates, at different concentrations. The experimental results suggest that although the role of water is dominant to the measured electrical conductivity, variations of two orders of magnitude are observed due to the different concentrations of leachates, in partially filled sandstone samples. Experimental data are well fitted with a Havriliak?Negami dielectric relaxation function, superimposed with a conductivity term. The parameters of the fitting function have been correlated to the concentration of leachate in the sandstone samples and considerable changes have been observed at low leachate?s concentration.

Jan 1, 2005

By R Moller

Reconciliation at large iron ore operations is a complex and time- consuming process. Often the volume of data and the large range of different stakeholders makes the process almost impossible. Up until recently geologists and engineers at these operations would spend hours cutting and pasting data in and out of monster spreadsheets, diligently comparing how resource/reserve models, grade control and survey pick-ups compare to what was actually produced. In 2003 the Sishen Iron Ore Mine in South Africa broke this cycle by implementing SnowdenÆs Reconcilor software. The implementation of a dedicated reconciliation system required a number of existing practices to be changed, with the involvement of stakeholders right across the mine. Data sources had to be clarified and validated, terminology had to be standardised, processes needed to be documented and some methodologies needed to be updated. This was a task that required significant effort by Kumba personnel so that the system could be successfully implemented. This paper provides a case study of the reconciliation system implementation at Sishen. It is a story of an operation that evolved from using a number of fragmented reconciliation processes to using a unified automated system. This paper outlines the key estimates and measurements that are used for reconciliation, details the characteristics of an automated web-based information management system to facilitate the process and provides some insights about the benefits that have been gained though the use of a rigorous reconciliation process.

Jan 1, 2005

By Hirokazu Narita

Keywords: solvent extraction, precious metals, thiodiglycolamide, rapid separation, hydrochloric acid The solvent extraction of some precious metals (Pd(II), Pt(IV), Rh(III) and Au(III)) and base metals (Fe(III), Cu(II) and Zn(II)) in a hydrochloric acid solution was carried out using N,N'-dimethyl-N,N'-dioctyl-thiodiglycolamide (MOTDA) dissolved in the mixed solution of 80 vol-% dodecane and 20 vol-% 2-ethylhexanol. The extraction percentages of Pd(II) and Au(III) in the 0.01 M MOTDA-1.0 M HCl solution system are 99.6% and 71.8%, respectively. In contrast, the other metal ions are hardly extracted under the studied conditions. The Au(III) and Pd(II) extracted in the organic phase are easily back-extracted with a 1.0 M thiourea/1.0 M HCl solution. A comparison with the conventional extractant for the Pd(II) separation, di-n-hexyl sulfide (DHS), revealed that the extraction rate of Pd(II) with MOTDA is much greater than that with DHS. The extraction percentage reached over 99% in less than a 2 min contact time. However, in the DHS-Pd(II) system, it takes about 240 min to achieve the extraction equilibrium. Furthermore, MOTDA can quantitatively extract Pd(II) up to half the molar amount of MOTDA. Therefore, MOTDA is a promising extractant for Pd(II) from the HCl solution after the removal of Au(III).

Jan 1, 2005

By S. Möllerherm, E. Drüppel

"The development of indicators to assess the sustainability of mineral raw materials operations is amajor task with respect to its actuality and difficulty. This holds true even more when dealing withenvironmental indicators.The use of existing environmental indicators in the mineral raw materials industry leads to false orat least distorted results. Therefore the Institute of Mining Engineering I from the RWTH AachenUniversity developed indicators and an assessment system for the mineral raw materials industryon operation, company and sector level on behalf of the Federal Ministry of Economics and Labour(Bundesministerium für Wirtschaft und Arbeit, BMWA) and the Federal Institute for Geosciencesand Natural Resources (Bundesanstalt für Geowissenschaften und Rohstoffe, BGR).In total 30 indicators were defined and designed to assess the performance of the mineral rawmaterials industry in terms of sustainable development, 10 indicators for each pillar (economical,ecological and social pillar).The following paper describes some of the results focussing on the development of environmentalindicators. These had to be adapted or completely new designed in order to match the specificcharacteristics of the mineral raw materials industry."

Jan 1, 2005

By Yingda Zhai

The range of interburden thickness between coal seams in Datong Mining District of China is large. From mining operation point of view, the closer is between the two seams, the greater is the impact from the upper seam when the lower seam is mined. This impact is most notable when the two seams are ultra-close. In this paper the definition of ultra-close seams and its practical method of determination are presented. Based on the difference in strata thickness in the interburden and the concept of "yield depth ratio" which is defined as the yield zone depth in the interburden to the total thickness of interburden, the roofs of the ultra-close multiple seams in the Datong District of China were divided into 3 types: (1) false roof or rock partings in coal seam. This type of roof does not require special handling except mining them simultaneously as one single seam. The roof thickness is slightly less than 0.5 m; (2) completely broken roof. In this type of roof, the yield depth ratio is larger than (or equal to) 1. When the roof thickness is larger than 0.5 m but less than 2.0 m, the yield depth ratio must be smaller than 1; and (3) fractured roof. In this type of roof, the yield depth ratio is less than 1 while the roof thickness is larger than 2.0 m. In retreat longwall mining, if the gateroads of the lower seam are located under the gob of upper seam, roof bolting can be used in the 3rd type of roof. But if the 2nd type roof exists, powered supports must be used.

