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By Leonard J. Friedman

The recovery of sulfur dioxide from metallurgical gases for the production of sulfuric acid has been an effective means of reducing sulfur dioxide emissions from non-ferrous smelters. Sulfuric acid has been produced from gas originating from fluid bed roasters, electric furnaces, reverberatory furnaces, flash smelting furnaces, Pierce Smith and flash converters, sinter machines, etc. The gas from each of these sources has a unique set of variables that affect the design and operation of the sulfuric acid plant. In addition, the sulfuric acid plant itself has been evolving, with new equipment designs and materials. This paper will review each of the unit operations in the gas cleaning and contact sections of the metallurgical sulfuric acid plant, discussing various equipment designs, materials and the handling of gas stream variables and impurities. The paper updates to 2006 previous works on metallurgical sulfuric acid plants by the authors.

Jan 1, 2006

By J. Fujioka, Y. F. Gu, C. Cui, D. Ping, A. Sato, H. Harada

"A new kind of cast & wrought (C&W) Ni-Co base superalloys named as ""TMW alloys"" are developed recently for compressor or turbine disks of gas turbine engines in High Temperature Materials 21 Project at National Institute for Materials Science (NIMS) in Japan. These Ni-Co base superalloys combine the characters of two kinds of y- y' two-phase alloys (Ni-base and Co-18at%Ti alloys) and have higher tensile strength and creep resistance than C&W UNDIMET 720Li superalloy."

Jan 1, 2006

By H. Yavuz

Closed form solutions assume opening shape to be circular to simplify the calculation of the ground response curve for the design of underground openings. However, in mining and civil engineering works, non-circular openings are commonly excavated. Therefore, there is a need to estimate the ground response curve for such openings. In this respect, a simple model for circular, arch and rectangular shape underground openings subject to a hydrostatic stress field is the aim of this study. A comprehensive numerical modelling, using the finite difference method, based on numerical modelling code FLAC version 4.0, was carried out. In addition to shape of an opening, the effect of rock mass strength, opening size, in situ stress on strain (tunnel deformation to tunnel radius) of the opening in response to applied support pressures was investigated parametrically by developing models for each specific condition. The strain results for each excavation shape obtained from this large number of models against the normalized strength of rock mass and internal support pressure with in situ stress magnitude were evaluated by multiple regression analysis. As a result, a model that was well correlated to data was developed for an overall estimate of the ground response curve depending on relevant effecting parameters. The regression coefficients of the model were given for estimating both roof and sidewall response curve of each excavation shape. The model was verified by statistical tests and by an analytical solution. Diagrams were also established to highlight the influence of relevant parameters and to estimate the support pressure for a stable opening staying within the acceptable limits of strain. Strains occurring in a rectangular opening are found to be larger than those in the arch and circular openings for the other fixed parameters. In the mean time, larger strains occur around an arch shape opening than a circular opening.

Jan 1, 2006

By Ali Kahriman

This paper presents the results of ground vibration and air blast measurements from tunnel blasting activities during the construction of the Beylerbeyi-Kucuksu waste water tunnel under a residential area in Istanbul, Turkey. Within the scope of the study, the blasting pattern of the tunnel was engineered using Tunnel2000 design software and field studies and measurements for evaluating the productivity and safety of shots were realized for 136 rounds. During the study, the advance of the tunnel, face condition, ground vibration, air blast and neighbours’ complains and comments after every round were observed and the tunnel pattern was improved. Finally, an empirical relation for this tunnel route was developed between scaled distance and maximum amount of explosives, to continue activities in a safe and productive manner.

