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By X Liu

The crystal chemistry of carbonate in Ca apatites, including Na-free and Na-bearing hydroxylapatite (CHAP) and Na-bearing fluorapatite (CFAP) and chlorapatite (CCLAP), has been investigated by Fourier transform infrared (FTIR) spectroscopy and single-crystal X-ray structure, using crystals synthesised from carbonate-rich melts at 1 GPa, 1400 - 1000¦C. The carbonate ion substitutes for both the X (OH, F, Cl) anion species in the apatite channel (type A carbonate) and the phosphate group (type B carbonate). The type A carbonate ion is oriented in the channel with two oxygen atoms close to the c-axis, and the type B carbonate ion is located close to the sloping faces of the substituted phosphate tetrahedron, with details varying with composition series. Sodium promotes the uptake of type B carbonate and also has a profound effect on FTIR spectra. Crystal compositions correspond approximately to the substitution formula Ca10-(y+z)Nay z[(PO4)6-(y+2z)(CO3)y+2z][X2-2x(CO3)x], with x + y up to 1.0 and z + 0.0 for CHAP, x + y + 4z + 0.4 for CCLAP, and x + y + 2z + 0.1 for CFAP, for equivalent conditions of synthesis. The sodium cation and A and B carbonate ion defects are locally coupled in all three composition series to facilitate charge compensation and minimise the effects of spatial accommodation. Synthetic Na-bearing type A-B CHAP with x + y + 0.5 has a similar chemical composition and FTIR spectrum to biological apatite.

Jan 1, 2008

By I M. Platten, Y Xie

Narrow vein gold mineralisation generally contains both fine (<100 ¦m) and coarse (>100 ¦m) gold particles. The in situ size and shape, deportment, distribution and abundance of the particles controls deposit sampling characteristics, grade distribution and metallurgical properties. Particles can range from individual disseminated grains, clusters of particles and masses above 1 cm in size. At each end of the coarse-gold to fine-gold spectrum, the samplability of a deposit ranges from relatively simple for fine-grained disseminated gold particles, through to extremely difficult for very coarse particles. Deposits generally show a background grade of mineralisation dominated by disseminated fine gold particles. Drilling will resolve the background grade well, though is likely to considerably understate the grade related to the coarser gold particles. Gold mineralogy has a significant impact on metallurgy, with key factors affecting recovery being particle size, deportment, liberation parameters and silver content of gold minerals. For coarse gold particles the focus should be on liberation and the early removal of the particles from the mill circuit by gravity concentrators and gold traps. Finer particles will require more grinding to liberate prior to flotation or cyanide extraction. The determination of gold particle sizing is thus required to minimise evaluation and geometallurgical uncertainty and lower project risk.

Jan 1, 2008

Because of the work of the pioneers of sampling theory, we know the principles, test work and equations to use to design sampling systems to meet targets for precision and accuracy. However, we do not see such æproperÆ systems deployed everywhere a sample is obtained around mineral processing plants. In many cases, we do not have solutions that satisfy all of the theoretical, economic and practical considerations. There are some well-known problems, such as high-volume streams with wide size distributions combined with a sparse valuable component that is heterogeneously distributed (such as gold ore SAG mill feeds). However, other difficult sampling issues are common, such as streams which vary widely over a day in flow rate and slurry density (many flotation concentrates), and loaded CIP carbon on transfer to elution. Inventory measurement issues abound, especially for leaching operations where daily inventory change is significant for metallurgical accounting. The result is that operators realise that although they issue reports daily, they do not know what is actually going on in their plant on a daily basis with sufficient confidence to quickly diagnose problems or confidently predict the benefits of potential enhancements. The industry needs practical and economic solutions that can be awarded the ætheoretically correct samplerÆ tick in order to better understand and optimise their processes.