Jan 1, 2005

By P. Srinivasan

Corrosion is a major operational problem in amine-treating plants causing significant expenditures each year, Corrosion may become more severe when the amine plants contain process contaminants ? namely heat-stable salts. The heat-stable salts enter the plants with feed-gas streams and makeup-solution, and/or are produced within the plants by reactions of alkanolamine and available carboxylic-acid anions, This work investigated interaction corrosion effects that may exist in amine-treating plants containing a mixture of heat-stable salts, The investigation was experimentally carried out in a 5 kmol/m3 monoethanolamine (MEA) solution containing 0,20 mol/mol carbon dioxide (CO2) loading at 80°C under atmospheric pressure using carbon steel 1018, Six heat-stable salts, including formate, oxalate, bicine, acetate, thiosulfate and chloride, were tested with a series of salt combinations, Potentiodynamic Polarization, Tafel Extrapolation, and Cyclic Polarization were used for revealing corrosion behavior, determining corrosion rate, and examining the pitting tendency, respectively, Results show that thiosulfate induces the most corrosive environment when present either individually or in the form of salt mixtures.

Jan 1, 2005

By J Petrolito

"To improve the economic and environmental performance of underground mining operations, it is common practice to return the metallurgical waste material underground as backfill. This is called hydraulic backfill and is used to fill the mined-out areas not exposed to further mining. To provide mechanical support for underground mining a cemented backfill is normally used. Since its introduction, cemented backfill has allowed mining companies to increase their ore extraction and improve working and environmental conditions. However, cemented backfill represents up to 50% to 85% of the mine’s operating cost compared with 5% to 10% for hydraulic backfill.These economic pressures have led mining companies to carry out research into the partial or total replacement of cement using a variety of alternative materials. The materials are generally site-specific materials, readily available, and cost-effective relative to cement. Such investigations have led to reduced cost of many backfill mixes while maintaining, and in some cases improving, the physical properties of cemented backfill. However, in most cases, cement still remains an integral part of any binder combination. This can be attributed to the alternative binders investigated being either non-binding materials or capable of generating only low-strength backfills, except when used in conjunction with cement.This paper provides a historical review of backfilling binder materials and their characteristics. In particular, it reviews the many alternative materials that have been proposed to either partially or fully replace Portland cement as the main binder."

Jan 1, 2005

In the UK during the 1990s the energy companies had developed a policy of æDash for GasÆ, building large natural gas power stations to produce more than 30 per cent of the UKÆs electricity demand. The price of imported thermal coal was dropping and the electricity generators were putting pressure on the UK coal producers to produce coal at a reduced cost. Imported coal from Columbia, South Africa, America and Australasia had increased their market share in thermal coal sales to over 50 per cent of a 55 Mtpa market. The pressure on the UK coal industry to reduce costs and improve productivity levels from an ever decreasing resource was high. Companies were benchmarking their operations on the imported coal producers and had to realign their organisations, productivity levels and costs to world best practice, not just technically, but in world class organisational management techniques.

Jan 1, 2005

By D. S. Salonine

Aluminum alloys are widely used in modern industry. Tubes and hollow shapes give great opportunities for structural purposes as well as fluid transport due to their stiffness and lightness, Extrusions on a mandrel or through a bridge die, that requires splitting of the billet with re-welding, produce hollow shapes with varied contours, fins and multiple cavities. Moving and stationary mandrels, mandrel lubrication, tooling for ribbed-tube heat exchangers, and for drilling pipes are considered. Bridge dies can be classified by the bridge position relative to the die face, by mandrel support structure, and by assembly type, The main parameters influencing the quality of the die-welded seams are considered, The difficulties of extruding various alloys through bridge dies are discussed in terms of metallurgical factors, Some approaches to the calculation of the stresses in a bridge are presented.

Jan 1, 2005

By H. Watari

In 1998, a voluntary agreement was reached between the European Commission and the European Car Manufacturers Association (ACEA) to reduce average carbon dioxide emissions of new cars to 25% below 1995 levels by 2008, Agreements have also been reached between the European Commission and the Japanese Automobile Manufacturers Association (JAMA) and the Korean Automobile Manufacturers Association (KAMA), However, the target average of carbon dioxide emissions of less than 140g/km in 2008 is a very challenging goal, Therefore, total product weight reduction is an objective for many manufacturers, This can be achieved utilizing materials possessing high strength and low weight, One material that has recently attracted interest is magnesium alloys, The magnesium alloys are expected to play an important role as next-generation materials, which have possibilities of contributing to lighten the total product weight when magnesium products can be used to replace aluminum and mild steel products.

