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By C. T. Yavuz

Higher environmental standards have made the removal of arsenic from water an important problem for environmental engineering. Iron oxide is a particularly interesting sorbent to consider for this application. Its magnetic properties allow relatively routine dispersal and recovery of the adsorbent into and from groundwater or industrial processing facilities; in addition, iron oxide has strong and specific interactions with both As(III) and As(V). Finally, this material can be produced with nanoscale dimensions which enhance both its capacity and removal. The objective of this study was to evaluate the potential arsenic adsorption by nanoscale iron oxides, specifically magnetite (Fe3O4) nanoparticles. We focused on the effect of magnetite particle size on the adsorption and desorption behavior of As(III) and As(V). The results show that the nanoparticle size has a dramatic effect on the adsorption and desorption of arsenic. As particle size is decreased from 300 nm to 12 nm the adsorption capacities for both As(III) and As(V) increase nearly 1000 times. Interestingly, this increase is more than expected from simple considerations of surface area and suggest that nanoscale iron oxide materials sorb arsenic through different means than bulk systems. The desorption process however, exhibits some hysteresis with the effect becoming more pronounced with small nanoparticles. This hysteresis most likely results from a higher arsenic affinity for magnetite nanoparticles. This work suggests that magnetite nanocrystals and magnetic separations offer a promising method for arsenic removal.

Jan 1, 2006

By T. Sakai

Present authors have succeeded in single pass large draught rolling of AZ31 and ZK60A magnesium alloy sheets below 200 °C without heating rolls by raising rolling speed above 1000 m/min. Heavy reduction larger than 60% can be applied by single pass high speed rolling even at room temperature. The rolled sheets showed fine recrystallized microstructure by dynamic recrystallization. The improvement of workability at lower rolling temperature is due to temperature rise by plastic working. In high speed rolling, almost all of the work done by plastic deformation is converted into the heat that raises the temperature of the sheet during rolling because the heat did not flow out of the sheet by conduction and radiation within very short time.

Jan 1, 2006

By M. Medraj, M. A. Arafin, D. P. Turner, P. Bocher

In this study, the kinetics of isothermal solidification during TLP bonding of Inconel 625 and 718 superalloys with nickel based multi-component filler alloy BNi-2 have been studied through a combination of direct experimentation and mathematical modeling in order to determine the effect of process variables and, thus, to optimize the process. The predicted isothermal solidification completion times from the boron diffusion model and migrating solid/liquid interface model were in good agreement with the experimentally determined values and, they were found to be significantly less than those of other nickel superalloys with different nickel based filler alloys. Further, significant reduction of holding time was observed with increasing bonding temperature and with decreasing joint gap. No significant grain growth in the base metals has been observed in the temperature range being investigated (1325 - 1394K).

Jan 1, 2006

By Xie Gang

The leaching experiment used by bacteria on the low grade sulfide copper ore which is difficult to leach was carried out. Some leaching bacteria which have good physiological and leaching activity were isolated and domesticated, and were adapted to leaching ore. The effective domesticated method was put forward. Some technological parameters such as ore acidification, potential controlling, leaching method, ore granularity, leaching acidity, leaching liquid quantity and acid consumption were obtained by column experiment and leaching ore in situ under the ore well. The results show it could leach 30.62% of copper from the low-grade sulfide copper ore within 24 weeks by column leaching method, and the bioleaching rate of copper is 22.83% by leaching in situ under the ore well in 8 months.