Jan 1, 2008

By Joseph Poplawski, Christian O’Keefe, Robert Maron

"Unique and difficult minerals processing measurement situations will be described and the application of passive array-based technology for performing these measurements will be illustrated. Examples of these situations include volume flow measurements in froth lines and flotation feed lines with entrained air, slurry lines with magnetite and other magnetic ore, slurry lines with abrasive or corrosive materials, high pressure lines, and slurry and non-slurry lines exhibiting scale buildup. Other situations include measurement of entrained air levels in pipes and in flotation columns. These measurements are achieved through CiDRA’s patented passive sonar array-based technology. This technology performs two independent measurements – flow rate and entrained air amounts. Two hardware implementations of this technology have resulted in a non-intrusive flow and entrained air meter which easily is installed on the outside of the pipe, and a submersible version for entrained air or gas holdup measurements which is used in flotation processes. Recent developments in extending this technology to solve other unique measurement problems such as valve movement confirmation will be covered.INTRODUCTIONThe minerals processing industry faces many unique and challenging process control conditions and environments. In terms of flow measurements, many of these situations are not being properly served by traditional flowmeters such as ultrasonic meters, magmeters, turbine meters, orifice plate meters, vortex flow meters, Coriolis flow meters, and venturi meters. A new class of flowmeters has been developed that solves these unique situations and flow measurement problems. This new class of flowmeter technology utilizes sonar-based processing algorithms and an array of passive sensors to measure not only flow, but also fluid composition. It does so accurately, reliably and without making contact with the fluid. These measurements are performed on practically any type of fluid within virtually any type of pipe.PRINCIPLE OF OPERATIONSonar array-based flowmeters are ideal for tracking and measuring the mean velocities of disturbances traveling in the axial direction of a pipe. These disturbances generally will convect with the flow, propagate in the pipe walls, or propagate in the fluid or slurry. First let us focus on the disturbances that convect with the flow. The disturbances that convect with the flow can be density variations, temperature variations or turbulent eddies. The overwhelming majority of industrial flows will have turbulent eddies convecting with the flow, thus providing an excellent means of measuring the flow rate as described below."

Jan 1, 2008

By Thomas Weyand, Thomas Claridge, Dale Nickels

"This paper addresses the initial results of a project to evaluate the suitability of copper mining tailings as raw material for the production of structural products using PMET’s patented technology. Preliminary testing indicated that high performance structural products were possible using these materials. A demonstration scale project produced approximately 1,500 bricks in various colors. These products fall under under ASTM C- 73 and were found to present properties suitable for severe weather applications. Although the products in this project were of typical brick dimensions, other products are possible, for example concrete block substitutes or pavers. These products from the PMET process are commercially known as Brixx. This paper will provide operational details of the production process, mineralogy and mechanical properties of the products.INTRODUCTIONPMET has developed process technology that can convert various siliceous waste materials into competent structural products. This technology is the subject of US patent # 6,068,803. In general, the process consists of mixing lime, water and the major feed stock, pressing to form a “green” shape, and curing the product in an autoclave for 6 hours with saturated steam at ~200oC. The curing process forms Tobermorite, which acts as a crystalline binder. Freeport-McMoRan approached PMET to see whether mine tailings from the Sierrita mine, containing significant amounts of clay, might be a suitable feed material for the production of structural products. “Brixx” is the commercial term used to describe the resultant structural product formed in the test work. This paper is a preliminary evaluation of a technology that is being considered by Freeport-McMoRan. This report is not an endorsement by Freeport-McMoRan of the process or products, nor is it a commitment to use this technology."

Jan 1, 2008

By B Vorster

Falls of Ground is one of the highest causes of incidents, accidents and fatal injuries in our mines today. These falls of ground may occur as soon as the face is exposed after blasting or after machine cutting. The falls of ground can also occur after support has been installed. There are many reasons why these falls occur before and after supporting of the face. It is therefore important to support the exposed face as soon as possible to prevent the falls of ground. It is also very important to support the face with the correct support products and to support the face as designed and required by the mining engineers. The possible reasons for falls of ground, possible support methods and the products available will be discussed in this presentation. In typical conventional narrow vein stoping operations, the use of conventional temporary support components to offer some support to workers, whilst the permanent and generally more elaborate support system gets installed or constructed, still results in injuries to people. The author wishes to discuss the following items in this paper:- ? Introduction ? Basic face behaviour after exposure ? Controllable Parameters ? Mining Engineers support designs ? Primary and Secondary Support ? Products available for prevention of falls of ground

Jan 1, 2008

By V N. Rudashevsky, F Melcher, J Lodziak, D Klosa, N S. Rudashevsky, M Sitnikova, L Gast

