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By S Brunt

A new elution process has been developed for the recovery of gold thiosulfate from ion exchange resins. This is a synergistic system which utilises a base eluent, such as nitrate or trithionate, along with an additive that improves the elution of gold. The use of the additive enables lower eluent concentrations to be adopted, as well as weaker eluents such as chloride. With the chloride + additive system, complete gold elution can be achieved within 12 BV when utilising an eluent flow of 5 BV/h. When the eluent flow is reduced to 2 BV/h, complete elution is achieved within 8 BV. Similar results are obtained when using nitrate or trithionate as the base eluent. A copper pre-elution process has also been developed, whereby the majority of copper can be stripped within 5 BV prior to gold elution. This method is a significant improvement on the ammonia + oxygen pre-elution previously suggested. The development of a new analytical procedure based on ion chromatography with UV detection is also described for the quantification of polythionates in leach solutions and loaded on resins. This enables analysis to be carried out for resin-in- leach type processes where the polythionates are being formed in solution and simultaneously adsorbed onto the resin.

Jan 1, 2007

By E. Spicer

X-Ray diffraction (XRD) provides useful information about the composition of an ore sample in terms of quantification of crystalline phases and amorphous content. The use of new, fast detection systems in XRD creates the opportunity to use this technique in modern process control. In the analysis of heavy mineral sands, XRD can identify the main mineral phases, such as ilmenite FeTiO3, rutile TiO2, Zircon ZrSiO4and quartz SiO2, and any other minor components present, such as anatase TiO2, magnetite Fe3O4, haematite Fe2O3or monazite (Ce, REE)PO4. Quantitative analysis is possible by various classical methods such as straight line or polynomial calibration with standards, but modern quantification analysis techniques such as Rietveld analysis (Bish and Howard, 1988) are attractive alternatives, as they do not require any standards or monitors. These methods offer impressive accuracy and speed of analysis. The Rietveld method compares calculated versus experimentally derived X-ray powder diffraction patterns for the sum of all crystalline phases. Another analysis technique offering great benefit to mining industries is cluster analysis. Enormous amounts of XRD measurement data are generated during the process control and material evaluation. New ways of handling such vast amounts of data are required to produce meaningful information for the end users. Cluster analysis greatly simplifies the analysis of a large amount of data from different processes or different raw materials, and automatically sorts closely related scans of an experiment into clusters and marks the most representative scan of each cluster as well as outlying patterns. The use of cluster analysis to evaluate the XRD data allows fast and reliable tracking of the process. It is the most economical procedure to have automatic data evaluation without involving any dedicated personnel in the process. Details of the techniques used, sample optimization methodologies, results, data precision and limitations will be discussed. The approach has potential as a relatively inexpensive, reliable tool, useful in the characterization of heavy minerals sand materials.

Jan 1, 2007

Gold mines produce unique water treatment requirements. This paper focuses on case studies of innovative processes used for treatment of water resulting from gold mining and processing. The case studies include treatment of mine dewatering water for beneficial application from an Australian gold mine, Bendigo Mining, as well as treatment for arsenic removal of tailings water from mining and processing at Goldcorp mines in Canada. Gold mining can often require dewatering to prevent groundwater seeping into and flooding the mine workings. Gold mining and processing often accumulate wastewaters in a tailings dam. The mine water can contain contaminants such as dissolved salts, iron, arsenic, manganese, heavy metals and odorous sulfates. Environmental discharge requirements as well as community needs for water drive mine operators to consider the most appropriate water treatment process. Treatment of gold mine water can require processes including oxidation, pH adjustment, coagulation, flocculation, clarification, further oxidation/adsorption of specific metals such as manganese, filtration, salt reduction utilising reverse osmosis, brine minimisation and other innovative technologies. These processes are discussed through the case studies with examination of the specific treatment process that is required. This paper uses real case studies of gold water treatment processes to explain and examine the technology and the reasons for designing specific processes. The focus is toward explaining innovative processes where the water is used for sustainable environmental discharge or treatment to a quality that can be beneficially used by the local community.

Jan 1, 2007

By S. Orr

In situ leaching is a complex, multidisciplinary process, which requires both mastering and integration of the different disciplines involved. Particularly, in-situ leaching is the intersection between geology (geochemistry, mineralogy, structural geology), hydrology (hydrogeology, well hydraulics), metallurgy (hydrometallurgy, electrochemistry, aqueous chemistry), and economics (mineable ore, cost of operations, market). The management of such a complex system requires all relevant knowledge base, integration, and continual optimization. Our presentation starts with a description of the "expert system" ? from data acquisition to information and knowledge, including determination of essential in-situ parameters, analyses, and modeling, which ultimately leads to an integrated, real-time, hierarchical management/control system.

