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By Pengkai Wang, Huimin Lu, Xiaoxiang Zhang

"In this paper, it was studied an electrochemical reduction process of carbon dioxide in ionic liquids such as 1-n-butyl-3-methylimidazolium hexafluorophosphate ([Bmim] PF6) as the electrolyte. The electrolysis experiments were carried out under current and potential controls. The cathode products contained carbon nanotubes, carbon nanofibers, nanographites, and amorphous carbon. To establish the actual current and potential ranges, the electroreduction of carbon dioxide dissolved in the ionic liquid was studied by cyclic voltammetry on glass-carbon (GC) electrode at room temperature. The electrochemical mechanism of carbon dioxide electroreduction was studied for explanation of all obtained results. Carbon dioxide in ionic liquids was electroreduced, similar to metals oxides being electroreduced in molten salts.IntroductionGlobal warming caused by the increase of carbon dioxide in the atmosphere has become one of the most concerning environment problems, so the solution to this greenhouse effect is very urgent. However, the carbon dioxide is also a cheap and abundant raw material that represents a potential source for the production of chemicals and fuels. Therefore, the development of the technologies that achieve simultaneous reduction and conversion of carbon dioxide to fuels is important. The electrochemical reduction of carbon dioxide is one of the effective approaches to transform CO2. Many investigations have been carried out on the electrochemical reduction of CO2 in both aqueous [1] and non-aqueous [2] electrolyte solutions with different electrodes. The solubility of CO2 in water is very low even under high pressure of CO2, and some investigators have brought focus into the electrochemical reduction of carbon dioxide in organic solvents, because they dissolved much more CO2 than water did. However, the hazardous or toxic properties of organic solvents hinder their use."

Jan 1, 2009

The platinum group of metals (PGMs) possess a range of unique chemical and physical properties and arc increasingly finding important uses in a wide variety of environmentally-related technologies (eg. catalytic conveners, fuel cells, electronics). The typical ore grade for PGM mineralisation is similar 10 gold (gil) but the processing is more akin to base metals (at percent). The typical scheme for a PGM project is a mine, flotation concentrator, smelter and refinery. The environmental costs could therefore expected to be more significant than gold mining -in contrast to the uses for PGMs in many environmentally focussed technologies. The global production of PGMs is dominated by South Africa due to their large economic PGM resources in the Bushveld Complex, while other countries playa minor but important role. Concerns arc being raised about the long-term ability to supply PGMs to meet future technological needs, as well as allegations of significant environmental and social impacts such as water pollution, unfair village relocation and compensation issues. This paper presents a detailed review of the platinum-PGM industry and major environmental costs such as water, energy and greenhouse emissions. The relationships between production statistics and environmental or ?sustainability metrics' are then investigated with a view to understanding the current trends in PGM mining and potential future implications. The paper presents a unique case study for a group of metals which are uniquely concentrated in one major region of the earth and pose some intriguing and difficult sustainability issues for the future.

Jan 1, 2009

By K. A. Lewandowski

Binders have been suggested as an aid for agglomeration to improve copper recovery in heap leaching operations. However, it has not been established if the use of binders would negatively affect the solvent extraction process, which is used to purify the pregnant leach solution from the heaps and remove any contaminants. Such negative effects would lead to an increase in processing costs or a decreased in copper production. The controlled studies reported here have shown that some binders (a polyacrylamide and a waste treatment additive) did not interfere with the solvent extraction process. Other binders (a polyvinyl acetate emulsion and tall oil pitch) negatively impacted copper solvent extraction and, therefore, should not be used in copper heap leaching plants.