A combination of novel and æclassicÆ methods, namely electric pulse disaggregation (EPD), hydroseparation (HS), preparation of monolayer polished sections, and mineral liberation analysis (MLA) was employed to study ores from platinum pipes (Bushveld Complex, South Africa), pristine PGE mineralisation of the Main Sulfide Zone (Great Dyke, Zimbabwe), as well as ancient and modern gold/PGM placer deposits. It is shown here that the EPD technique liberates mineral grains of interest without any visible destruction allowing the study and analysis of individual rock-forming and ore minerals, in our case especially platinum-group minerals. The HS method is an effective tool in concentrating heavy minerals by factors up to 10 000 fold. As near-total recovery of grains >10 ¦m is achieved, the nugget effect can be overcome also in case of limited availability of samples (drill core, museum specimens). The MLA technique is a fast tool to detect and characterise mineral phases in ores and ore processing products. Many mineralogical parameters of individual grains and mineral assemblages can be deducted and documented. The results show that the techniques employed, either on their own or in combination, provide a wide range of additional information especially on platinum ores which is beneficial to both the researcher and the metallurgist.

Jan 1, 2008

By L Faulkner

The Tarnagulla Gold Project in Central Victoria, Australia, was developed and operated by Reef Mining NL between 1994 and early 2000, producing 53 000 ounces of gold from the Nick OÆTime Shoot, a single narrow vein shoot structure within part of the larger Poverty Reef, with a strike length ranging from 30 m to 60 m. The ore shoot was developed over a vertical interval of 190 m, using a small cross-section decline and small, mechanised equipment. Various stoping methods were employed including mechanised cut-and-fill with a single boom jumbo, hand-held mining using airleg drills and rope scrapers, and small uphole retreat stopes using a line of sight remote operated LHD to recover a crown pillar. Experience during stoping showed that airleg drilling and rope scrapers gave much better dilution control than diesel equipment. Innovations included a low-cost hydraulic fill system. Due to the small scale of the deposit, the feasibility studies, planning and permitting for the mine were based on very limited drilling information; however, the mine was brought into production within two years of the discovery. While the mine made an operating profit, it failed to fully repay capital at the low gold price then prevailing. Applying the lessons learned from the operation to optimise the access and stoping method, the project is re-examined at todayÆs gold price and operating costs. Central Victoria has the potential to host many similar small deposits. The authors were respectively Non-Executive Director and Resident Manager for Reef Mining NL when the mine was operating.

Jan 1, 2008

By J. Danoczi

Specially designed X-ray machines are used extensively on diamond mines for the recovery of diamonds from ores. These machines are extremely expensive and, at present, there are no reliable methods of determining if the equipment is performing efficiently. The objective of this work was to manufacture translucent X-ray diamond simulants, which would emit varying but known luminescence signals when exposed to X-rays. These X-ray diamond simulants could then be used to determine the efficiency of diamond recovery operations.

Jan 1, 2008

By S. Zaharia

The authors present the state-of-the-art regarding natural and anthropic hazards on the stability of the saliferous Costiui basin. The factors that may potentially result in sliding, piping and collapse, are emphasized, given the existence of a large number of old salt mines. Also, a geotechnical risk map of this hydrosalt complex in Romania is presented.

Jan 1, 2008

By James O'Brien, Lyman Frost, S. Elangovan, J. Stephen Herring, Joseph Hartvigsen, Carl Stoots, Anthony Nickens

"Carbon dioxide recovered from concentrated sources, such as metallurgical reduction furnaces, cement kilns and fossil power plants can provide a valuable feedstock for a synthetic fuels industry based on energy from nuclear, solar, wind and hydropower sources. High temperature co-electrolysis of CO2 and steam to produce synthesis gas has been demonstrated using reversible solid oxide fuel cell technology. Where a source of high temperature process heat is available, such as from an advanced high temperature nuclear reactor or solar dish concentrator, the endothermic electrolysis reactions can utilize both thermal and electrical inputs in such a way that the conversion efficiency within the cell is 100%. Synthesis gas produced in a coelectrolysis cell has been further reacted over a catalyst to produce conventional hydrocarbon fuels. Widespread implementation of synfuel production from CO2 will enable a much larger reliance on intermittent renewable energy than can be accommodated by conventional electric demand profiles.IntroductionFor the past several years, Ceramatec, Inc and the Idaho National Laboratory (INL), have been studying the feasibility of high temperature solid oxide electrolysis for large-scale, nuclearpowered hydrogen production under the U.S. DOE’s nuclear hydrogen initiative (NHI) as an alternative to the thermochemical process. Parallel to this effort, the INL and Ceramatec have been researching high temperature co-electrolysis of mixtures of steam and CO2 to produce syngas:"