Jan 1, 2007

By D. Sohn

Work accidents have an essential impact on the economy of a country and in final consequence on each company. The main purpose of industrial OHS is to maintain and promote the health of all employees. Healthy working conditions increase efficiency and motivation and safeguard the success of the business against the background of the extremely dynamic processes of change. Maintaining and promoting the health of all employees, weather in operation, administration or on the mining site, has become therefore not only an ethical requirement but also an economic must. Creating a suitable working environment for people today entails much more than just preventing accidents and work-related illnesses. It is important to be proactive in establishing an even better culture of prevention and to convince everyone, workers and managers alike, of its importance. Especially in the age of rapid changes and above all in view of global competition we are more dependent than ever on healthy, enthusiastic, competent and creative employees. OHS provides you with the necessary competitive edge.

Jan 1, 2007

By Paul C. Schmall, Lucian P. Spiteri, Arthur B. Corwin

Moving groundwater is generally recognized as the most adversarial condition for ground freezing. Moving groundwater can occur due to natural or man-induced groundwater flow, but either way may result in freeze formation difficulties. History has shown that if the condition goes undetected, catastrophic failure of the frozen shaft or excavation can occur. The success of ground freezing under potentially flowing groundwater conditions depends on an evaluation of the likelihood for this condition; an accurate and early diagnosis, with a careful evaluation of freeze pipe temperatures and piezometer water levels; and timely reaction to mitigate the possible delays. Successful remedial measures have included the reduction of ground permeability by modifying the soil properties between the freeze pipes with various kinds of grouting, or increasing the freezing effect by adding freeze pipes and/or the use of liquid nitrogen as the freezing agent.

Jan 1, 2007

By G. Denton, P. den Hoed, A. Luckos

The potential application of fluidized beds in several sectors of the ferroalloy industry is promising. They can be used in the direct reduction of iron ores to produce a feed for steelmaking, in the reduction of manganese dioxide to produce a lesser oxide for feeding to smelters, in the preheating of chromite for the production of ferrochrome, and in the calcining and pre-reduction of nickel laterites for the production of ferronickel. This paper discusses the potential of fluidized beds in theses processes and highlights the advantages of the technology over other technologies, such as rotary kilns. Two primary advantages?(1) that fluidized beds can treat fine materials and (2) that fluidized beds can be integrated with smelters in a way that allows for more efficient use of energy?may well see the technology gain prominence as more deposits of lower grade are mined and industries strive to use their resources more efficiently. In discussing the potential of the technology in the ferroalloy industry, this paper focuses on the application of fluidized beds in the smelting of chromite, nickel laterites, and manganese ores. Central to the successful operation of this technology is a knowledge of how particle properties influence the behaviour and design of fluidized beds.

Jan 1, 2007

By Kray Luxbacher

Three-dimensional time-lapse velocity tomograms were generated to image stress redistribution around a longwall panel to produce a better understanding of the mechanisms that lead to ground failure. Mining-induced microseismic events provided passive sources for the three-dimensional velocity tomography. Surface-mounted geophones monitored microseismic activity for 18 days. Most similar studies have utilized active sources including longwall shearers, controlled explosions, and hammer blows. These active sources generally require a person to initiate and measure the location and time of the source, and are not conducive to continuous monitoring. This method utilizes mining induced microseismic events as passive sources and lends itself well to continuous monitoring. Two event location methods were compared in order to move toward quantification of tomographic results in terms of ground conditions. Additionally, LAMODEL was utilized to determine the expected stress distribution around the longwall panel and compare these images to the velocity tomograms. Eighteen tomograms were generated, one per day, and high velocity regions in the set of tomograms generated from the initial location algorithm correlated with abutment stress redistribution predicted by numerical modeling. This research is significant as it has the potential to improve safety in underground mines and is the only example of long term passive velocity tomography implementation for the purpose of inferring stress redistribution around an area of active mining. Though still immature, this technology has the potential to allow mine personnel to image areas of active mining on a regular basis and detect areas with anomalous velocity distributions indicating potential safety hazards.