Jan 1, 2006

By Vasil Kopaleishvili

The bainitic Fe-C-Si alloys with optimum content of retained austenite serve as ?containers? for storing of hydrogen. Both the vacancies of fcc lattice and the possibility of forming hydrides of silicon and other alloying elements will be used. The idea is based on our scientific hypothesis. There is the silicon threshold (Si=0,50%) in "Fe-Si" system and Fe-C bainitic alloys, above which it causes self-organized phenomena: sudden increase of hydrogen solubility and amount of retained austenite in the alloy after ??ß transformation, formation of two supersaturated solid solutions <a??r>, "rejuvenation? and its reverse process. Rapprochement of iron atoms when Si=0,50%, causes appearance of new covalent forces where uncompensated electrons of 3d-subshell are involved and it provokes synergetic phenomena. They ?free? silicon atoms from the previous bonds. After that silicon itself becomes a getter of hydrogen using vacancies (14) of 3P2(6)d0(10) subshell and it results in sudden increase of hydrogen solubility in metal. Simultaneously sudden decrease of iron activity takes place. That in its turn ?releases? the carbon. Thus, its redistribution, controlling the bainitic transformation, is hastened. It stipulates for creation of ?brittle bainite" B[a(C,H)+?r(C,H)] after ??ß transformation. While weathering of metal, "rejuvenating", hydrogen diffuses in ?islets? of retained austenite and ?relaxed bainite? (B[(C)+?r(C,H+H)]) is obtained. When heating austenite ?(C,H) is obtained, and after cooling ?brittle bainite? is obtained, etc. Presented scientific hypothesis explains the available experimental facts ("rejuvenation? and its reverse process, graphitization, weldability, forming of flakes, reaching high strength, etc.) in a new manner, as well as, gives real opportunity for creating of new trends in many fields, e.g. iron based HAA. Provisional data having been obtained are encouraging.

Jan 1, 2006

By Victor Bredykhin

The reasons of formation low quality cathode deposits and conditions of the anode passivation in electrorefining of copper silver alloys with increased (more then 5%) silver content in electrolyte, g/l: Cu - 40; H2SO4-50; 150 and 250; T= 401C have been investigated. As it is shown, increased acidity, anodic current density and silver content in anodes favor passivation. The assumption is made that the ingress of silver on cathodeis the most probable reason of growing dendrites on cathode. We have determined that addition of ethylene carbonic acid to electrolyte in the amount of 3,5 ÷ 10 ml/l suppresses the dendrite formation.

Jan 1, 2006

The AusIMM is concerned about the longer tem sustainability of the minerals sector in Australasia. Our contention is that the sustainability of the sector is at risk if we do not: &nbsp; ò encourage more exploration in Australasia by removing impediments and&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; &nbsp; increasing incentives; ò fund our university and research centres appropriately to increase both our &nbsp; prospectivity, and our processing efficiencies; and ò manage our human resources better. &nbsp; This paper will focus on how we can better manage our human resources to assist in ensuring sustainability of the sector in Australasia . &nbsp; From a production point of view: &nbsp; Economic output = f (Land, Labour, Capital, Environment) where Land refers to all of the natural resources used in production. As well as land itself it includes water, forest, fisheries, oil, gas and mineral deposits. Labour refers to the skills and capabilities used by humans in the production process. Capital describes all of the manufactured aids used in the process of production1. The challenge for management is to ensure maximum efficiency and effectiveness of labour in the production process whilst maintaining sustainable development. &nbsp; The 1992 Rio Summit defined sustainable development as maintaining and enhancing: &nbsp; ò natural capital û defined as all natural resources, both environmental and &nbsp; those of traditional economic value; ò manufactured capital û made by human kind, including produced goods,&nbsp;&nbsp; &nbsp; infrastructure and built environment; ò human capital û defined as the health, well being, intellectual capabilities and &nbsp; spiritual welfare of individuals; and ò social capital û defined as social relations and consultations within and &nbsp; between societies, their norms and functionality2. &nbsp; The minerals sector in Australasia has successfully focused on the technical aspects of each of these components of sustainable development with primary attention applied to natural capital and efficient utilisation of manufactured capital. The technical aspects of human capital and social have also been addressed through an emphasis on occupational health and safety and interaction with local communities however I suggest that, to date, insufficient emphasis has been placed on labour (human capital) to maximise economic output1. &nbsp; It has become increasingly common practice to identify land as natural capital, labour as human capital and capital as physical capital. That is labour has been treated as a commodity rather than an opportunity to create a comparative advantage and this will be the greatest challenge for mine management to show leadership over the next decade of the 21st Century. &nbsp; This paper will outline characteristics of the sector which are relevant to the management and utilisation of labour, outline the outcomes of recent AusIMM surveys, review the reasons for the current and future anticipated skills shortages, some innovative responses to the challenges and finally, suggestions on how mine management can show leadership.