Jan 1, 2006

By R. P. Kofluk

The nickel-cobalt sulphides produced from limonitic laterite ores by Moa Nickel S.A. in Cuba are refined at the Corefco nickel-cobalt refinery in Canada. Significant economic implications are associated with the refining of precipitated sulphides containing elevated iron contents. The Moa Nickel S.A. operations encompass laterite mining, high pressure acid leaching (H PAL), and ultimately, precipitation of a mixed sulphide product. These processes are reviewed as they pertain to the control of iron and the formation of a mixed sulphide containing nominally 55% Ni, 5% Co and 1% Fe. The contributors to the iron content of the mixed sulphide product are reviewed; the major contributors are the HPAL operation and sulphide precipitation. The precipitation of iron during sulphide precipitation is influenced by the solution acidity, the iron and copper concentrations in the feed solution, and the presence of laterite leach solids. The significance of the copper concentration of the sulphide precipitation solutions is manifested by both physical and chemical modifications of the sulphide precipitates, presumably through the formation of fine copper sulfide seed particles.

Jan 1, 2006

By Murray Johnston

New measurements have been made on the equilibrium distribution of selenium and tellurium between molten slag and metal phases. Distribution coefficients of Se and Te between magnesia-saturated calcium ferrite slag and copper or silver alloys were measured over the temperature range 1473 and 1673 K under controlled oxygen patrial pressures of 10-11 to 10-0.68atm. The results demonstrate that the minor elements are present in the calcium ferrite slag as the selenide (Se2-) and telluride (Te2-) respectively, up to a PO2 of 10-6 atm. As conditions become more oxidising, Te undergoes a transition to the divalent oxide whereas Se does not. Increasing the temperature was found to enhance partitioning of the minor elements to the slag. In terms of activities, at 1573 K, Se showed strong negative deviation from the ideal behaviour in the slag, while Te showed only slight positive deviation.

Jan 1, 2006

By E. M. Timoshenko

Autoclave technology can be effectively used for liberation of complex mineral raw materials to transfer valuable constituents into solution for their subsequent recovery or to refine feed material in order to remove deleterious impurities, e.g. arsenic. The high efficiency of autoclave processes is attributed to the fact that they are suitable for processing of refractory raw materials, have low capital costs, high productivity, ensure integrated utilization of the feed materials, produce innovative saleable products, completely eliminate any air emissions, provide low-waste or waste-less technology, mechanization and automation of production processes. In the immediate future, it might be expected that autoclave processes will find use on commercial scale for production of heavy non-ferrous metals in combination with other processes (hydrometallurgical, upgrading, sorption and solvent extraction, electrolytic, etc.) to ensure: - Integrated processing of refractory ores and concentrates (pyrrhotite, zinc, copper-zinc, lead-zinc, nickel-cobalt, copper, pyrite); - Production of metallic powders of base metals as commercial products (copper, cobalt, nickel, etc.), composites on their bases, final products and saleable salts. Processing technologies incorporating autoclave processes, especially at the stage of liberation (chemical upgrading) of raw materials are characterized generally by high overall recoveries of valuable constituents significantly exceeding recoveries common for conventional pyrometallurgical processes (for some elements by several tens of percent).

Jan 1, 2006

By Chuan-fu Zhang

The fibrous precursor can be obtained by coordination precipitation process, using oxalate, cobalt chloride and ammonia. XRD pattern of precursor precipitated at pH=9.0 is different from that of ß-CoC2O4?2H2O precipitated at pH=1.0 which indicates that the precursor powders are one type of cobalt complex. According to the results of element analysis and IR spectra, it can be inferred that the composition of the precursor is [Co(NH3)x]C2O4?H2O(x=1.2?..6) formed by the coordination reaction at pH=9.00 in the Co(II)-C2O42--NH3-NH4+-H2O system. It?s found that the fibrous cobalt powders greatly inherited the morphologies of the precursors. Many factors could affect the formation of the fibrous cobalt precursor powders, such as the initial Co2+concentration, pH value and so on. The SEM images show how they influence the morphologies of the precursor powders. By adding proper surfactant, the dispersion of the precursor powders would be improved. At last, the final product-fibrous cobalt powders which are about 0.3~0.5min size and 40~60 in aspect ratio were produced by thermal decomposition of fibrous cobalt complex at 400~500°C in the weak reducing atmosphere.