Jan 1, 2007

By William Hustrulid

The National Institute for Occupational Safety and Health (NIOSH), as part of a comprehensive program to improve mine safety through the widespread acceptance of careful excavation principles in drifting, have revisited standard drift round design concepts. Although the initial emphasis was on contour row design and providing improved design tools for blasting with de-coupled charges, the focus has broadened into the development of a general gas pressure-based drift round design approach. The concept of a damage radius (Rd) for a given explosive-hole-rock mass combination is introduced. With the damage radius as the basic building block, the blast holes are positioned on the face, beginning with the buffer row, to achieve the desired excavation size, shape and smoothness. The design of the contour row of holes is also performed using a pressure-based approach. The paper presents in some detail the overall approach and the required gas pressure-based design equations.

Jan 1, 2007

By A. -M. Lafront

The corrosion resistance of die-cast and freely-solidified and electromagnetically-stirred thixocast AZ91D alloy has been studied using electrochemical noise technique in a 0.05M NaCI solution at pH 6.1 and 25°C. Specimens polished at different depths were immersed for a period of 75 min in order to assess the influence of the microstructure on corrosion kinetics and morphology. At depths between 10 and 50 µm (skin), all specimens showed general non-uniform corrosion with the lowest corrosion resistance. Between 100 and 200 µmn (interior skin), the observed corrosion was accompanied by superficial undefined pits due to metastable pitting. The corrosion form for 100-200 µm gave the best corrosion resistance. Stable pitting corrosion was observed beyond 400 µm deep on the bulk specimens. The skin of all thixocast specimens prepared billets showed a more corroded surface than that of die-cast. The interior skin as well as the bulk specimens showed better performance than that of the die-cast specimens.

Jan 1, 2007

By Alton Dunaway, Kevin Sullivan, Charles Gray, Doug Hall, Kevin Grant, Kelly Thiel, John Paulson, Bruce Leland, Cole Boyd

Beaver (Castor canadensis) are responsible for economic losses exceeding $4 billion over the last 4 decades in the southeastern United States alone. A large portion of these damages occurs to public roads and highways, forests, agricultural resources, and other property from flooding caused by beaver dams. The United States Department of agriculture, Animal Plant Health Inspection Service, Wildlife Services (WS) program is a non-regulatory Federal program directed by Congress to assist resource owners with managing damage caused by wildlife.

Jan 1, 2007

By T. Wennberg

An elevated location of a paste thickener on a ridge close to the disposal area is considered at a Swedish iron ore mine. About 0.7 M tonnes of thickened tailings are planned to be layered as paste in the vicinity of the thickener over several years with pipeline lengths of up to 900 m after about 20 years. In order to clarify the pipeline pumping characteristics of the tailings product for volumetric solids concentration from 40 to 50%, experiments in loop systems with pipeline inner diameters from 0.063 to 0.152 m have been carried out with various types of pumps. The results and comparisons carried out here showed that the performance of centrifugal pumps cannot simply be related to the rheology, but factors related to pump design and build-up tendencies of material within the pump and other particle properties may be of equal importance. During the first years of operation only one thickener underflow pump is required. The reliability and performance for various pump configurations are planned to be investigated systematically in order to meet the most effective long-term solution for paste thickener operation, pipeline distribution and placement in the disposal area as the discharge point advances over the life of the project.

Jan 1, 2007

By B Ilich, M Brad, R Brandli, E MarT

The Wirtgen surface miner was investigated for application to the Cloud Break iron ore deposit since it can selectively mine thin seams and there is no requirement for drilling and blasting or primary crushing as the surface miner cuts and breaks the rock to secondary cone crusher feed size. A physical metallurgical study of the surface miner run-of-mine (ROM) from Cloud Break was conducted to better understand the product size distribution, amount of -31.5 +6.3 mm lump produced, lump stability and physical metallurgical quality compared to conventional drill and blast techniques. Since the Cloud Break mine was not in production, the lump product from crushing and screening of surface miner ROM was compared with product simulations using traditional premining physical metallurgical processing techniques including drop testing of PQ diamond core. Drop test conditioning is widely used in the iron ore industry to simulate blasting, crushing and screening at the mine and subsequent product degradation during handling from mine to port to predict both the amount of lump product on ship and the size distribution of the fines and lump. The size distributions of surface miner ROM for hard, medium and friable ore types show very tight size distributions with very little above 100 - 150 mm, about 60 per cent of the distribution between 75 and 6.3 mm, with less below 1 mm compared to conventional drill and blast ROM. Crushing, screening and drop test conditioning of the surface miner ROM produced more lump in equivalent ore types compared to drill and blast techniques or their breakage simulation using PQ diamond core. The higher lump yield from the surface miner was also confirmed by pilot scale crushing of some 7400 t of surface miner ROM from the Cloud Break trial pit. The lump produced from surface miner ROM was quite stable and showed similar low degradation characteristics to lump simulated from drill and blasting techniques. Product size distribution simulations using conditioned crushed lump from 1 m diameter Bauer hole samples were found to compare well with processed PQ core samples and surface miner product from trial mining at Cloud Break. The Bauer sample method is therefore considered to be a very useful close simulation to actual lump production, although the lump yield is lower.