Jan 1, 2009

At the Prospectors and Developers Annual Convention (PDAC) in Toronto, Canada mining and exploration companies of all sizes were on hand to discuss the year that was and those that will be. The following is a look at some of the companies with Canadian operations that were on hand for PDAC 2009. Iamgold Corporation is a leading mid-tier gold mining company producing approximately 31 t (1 million oz) of gold from seven mines on three continents. With record revenues of $870 million ? up 28 percent when compared to 2007 ? the company is focused on growth with a target to reach 56 t (1.8 million oz) gold production by 2012. During 2008, the company acquired the Essakane project in West Africa. The project is fully permitted, under construction and will contribute more than 9.3 t (300,000 oz) of lower cost production by late 2008. Iamgold increased its reserves by 55 percent, to 385 t (12.4 million oz) and its resources in-creased by 16 percent to 821 t (26.4 million oz) in 2008. Going forward, Iamgold has three areas of focus ? West Africa, Guyana Shield and Quebec ? with seven gold operations, five advanced projects and the Niobec niobium mine included. The Rosebel Mine in Suriname is Iamgold?s fl agship property. With measured and indicated resources of 300 t (9.6 million oz), it accounts for 30 percent of Iamgold?s production. Production there was up 20 percent compared with 2007 and further production increases are expected in 2009 and 2010. Mill expansion and optimization increased throughput from 8.9 Mt/a (9.8 million st) to 10 Mt/a (11 million stpy). In West Africa, Iamgold has joint ventures at Sadiola in Mali; Tarkwa in Ghana; Yatela in Mali and Daman in Ghana. Iamgold also has 100 percent ownership of the Mupane gold mine in Botswana and the Doyon gold mine in Quebec, Canada. Also in Quebec, Iamgold has 100 per-cent ownership of the Niobec niobium mine in Quebec. Niobium is used in high strength specialty steels.

Jan 1, 2009

By Cheng Lin

The Group Equivalent Pile (GEP) approach was proposed by researchers to analyze a laterally loaded pile group. This approach enables engineers to evaluate the behavior of a pile group in single pile analysis software, such as LPILE. A previous study showed that the calculated results using the GEP approach for piles agreed well with field test data. To evaluate the accuracy of the GEP method for analyzing laterally loaded shafts, two case studies with different shaft diameters were performed in this study. The comparisons showed that the calculated results using the GEP method and considering the contribution of the shaft cap if embedded generally agreed with the measured from the full-scale tests.

Jan 1, 2009

By Wilson Acchar

The accelerated growth of urbanization processes and current environmental concerns brought to light the existing enormous quantity of construction and demolition waste (C&DW). Considering the frequent lack of adequate landfill areas available for the disposal of these materials, their use in the manufacture of ceramic products has been attracting a growing interest from researchers and is becoming common practice, with the consequent relief in public administration concerns for the C&DW appropriate management. This work describes the study of clay-based products added with C&DW collected directly from the construction industry. Samples containing up to 50 wt.% C&DW were uniaxially pressed and sintered in air in an electric furnace (950-1150 °C, 1 hour). Sintered test pieces were characterized by X-ray diffraction, apparent density, open porosity and flexural strength. The results showed that up to 50 wt.% C&DW can be added to the clay material, with no degradation in the final product properties.

Jan 1, 2009

By R McCarthy, P Darvall

FerrAus Limited's Robertson Range and Davidson Creek iron ore projects are located on the far eastern margin of the Hamersley Province, approximately 100 km to the east of Newman, Western Australia. The deposits are primarily formed of bedded haematite-goethite-limonite mineralisation within the Marra Mamba Formation, comprising a total combined resource of 164 Mt at 58.6 per cent Fe. The deposits represent relatively new discoveries for the Hamersley Province. The potential for mineralisation at Robertson Range was identified by Rio Tinto Exploration in 2000, while Davidson Creek remained untested until 2007. One of the main reasons for this is that these deposits are almost exclusively concealed beneath Tertiary sediments and recent transported cover making them difficult targets for conventional, prospecting style exploration. Since commencing exploration in the project area, FerrAus has collected nearly 20 000 stations of gravity data within the Robertson Range and Davidson Creek project areas, with most of this data collected at a 50 100 m station spacing. Gravity has proven itself to be an effective technique at predicting the position of the target host stratigraphy and has been a key driver in the exploration for concealed iron ore deposits. However, there is not always a perfect correlation between the position of gravity anomalies and concealed ore. The response of deep haematite bodies may be masked by low-density cover rocks, while other dense lithologies may be the cause of gravity anomalies which appear similar to the Marra Mamba targets. Hence, effective use of the gravity data requires interpretation in a geologic context with an understanding of the capabilities and limitations of the technique.

