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By M Wilkes, C-Q Liu

Microbial oxidation of refractory sulphide ores (particularly gold and copper ores) are well-established techniques that are increasingly employed because of their low capital and operating costs and environmental benefits. CSIRO has established a multidivisional project, the æBioMineral Processing InitiativeÆ, with the goal of generating new and improved high temperature micro-organisms for biological oxidation of these refractory ores. The project is currently focused on the discovery/generation of novel hyperthermophiles for the bioleaching of copper from chalcopyrite. As part of this project we are investigating the practicalities of genetic modification of iron/sulphur oxidising micro-organisms. The molecular biology of iron/sulphur oxidising acidophiles is still in its infancy. This work is aimed at improving our knowledge of vectors, promoters, selectable markers, gene transfer and expression in these organisms. The Acidithiobacillus ferrooxidans genome is currently available and genomics is proceeding at a rate where in the next few years we can expect at least one or two relevant microbial genomes to be sequenced each year. New genes that impart useful characteristics to iron/sulphur oxidising acidophiles will be available from published genomes and the study of newly isolated hyperthermophiles. We need to be in a position to clone and express those genes. This paper will describe the isolation, transfer and expression of thiocyanate hydrolase genes in Escherichia coli and At. ferrooxidans. Most common antibiotics are not effective against iron/sulphur oxidising acidophiles. Also, the use of antibiotics or their resistance markers outside of a laboratory setting would not be appropriate. Resistance to thiocyanate should be a useful selectable marker, without implications for human or animal health. Additionally, thiocyanate resistant iron/sulphur oxidising acidophiles might have application in gold bio-oxidation plants in arid areas where reuse of contaminated tailings water is desirable. The cloning of thiocyanate genes in broad host range plasmids under the control of E. coli and At. ferrooxidans promoters and the expression and phenotypic effects in both species will be described.

Jan 1, 2002

By G. M. Ritcey, V. M. McNamara

"In the processing of gold ores by the cyanidation route, effluents which are discharged to the tailings areas can contain up to several hundred parts per million of cyanide in complex combination with similar quantities of heavy metals. Complicating this obvious problem of waste control are concentrations of thiosalts and thiocyanates which are roughly equivalent to the amounts of cyanide species. Although most gold mills are located in thinly populated areas, such contaminants can represent a potential environmental problem due to the various limitations exhibited by on-property ponding.The former Extraction Metallurgy Division of CANMET recognized the problem and, in early 1974, invited representatives of the gold mills to Ottawa to discuss the situation. At that meeting members of the Division presented a ""state of the art"" literature survey of cyanide abatement technology for waste solutions, together with preliminary cost estimate data(1). Shortly thereafter, Environment Canada, together with Environment Ontario, decided upon a guideline of 0.1 ppm (0.1 mg/l) total cyanide content as tolerable for an effluent stream which is discharged, in any manner, to the watershed."

Jan 1, 1978

By Patrick H. O’Neill

The Choco placers, mined continuously since the earliest expeditions of the Spanish conquistadors, were exploited by the Indians prior to the conquest. Platinum is found in varying percentages with gold throughout the Choco placers and is found in minor percentages in some placers in other parts of Colombia. The Choco Department is on the west coast of Colombia between the western range of the Andes and the Pacific Ocean and extends from the San Juan River north beyond Panama to the Caribbean. The first reference in European literature to platinum was by Julius Caesar Scaliger in 1557. He did not assign any name to it but referred to it as an infusible metal found in the mines in the New World. The Spaniards had given it the name platina, which is the diminutive for plata, the Spanish word for silver. Don Antonio de Ulloa first recorded the name while on an official visit to the Choco from Spain in 1735.

May 1, 1956

By Robert Berggren

THE hot-milling process for reconditioning rock-drill bits is not new. It has been employed by a few mines for years and in the past decade it has been widely adopted, as its advantages have become better known. Because of the extensive commercial development in England and Canada of machines to operate on this principle, general acceptance has been largely in the British possessions and until recently has been chiefly in the field of conventional steel. In the past two years there has been a definite trend toward hot-milling of detachable bits in Canada, t but only in the past year has any considerable attempt been made to build special machines for this type of work. Generally a machine designed for con-ventional steel has been used and special holders employed to manipulate the bit. As early as 1934 at least one operator in the United States had adapted hot-milling to conventional steel with a substantial saving in resharpening costs. Several other operators have taken it up but there has been no widespread adoption of the method in this country by users of conventional steel. This may be partly explained by the fact that until recently no American manufacturer produced this equipment and operators have been obliged to build their own hot-millers or import them. Several years ago a few machines were built in Seattle, Wash-ington, and operated in some mines in the northwest, but, for reasons not generally known, the effort was abandoned.

