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By M. D. Max, A. H. Johnson

INTRODUCTION Gas hydrates have considerable potential to be a major energy resource owing to their apparent abundance in Arctic regions and along continental margins throughout the world (Kvenvolden, 1988). Yet, the oil and gas industry has been slow to pursue this opportunity. The primary reasons for this are the large conventional reserve base for natural gas worldwide and the perception that gas hydrate will not be a viable resource for another twenty or thirty years. Gas hydrates are thus viewed as a potential resource for the distant future, but not a valid investment for the near term. This paper addresses both global gas markets and gas hydrate technology, and shows that the commercial development of gas hydrate could proceed rapidly enough to constitute a near-term energy resource. GLOBAL GAS MARKETS The proven worldwide reserves of conventional natural gas are truly enormous, totaling over 6,000 TCF according to BP (2004). Moreover, those reserves have nearly doubled during the past two decades and now represent 67 years of consumption at the current production rates of 80 TCF per year (Fig. 1). This reserve increase has occurred even as global production of natural gas has increased by 67% during the same two decades (Fig. 2). While declining conventional gas reserves are a concern in North America, especially in regions where established infrastructure exists to bring gas to consumers, large new discoveries continue to be made elsewhere in the world. Indeed, in many parts of the world (such as the Middle East and parts of West Africa), natural gas has been regarded as an essentially worthless byproduct of oil production or exists in stranded gas fields. Given this situation, pursuing unconventional gas resources that are inherently riskier exploration targets and more expensive to produce would appear to have little rationale from a business standpoint.

Jan 1, 2006

By Hong Yong Sohn

On the occasion of this symposium in my name, I reflect upon the contributions of my academic mentors and early associates who helped shape my professional career. I was fortunate to have these people around me during my graduate work and at the start of my professional career. In forming my view of the technical field and career, they represented academia, research institutions, industry, and different parts of the world.

Jan 1, 2006

By P. Personnet, D. Wheaton, E. Couzinie, V. Demetriou, Brooks. W., G. Girault, M. Meyer, L. Charbonnel

A common problem in Gas Treatment Centers (GTC) from primary aluminium smelters is the temperature of the gas to be treated : above a threshold, filtering media are irreversibly damaged. The traditional way of dealing with high gas temperature is to dilute with fresh air, which implies over sizing - and therefore higher cost for - the GTC in order to have the capacity to treat this dilution air without compromising on pot suction. A system was developed which decreases gas temperature without having to use dilution air. This system is based on water pulverization in gas collectors. The water vaporization leads to a temperature decrease of the gas. A pilot system was trialed in our R&D unit. Satisfactory results led to the development of an industrial system based on Envirocare equipment (partnership), which was trialed in our production plant in Tomago (NSW, Australia). This patented system was then generalized in this plant, which is now using it with success during austral summer.

Jan 1, 2006

By R. C. Freas

Limestone is a basic raw material in the production of cement, lime, a wide variety of industrial products, and a significant percentage of the crushed stone produced in the United States annually. It is used in fluxes, glass making, mineral fillers, environmental applications such as flue gas desulphurization and water treatment, soil conditioners, animal feeds, and as a construction aggregate. This presentation provides an overview of limestone distribution in the United States, it’s production, the variety of products produced, and a brief review of the primary uses for limestone.

Jan 1, 2006

By Jeong-Hwan Kim

The liquid-liquid reactive process (solution process) is often adopted as a synthetic method for precipitated calcium carbonate (PCC) in laboratory studies for its simplicity in operation or ease in controlling process variables. Still, PCC are produced commercially by passing carbon dioxide through a milk of lime, i.e., by a gas-liquid reacting method (carbonation process). Few studies on the carbonation process have been conducted, since the process variables are interrelated and difficult to control compared to the solution process. In this study, both carbonation and solution processes were employed to study the polymorphs of calcium carbonate and growth rate of PCC crystals. The effects of the characteristics of limestone ores as a raw material in the synthetic system of PCC on the synthetic characteristics of PCC were also investigated. To control the nucleation rate in the synthetic systems, the shape factor was considered most important. Single-phase aragonite PCC could be synthesized under a variety of controlled experimental conditions such as ionic strength, solution composition, concentrations of additive ions, and temperature.