Jan 1, 2009

By O?Connor. D. F.

The ever increasing energy costs associated with mining at depth has become an important issue that needs to be addressed for future sustainable production. Vale Inco Limited?s Creighton Mine being the deepest has the highest energy cost per ton due to the ventilation system requirements. A review of the ventilation systems was undertaken with respect to current practices and identification of opportunities to the practical application of technology that would facilitate energy savings. Energy conservation initiatives such as time of day controls have been implemented; however there still remained some opportunity for further reduction. Based on previous studies that identified opportunities due to actual time spent in the workplace, our mining method and ventilation design, it was determined that Ventilation on Demand (VOD) could provide further additional energy reductions with respect to our auxiliary fans. A pilot project has recently been initiated to apply a Ventilation on Demand concept to two 112 kW auxiliary fans and their related workings located on the 2340m level of Creighton Mine. The project objective is to determine the practical methodology and application of this technology in the field. This project involves the installation of variable frequency drive (VFD) starters on the auxiliary fans to allow variable volume (through speed control) based on demand. The required flow is determined based on equipment and/or personnel via identification tags. The Fans adjust to the flow requirements as measured by flow sensors. Since the fans are sized for the final requirements the required flows can be achieved regardless of system length. Energy savings are realized by supplying only the volumes (power) as required and only when required. This paper discusses the rational and program being tested at the VALE Inco Limited, Creighton Mine.

Jan 1, 2009

By R. Q. Honaker

Dense medium processes are used to clean over 50% of the coal that is fed into preparation plant facilities worldwide. The dense medium is formed using ultrafine magnetite which is recovered after the cleaning step using drain-and-rinse screens and magnetic separators. Despite the high efficiency of the recovery system, magnetite losses of around 0.5 to 1.0 kg/ton are common. Considering the recent escalation of magnetite to around $300/ton, an alternative source of magnetic material from coal combustion bottom ash has been investigated. A relatively low cost recovery system has been developed. Dense-medium tests using the bottom ash magnetics revealed a high level of efficiency as indicated by probable error values around 0.03 over the range of medium densities investigated. The results from both the recovery and coal cleaning efforts will be discussed in detail.

Jan 1, 2009

This study was conducted to establish the effects of a diesel particulate filter (DPF) system with sintered metal substrate on the concentrations and size distributions of nano and ultrafine aerosols and concentrations of nitric oxides in underground mine air. The study focused on the formation and transformation of nucleation mode particles in mine air under prevailing test conditions. Experimental work was conducted in the NIOSH Diesel Laboratory at the Lake Lynn Laboratory experimental mine, a facility developed to allow evaluation of control technologies directly in underground conditions. The DPF system was examined for four repeatable steady-state engine modes using a naturally aspirated mechanically controlled Isuzu C240 diesel engine fueled with ultralow sulfur fuel. The engine coupled to an eddy-current dynamometer was operated in the underground drift with tightly controlled ventilation. Measurements upwind and downwind of the exhaust system discharge were used to quantify the effects of the DPF system on the mine air. A baseline was established using a standard muffler. The study showed that sintered metal DPF systems reduced the total mass of aerosols in the mine air by more than ten-fold when compared to a muffler. The nucleation mode aerosols (50dem<40 nm) in mine air were found to be strongly influenced by engine operating mode. The concentration of nucleation mode aerosols was found to be significantly higher for high-load modes than for low-load modes. The muffler and DPF system resulted in comparable total nitrogen oxides (NOx) concentrations. However, the nitrogen dioxide (NO2) fraction of the total NOx was found to be substantially higher for both systems for low-load modes than for high-load modes.