Jan 1, 2008

By Xinzhi Du

Coal strength is essential to analyze the stability of excavation in coal. It is well known that the strength of coal tested in the laboratory is size-dependent, and different size specimens will produce different strength. Many researchers have studied the uniaxial compressive strength of coal and developed a number of empirical formulae to describe the strength variation with specimen size. According to a comprehensive data base that includes most of the laboratory testing results in the last century in U.S. and South Africa, the size effect and shape effect were reviewed and analyzed. The results show that different groups of coal specimens have different size effect on the compressive strength. The critical size for the size effect from the data analysis is about 40 in. The shape (W/H) of the specimens has a large effect on the compressive strength. The pillar strength formulae obtained from the data regression have a larger strength than all other existing formulae. Most pillar strength formulae have their own place in coal pillar design field. In order to analyze the difference of those formulae, twelve design formulae have been selected to compare using the Pittsburgh coal seam. The intention is not to determine the preferred formulae, but only to compare them, and see how do the W/H ratio, width, length, angle, cross-section area and effective width affect different pillar strength formulae?

Jan 1, 2008

By Tamara Whitaker, James Gunderson, Ruilin Yang

This paper presents the results of a vibration control project conducted in soft overburden at a surface coal mine located in the western United States. The study uses near-field blast vibration monitoring, analysis and modeling techniques developed in house. Accelerometer-equipped seismographs were utilized for near-field vibration monitoring and analysis. Vibration control was achieved through field data regression as well as vibration modeling using the multiple seed near-field blast vibration model (Yang and Scovira, 2007). The regression was conducted between peak particle vibration parameters and the minimum scaled distance per delay. From the regression analysis, the curves of upper bounds for peak particle vibration parameters and charge weight were developed. The dominant frequencies of the blast vibration were also addressed in this project. The regression curves and near-field vibration model guided the blast design to control blast vibration for maximizing the recovery of coal and maintaining mine productivity.

Jan 1, 2008

By Dan Payne

The Crinum mine has recently completed workings in the southern area of the mine. Over the 10 years of longwall production 40 million tonnes have been extracted and the mine has experienced over 40 longwall face, 3 main gateend, and 2 tail gateend roof falls as well as 5 roadway roof falls away from the longwall. Weak roof (less than 10MPa (1450psi) in the bolted horizon) has been the principal roof control issue at the mine. However, weak, highly cleated coal, water inflow from overlying aquifers, some minor structure and a diatreme in the main headings have also contributed to the challenges at the mine. This paper describes the geotechnical experience over the 10 years, the mine?s approach to addressing the issues and the relative success of these approaches.

Jan 1, 2008

By J W. Harris

There are numerous detrital diamond deposits worldwide with uncertain or disputed links to known primary kimberlite/lamproite sources. In this study, we utilise 40Ar/39Ar dating of clinopyroxene inclusions in diamonds as a provenance tool applied to the mega-placer deposits along the West Coast of southern Africa. These data demonstrate that most West Coast diamonds originated known Cretaceous kimberlites on the Kaapvaal craton with negligible input from proximal Permian glacial deposits. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Xiao Y. Yan

A fused salt electrochemical process was investigated for the synthesis of non-oxide ceramic powders directly from metal oxides, boric oxide, and carbon powders by electro-deoxidation. Sintered pellets of the mixed powders were designed to act as a composite cathode in the electrolytic cell. Electrolysis was carried out in molten CaCl2-NaCl eutectic at 3.1 V and at 600-900 ºC under argon. The favoured cathodic reaction was the removal of the oxygen from the oxides to produce metal atoms that reacted with either the reduced boron atoms, forming a metal boride, or the carbon initially present in the sintered pellets to produce a metal carbide. The technical viability of the process was demonstrated by the electro-deoxidation of sintered pellets of TiO2/B2O3 and TiO2/C to produce TiB2 and TiC, respectively. Compared to existing carbothermic reduction process, this new electrochemical process may be less energy intensive and may lead to lower production costs. I