Jan 1, 2006

By Neil E. Izatt

The use of Molecular Recognition Technology (MRT), a selective separations technology using specifically designed ligands, has been established as an effective process for removal of metal ions found in many hydrometallurgical, chemical, and wastewater streams. The MRT process has been proven to be highly efficient and effective for indium extraction and recovery from zinc acid leach, electrolyte, chemical process and waste streams. A high percentage of the indium is recovered in a solid product format. MRT has also proven effective for germanium extraction and recovery from similar feed streams. This paper provides the indium and germanium metal recovery flow sheets and analytical results of the metal load and recovery steps.

Jan 1, 2006

By James A. Finch, Stéphanie Somot

"The self-heating facility developed at the Noranda Technology Centre [Rosenblum and coworkers, 2001; 1995] has now been established in the Department of Mining, Metals and Materials Engineering at McGill University. A research program into mechanisms has been initiated (with support now from four industrial partners under Camiro). The first investigation is into the role of pyrrhotite (Po), the most commonly suspected mineral to trigger self-heating. Following a standard experimental protocol, self-heating was assessed on samples of Po mixed with sand as an inert material. With increasing Po content, self heating progressively increased but, interestingly, the samples visually appeared less and less oxidized. A high Po content, it was hypothesized, may give a more reducing environment favouring formation of H2S. The presence of this gas could be significant as it has a high exothermic heat of reaction with oxygen. The system was modified to test the hypothesis by including copper pieces and copper sulphate to react with (and therefore reveal) the gas as copper sulphide. Evidence is presented in support of H2S production, which to our knowledge has not been shown before and introduces a potentially important avenue of investigation into self-heating mechanisms.INTRODUCTIONSelf-heating of sulphide minerals poses potential environmental and safety hazards in mining of ores, and storage and transport of concentrates. While some conditions are known to be critical, the reactions remain poorly understood making self-heating difficult to predict and control.A major advance in measurement was introduced by Rosenblum and co-workers [Rosenblum et al., 2001; Rosenblum and Spira 1995]. A self-heating assessment method was developed and applied to various sulphide-bearing materials The method is based upon automated calorimetric cells with data acquisition, now available to McGill researchers and which have been used for the study reported here."

Jan 1, 2006

By Chu E. Ho

Key variables that govern the jet cutting process are examined based on fundamental theories of jet hydrodynamics and soil mechanics. Under normal conditions of jet grouting operations, lift speed and rotation speed are found to be of less importance than the depth of jetting, nozzle pressure, nozzle diameter, and the soil bearing resistance, with regards to their influence on jet cutting distance. An analytical equation linking the governing variables is proposed, which allows for the possibility of evaluating column diameters achievable in different ground conditions based on theoretical calculations. When used in conjunction with shallow jet grouting field trials, the equation can provide a means for extrapolating trial results to conditions at actual depths for production jet grouting.

Jan 1, 2006

By F. T. Cawood

Monitoring of the slopes of surface mines can prevent loss of life, loss of equipment, loss of production and possibly the loss of the mine. The effectiveness of such monitoring depends on the extent to which slopes give adequate advanced warning before failing, and on the ability of the monitoring system to detect such warning. In this paper an overview is given of slope monitoring requirements, from both the geotechnical and survey points of view, as well as the types of equipment and instrumentation that are available. Legal issues relevant to slope monitoring are also dealt with. It is concluded that conventional geotechnical and survey instrumentation will continue to have their place in slope monitoring. However, the slope monitoring scene has changed substantially in recent years. A real and volume-based monitoring equipment is now available and this has provided, and will continue to provide, the means to improve safety, and to enhance productivity in mining. Its benefit to slope management is substantial. In the near future it is expected that data obtained from such equipment will add a much needed new dimension to slope engineering, and be used to improve slope designs and to optimize slope angles.

Jan 1, 2006

The correct assessment and understanding of geotechnical conditions is fundamental to mine design and, hence, successful (safe and efficient) mine planning, design and operations. However, this assessment and understanding is simply not possible unless there is a sound appreciation of the geology of the project. This paper addresses geological uncertainty in mine engineering and its communication, and shows that a mining project that does not take geology properly into account in the engineering phase is fraught. Uncertainty levels become excessive, which leads to hazards and consequential risks in design and operations in terms of both safety and efficiency. Several examples, both positive and negative, are provided to make the point. The paper concludes that mining geologists must become more overtly cognisant of the influence of geology on mine engineering. Equally importantly, mining (and geotechnical) engineers must communicate better with their geological colleagues to ensure that they (the engineers) have a clear understating of the geological issues affecting their operations. The engineers must know how to ask the right questions of the geologists. Engineers who do not understand and take account of geology in their designs and operations are failing the expectations of stakeholders.