Jan 1, 2009

By A. D. Dalvi

With the current economic situation, the demand for nickel and other base metals has fallen significantly. More than 440 kt/yr world nickel capacity has been taken out of production within the last year, or more than 25% of the total [1]. This situation is similar to that at the end of 1970?s and it will take a number of years for the demand to recover to the levels before the economic downturn. In the meantime, the challenges facing the industry have increased due to diminishing ore grades, more inaccessible and complex deposits, mounting capital and operating costs and the various external pressures which include socio-economic, environmental, and energy challenges. All industries will be faced with paying the ?total ownership costs? in the future. This will only increase the burden on the industry. How to cope with this in what Thomas Friedman calls the ?Energy-Climate Era? [2] will be the most pressing challenge for the next generation of metallurgists and managers. It will force us to take a broader view of the problems and the solutions beyond mere technical. The metallurgists, engineers and project managers will have to look at the overall projects and their objectives in designing the solutions, requiring a top-down strategic approach.

Jan 1, 2009

By D. L. Jones

CESL has developed a novel hydromctallurgical process for treating Cu and Ni sulphide concentrates, including bulk concentrates. Both Cu and I\i are leached efficiently into solution, using a proprietary pressure oxidation process, along with other base metals, notably Co. A previous publication has described the Cu recovery from a low grade bulk concentrate, Mesaba, using this CESL Process, including an extensive piloting campaign. Ni and Co recovery from the same solution was investigated at the time, but not finalized. This paper will describe the latest work at CESL on Ni and Co recovery from the same concentrate.

Jan 1, 2009

Ceremonies for the induction of five mining industry pioneers into the National Mining Hall of Fame will be on Sept. 12, 2009 at the Charles F. Barber Pavilion of the Museum Convention Center in Leadville, CO. The five inductees are: Paul A. Bailey, 82, Richard T. Moolick, 89, William Braden and Alonzo Pawling and Henry Harnischfeger. Paul A. Bailly was president of Bear Creek Mining Co., the U.S. exploration subsidiary of Kennecott Copper, from 1961 to 1967. In 1968, he joined Occidental Petroleum Corp. and was tasked with creating the company?s international mining division, Oxymin, which he led as president through 1983. During his distinguished career, Bailly participated in numerous significant mineral discoveries, developed a new exploration philosophy and made important additions to the mineral exploration literature. William Braden was the first to recognize the immense potential of the El Teniente orebody in Chile. He founded Braden Copper Co. and developed the El Teniente Mine which now, 100 years later, remains the world?s largest underground copper mine. Braden?s endeavor survives to-day as the El Teniente division of the Chilean state copper company, CODELCO. T. (Dick) Moolick established a lasting legacy in the mining industry, first during a 35 year career with Phelps Dodge Corp. and then as the driving force in establishing the National Mining Hall of Fame and Museum in Leadville. The Hall of Fame and Museum ? a monument to the memory of the men and women who pioneered the discovery and development of the United States? natural resources ? has become one of the fi nest museums in the western United States.

