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By L. Cornish, P. A. Olubambi, J. H. Potgieter

Four 22%Cr series duplex stainless steels alloys containing varying nickel contents of approximately 5, 7, 9 and 13% were melted in a vacuum induction furnace, hot rolled, solution annealed and water quenched. Their corrosion behaviour was investigated in sulphuric acid and sodium chloride solutions using a potentiodynamic polarization technique. Increasing nickel contents have appreciable influence on their corrosion behaviour. Polarization curves show similarities in the uniform corrosion behaviour of the alloys in the solutions and a significant difference in their pitting behaviour in chloride environments. Alloy 2209 generally exhibited highest resistance to uniform corrosion while 2213 displayed distinct and best pitting corrosion resistance. Their corrosion behaviour were attributed to the influence of nickel on phase modification, microstructural refinement, and the probably types of films formed in different environments. Keywords: Duplex stainless steel; Nickel; Microstructure; Phase modification; Corrosion

Jan 1, 2006

By C. Kasatuka

Globalization creates investment opportunities for enterprises around the world. Attracting foreign investment has been a key challenge for economic growth in developing countries. Corruption, political instability, armed conflict, and other internal problems affect foreign direct investment (FDI) inflows negatively. A framework of criteria provides a basis for comparing non-commercial risk (NCR) among twenty-three mineral economies. Countries competing for foreign direct investment inflows are ranked from least to most risky. This study compares Inward FDI Performance Index (IND) with NCR ratings in developing countries and shows that risk is increasingly mitigated by means of appropriately structured insurance. Given the option for countries with similar mineral potential, investors will generally invest in the country that offers lower non-commercial risk. Keywords: foreign direct investment, non-commercial risk, developing countries.

Jan 1, 2006

By Marshall Khan

The Goodfellow Expert Furnace System Optimization Process (Goodfellow EFSOP?) is a proprietary process that uses real-time and continuous off-gas analysis, along with process monitoring to optimize the operation of electric arc furnaces (EAF) for steelmaking. With the exception of off-gas composition, dynamic process measurements within the EAF are not possible due to the harsh operating environment. The Goodfellow EFSOP? system provides a dynamic indication of the operating conditions within the EAF. Continuous measurement of furnace off-gas composition, along with other furnace operating parameters is used to elucidate the fate of chemical energy usage within the EAF including: the evolution of carbon from the molten steel bath; the in-leakage of air into the furnace; the extent of combustion above the molten steel bath and the occurrence of dangerous water-leaks from the furnace cooling system. The ability to measure the process reliably and continuously enables Techint Goodfellow Technologies Inc (TGTI) to implement dynamic process control of combustion within the electric arc furnace and to optimize the overall operation through adjustments to the EAF process based on off-gas measurement. This paper discusses the methodology and results achieved from several recent Goodfellow EFSOP? installations in South East Asia.

Jan 1, 2006

By J Parmenter

Issues around water û its quality, use, availability and environmental value û can be a major point of tension between mineral projects and local communities. Failure to manage these issues appropriately can jeopardise the obtaining of regulatory approvals for new projects and place at risk the æsocial licence to operateÆ of existing operations. Conversely, there may also be significant opportunities for companies to engage constructively with communities over water issues and to make a positive contribution to the sustainable development of these communities. Using case studies, this paper will explore the various types of social risks and opportunities associated with water and mineral resource development and identify key learnings relating to the management of these issues.