Jan 1, 2006

By O Dahl, I M. Platten, E J. Sides

Many narrow-vein gold deposits are characterised by a high to extreme nugget effect and the presence of coarse gold. They rank amongst the most difficult of deposits to produce an accurate and precise resource estimate. This contribution presents a case study from the Nalunaq Gold Mine in Southern Greenland. The mine commenced operation in May 2004 and is currently operating at a rate of 400 tonnes per day, to produce about 100 000 oz gold per annum from a total resource base of 1.2 Moz. Mineralisation is characterised by quartz veins that are hosted within a shear zone that is continuous over about 1000 m. The principal orebody is the Main Vein structure, which ranges up to 3 m in width, maintains an average dip of 35¦SE, and contains significant gold grades (1000s g/t Au). Gold particles are often visible, with 25 per cent being greater than 250 microns in size. Variography using underground development samples indicates a nugget effect of about 75 per cent. For the 2005 resource estimate, a 2D metal accumulation ordinary kriged block model was used to produce a global grade for the Target and South Blocks of the Main Vein. Grade control chip-channel samples are collected from æshantyÆ drive footwalls, and used as the basis for both the kriged block model and to determine the grade of individual stope blocks by peripheral weighted averages. Geology plays a key role in mining efficiency, given the locally variable nature of the ore zone.

Jan 1, 2006

By Tim O’Neil

The earthmover tire shortage has been a case of bust and boom for the tire industry. Tire producers were unwilling to invest ahead of the mining boom. In their defense, though, the metals sector of the mining industry tends to be cyclic, tire manufacturers are not prescient. Until two years ago, low tire demand depressed prices. The incentive to invest in new, big-tire capacity was almost nonexistent, according to Prashant Prabhu, president of Michelin Earthmover Tire worldwide. “There has been very poor anticipation or a miscaluation of the amplitude of the (tire) demand on the part of just about everybody,” said Prabhu. What a turnaround. The earthmover tire market has grown by 30 percent over the past two years. Now there are not enough earth-mover tires and likely won’t be for the next two years. Goodyear said it was offering customers bias-ply tires when it could not supply enough radial-ply tires. Komatsu said it lost equipment sales because it could not provide the tires that customers requested. Volvo and Caterpillar said they are delivering some vehicles without tires, either promising tires later or leaving the customers – mine operators – to find their own rubber.

Jan 1, 2006

By Hazoor Singh Sidhu

Materials degradation due to corrosion is the major problem in power generation equipment, gas turbine, fluidized bed combustion, industrial waste incinerators etc. Some super alloys have been developed, but they are unable to have different properties to meet the demand of today?s industry. Therefore, a composite system of a base material providing the necessary mechanical strength with a protective surface layer different in structure and/or chemical composition can be an optimum choice in combining material properties. Thermal spray coating of the components before they put into service by suitable surfacing alloy and with suitable coating method can increase the life of these components several fold. Choice of right coating method and alloy for a particular application is extremely important to get the desired service life. The corrosion of some materials and the role of HVOF thermal spray coatings to counteract the same have been reviewed, with an aim to understand the phenomena along with various applications.

Jan 1, 2006

By W. Beres, M. Bielawski

Recent research on the development of erosion resistant coatings has been directed to the finite element modelling of the behavior of coating and substrate, and their interface under the impact of eroding particles. The approach presented in this paper is based on advanced computer simulation techniques using ABAQUS/Explicit to investigate stress and strain at the surface and at the coating/substrate interface of multilayer coatings under single particle impact. It was found previously that solid particle erosion mechanisms are predominantly governed by the kinetic energy of the impacting particles. However, recent modelling efforts revealed that effects of various material models could be also significant. Therefore, different material models representing relevant coating and substrate properties were investigated and the effects of these models on the coating/substrate response were studied. Particularly, differences between elastic, elastic-plastic and brittle cracking model responses were assessed.