Jan 1, 2007

By A. D. Thomas

Some years ago, the authors developed an analysis of non-Newtonian pipe flow based on enhanced turbulent microscale and associated sublayer thickening. This analysis, which can be used for various rheologic modelling equations, has in the past been applied to smooth-walled pipes. The present paper extends the analysis to rough walls, using the popular Bingham plastic equation as a representative rheological behaviour in order to prepare friction-factor plots for comparison with measured results. The conditions for laminar-turbulent transition for both smooth and rough walls are also considered, and comparisons are made with earlier correlations and with experimental data.

Jan 1, 2007

By J. O. Marsden

Over the past eight years, Phelps Dodge (a subsidiary of Freeport-McMoRan Copper & Gold, Inc.) devoted a significant amount of effort to the development of a suite of processes for the effective hydrometallurgical treatment of copper sulfide concentrates. This effort resulted in the development of high-temperature (>200ºC) and medium-temperature (150° to 165ºC) pressure leaching processes. Specific configurations of both processes have been commercially demonstrated at Phelps Dodge?s facility in Bagdad, Arizona. This paper reviews in detail the chemistry of medium-temperature pressure leaching of copper concentrates and reports on the process development work conducted by Phelps Dodge and others for this technology. This paper is Part I of a four-part series on this technology. Part II covers the development of medium-temperature pressure leaching and direct electrowinning technology; Part III considers the large-scale demonstration of the MT-DEW-SX process at Bagdad, Arizona; and Part IV addresses the development and design of a full-scale commercial application at Morenci, Arizona.

Jan 1, 2007

By Li-ming Qi

During mining, the stress in the coal face varies, and, at the same time, the gas flows from the coal body into the excavation, which will cause the gas pressure to change continuously. Assuming the coal gas content of the coal to be constant, and applying the law of energy conservation, the influence of stress concentration on the gas pressure was analysed. It was found that the stress is proportional to the gas pressure. Finally, as a result of analysis and the law of gas flow, the gas pressure dynamic distribution ahead of tunnelling was modelled, and the mechanism by which blasting induces outburst was explained by making use of the model. Keywords: gas pressure, stress concentration, excavation, tunnel.

Jan 1, 2007

By J. A. Finch

"Much progress has been made over the last several years in the ability to measure flotation cell hydrodynamic parameters in both the laboratory and plant. These techniques have allowed fundamental research to proceed to determine the effects that frother chemistry has on the main hydrodynamic parameters (gas hold up, bubble size) as well as on the amount of froth generation and water content of froth. A research program was begun that brought together a team consisting of private companies and a University with expertise in hydrodynamic characterization (McGill), flotation reagent applications (Flottec) and chemical synthesis (Sasol N.A.) with the purpose of characterizing frother chemistries with two goals in mind: Determine which frother chemistry can provide optimized cell hydrodynamics; and, create new frother chemistries with specific hydrodynamic properties.This paper describes the key steps that were taken that led to the development of new frother chemistry for use in flotation.The first step was the characterization of the major frother chemical families in a two phase system. The parameters measured were gas hold up, bubble size, froth height and water carrying rate at different concentrations and gas velocities.Analysis of the data indicated that definite patterns existed between frother chemistry and hydrodynamics and showed that frothers could be grouped into classes. More importantly, by modifying known frothers through chemical reaction it was shown that these frothers could be moved from one class to another. As a result of this better understanding of the interdependence of hydrodynamic and chemical properties, a new frother chemistry was proposed that was predicted to perform similarly to MIBC.The new frother was synthesized and hydrodynamic testing confirmed that the chemical performed similar to MIBC. Laboratory flotation tests were conducted on two different ore types that also confirmed the similar performance of the new chemical and MIBC. Subsequently, the new product was placed on a plant for a short period of time. The results showed that the product was an excellent frother but increased the flotation rate slightly more than MIBC at the same addition rate.Further research showed that the new frother chemistry was a family of products. By changing the reaction the resultant products could be made to be slightly weaker or stronger than MIBC but that this chemistry cannot provide hydrodynamic/froth characteristics similar to strong frothers like glycols and glycol ethers. Further work is planned to conduct longer plant trials to confirm the efficacy of this new frother family."