Jan 1, 2006

By Russell Frith

For many years, underground rock mechanics and in particular, roadway/tunnel roof stability has been underpinned by the often unchallenged assumption that roof strength (as defined by the UCS) and stiffness (E) are key stability controls. This has logically led to the proliferation of laboratory testing of rock specimens and the development of indirect geophysical methods to gain estimates of these two rock parameters. Furthermore, many design methods are significantly focussed on replicating rock mass behaviour through either intact or failed constitutive models. Demonstrably the strength and stiffness of the host rock material is commonly used as one of the key indicators of excavation roof stability and it finds either direct or indirect use in just about every rock mass rating system in use today. In more recent times there has been a common move to consider and apply (even if only conceptually at the current time) structural engineering type principles (e.g. buckling) to coal mine roadway roof (and rib) stability. Similarly our knowledge of the in situ stress environment and its likely origins has improved significantly, largely through stress measurements and subsequent analysis. This paper combines knowledge in both of these fundamental areas through a deterministic model for roadway roof stability and in combination with field examples, reaches the almost certainly controversial conclusion that UCS and E are commonly irrelevant, albeit that the former may provide an indication of other relevant geotechnical parameters (e.g. bedding cohesion). As with all hypotheses or rules, there are naturally exceptions and in this case, the most obvious is the tailgate of the longwall panel (with adjacent goaf). Due to the significant change in the strata loading environment of a longwall tailgate as compared to first workings for example, the stability equation materially changes so that UCS and E become critical controls. The point of the paper is to present a different perspective on a traditional mining problem and to challenge geotechnical professionals to keep thinking ?outside of the square? in the never-ending endeavour to improve our understanding of the engineering problems we regularly face. Such an understanding impacts upon such issues as geotechnical data collection from borecore, support hardware requirements and design capabilities. Therefore making the assumption that our understanding is always fundamentally correct could in fact be limiting the development of new and improved engineering in the future.

Jan 1, 2006

By A Jha, R Merz

The substantial growth in world demand for Queensland coking coal has seen a number of new coal mine developments in the Bowen Basin in recent times. The Bowen-Broken Water Supply Scheme (BBWSS) is presently based on water supplied from Eungella Dam and storages at Collinsville to two major pipelines. In early 2004, three successive years of well-below average rainfall had left Eungella Dam at critical levels, threatening the regionÆs mines, which rely on it for their essential water supply. SunWater noted that without significant inflows into Eungella Dam, or the development of a new water supply to the region, existing mines would be severely restricted in water supply, and downstream economic impacts to the region would follow. SunWater investigated the opportunities for additional supply capabilities, including combinations of off-stream storages, additional pipelines, and raising Eungella Dam. An off-stream storage (OSS) was selected as being the preferred option to improve the reliability of the system and head off impending falls in announced allocation for the system. The integrated quantity quality model (IQQM) is the Queensland GovernmentÆs preferred model to define and assess total catchment performance against water security and environmental objectives. Modelling of the performance of the water supply system, with and without the proposed OSS, was required to provide justification to the customers of the system that the OSS was in fact required, and also to optimise the configuration of the OSS within time and budgetary constraints. In the case of the BBWSS, no environmental base flows are dictated by the Department of Natural Resources, Mines and Water (NRM&W) at present and the primary reason for applying IQQM was therefore to investigate the trade-offs between supply options and reliability. SunWater produced IQQM outputs for a range of scenarios for the proposed off-stream storage, and these IQQM outputs were then used as input to a decision-support tool based on the GoldSim modelling package. The GoldSim model was then applied to investigate the water supply reliability for high priority users resulting from various existing and/or proposed water supply infrastructure configurations coupled to the hydrologic system. The GoldSim model included the ability to assess the long-term water supply reliability impacts for each of the water supply end-users for a wide range of user-defined scenarios. Non-technical model users were able to change the size of the off-stream storage, pipeline capacities and assumed climatic conditions and test for themselves the relative benefits (in terms of water supply reliability) of different infrastructure configurations under consideration. The decision tool was of significant benefit in assisting the decision process to SunWaterÆs mining customers. These customers needed to decide if they felt that the increased reliability in their water supplies from the system that would be created warranted the estimated increased charges that would require to be levied to recover costs of the new infrastructure with appropriate profit margins. The conjunctive use of IQQM and GoldSim was successful in demonstrating the impact of both hydrological and non-hydrological issues on the future water supply reliability in the BBWSS and resulted in a decision to proceed with the construction of a new OSS.

Jan 1, 2006

By W. Beres, R. E. Miller, B. Shiari, L. R. Zhao

A dynamic multiscale (MD/FE) method has been used to study dislocation generation and plastic deformation during a nanoindentation process which is physically associated with the generation of heat within the specimen and as a consequence with a temperature rise. Two different techniques are applied to study the temperature effect on the nanoindention process. In the first technique, a global Nose-Hoover thermostat is applied to the entire atomistic region to keep temperature constant during simulation (finite temperature approach). In the second method, the thermostat is applied only on a damping region along the MD/FE interface. Both techniques are able to effectively and efficiently absorb high frequency reflected waves from atomistic/continuum interface. The temperature profile of the atomistic region beneath the indenter is reported and discussed at four different initial substrate temperatures for both techniques. The loaddisplacement (load/unload) curves for different temperature-controlling techniques are compared and discussed. The nucleation and propagation of dislocations in the atomistic region are investigated for both techniques. Correlations between the observed features in the load-displacement curves with the motion and pile-up of dislocations are reported as a function of temperature.