Jan 1, 2006

By Xiaowen Liu

The DSC/TG, IR and XRD analysis were used to characterize the heating phase transformation of illite, which came from Ouhai deposit, China. It was discovered that the dehydration and de-hydroxylation of illite carried out stage by stage during heating. The adsorptive water and layer-inter water were dehydrated from room temperature to 500°C; and dehydroxylated in the range 500°C~800°C. In these stages of process, illite?s layer structure kept almost unchanged. After 800°Cillite began to change into disorder structure. At about 1100°C, the layer structure of illite had been destroyed, and amorphous SiO2 and mullite crystallite appeared. At about 1200°C the structure of illite completely destroyed and mullite crystal phase had become perfect..

Jan 1, 2006

By Wenquan Zhang

Based on the mining and geological conditions of Wadong Mine, Longkou City, Shandong Province, China, a viscoelastic model with proper creep parameters was established. The 3-D ANSYS was used to simulate surface subsidence, analyze overburden subsidence characteristics, and propose the rational mining and pillar widths for mining in weak rocks and under special mining conditions, and provide the policy makers scientific data for decision making on mining activities.

Jan 1, 2006

By H. Nan

Using the case of Qianqiu Mine, Yima Coal Mining Administration, theoretical analysis, laboratory physical simulation, and underground observation were performed to study the major parameters for fully mechanized sublevel caving mining method, including drawing spacing, drawing sequence, drawing numbers, and number of shields performing simultaneous drawing. The effects of those parameters on coal recovery and amount of waste rocks were also investigated. The optimal coal drawing technology for this case was obtained.

Jan 1, 2006

By K. Ronald Chapman, Claus Ludwig, Doug Jenevein

"In the spring of 2005 Schnabel Foundation Company completed a $15.2 million Design/Build subcontract to underpin 11 structures, and provide 202,800 square feet of earth retention for the Reno Transportation Rail Access Corridor (ReTRAC) project in Reno, Nevada. Schnabel’s work was part of a Design/Build contract to depress a railroad alignment through downtown Reno. The depressed section was 2.2 miles long, 54 ft wide, and up to 35 ft deep (3.5 km long, 16.5m wide and up to 10.7m deep). The trench structure was required to be watertight. SUBCONTRACT WORK OVERVIEWEleven buildings along the track alignment required underpinning. Three types of underpinning were used, designated Type 1, Type 2 and Type 3.At four buildings the trench retaining walls were to be located directly under the exterior footings. This alignment eliminated traditional underpinning and cut-off wall techniques that could normally be used to support structures. Type 1 underpinning was used at these buildings. This underpinning system consisted of a combination of permeation grouting, hand-dug piers, and permanent tiebacks. This underpinning system became the new watertight trench walls.Five buildings were located a few feet behind the trench walls, and their exterior walls were supported by continuous footings. Type 2 micropile/pile cap underpinning (patent pending) was used to support these buildings.The remaining two buildings were also located a few feet behind the trench walls, but they had column footings along the exterior walls. At these structures traditional micropile underpinning was provided through the existing footings. This is described as Type 3 underpinning.Temporary earth retention was required on both sides of the trench along most of the alignment. This shoring supported frontage roads, private property and surcharge from the temporary railroad shoofly running parallel to one side of the trench.SUBSURFACE CONDITIONSThe soil along the trench alignment consisted of river outwash deposits. The top 2 to 18 feet (0.6m to 5.5m) generally consisted of flood plain silt and sand deposits, or fine-grained fills. These fine-grained soils are underlain by the Tahoe Outwash Formation which consists of interbedded layers of sand; sand and gravel; and sand, gravel, cobbles and boulders. Some of these layers encountered during construction consisted of 30 to 50 percent cobbles and boulders, with some boulders up to eight feet in diameter.A major challenge to the design and construction of the trench structures and the underpinning was the ground water table which was 10 feet (3m) above subgrade in the deepest portions of the trench. Based on specification restrictions, temporary and permanent dewatering was not feasible. As a result, the selected design and construction methods had to consider three water conditions: the anticipated groundwater level during construction (CGW), the groundwater level for permanent design (DGW), and an additional special design condition with water at street grade."