Jan 1, 2006

By H A. Myburgh

The beneficiation of heavy metal oxides, such as iron ore, is usually performed with heavy medium separation in cyclones, static baths and lately with Larcodems. Atomized ferrosilicon is most suitable as a heavy medium at densities above 3600 kg/m3 whereas a mixture of milled and atomized ferrosilicon is suitable at densities below 3600 kg/m3. When operating a beneficiation plant at densities higher than 3600 kg/m3 the quality of the ferrosilicon particles is an important factor that influences the control of the beneficiation process. Therefore, it is important to know how the rheology would be affected by the ferrosilicon quality as it also influences the control of the process at these elevated densities. Background The Kumba Resources Sishen Iron Ore Mine in South Africa produces 26.5 Mt iron ore per annum from its beneficiation plant. The ore body consists mainly of laminated and massive type hematite ore that is crushed down to ?90mm before being beneficiated by means of a combination of Wemco drums, Larcodem and dense medium cyclone separators. The need for higher densities When the percentage of high-density gangue2 is higher than normal in the run-of-mine (ROM), a higher separation density is necessary to produce a product to specification. Certain ore types of this quality in the Sishen reserves require a separating density higher than 4000 kg/m3, whereas densities would normally average 3600 kg/m3 when beneficiating ores of normal high-density gangue content. Sink and float tests conducted on the ROM material at Sishen revealed some interesting characteristics. In the waste fraction, (density < 3600 kg/m3) it was found that the %Fe was <21% (Fig. 1). Similarly, for the product fraction (density >3000 kg/m3), the percentage Fe varied between 35% and 67.2%. The bulk of the material (88%) actually had a density greater than 4000 kg/m3 and a Fe content that varied between 63% and 67.2%. At a density interval of 3600 to 4000 kg/m3, the Fe content varied from 37% to 60% with an average of 45%.

Jan 1, 2006

By E. Ghali, B. Arsenault

Aluminum alloys play an important role in the manufacturing of air and ground vehicles. However, with such alloys, corrosion damage is often found on structural components subjected to fatigue loading. The alloying provides large benefit in terms of the high specific tensile strength (ultimate strength/density ratio) to the aluminum alloy but causes the aluminum alloy to be more sensitive to localized corrosion due to complex microscopic heterogeneities such as secondary phases. This paper investigates thermal spray coating namely arc spraying to evaluate the protection against environmentally assisted cracking (EAC) and localized corrosion on Aircraft structural 7075 T651 aluminum alloys. In particular, EAC and pitting corrosion at the interface coating-substrate are a challenge for thermal spray protective coatings on aluminum alloys under cyclic load and immersion. To address these issues, different surface preparation techniques prior to arc spraying were considered such as chemical de-oxidation, laser ablation, shot peening and grit blasting. Results indicate that surface preparation and improved coating process parameters play an important role to provide a coating conferring a protection against both localized corrosion and EAC.

Jan 1, 2006

By Steven D. Dapp

The use of base grouting (tip grouting) to enhance the axial capacity of drilled shaft foundations can achieve improvements in economy and reliability for many types of projects and soil profiles. Recent experiences on a range of different construction projects in the Southeastern U.S. illustrate the most attractive opportunities for utilizing this technique and some limitations of the method. The quality assurance provided by measurements obtained during post grouting the pile toe is another important aspect favoring its use; the base grouting is shown to identify weaker piles and provide a means of remediating some deficiencies so that increased foundation reliability is achieved. This paper provides an overview of the methods used to evaluate and design for base grouted shafts along with lessons learned from several case histories.

Jan 1, 2006

By Andrey Dmitriev

The solution of set of equations for the bottom zone presented by a condition of a thermodynamic equilibrium, namely, an equilibrium constant of wustite reduction by carbon oxide, material and thermal the balances, supplemented by the equation of the heat balance for the top zone, allows to calculate the base indices of blast furnace smelting. The calculated indices are extreme accessible at the given parameters of charge and blast. Application of actual degrees of the use of gas instead of equilibrium allows the calculations of actual indices of the blast furnace smelting process.