Jan 1, 2006

Launching the Queensland Water Plan 2005 - 2010 in August 2005, Premier Peter Beattie compared the stateÆs water resources with liquid gold. QueenslandÆs peak industry body for the minerals and energy sector, the Queensland Resources Council (QRC), believes the analogy is appropriate. During early development of an industry water strategy, it has become apparent that water is like liquid gold, in that it is revered, hoarded, recycled, priced on purity, a magnet for speculators, both difficult and expensive to transport effectively, heavily regulated and fundamentally linked to issues of security. To date it has generally been economic and relatively straightforward for the resources sector to secure water. Although production has not been compromised, this must not be grounds for complacency as there is every indication that water will continue to become increasingly expensive, more tightly regulated and, relative to a growing demand for a finite water supply, increasingly scarce. During 2006, QRC has developed and is implementing a voluntary industry water strategy to address a range of challenges confronting the resource sectorÆs security of access to water. As a consequence of, at times, protracted community consultations over QueenslandÆs catchment-based water planning processes it has become clear that many community stakeholders have outdated perceptions of the stateÆs resources sector. Once established, QRCÆs water strategy will incorporate a community engagement campaign to present the industryÆs credentials as a leader in water resource management. The development of QRCÆs water strategy, and the challenges the strategy is designed to address, provides insight into the fundamental reforms that are occurring in how water is managed and regulated in Queensland. These reforms have implications for how government policies are designed and administered and also for how industry engages with communities during this transition process.

Jan 1, 2006

By K. Rajani Kanth

Environmental problem is the major concern for any industry and there is a great need to that along green lines. Sangam Dairy being one of the most famous and wide spread Dairies in India, produces wide spectrum of milk products. The BOD levels of effluent water of this industry with MIF treatment were found to be around 100 ppm. Lot of research has been expended in the past to bring down the BOD levels to bare minimum. The main objective of the present study is to minimize the BOD level to the required level stipulated by environmental standards by employing various seeding materials. For this purpose microbes like Bacillus Subtiles, Pseudomonas, Aspergillas, Staphylococcus, and Pencilium have been employed and BOD levels were analyzed. Various Reagents, solutions with different dilution levels have been successfully prepared. Initial and final Dissolved Oxygen levels were determined before and after incubation. From the DO data, BOD was evaluated for all samples and comparison analysis of various seeding material was carried to suggest the efficient seeding material for the ETP plant. In the process, solutions of different dilutions have been prepared using difficult reagents. These samples are treated with above mentioned microbes and BOD levels are estimated. It has been observed that staphylococcus and Pseudomonas proved to be the best seeding materials. When there microbes have employed BOD levels fall to less than 10 and 20 ppm respectively

Jan 1, 2006

By R. L. Pienaar

Paper written on project work carried out in partial fulfilment of B Eng (Min. Eng.) degree A study was conducted to investigated and compare the feasibility of two single level extraction layouts for an intact part of theorebody of the De Beers diamond mine, Koffiefontein. Two layouts were chosen and the tonnage profile, development schedule and production ring blast layouts were calculated by applying the information acquired through a literature study. Current principles used on the mine were also applied. The first layout chosen is described as a simple straightforward layout with 6 production tunnels spaced 15 m apart, and is referred to as Layout A. The second layout, named Layout B, is described as a complex chevron layout with 9 production tunnels spaced 15 m apart. This layout has a rim tunnel situated in the kimberlite ground, which is called a chevron and this made the layout more complex than Layout A. By comparing the financial results of the two layouts, it was found that Layout B is a more feasible option than Layout A. Sensitivity analyses show that both layouts are extremely sensitive to the revenue of the projects. Therefore it is recommended that Layout B can prove to be a source of additional tonnage to add to the total tonnage profile of the mine and to extend the life of mine by 20 months, only if certain financial/economic factors improve. There is, however, still some areas of the project that need to be investigated.