Jan 1, 2006

By Thomas M. Brady

The Spokane Research Laboratory/NIOSH and the University of British Columbia (UBC) geomechanics group are focusing on the development of safe and cost-effective underground design guidelines for weak rock masses having an RMR in the range of 15 to 45. Weak ground conditions, ground support, and mining methods used in several North American underground mines were observed. The RMR values were calculated to update both manned entry span design and non-entry stability graphs, plus a database on underhand mining methods was created to reflect existing North American mining conditions. The immediate rock mass was characterized and analyzed in terms of prevailing type of ground support, potential failure mechanisms, and rock behavior to define how existing design curves must be modified for the existing weak rock mass. The current NIOSH research attempts to provide rock mechanics tools to assist a mine operator in making sound economic decisions that will also ensure a safe working environment.

Jan 1, 2006

By Alex Moyano

At present, the Codelco Norte smelter processes in the Teniente Converter and the Flash smelting Furnace 1,420,000 t/y of its Chuquicamata concentrate with an arsenic content of up to 1.5%. In a near future Codelco-Chile is considering different processing options for a new projected concentrates from the Alejandro Hales mine (former Mansa Mina mine with an arsenic content of up to 6%). The main option is the possibility to process 3,000 t/d of mixing concentrates from the Alejandro Hales and the Chuquicamata mines, in the Teniente Converter. The main feature of this smelting unit will be high volatilization of arsenic when processing high arsenic-bearing concentrates. The CN smelter staff carried out a technical feasibility study to evaluate the processing of high arsenic-bearing concentrates directly in the Teniente Converter, thus the low arsenic-bearing concentrates can be processed in the FSF. Accordingly, laboratory scale tests were carried out at the Tohoku University facilities. The lab-scale results allowed an industrial scale test at the Codelco Norte smelter to smelt 2,300 tpd of high arsenic-bearing concentrates in the TC and evaluate the metallurgical impact in the smelting, converting and refining areas of the smelter. The main industrial-scale result confirmed the stabilization of the arsenic content at 0.5% in the 70% Cu produced white metal at the test condition.

Jan 1, 2006

By S. Ubaldini

Acid mine drainage (AMD) is a common problem in different areas with a past history of mining activities, which is characterized by low pH (2-4.5) and significant toxic metals concentration. The main aim of the present work was to perform a process feasibility analysis in order to remove heavy metals (Cd, Zn, Ni, Mn, Cu) from AMD (Acid Mine Drainage) in a relatively cheap and environmentally friendly way, by means of electrowinning and biosorption. A first characterization of an Italian AMD sample was performed evidencing a zinc concentration around 2 g/L, cadmium and nickel content of about 4 mg/L, manganese of 85 mg/L and iron 190 mg/L. Electrowinning tests lead to the following metal removal after three hours treatment: Zn 99%, Ni 99.9%, Cd 99.9%, Cu 99%, Mn 87%, Fe 96%. Moreover, an high grade of purity of the metal deposit has been achieved (Zn>95%), as observed by X-ray diffraction analysis. Considering that metals concentration in the effluent was still above legal limits (in particular for Zn, Mn and Fe), a further biosorption treatment was planned in order to produce an effluent fitting environmental limits. Experimental electrowinning tests and literature multimetal column biosorption data have been used in order to perform a preliminary techno-economic feasibility analysis of the process aimed at metal removal from AMD. A treatment cost of about 6.5 ?/m3 AMD has been estimated, for a plant capacity of 10 m3/h AMD inlet flow rate.