Jan 1, 2009

By R. L. Virta

Editor?s note: Each year, the June issue of Mining Engineering features an industrial minerals review. Several people put in a fair amount of time in developing the material for this issue. Thank you to the industrial minerals annual review editor, to the technical committees chair and vice-chair, and to the authors of the individual commodity profiles. Jim Norman, member SME, of GeoTrans Inc., is the industrial minerals annual review editor. Abani Samal, member SME, of Pincock Allen & Holt, is chair of the industrial minerals technical committees. Technical committee vice chairs include: ? Abani Samal, member SME, of Pincock Allen & Holt, agricultural minerals. ? Aaron McMahon member SME, of Pincock Allen & Holt, ceramics and refractories ? Bradley S. Van Gosen, member SME, of the U.S. Geological Survey, chemical raw materials. ? Mark Zdunczyk, member SME, of Continental Placer Inc., construction materials. ? Jerry Gauntt, member SME, of Marston, fillers and pigments. ? Michael Cheshire, member SME, of Indiana University, sorbents, filters and process aids. ? Candace Trimble, Oil-Dri Corp. of America, specialty minerals. Their help makes possible this June industrial miner-als issue. On behalf of ME readers, the editors thank them. Ball Clay Four companies ? H.C. Spinks Clay (owned by Lhoist Group), Kentucky-Tennessee Clay (owned by Imerys Group), Old Hickory Clay, and Unimin Corp. ? mined ball clay in four states in 2008. Production, on the basis of preliminary data, was 964 kt (1.1 millon st) with an estimated value of $45.3 million. That was a 10- percent decrease in tonnage from 1.07 Mt (1.2 mil-lion st) with a value of $49.2 million that was produced in 2007. Tennessee was the leading producer state with 63 percent of domestic production, followed by Texas, Mississippi and Kentucky. About 73 percent of production was airfloat, 16 percent was crude and 11 percent was water-slurried.

Jan 1, 2009

By A. Tello

Variography was introduced by Dr. Pierre Gy to monitor a process, in the sixties. Later on, Francis Pitard extended this concept, building a complete system of variographic controls for different applications. Nevertheless, the existence of information about its use as a way to effectively control plants has been limited. There are infinite areas where variography and chronostatistics can be used. In this paper, two different cases related to gold and silver recovery, through well known but complex metallurgical routes are studied. The use of effective management of process variability software (EMPV) has shown to be a suitable solution to clarify problems at the plant and, consequently, a solution to the encountered problems has been proposed. Chronostatistics is like opening a new world to the metallurgist, making the process variability speak in a more comprehensive and in depth way. Once the ore has been extracted from the mine, sampling is necessary at each sequence of the metallurgical process involved. As a first example, leaching of the ore with cyanide in agitated tanks is another case of a complex metallurgy. The aim of the process is to know about residual values in the tailings in order to optimize process. As a second example, leaching of gold and silver in ore heaps, has to be optimized in terms of time, reagents consumption and, of course, in predicting a reasonable recovery. This last issue appears to be crucial. After cyanide leaching at the heaps, a carbon in columns process is involved, where there are a series of carbon loaded columns that are submitted to a dynamic process of load and unload, to finally deliver an enriched solution to the precious metal electrowinning plant. In both cases, variography has been a good approach to show metallurgists ways to improve the operation.

Jan 1, 2009

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Jan 1, 2009

The South American mining community leads the world in recognition and adoption of the latest grinding mill relining technologies. Clearly this region has recognised the benefits of improved relining performance as a defence against the Global Economic Crisis. Five of the six RUSSELL TWIN 8 Mill Relining Systems, ordered to date, are either operating or being manufactured for South American mine sites. The sixth is for Sino IronÆs Cape Preston Project in Western Australia. This paradigm shift, towards very short relining times, aims at displacing mill relining activities from the critical path of concentrator maintenance shutdown schedules. The first uses of the RUSSELL TWIN 8 Mill Relining System have seen some of the highest semi-autogenous grinding (SAG) mill new liner placement rates ever observed by Russell Mineral Equipment (RME), as would be expected with two, independent Machines working simultaneously in the one mill. The liner replacement rate, averaged over the whole reline is good (27 per cent improvement over single Machine System in the same mill) but short of full potential. This modest result can be attributed to reline crews unfamiliarity with RUSSELL TWIN 8 System operation. This paper compares a sample of conventional (single machine) RME Mill Relining System performance data with one ædouble headÆ mill liner handler by others. Early performance of EscondidaÆs new RUSSELL TWIN 8 System performance is then compared with recent single machine data from Escondida, immediately prior to RUSSELL TWIN 8 commissioning. RME and Escondida look to constantly improving RUSSELL TWIN 8 System performance as full operational familiarity is achieved. The preparation of this paper revealed a need to develop a global industry standard for mill relining data collection. A web based platform to develop data collection templates is also discussed in Appendix 1.