Jan 1, 2006

By Kazuya Koyama

We are studying the hydrometallurgical recycling process of indium from an Indium-Tin-Oxide(ITO) target. For this process, it is necessary to remove Sn(IV) ions from the aqueous hydrochloric acid solutions containing In(III). In this study, the removal of Sn(IV) ions by a potentiostatic electrolysis method was examined. The polarization measurements and potentiostatic electrolyses were carried out under a nitrogen atmosphere. In the Sn(IV) solution, current begins to rise at the cathode potential of -0.26 V vs. SHE, and increases with a reduction in the cathode potential. In the In(III) solution, current begins to rise at a cathode potential of -0.43 V vs. SHE. Metallic tin was electrodeposited without indium electrodeposition at the cathode potentials of -0.30 and -0.40V vs. SHE. More than 98% of the Sn(IV) was removed at the cathode potential of -0.40 V after the electrolysis for 3hrs. Both tin and indium were electrodeposited at the cathode potential of -0.50V vs. SHE.

Jan 1, 2006

By Francis Vanbellen

Umicore Precious Metals Refining operates an integrated precious metals smelting and refining plant in Hoboken, Belgium. Once a smelter and refiner of complex concentrates, the plant today?s feed consists exclusively of industrial and consumer recycled products, making it the world?s largest recycling facility for precious metals. Unlike the fairy tale of the Frog Prince, it took much more than a princess? kiss to successfully realize this makeover. A completely renewed plant has been built over the past decade. The most visible technological innovation was the commissioning of the Pb-Cu smelter. Its flexibility towards very different types of feed makes it perfectly suited as main entry to the Hoboken flow sheet. A new Cu-leaching & electro winning plant and precious metals refinery make up the Precious Metals Operations (PMO) whose targets are fast throughput and maximized yields for gold, silver and the platinum group metals. The Base Metals Operations (BMO), flexibly process the by-products from the PMO, valorizing ?impurities? like indium, tellurium, selenium and others. Off gas and waste water treatments ensure compliance with strict environmental standards. Precious metals recycling is an art that goes beyond mastering a unique flow sheet. Umicore Precious Metals Refining offers a complete recycling service, taking care of sampling and assaying, metals management and logistics. The quality of this integral service is recognized through the attribution of ISO certifications for our operational activities, sampling and the environmental care. And it?s an art that follows Michelangelo?s experience: ?Art is 5% of inspiration and 95% of transpiration.?

Jan 1, 2006

By D. C. Oldroyd

Western Coalfield?s Tandsi Mine, has difficult support conditions and a history of roof falls, resulting in mining roadway widths and depths being restricted for safety reasons. Rock Mechanics Technology Ltd was contracted to improve the support system to allow the introduction of mechanised room and pillar mining. The introduction of a ?world best practice? bolting system resulted in major improvement in roof stability, allowing mining restrictions to be lifted and Tandsi to become one of the first two Indian mines to introduce a mechanised continuous miner system. The first year?s production was some six times previous levels. Because of the improvement in the support system, RMT was also able to design a partial de-pillaring system suitable for the Tandsi continuous miner districts together with the introduction of monitoring procedures and guidelines to maintain safe roof support conditions. In situ monitoring of pillar and roof behaviour was undertaken as the first pillars were extracted to confirm the design. De-pillaring operations have also proved highly productive, and to date there has been no associated support related major injury or dangerous occurrence. The success of this project demonstrates the potential for mechanised room and pillar mining in India.