Jan 1, 2005

By S. Asokan, D. Rathod, Ch. V. G. K. Murty

Tata Steel, a steel arm of Tata Group, is Asia's first and India's largest integrated private sector steel company. Tata Steel’s turnover in fiscal 2004-05 was nearly US$ 3.25 billion. As part of its vision to grow in related industries, Tata Steel is poised to enter the Titania businesses in the Indian state of Tamil Nadu. The Titania project will involve mining, separation of ilmenite & other co-minerals, beneficiation of ilmenite to synthetic Rutile and further maximum value addition to Titanium metal. This paper outlines the journey from the concept to current findings of the Bankable Feasibility Study in developing Sattankulam Heavy Mineral Sands Deposits in the State of Tamil Nadu, India by Tata Steel.

Jan 1, 2005

By P. Christmann

"In June or July 2005, the European Commission will present its Thematic Strategy on the Sustainable Use of Natural Resources proposal to the Council and European Parliament, one of the seven Thematic Strategies to be developed and implemented under the 6th European Environment Action Programme in support of the European Union’s Sustainable Development Strategy defined by the European Union’s Head of State at the Göteborg European Council, in June 2001. The time scale for this Thematic Strategy is 25 years (2005-2030). This paper discusses some of the key issues related to the EU minerals and metals industry that needs to be addressed by the Strategy. These are: - the need for access to mineral reserves in the EU and abroad; - the need to strenghten the capacity of developing countries to sustainably promote and regulate the use of their mineral potential; - the need for an EU mineral resources intelligence capacity. There are additional important needs, which are not discussed in this paper, such as: - the need to foster further innovation in mining, ore beneficiation and metallurgical technologies; - the need to integrate and simplify the exisitng complex regulatory framework applicable to the EU mining industry and to effectively implement existing legislation."

Jan 1, 2005

By Mayank Srivastava, Satya Harpalani

Production of methane is an inevitable consequence of mining coal. Although the number of mines practicing recovery of methane prior to, or during, coal mining is increasing, ventilation air methane (VAM) is still a significant source of methane addition in to atmosphere. Recent studies have shown that there are ways to recover the VAM energy, while simultaneously reducing the methane emission in to atmosphere. This paper discusses a case study, currently underway, to develop a technique to quantify the VAM emission from a mine. It also presents the different VAM utilization techniques and the suitability of one for the mine being studied. Finally, the paper summarizes the research issues that require further investigation.

Jan 1, 2005

By C. Srinivasan

Microseismic emissions are generated by deformation and cracking of rock around an opening inside a mine. The rock tends to achieve equilibrium in a new geometry under changing stress conditions was found to provide useful clues to the impending roof falls and ground instability. The typical characteristics of these microseismic event patterns is shown to be of diagnostic value in sensing in advance rook fall that invariably follow such events. In most of the longwall faces, the main problem faced was due to strata behavior in the presence of massive sandstone bed, which is generally difficult to cave. Microseismic monitoring system was used to monitor strata behavior during longwall mining operation at Rajendra underground coal mine of South Eastern Coal Fields limited (SECL). More than 44,000 microseismic events with local magnitude between -3.4 and 0.5 were recorded during the monitoring period from September, 2001 to March 2003. Analysis of these events was correlated with respect to roof falls. The time series of range of source parameters such as Radiated energy, seismic moment, Energy Index, Seismic Schmidt number, time of occurrence and location of fractures before and during roof fall exhibit qualitatively distinct patterns about six hours before roof falls. &ong the several seismic parameters investigated the microseismic event rate as precursor was found to be most significant indicator of an impending roof fall. The results are discussed as case study in this paper.