Jan 1, 2006

By Dale Preece

A carefully designed and controlled in-place destruction experiment was performed on a concrete bunker buried in 4.27 m (14 ft.) of soil. The objective was to determine if the explosive charges would collapse the structure in-place without requiring mechanical excavation. Collapse of the buried structure was first attempted by drilling holes in the soil and placing four 13.38 Kg (29.5 lb) Comp B explosive charges at a depth of 2.13 m (6.7 ft.). The configuration of the charges when detonated was 2.13 m (6.7 ft.) off the top of the concrete roof and 3.66 m (12 ft.) apart in a square pattern. Detonation of these charges created a crater ~4.88 m (16 ft.) in diameter and 2.13 m (6.7 ft.) deep, leaving ~2.13 m (6.7 ft.) of soil covering. Very limited spalling occurred on the ceiling of the concrete structure as a result of detonating these four charges. The second attempt to collapse the structure consisted of placing another single 13.38 Kg (29.5 lb) charge, identical to the first four, near the geometrical center of the bunker roof. This charge was detonated in the soil cover 100 to 200 mm (4 to 8 in.) above the reinforced concrete roof, collapsing it. Due to the collapsed roof and remaining soil cover, the structure had been collapsed in place, requiring no further demolition.

Jan 1, 2006

By J de Vries

Arthur Page, a past President of AT&T said:All businesses in a democratic society begin with public permission, and exist by public approval. Product stewardship in its most basic form is simply risk management applied to the products we produce. Conceptually it may be considered as a more expansive approach to many existing safety, heath and environmental programs. Key differences include the extension of responsibility beyond the direct control of management, and consideration of the implications your products and processes have on the broader community, as opposed to the confines of an individual mine site or operation. This paper reviews the processes used by Orica Ltd to manage its product stewardship program. OricaÆs product stewardship program is expansive and supports activities and business that range from manufacture and delivery of commercial explosives and sodium cyanide to mines throughout the world, supply and operation of municipal water facilities, and manufacture and distribution of consumer products such as household paints and adhesives. We highlight the development of the program through experience both good and bad, and by use of case studies to illustrate how an active product stewardship program is an effective business risk mitigation strategy.

Jan 1, 2006

By Kenneth L. Cashdollar

The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) and the Mine Safety and Health Administration (MSHA) conducted joint research on dust explosions by studying post-explosion dust samples. The samples were collected after full-scale explosions at the PRL Lake Lynn Experimental Mine and after laboratory explosions in the PRL 20-L chamber and the Fike 1-m3 chamber. The dusts studied included both high and low volatile bituminous coals. Low temperature ashing for 24 hr at 515°C was used to measure the incombustible content of the dust before and after the explosions. The data showed that the post-explosion incombustible content was always as high as or higher than the initial incombustible content. The MSHA alcohol coking test-was used to determine the amount of coked dust in the post-explosion samples. The results showed that almost all coal dust that was suspended within the explosion flame produced significant amounts of coke. Measurements of floor dust concentrations after LLEM explosions were compared to the initial dust loadings to determine the transport distance of dust during an explosion. All of these data will be useful in future forensic investigations of accidental dust explosions in coal mines or elsewhere. Disclaimer: The findings and conclusions in this report are those of the authors and do not necessarily represent the views of the National Institute for Occupational Safety and Health or the Mine Safety and Health Administration.

Jan 1, 2006

By B Hall

The authors have undertaken many independent mine optimisation and operational improvement projects at Australian and international mining operations over the past decade. This work has provided an understanding of the underlying practices responsible for the good long-term performance of some operations, and the failure of others to achieve their objectives. Good long-term performance, and value creation can be achieved through a logical and rigorous process of identifying the optimal mine plan (æThe PlanÆ) that delivers the corporate goals, establishing appropriate performance measures that are aligned with these goals, and ongoing monitoring of compliance with the established targets to ensure the operation reliably achieves The Plan. A number of practical methods have been developed and implemented to assist mining operations deliver their corporate goals. This paper outlines some of these methods, providing some fundamental guidelines that will assist in the establishment, and reliable achievement of The Plan that delivers the corporate goals.

Jan 1, 2006