Jan 1, 2006

By H. Hejny

The minerals industry, comprising producers and users of industrial minerals and metals, aggregates and ornamental or dimensional stone, oil, gas and derivates as well as coal and by-products, provides vital inputs to Europe&apos;s economy and social well-being. Because of their great diversity, minerals and their derived products are necessary for almost every aspect of life. The European Technology Platform on Sustainable Mineral Resources (ETP SMR) unites hundreds stakeholders from industry, the re-search community, public authorities, the financial community, regulators, consumers and civil society around the major technological challenges to the sector, in order to jointly act towards a common vision. The Platform will contribute to strengthening one of the fundamental pillars of the European economy and society. The Strategic Research Agenda (SRA) of the ETP SMR is designed to act as a realistic and inspirational guide to defining a comprehensive research programme that will mobilise stake-holders and ensure that European competences are at the forefront of science & technology worldwide. It will help to stimulate investment in research and provide guidance for policy options. The SRA shows the way the mineral industry has to proceed in forthcoming decades if it is to serve European society in the way necessary. Without a strong European minerals industry, the future development of the EU economy risks to be curbed significantly.

Jan 1, 2006

By S. Frimpong

Cable shovel requires continuous monitoring through excavation to achieve reliability, longevity and economic usage. The operating environment and the stress and deformation fields on the front-end assembly must continually be monitored to avoid random fatigue failure. In this paper, the authors advance frontiers of cable shovel reliability through real-time stress and deformation monitoring during excavation. Cable shovel boom stress and deformation analysis are developed using a combination of flexible and rigid body approach. A virtual prototype is developed to simulate the cable shovel excavation in oil sands and to examine the motion, stress and local deformation of the boom. A numerical example is used examine cable shovel boom durability using stress and deformation fields simulation. The results show that stress and deformation are large around the joint between the upper body and the boom. The simulation of the effect of material properties on boom deformation shows that the deformation is larger in hard formation than in soft formation. The study provides a solid foundation for further study of failure life analysis of the cable shovel components.

Jan 1, 2006

By K R. Vining, T E. Norgate

A study was carried out to compare the environmental impacts of the two major iron ore agglomeration processes, sintering and pelletising, using life cycle assessment (LCA) methodology. The following agglomeration processing routes, with the fuel options shown, were investigated:sintering with combined natural gas/coke breeze or charcoal as fuel, grate-kiln pelletising with combined natural gas/coke breeze as fuel, and straight-grate pelletising with combined natural gas/coke breeze as fuel. Inventory data for each process derived from the literature, and in some instances supplemented by additional simulations and calculations, were used in the study and the environmental impact categories considered were gross energy requirement (GER), global warming potential (GWP) and acidification potential (AP). The results of the study showed that the GER, GWP and AP for a sinter plant are higher than those for a pellet plant for the same amount of metallic iron in the agglomerated products. These results are partly due to higher consumption of solid fuel and flux in the sintering process. However, it should be pointed out that the study only compared substantially fluxed sinters with acid pellets that may require additional flux (and hence potentially more greenhouse gases emissions) to be a balanced blast furnace feedstock. Extending the LCA to the blast furnace process stage was beyond the scope of the current study. Within the sinter plant, the sintering stage itself is the largest contributor to the GER, GWP and AP. In the case of pellet plant, the pellet induration stage is the largest contributor to the various environmental impacts. The GER and GWP of a straight-grate pellet plant are marginally higher than those of a grate-kiln pellet plant due to the higher electrical power required by the straight grate system. The substitution of coke breeze with charcoal in the sintering process results in an increase in GER but a decrease in GWP. However, a substantial proportion of the GER is derived from renewable sources (wood), resulting in a decrease in the non-renewable components of this environmental impact. Given the source of the inventory data and the assumptions and approximations made in carrying out the LCAs, it is emphasised that the results presented in this paper should be considered as indicative rather than as definitive results for the two iron ore agglomeration processing routes considered.