Jan 1, 2005

A major new mine to be developed at Pike River during 2005 has been designed to have a minimal impact upon the environment, and an overall net conservation gain. The Pike River Coalfield is located on the West Coast of the South Island of New Zealand on the top of the Paparoa Range approximately 46 km north east of the coastal town of Greymouth. Pike River Coal Company Ltd (PRCC) holds a 40 year mining permit over the coalfield.   In October 2004, the Minister of Conservation granted PRCC access through 1.25 km of Department of Conservation land via an access agreement, and the Environment Court issued a number of consents for the development and operation of the mine, in addition to some existing consents.   The underground mine at Pike River is located under land administered by Department of Conservation, and has been designed to avoid or mitigate adverse environmental effects and integrate into the natural bush surroundings. The mine process has been designed to operate within an environmentally sensitive area and will incorporate technologically advanced methods of mining and processing. The mine process involves hydro mining of the coal, and transportation via a 12 km coal water slurry pipeline, to a dewatering complex located on PRCC land. This will ensure that traffic in the Pike River Catchment up to the mine is minimised.   An extensive series of management plans and monitoring programmes will be used to ensure that the environmental effects of the mine activities are minimised, by evaluating the performance of managerial procedures, and physical mechanisms in place to avoid or mitigate the effects. Trial mining and substance management plans in conjunction with an orthophoto and surface monitoring protocol will ensure that surface features, and water ways are protected from any adverse effects. The Blue Duck enhancement, and pest and predator control programme will help ensure that an overall net conservation gain is achieved.   Developing transparent working relationships and good communication with Department of Conservation, Iwi (Ngati Waewae and Ngai Tahu), and local environment groups has been and remains very important in the development of this project.

Jan 1, 2005

By Dana C. Reinke

A job analysis is a written list of the tasks associated with doing a particular job. In drilling, describing the steps associated with adding rod to the drill steel would be an example of a task associated with the job. How to hammer casing or fish a lost drill bit out of a hole would also be job tasks. Develop a written list of job tasks. Ask drillers in your company if the tasks listed are correct and accurately reflect how to perform the job. While each driller may do the job a little differently, some tried?and?true methods are required to perform certain tasks safely and correctly. You may find a separate analysis is needed for different drilling jobs (e.g., a residential well or a monitoring well). Also remember to include the tasks of both the helper and the driller.

Jan 1, 2005

By M. Pantazidou

Motivated by recent EU legislation already entered into force or in preparation, this article aims at offering glimpses of the future landscape in the area of subsurface protection against contamination from point sources. Towards this end, it discusses the most salient parts of legislation for the protection of water resources. It then presents results from the wide consultation rounds organized by the European Commission in order to both receive input and help make all opinions heard on the issue of soil protection. Finally, it introduces key provisions of the recent legislation on environmental liability. From the above pieces of legislation, this paper highlights the elements that concern specifically the protection of the subsurface against spills of hazardous wastes from point sources and the requirements for subsurface restoration.

Jan 1, 2005

By C. James, J. Siefke, D. Shumway

The Mojave Desert is a particularly fragile ecosystem that faces several significant impacts. These include rapid housing development, overdrafted water supplies, and loss of wildlife habitat as a result of mining, industrial activity and urban sprawl. Over the past three years, a diverse group of educators, natural resource managers and business leaders has been assembled under the auspices of a local college to provide unique natural resource education opportunities for the region. By leveraging the collective experience of these present generation natural resource professionals, the Mojave Sustainability Project hopes to provide the next generation of professionals with that knowledge and those technical skills upon which tomorrow’s community can rely. This paper is a case study of how partnerships between academia, government, industry and the community can serve to address the regional social, environmental, and economic needs of today, while investing in the development of those professionals who will balance these needs tomorrow.

Jan 1, 2005

By Joseph Haid, om, Rio Yang, Kelly Fleetwood

Some coal mining operations in the Powder River Basin are currently observing a number of blast holes detonating sympathetically within their cast blasts. Sympathetic detonation can cause poor cast results, high blast vibration levels, excessive back break and fly rock, along with a number of other undesirable blast results. The reduction or the total elimination of blast hole sympathetic detonation is of paramount importance to the coal mining companies operating in the Powder River Basin. This paper describes a systematic approach to prevent cast blast holes from detonating sympathetically through the use of the electronic initiation and expanded blast patterns. In-situ measurements outlined in this paper were recorded from pressure probes, velocity of detonation probes and near field accelerometers, along with digital images generated from a high speed CCD camera. Large diameter angled drill holes were also checked for any measurable amount of deviation by a cable type borehole measurement tool. The field measurements provided the scientific evidence, statistical data, and documentation necessary to develop a sound method or a “road map” that would minimize and in some situations prevent the occurrence of blast hole sympathetic detonation.

Jan 1, 2005

By S. Qian

Galvanic corrosion is a potentially major concern associated with the application of stainless steel reinforcement which is in direct (electrical) contact with carbon steel reinforcement in concrete structures. Judicious use of stainless steel rebar in both new construction and rehabilitation of older structures is a viable, cost-effective option for extending service life and reducing maintenance costs. Questions, however, had arisen about the possibility of increased corrosion due to galvanic effects. This paper investigates the galvanic-coupling behaviours of three different types of stainless steel and carbon steel. Tests were performed both in electrochemical cells and with specimens in concrete inside an environmental chamber. The results show that oxygen reduction on stainless steel is the rate-determining factor for galvanic coupling of these two metals. It is much lower than that of passive carbon steel. As a result, the galvanic coupling of stainless steel with carbon steel will not increase the risk of corrosion of carbon steel reinforcement.

Jan 1, 2005