Jan 1, 2008

By Milorad Cirkovic, Mile Bugarin, Vlastimir Trujic

"Industrial scale testing was performed in the plant-site of Bor Company. Charging sample was from 4-5 tons for each particular test. All operations in industrial scale investigations were carried out in one furnace. For the aim of successful realization of experiments, and primarily for safety and prevention the risk of toxic contamination the working environment, a plant was designed and constructed for cooling and wet dedusting of gases formed during smelting process, zinc removal and flame refinement of molten metal. For the requirements of industrial investigations a complete plant for cooling and wet dedusting of gases has been constructed for brass scrap processing. In this plant, the original ultra-sonic water spraying devices have been installed. The efficiency of such simplified system for gas treatment has been 98,6%. Introduction Permanent development of techniques and technology causes formation the considerable quantities of secondary raw materials that are much more relevant as the raw material base for many metals. Due to a fact that large quantities of metal, are concentrated in the waste materials, large consideration is given to this topic, and numerous technologies for this waste recycling are developed in the world nowadays. High energz price and permanent increase of metal price on the world market have made that secondary raw material tretament, for the aim of various metals production, becomes more and more relevant in the world. In comparison of metal production using enrichment and metallurgical treatment of primary raw materials, the non-ferrous metals production from secondary raw materials has a range of advantages, as well as: - Low level of capital investments, - High technological recovery of qualitative secondary raw materils, - Considerably low consumption of energetic resources regarding to the treatment of primary raw materials (ore and concentrate), - Reduced consumption of unrecoverable mineral resources, - Reduced enviroment pollution [1,6]."

Jan 1, 2008

By D. I. Smith

Constructing tunnels in congested urban areas requires tunnels to be placed closer together and with less cover than was previously necessary. Contract CQ031 of New York?s East Side Access project will construct four six-meter diameter bored tunnels in a three-up one-down ?T? configuration, with less than three meters of soil between the tunnels. Mixed-face rock and glacial till conditions with a high ground water table will be encountered under active railroad yards. The tunnels will also pass beneath the busiest railroad interlocking in North America with cover as shallow as three meters. This paper discusses the challenges of designing segmentally lined tunnels for these conditions.

Jan 1, 2008

By Kyle L. Murrell

Along the southeast United States coast, clayey silt and silty clay marine formations may cause pile installation and integrity problems. More specifically, excess pore pressures which develop in these soils during driving can cause high displacement piles to rebound or ?bounce?. Bounce is defined as a large (¾-in. to more than 1-in.) downward pile displacement during the hammer blow with little to no net displacement at the end of the blow. Pile bounce can generate damaging tension stresses and result in inefficient pile installation. A case history is presented where pile bounce was observed during the installation of 20-in. square ?high displacement? prestressed concrete piles which support a new ferry terminal in coastal North Carolina. High-strain dynamic pile testing was performed during test pile installation to evaluate driving stresses, pile capacities, and hammer performance. During and after installation of numerous production piles, circumferential cracking was observed on some of the piles. Additional high-strain dynamic pile testing was performed on two piles installed with a hammer having a heavier ram than the initial hammer. The new driving system generated lower tension stresses and installed the 20-in. piles more efficiently. Low-strain integrity testing was performed on the piles to qualitatively assess the cracks and locate any unidentified cracks. The low-strain testing was performed on piles installed at least a week prior to testing and on piles installed immediately prior to testing. When low-strain testing was performed immediately after pile installation before dissipation of excess pore pressures, pile integrity could be evaluated to depths of at least 12 pile diameters deeper than when performed weeks after installation.

Jan 1, 2008

By M F. Lee

In order to make good decisions, as to whether large diameter raise bored shafts can be constructed in blocky rock at a particular location, mine planners, management, geotechnical engineers and contractors must understand and consider a range of geotechnical issues. Firstly, mine management must ensure that adequate time and resources are available to find appropriate shaft sites. Deep weathering, adverse structures, groundwater, etc might mean that the most desirable location, with respect to other mine development, might not be suitable. Special site investigation drilling, etc may be necessary. Even then, alternative construction options might be necessary, other than just reaming through to the surface. A site investigation borehole should then be drilled to investigate specific and general ground conditions along the raise alignment. Often, only small sections of weak blocky rock dictate raise stability. While the empirical McCracken and Stacey method is typically used in Australia to assess raise stability and assess geotechnical risk, until recently it had no published performance data.An Australian database of raise performance now exists and is presented below, courtesy of an industry survey by the Eastern Australian Ground Control Group. Raise diameter and ground conditions (in terms of a lower bound Qr value) is presented for 50 cases versus raise performance.

Jan 1, 2008