Jan 1, 2006

By Jung-Ah Kim

Precipitated Calcium Carbonate (PCC) is obtained through calcination, hydration, and carbonation. Thus, the change in each process condition determines the particle size or morphology of PCC. To date, studies on precipitated calcium carbonate have mainly focused on process manufacturing PCC, aimed matter. Still, few studies on calcination or hydration have been conducted. Therefore, this study sought to investigate the effect of hydration condition on the synthesis characteristics of aragonite PCC. Results showed that the particle size of calcium hydroxide changed based on the variation of the initial hydration temperature. In particular, higher initial temperature resulted in the larger particle size of calcium hydroxide used in synthesis. The particle size and yield of aragonite also increased when calcium hydroxide made at high temperature was used. The water/solid ratio or total amount at the hydration time had no effect on the manufacturing process of aragonite, however.

Jan 1, 2006

By Robert Thurner

The underground car park "Admonterhof in the historical centre of Graz is an example for the technical and economical success of a complicated structural design using a concept on the basis of the observational method. The intention to built a 20 m deep excavation beneath a protected monument was accompanied by some essential issues: the preservation of the existing state avoiding extensive displacements by means of a girder grid of reinforced concrete, its support on large bored piles and small steel-tube piles with possible active compensation of differential settlements, the excavation support in none built-up areas with secant bored piles, the underpinning of existing buildings with different structures by means of jet grouting. Furthermore the hydraulic gradient and the permeability of a rock formation in a part of the excavation had to be explored with the purpose to control the inflow of groundwater with a level difference of more than 10 m.

Jan 1, 2006

By F. Sachanidis

The lignite surface mines of Ptolemais basin operate according to special environmental terms regarding the concentrations of heavy metals and trace elements in water discharges. Based ?n the results of lab analyses and in-situ measurements conducted so far it is concluded that the concentrations of heavy - toxic metals and other trace elements are low or negligible. The deviations from the upper concentration limits specified by laws and regulations are rare and non-systematic both on their spatial or temporal distribution. The same results prove also the relation between water quality and type and nature of the sediments forming the Ptolemais basin and the carbonated and metamorphic rocks forming the surrounding mountain areas.

Jan 1, 2006

By M Scott, J J. McEwan

Silver and silver alloys tarnish readily by the formation of tarnish on the surface when exposed to a wide range of sulphur-containing atmospheres. This tarnish is unsightly and undesirable and can be removed either with a silver polish or a chemical dip. Polishes are, however, not suitable for irregular and embossed surfaces such as on coins, medallions and jewellery items, because of uneven removal of the tarnish layer and excessive wear. Successful tarnish protection can be achieved by either storing the items away from the aggressive atmosphere or by coating/treating the exposed surfaces with a protective layer. Storage is feasible for collections but is not suitable for items that are handled or worn regularly, such as jewellery. A number of commercial coatings and treatments have been developed, but to date there has not been a systematic evaluation of tarnish protection. This paper details the performance of a range of generic coatings in an accelerated tarnish test. The degree of tarnish was evaluated by means of loss in reflectivity and change in colour. Four coatings/treatments improved the tarnish resistance of silver by more than tenfold. These include an organic lacquer, rhodium electroplating and an organic self-assembled monolayer (SAM) conversion coating. Research is continuing to optimise these coatings. Keywords: silver alloys, tarnish resistant coatings, silver polishes.

Jan 1, 2006

By Carl Havemann

[PAPER PRESENTED AT THE 8thINTERNATIONAL CORROSION CONFERENCE HELD AT THE SA NATIONAL MUSEUM OF MILITARY HISTORY, SAXONWOLD JOHANNESBURG DURING 14-15 NOVEMBER, 2006.]

Jan 1, 2006