Jan 1, 2007

By Ricardo Dobry, Alain Pecker, George E. Leventis, Ralph B. Peck

"This year’s DFI Outstanding Project Award is for the design and construction of the foundation scheme for the largest cable-stayed bridge in the world. In 1993, Gefyra, SA (a French/Greek consortium led by VINCI of Paris, France) was awarded a €750 million ($1billion+ USD) Concession Contract to design, build, fi nance, operate and maintain a three-span cable-stayed suspension bridge connecting the Peloponnese, Greece’s southernmost peninsula, with the mainland across the Gulf of Corinth. The contract extends over a 42-year period, 7 years for design and construction and 35 years for operation. The project was fi nanced through a combination of public funds, private equity and bank loans. Alternative foundation concepts that were considered included traditional driven piles, deeply embedded caissons and soil improvement. PROJECT CHALLENGESThe extreme technical challenges faced included:??Weak foundation soils composed of soft alluvial deposits consisting of interbedded layers of granular and cohesive materials with thin layers and lenses of gravel and liquefi able sand pockets; rock is believed to be at a depth of 1,000 m (3,500 ft) or more.??A very deep seabed exceeding 60 m (200 ft).??The requirement to withstand the collision of 180,000-ton tankers traveling at 16 knots.??Maximum wind forces of 250 km/hour (155 mi/hour).??Design seismic forces corresponding to Richter magnitudes of 7.0+ with peak ground accelerations of 0.48 g at seabed.??Design tectonic movements of 2 m (7 ft) in any direction between any two adjacent bridge pier foundations/pylons.Considering subsurface conditions and local seismicity and water depths, foundation design and construction methods were the key drivers for this project. In large part, the success of the project is owed to the unprecedented partnering and collaboration between all partners involved fostered under the leadership of Jean Paul Teyssandier and Gilles De Maublanc of VINCI Group (France) who served as lead Concessionaire and General Contractor. The joint venture’s lead Greek partners were Elliniki Technodomiki/AKTOR and J&P/AVAX. Alain Pecker of Geodynamique et Structure (France) served as lead Geotechnical Consultant/ Designer while Buckland and Taylor (Canada) served as Design Checkers with Ralph Peck and Ricardo Dobry (U.S.) as Special Advisors on foundation issues, Langan International/Langan Engineering and Environmental Services P.C. (George E. Leventis, Gregory Biesiadecki and Diane Fiorelli) served as Technical Advisor on geotechnical, geodynamic and foundation/marine construction issues."

Jan 1, 2007

By Arthur L. Miller

Recent studies suggest that trace metals emitted by internal combustion engines are derived mainly from combustion of lubrication oil. This hypothesis was examined by investigation of the formation of particulate matter emitted from an internal combustion engine in the absence of fuel-derived soot. Emissions from a modified CAT 3304 diesel engine fueled with hydrogen gas were characterized. The role of organic carbon and metals from lubrication oil on particle formation was investigated under selected engine conditions. The engine produced exhaust aerosol with log normal-size distributions and particle concentrations between 105 and 101 cm-3 with geometric mean diameters from 18 to 31 nm. The particles contained organic carbon, little or no elemental carbon, and a much larger percentage of metals than particles from diesel engines. The maximum total carbon emission rate was estimated at 1.08 g h-1, which is much lower than the emission rate of the original diesel engine. There was also evidence that less volatile elements, such as iron, self-nucleated to form nanoparticles, some of which survive the coagulation process.

Jan 1, 2007

Paper 1: Risk of gastrointestinal cancers from inhalation and ingestion of asbestos, John F. Gamble Selikoff suggested the hypothesis that asbestos exposure is causally associated with increased risk of gastrointestinal (GI) cancers in an early study of insulation workers. In this paper, John Gamble reports on his extensive review and reanalysis studies that address the relationship between asbestos exposure and GI cancers. The purpose of the review was to evaluate the association between asbestos exposure and risks of stomach, colorectal, colon, and rectal cancers separately. Gamble evaluated exposure?response (E?R) relationships using surrogate exposure methods ??because few individual studies of GI cancer have reported exposure? response analyses.?? The principal asbestos exposure surrogates are: (1) the rate ratio (RR) for lung cancer; and (2) the percent of mesothelioma among exposed workers. Analyzing SMRs for GI cancers from individual studies versus the risk of lung cancer and mesothelioma provides crude estimates of E?Rs for asbestos exposure and GI cancer. Briefly, Gamble justifies the surrogate approach as follows:

Jan 1, 2007