Jan 1, 1940

By Frank Ebbutt

Introduction The property of the Britannia Mining and Smelting Company, Limited, is situated on the east side of Howe sound, about six miles from its head. It is roughly thirty miles by water from Vancouver, one of the important ports of the Pacific and the industrial and financial centre of British Columbia. Howe sound is navigable for ocean-going vessels and Britannia Beach is a daily port of call for the commodious boats of the Union Steam-ship Company, sailing from Vancouver. Few mines are so ideally situated or have so many or varied natural advantages. Copper was first found on Britannia mountain in 1888, by Forbes, but it was not until 1898 that five claims were staked here by Oliver Furry, a trapper. It is from these claims that the major production during the past thirty years has come. In 1900 the Britannia Copper Syndicate was formed and development of the property was commenced. In 1903 the late Grant B. Schley obtained control, and through his efforts the Britannia Mining and Smelting Company was organized in 1908 as a subsidiary of the Howe Sound Company. Since that time, a persistent and progressive policy has been followed, which has resulted in a prolonged and profitable operation. The country in the immediate vicinity of the mine is marked by strong relief, with mountains rising abruptly from tide-water to elevations of 5,000 feet and more. Two broad transverse valleys deeply dissect the area. These are the valleys of Britannia creek and Furry creek. The region has under-gone prolonged and relatively recent glaciation. Over much of the surface there is deep overburden and dense vegetation. The geology of the mine and vicinity has been described in reports by S. J. Schofield (1), H. T. James (2), J. G. Barry, and others (3). The present writer is in accord with much of this literature on Britannia, but during recent years, extended observations made underground have shown that the 'quartz porphyry', or 'mine porphyry', of several of the earlier writers is not the host rock to the commercial mineralization; and he contends that the mineralization occurs in highly altered phases of a complex series of ruffs, flows, and pyroclastics and their autoclastic metamorphosed products.

Jan 1, 1935

By M. Weinstein, J. F. Elliott

IN conjunction with a study on the solubility of hydrogen in liquid pure iron and iron alloys, new and

Jan 1, 1963

By Chaz Weaver, James Sheahan, Michael Mo

"The Virginia Department of Transportation (VDOT) undertook a program to replace four bridges along approximately 4 mi (6.4 km) of US 340 in Northwest Virginia. Two of these bridges, which span Compton Creek and the Norfolk Southern Railroad respectively, are the subject of this article. HDR provided roadway and structural design as well as geotechnical engineering services for the Norfolk Southern Railroad Bridge while their subconsultant, Saeed Associates, provided structural engineering services in support of the HDR roadway and geotechnical team for the Compton Creek Bridge.The project is located in the Valley and Ridge Geologic Province of Virginia, on an alignment that is adjacent to the Shenandoah River. The project lies within the Beekmantown Group consisting of limestone and dolostone that are prevalent and prone to karstic activity in a band that passes through the project area and north into Central and Eastern Pennsylvania. This area has been impacted by karst limestone conditions where caves and sinkhole activity is common. Caves at Luray and Front Royal, located to the south and north of the project, respectively, are popular public attractions.Since the potential for variability of subsurface conditions can be, and often is, greater in karst terrain, the need to develop a design that provides as much flexibility as possible during construction, and then to be prepared to efficiently review and respond to construction questions is heightened. Coordination and communication among the design staff, VDOT’s design and construction staff, and the contractor was a key factor in completion of this project.Compton Creek BridgeThe alignment for the new Compton Creek Bridge is located about 125 ft (38 m) west of the existing bridge, placing it between that bridge and the existing Norfolk Southern Railroad Bridge. No information about the foundations was available for the existing bridges. Borings in the Compton Creek valley encountered extensive voids (some clay filled and some open) with numerous boulders, rock ledges and pinnacles, particularly on the north side of the creek. Geophysical and geotechnical investigations indicated that below a poor and variable upper zone of rock was a layer of more competent and consistent limestone, which appeared to contain little or no voids."