Jan 1, 2009

By L. Tonc

In 2004, the engineers at the Deer Creek Mine located near Huntington, Utah initiated the ventilation planning to exploit a remote area of the mine?s reserves. This area was located under a mountain which would not allow for the incorporation of an additional shaft or portal access near the proposed longwall panels. With this constraint along with the desire to maintain a two entry gate road system and the expected condition of frequent coal wash outs a ventilation plan was established. Different options were examined that included; increasing the current exhaust fan power, adding another exhaust fan installation, converting the ventilation fans in the active portion of the mine to a forcing system, and modifying the ventilation system in the active area of the mine to a push-pull system. The push-pull ventilation system was ultimately selected. This paper details the design process of the ventilation system upgrade, the procurement process for the new fans, and the new fan startup testing.

Jan 1, 2009

By Klaus-Markus Peters, James G. Hemrick, John Damiano

"Work was performed by Oak Ridge National Laboratory (ORNL), in collaboration with industrial refractory manufacturers, refractory users, and academic institutions, to employ novel refractory systems and techniques to reduce energy consumption of molten material processing vessels found in industries such as aluminum, glass and pulp and paper. The energy savings strategies discussed are achieved through reduction of chemical reactions, elimination of mechanical degradation caused by the service environment, reduction of temperature limitations of materials, and elimination of costly installation and repair needs. Key results of several case studies resulting from US Department of Energy (DOE) funded research programs are discussed with emphasis on applicability of these results to high temperature processing industries.IntroductionRefractory materials are limited in their application by many factors including chemical reactions between the service environment and the refractory material, mechanical degradation of the refractory material by the service environment, temperature limitations on the use of a particular refractory material, and the inability to install or repair the refractory material in a cost effective manner or while the vessel is in service. All of these limitations reduce the energy efficiency of the process as degraded refractory materials lead to loss of process heat (reduced insulation by refractories) and the need for maintenance through repair or replacement of refractory linings.This situation is conceptualized in Figure 1 which shows that when the thickness of the refractory wall is reduced by chemical or mechanical degradation, the heat losses through the wall increase exponentially. The subsequent maintenance to repair such conditions often requires cooling of the furnace or refractory lined vessel which entails loss of energy due to cooling and consumption of energy due to reheating. Additionally, production time and capability are sacrificed.Additionally, in most applications where refractories are used (metal melting furnaces, glass furnaces, steel making furnaces, gasifiers, etc.) wear of the refractory lining is not uniform. Very often, specific areas will wear (become thinner) more rapidly due to exposure to more corrosive or erosive conditions. This concept is illustrated in Figure 2, through the example of excessive metal line corrosion."

Jan 1, 2009

By C. D. Litton

Laboratory experiments were conducted to determine the responses of a prototype smoke detector and a commercially available photoelectric smoke detector to smoke particles generated from various combustion sources. The prototype smoke detector combines optical scattering measurements with ionization chamber measurements in order to reduce/eliminate nuisance alarms due to the presence of airborne dusts or diesel exhaust particles. The commercially available smoke detector is designed for use in harsh environments where airborne dust represents a major problem due both to nuisance alarms and detector contamination. In the experiments, the responses of the two detectors were measured when exposed to smoke particles from the exhaust of a diesel engine and from a variety of fire sources, including wood, coal, styrene butadiene rubber, and No. 2 diesel fuel. For the solid fuels, data were obtained for both smoldering and flaming combustion. This report describes the experiments, their results, and the use of these results as they apply to early-warning fire sensors capable of the rapid and reliable detection of fires in atmospheres that may or may not be contaminated by either airborne dust or the products produced from diesel engines. Subsequent to these laboratory experiments, six smoke detectors were installed in an underground limestone mine for further testing and evaluation. DISCLAIMER: The findings and conclusions in this report have not been formally disseminated by the National Institute for Occupational Safety and Health and should not be construed to represent any agency determination or policy.

Jan 1, 2009