Jan 1, 2006

By Xu Weihong

After being pre-treated, composite electro-deposits of semi-bright nickel/nano-SiO2 with bright nickel or with amorphous Ni-P alloy, and Composite electro-deposits of Zinc were prepared on Nd-Fe-B magnetic material. The effect of cathodic current density, nano-SiO2 concentration, stirring strength and surfactants on the corrosion resistance of electro-deposits were studied. In addition surface appearance and structure of the composite coatings were analyzed by SEM. The present investigation shows that the corrosion resistance of composite electro-deposits of semi-bright nickel/nano-SiO2 with amorphous Ni-P alloy was the best, the solution system of semi-bright nickel/nano-SiO2 with bright nickel was stable and its electro-deposits also had an excellent corrosion resistance, composite electro-deposits of Zinc not only had good corrosion resistance, but also low cost, thus making it an excellent electro-deposit for medium or low-class Nd-Fe-B magnetic material.

Jan 1, 2006

By D. Bouchard, J. Langlais, A. Lemieux, N. Andrade

A concerted effort between Akan International Limited and the National Research Council of Canada (NRC) has been initiated to develop a liquid-based slurrymaking process, dubbed SEED (Swirled Enthalpy Equilibration Device) for semi-solid forming. The technology is presently entering the industrial and commercial stages, and will be used by the first customers at the end of 2006. Semi-solid processing of aluminium alloys offers many advantages in fabricating economically near-net-shape parts of superior quality. The SEED process helps to overcome problems experienced with thixocasting and especially the high cost of feedstock. The SEED process involves two main steps: 1) heat extraction to achieve a desired liquid/solid mixture, and 2) drainage of an excess liquid to produce a self-supporting semi-solid slug that is formed under pressure. The heat transfer plays an important role (enthalpy equilibrium) during the manufacture of the semi-solid slurry and its analysis is briefly described. The semisolid material is obtained using different processing times and initial conditions. The impact on the solid fraction distribution and the morphological evolution of the microstructure is presented. The influence of the SEED processing parameters (slurry preparation) and the resulting mechanical properties for the alloy A356 are also reported.

Jan 1, 2006

By B D. Burford

High intensity stirred milling using the IsaMill has been the enabling technology for many projects by transforming the economics of fine grinding and simplifying circuit design. IsaMill grinding technology was originally developed for large-scale grinding to P80 sizings of 7 ¦m. The IsaMill is a high throughput, high efficiency mill that produces sharp product size distributions in open circuit configuration. The ability to grind in an inert environment, using a wide variety of media types, can give further metallurgical and economic benefits. The high energy intensity results in a small footprint that enhances the ability to distribute grinding power throughout the circuit, applying grinding energy to the minerals that need it. Recent scale up developments in IsaMill technology have enabled the benefits to be extended to large-scale conventional grind sizes, until now the domain of ball and tower mills. This paper will examine the crossover of IsaMill technology from ultrafine applications into the more conventional grinding area (P80 20 - 150 ¦m). Scale-up developments in IsaMill technology that have enabled this are reviewed. The upcoming commissioning of a 3.0 MW M10,000 IsaMill, the most powerful to date, grinding to P80 55 ¦m at PPL in South Africa will be discussed, as will the recent commissioning of a 2.6 MW M10,000 IsaMill at Kumtor. Recent testwork at McArthur River, where an IsaMill is being considered as an addition to the primary grinding circuit to replace the current tower mill will be reviewed. The potential combination of HPGR and IsaMill to transform concentrator grinding economics will also be discussed. Large-scale IsaMill technology has the ability to transform circuit design and energy efficiency for both coarse and fine grinding.

Jan 1, 2006

By Michael J. Brnich

During the past 15 years the number of reportable mine fires has declined. A decline in the number of reportable fires is a gross indicator that allows experts to say something about the underground coal industry generally: There has been some improvement in overall mine fire preparedness. However, such an indicator is less reliable as a predictor of readiness at any particular operation. An indication of fire fighting preparedness would have to be assessed from evidence gathered at the mine site. In other words, there are two levels from which to view the problem. On a general level, there has been significant improvement in the industry's fire response capabilities over the past two decades. Specifically, however, little data has been gathered on a site-by-site basis to determine what improvements might be made on a local level. These improvements would move beyond regulatory compliance. It is expected that this manuscript, based on work conducted at an underground coal mine in the western United States, will help to focus attention on some central concerns involving this critical issue.