Jan 1, 2017

By A. A. Wallach

During the early design stages of the San Manuel Concentrator, numerous questions were raised concerning the required slope for tailings pipelines. The tailings disposal area which had been selected was so situated, that an average down-slope of 5% existed. A gravity tailings disposal system was to be designed and it was necessary to determine the optimum pipeline slope for design purposes. This information was also necessary to determine the life of the available disposal areas before tailings pumping would be required. At approximately the same time as this problem arose, it was reported that a concentrator in the southwest was having considerable operational difficulties due to periodic plugging of tailings lines. These factors combined made it seem desirable to conduct some sort of test work which might give information concerning the flow characteristics of the tailings to be produced, from the San Manuel Concentrator. It was felt that the maximum information could be obtained if a tailings line could be erected which would allow for varying slopes, varying heads and accurate measurement of pulp velocity. A five-foot Denver Agitator was installed on a bank overlooking a cut for a rail- road track. Approximately 160 feet for new &-inch pipeline with victaulic connections was installed on low trestles along the track, with provisions made for varying the slope of the line by use of accurately constructed sets of shims, A valve discharge was installed on the tank so agitated pulp could be run into a standpipe at controlled volumes. This standpipe was 10 inches in diameter and approximately 5 feet high. A 4-inch nipple welded into the side of the standpipe approximately one inch from the bottom was connected to the 4-inch pipeline. At the discharge end of the 4-inch pipeline a launder arrangement was so constructed that the entire discharge could run into a pump sump or into 50-gallon measuring vessels. In normal operation the flow was from the agitator to the standpipe through the pipeline into the pump sump and from there pumped back to the agitator tank.

Jan 1, 1958

By A. B. Hooker, L. C. IlsLey

"Observation of the use of trailing cables in ""mines shows that the chief limiting factor in the life of the cables and their safe use is the smashing or crushing of the cables in service, together with the effects of consequent splicing.Trailing cables are crushed when run over by cars, mining machines; and locomotives or when hit by falls of roof. Crushing damages the insulation and may cause failure at once or in later use. Failure may be either by short circuit between the conductors or by grounding to the track. The failure of a live cable causes electric arcs capable of igniting explosive mixtures of methane and air. Every cable failure in a gassy or dusty mine is, therefore, a real or potential hazard.Some mine operators do not allow the splicing of trailing cables for use in gassy mines, bet require that a damaged cable be immediately replaced and if repaired that it be used only in nongassy mines. Other operators allow the making of temporary splices to permit completion of the shift but require that such splices be remade and vulcanized before the cable is used again.Still other operators allow the continued use of temporary splices, which in general means that a cable is used until the splices give trouble in reeling, or overheat, or pull apart. Then the spliced sections are either cut out or the whole cable is replaced.Splices often determine the useful life of a cable. A splice poorly made may pull apart ueder mechanical strain and cause arcing that burn* the surrounding cable or ignites as or coal-dust. If it has lower conductivity a splice is the first part of the cable to heat; it may become so hot under load that it will burn apart and damage other parts of the cable, or, if it be a soldered splice, the solder may melt and allow parting of the cable. A poorly made splice often has insufficient insulation which may alloy short-circuiting between conductors or permit external contacts capable of giving an electric shock to one handling the cable. The splice is sometimes bulky from too much insulation and takes up too much room on the reel, causing uneven reeling; also by catching on the spooling device the oversized splice may receive expressive pulls and wear. Splicing is therefore a very important factor in the use of trailing cables."