Jan 1, 2006

By Dieter Offenthaler

Catalysts used in petroleum industry often contain valuable amounts of PGMs. The typical recycling route for those materials is the pyrometallurgical one, but this treatment way offers limited flexibility with respect to small charge weights. A new process, combining a pyrometallurgical pre-treatment step of the ceramic carriers with a hydrometallurgical leaching procedure overcomes this disadvantage. It not only allows the economical treatment of even very small charge weights, but also gives the possibility to maximize the PGM yield by individually adapting the process to the different charge materials. Due to an ingenious process design, where all leaching agents and effluents are recycled in a closed loop and therefore no waste waters leave the process, process operation becomes very economical. However, the temperature-time-regime in the pyrometallurgical pre-treatment step is of major importance for the success of the whole process. Therefore various investigations have been done to identify how the different process variables in the pyrometallurgical pre-treatment influence the subsequent leaching procedure. It turned out, that the adjustment of the correct phase-modification in the ceramic carrier materials during the pyrometallurgical treatment is the key factor of this process step. Although it is a troublesome issue to exactly adjust the correct phase modifications, it is the prerequisite to take advantage of the benefits of this new process concept.

Jan 1, 2006

By J. Dupre, A. Gontcharov, H. Pepin

Produced by the conventional TIG welding CMSX-4 welds had been studied. It was demostrated that microstructure of welds depended on filler materials, welding parameters and joint design. Epitaxial solidification of CMSX-4 clad deposits produced a directionally solidified structure while welding with the similar filler material. Defects free clad welds were obtained by TIG welding without preheating using similar and dissimilar filler materials.

Jan 1, 2006

By Robert Hopler

The 1800’s were a time of tremendous advancements in science and experimentation, and earthquakes were a subject of great interest. The meetings of the British Association for the Advancement of Science in 1853 and 1854 are good examples of this. The proceedings of the Association for the 1854 meeting includes a table entitled “Catalogue of Recorded Earthquakes from 1784 to 1850” which takes up 326 pages, and lists available information on approximately 3000 earthquakes. The 1853 proceedings have a similar table for earthquakes recorded from 1606 B.C. to 1783. In the 1854 volume there is a “Report of the Committee on Earthquakes,” which provides us with a view of the general state of the science. Excerpts from that report follow:

Jan 1, 2006

By A. Zutshi

Production of CO2 is an inevitable consequence of burning fossil fuels, with the only CO2 sequestration technique feasible in the immediate future being its injection in various geologic media. This paper discusses the factors that influence the injection, movement, and storage of CO2 into deep coal seams, while simultaneously increasing the production of methane. The results of a laboratory-scale study to evaluate the movement of CO2 in coal, its ability to displace methane, and the capacity of coal to retain CO2 are presented. The findings are compared with observations at one of the two field-scale pilot operations practicing CO2 injection in coal. Finally, the paper summarizes the research issues that require further investigation.

Jan 1, 2006

Steel Ladle in Bhilai Steel Plant, SAIL, India, passes through VAD & LF-RH route and this exposes refractory lining to a severe operating conditions. Ladles are lined with in-house manufactured MgO-C refractories. Lining life used to be 35 heats, out of which 18-20 heats were through VAD/LF-RH, hence, ladle availability had become a constraint. Laboratory studies were carried-out to optimize granulometry and composition. Granulometry was developed by adopting Andearssen packing model. A suitable plasiticiser was identified to eliminate inconsistency caused due to variation in resin quality and weather condition. It reduced variation in green bulk density from 6 to 1.3%. Abrasion and slag erosion studies were conducted, which shows that with increase of carbon, abrasion resistance decreases and corrosion resistance improves. Based on these studies, graphite in slag zone was increased from 10 to 12.5% and in metal zone it was reduced to 7.5%. Different process parameters of brick making were optimized to make MgO-C bricks of maximum bulk density with reduced coke porosity. Modified bricks have bulk density of 2.99-3.02 g/cc and coke porosity of 9.5-10.5%. Further, shape of the bricks were changed from side arch to mini keys and thickness was increased from 80 to 100 mm. Mini key bricks are pressed from sides, thus eliminating variation in thickness which is critical dimension for dry joints. These modifications improved average lining life of steel ladles to 64 heats, which includes 37-40 secondary heats. Maximum life obtained is 87 heats.

Jan 1, 2006