Jan 1, 2006

By D. N. Bigby

This paper concentrates on ground control innovation in Europe since the first Morgantown conference, mainly from a UK perspective. In particular, it describes the rock engineering and ground control tools developed to address the mine support and design problems associated with coal mining at great depth in areas influenced by previous workings. The differences in approach across the Western European industries are also examined. Perhaps the most significant change in the period has been in the science of coal mine rock mechanics itself, with support design now based firmly on measurement, analysis and understanding. The ground control innovations described here have played their part in increasing the efficiency with which coal is mined and in increasing safety to the extent that fall of ground accidents are now rare.

Jan 1, 2006

By Patrick R. Atkins

Energy issues will have increasing impacts on decision making in all facets of society over the next few decades. Industrial users of energy and producers of products that affect energy use must be fully aware of the implications of their processes and products on the energy situation. This paper describes a model that has been developed for the aluminum industry that allows scenarios to be evaluated to gain improved understanding of possible implications for our businesses. A brief overview of the model is provided.

Jan 1, 2006

By P J. Terbrugge, O K. H Steffen

Open pit slope design has conventionally been effected as a bottom up function utilising available geotechnical information. This results in a decision criterion based on Probability of Failure and Factor of Safety with a risk assessment being carried out on the proposed design slopes. The design approach recommended reverses the process using fault event tree decision methodology. The consequences of this approach are that acceptable risk criteria have to be determined by mine owners. Slopes are then designed by the technical staff to achieve these corporate goals. Benefits that arise from the process are that the owners take a proactive decision on the risk benefit relationship allowing the technical staff to optimise the geotechnical exploration programme and design.

Jan 1, 2006

By M. Hopf, E. Rossouw

Keywords: Pyrometallurgy, furnace, copper coolers, freeze lining, monitoring, Saveway The use of water-cooled copper components as sidewall elements of submerged arc furnaces and other pyrometallurgical applications has become increasingly common. The high cooling efficiency of copper has made it possible to increase the service life of furnace refractories when compared to conventional refractory linings. However even the self-healing effect of ?freezing? worn areas of the lining does not necessarily protect the copper coolers against wear or corrosion completely. In order to avoid furnace explosions, various methods have been used to monitor the wear of coolers. Unfortunately, these have not been able to consistently identify localized wear. Thos Begbie (South African) and SAVEWAY (German) jointly developed technology to embed a line sensor into the copper cooler during the casting process. This system allows an exhaustive monitoring of the copper cooler. A SAVELINE sensor is placed inside the copper-cooling panel between the water-cooling passage and the hot face of the panel. The sensor follows the meandering shape of the cooling water channels. In the first instance, the sensor provides analogue information as the thickness of the copper reduces. Secondly, this wear signal will be confirmed by a signal of interruption if the sensor is washed away. Because of the structure of the sensor, a self-diagnosis is possible and indications can be confirmed (double proofed). Subsequent to the manufacture of some test pieces, coolers for a large submerged arc furnace were manufactured. The sensorized coolers have been installed at the intermittent surface (slag line) where the largest amount of corrosion has been encountered. The system has been operating since December 2005 in what is considered one of the largest submerged arc furnaces in South Africa.

Jan 1, 2006

By L. Jiang

The evolution of twinning in an AM30 Mg alloy was examined by uniaxial tension and compression testing at temperatures from ambient to 250°C and a strain rate of 0.1/s. The samples were cut along the extrusion direction from extruded AM30 Mg alloy tubes. Specimens deformed to various strain levels were examined by optical microscopy and electron backscattered diffraction (EBSD) techniques. The results indicate that the initial extrusion texture plays an important role in the formation of different types of twins and that the twinning behavior also depends on the strain path. Contraction and double twinning are the dominant twinning mechanisms in uniaxial tension, while extension twinning prevails in uniaxial compression. The different twinning behaviors are shown to be responsible for the sharply contrasting strain hardening characteristics of the experimental flow curves.

Jan 1, 2006

By M. Hagfors

On the underwater testing of explosives, the measuring system consists of water filled test pond, tourmaline based pressure sensor, measuring cable and measuring unit, which supplies the DC current to the pressure sensor. Depending on the length of the measuring cable, it is always possible that some signal damping may occur in case the measurements are carried out without the signal amplifier to keep the measuring system as simple as possible. Therefore the length of the measuring cable should always be as short as possible.

Jan 1, 2006