Mar 1, 1932

By R. O. Pynnonen

This publication presents a study by the Federal Bureau of Mines of 494 accidents in open-pit iron-ore mines, beneficiation plants, and shops of the Lake Superior district from March 1949 to June 1956. These accidents caused 499 lost-time injuries, including 12 fatalities. A similar Bureau publication, Information Circular 7744, Analysis of 346 Accidents, Underground Iron-Ore Mines, Lake Superior District, was published in April 1956. Accident reports were analyzed by the Bureau to show the causes of in-juries and the unsafe practices or conditions that caused the accidents. Also shown are the time charges, times of occurrence, ages of the injured by job classification, and experience of the injured in mines and on the job being performed when hurt. Detailed information is presented on approximately 27 percent of the total number of disabling accidents that occurred in open-pit iron-ore mines, beneficiation plants, and shops in the district during the period covered. The text also contains tabulations of the accident experience and graphs with straight-line injury-frequency, injury-severity, and fatality trends for the period 1946-57.

Jan 1, 1959

By M. J. deBastiani, John Kostuik

The Denison orebody, located on the north limb of a syncline, rests at depths of 800 ft in the northern end of the property to 3000 ft at the southern end, and has a composite dip of 19º, varying locally from 0º to 45º. It is composed essentially of two pyritized conglomerate beds separated by a varying thickness of quartzite. The thickness of the upper conglomerate reef of the main ore zone varies from 2 to 15 ft while the lower reef is from 2 to 12 ft. Mining, whether carried out over the entire section of the reefs and quartzite or by selective mining of the reefs, is accomplished by room and pillar methods, with an initial 67% extraction on the advance towards the property boundaries. The underground ore handling requirement in such an orebody has become one of the most challenging problems in mining.

Jan 8, 1966

By L. W. Bahney

Frequently in using a thermo-electric pyrorneter for measuring the temperature of a furnace, a hole is drilled at the back or side of the furnace, through which is introduced the tube containing the thermo-couple. At times the couple is left almost where it drops, for the reason that it soon becomes too hot to be handled easily, and the space at the back or side of the furnace may be so small and uncomfortably hot that an easy and accurate adjustment is nearly impossible. In order to overcome this clumsy and unscientific method of using the thermo-electric pyrorneter, I designed an adjustable stand, to hold the clay or quartz tube inclosing the platinum and platinum-rhodium leads that constitute the couple of the Le Chate-lier thermo-electric pyrometer. This stand also allows an easy and rapid adjustment of position to varying heights and angles, as may be desired for special reading, This stand is illustrated in Fig. 1. The couple in the tube might be of better service if the tube were held a little higher above the charge in a roasting-dish, changing the height and angle if desired. The stand, made of 1.5-in. water-pipe and mounted on casters, is heavy enough so it cannot be tipped over easily. It is adjusted to any position, and has a universal clamp which holds the clay or quartz protecting-tube. To avoid disturbing the wires of the couple at the cold junction each time the tube is moved, the cooling-bottle sets in a wire basket so placed that it moves forward or back with the couple. To overcome the necessity of leveling and adjusting a galvanometer at each furnace, a switch-board is used to connect

Jan 1, 1910

By D. Krammer, E. S. Machlin

The effect of a brior high-temperature creep strain on the low-temperature ductility of commercially pure nickel has been evaluated. The low-temperature (-196°C) ductility decreases linearly with an increase in prior high-temperature (920°C) creep strain. The effect is experimentally correlated to the formation of inter crystalline cracks and voids during the prior high-temperature creep strain. The magnitude of the effect is also believed to be a function of the notch sensitivity of the material. SEVERAL mechanisms have been presented to explain the process of inter crystalline cracking in metals undergoing high-temperature creep. zenerl has suggested that grain boundary relaxation of shear stresses could build up high stresses at ob- stacles to grain boundary shear and thereby nucleate a crack. Chang and rant' have experimentally demonstrated that cracks do form at obstacles to grain boundary shear such as lines where three grains meet. The role of vacancies in the mechanism of high-temperature inter crystalline cracking has been explored by Machlt with the conclusion that the nu-cleation of voids by vacancy condensation is almost

Jan 1, 1960

Australia had an active uranium mining industry in the 1950s with uranium oxide being supplied under contract to the atomic energy authorities of the U.K. and U.S.A. In the 1960s, when these con- tracts concluded, domestic production ceased, apart from Rum Jungle, whose production until 1971 was stockpiled. By the 1970s, the demand for uranium from the electrical utility industry had risen sharply and the effects on Australia were notable. The Mary Kath- leen mine re-opened in 1976 but, more significantly, exploration activity suddenly expanded with the re- sult that several world-standard deposits were locat- ed. Western world requirements for uranium based on increasing energy consumption and a changing energy mix, will warrant the development of Aust- ralia's resources. By 1985 our mines could be pro- ducing 9,500 tonnes of uranium oxide yearly and by 1995 the export value from uranium could reach that from wool. In terms of benefit to the community the economic rewards are considerable but, in terms of providing energy to the world, Australia's uranium is vital.

Jan 1, 1978

By Kavetsky A

A new model of flotation is presented which allows predictive calculations of total solids flows and metal grades and recoveries to be made for industrial flowsheets. A method of making these calculations is presented and illustrated with examples. The problem of determining sufficient flotability characteristics from a sample of circuit feed to predict the behaviour of that specific ground ore in the flotation circuit (ie performing flotometric analysis) is addressed, and some suggestions are made for its solution. A feature of the flotation model is its practical technological orientation, allowing determination of a small number of ore flotability parameters by fitting observed batch kinetic flotation data. The unit model explicitly includes the cell aeration as total bubble area per unit pulp volume, and pulp residence time. Although more complex unit models are feasible, it is thought that this model is sufficiently realistic to illustrate the points made. The modelling approach is illustrated by application to flotation data from a Kambalda ickel circuit. The model is parameterised and ore flotability parameters are back-calculated from batch kinetic data. These parameters are then used to fit the observed behaviour of the industrial circuit by numerically adjusting the unit aerations. Finally, it is shown how the model may be used to predict the effect of circuit and ore changes on the circuit's technological indices.

Jan 1, 1992

By Philip A. Dirige

This paper presents the variability of responses of paste backfill specimens that have been prepared with varying binding agent and binder combinations, when subjected to uniaxial compressive strength testing. A testing program conducted for an underground operating mine to produce cost efficient paste fill recipes using four different binding agents, in various ratios and combinations, is presented to illustrate the responses. These binding agents are Normal Portland Cement Type-10 (NPC T-10), oxidation or sulphide attack resistant binder (Binder A), replacement binder B (Binder B), and replacement binder C (Binder C). The paste fill recipes were prepared at 2, 3.5 and 5% binder content at varying binder combinations, at fixed size and tested in a Material Testing System (MTS) under constant strain rate conditions following cure times of 7, 14, 28, 56, 90, 112, 180 and 240 days. The results of tests suggested that the strength data clearly shows a trend of increasing strength with increasing binder content but not necessarily cure time. It is noted that all the blends achieved dramatic increases in strength up to 28 days of cure and then either increased or decreased moderately beyond 28 days curing, depending on the binder content and binder combination. The moderate decrease is apparent for the 2% paste fill blends and in some binder combinations of the 3.5 and 5% blends, which indicated lackluster performance beyond 28 days curing. This lackluster strength performance indicated that the binder content and combination may not be sufficient for the paste fill to achieve complete hydration and acquire adequate strength performance beyond 28 days. This study indicated that economic paste fill recipes can be designed with confidence using affordable alternative binders. However, it is noted that these alternate binders cannot be used as stand alone binders but should be used in combination with NPC to facilitate hydration of the paste fill.

May 1, 2006

By J. A. King, D. A. Knight

"The Porgera orebody is located in mountainous terrain in Enga Province, Papua New Guinea. An underground mine has been developed which produces up to 2000 t/d of ore grading over 2 ozs Au/t. Some 79% of the gold in the ore is free, with the balance in a highly refractory form as sub-microscopic gold evenly disseminated within a pyrite matrix.This paper describes the metallurgical plant that uses flotation and cyanidation circuits to effectively recover the free gold in the ore feed, allowing for wide variation in the gold head grade. The refractory gold component in the ore is stored as leached pyrite flotation concentrate and this concentrate will be later treated by autoclaving techniques to recover the contained gold.The ProiectThe property is located in the Porgera Valley 600 Km North West of Port Moresby. The remote location is 2500 m above sea level. The mine area has 3600 mm of annual rainfall and a temperate climate with temperatures ranging from 10° c to 22° c throughout the year.Alluvial gold was reported in the Porgera area in 1938 and has been an important source of revenue for the area for many years. Intermittent exploration was carried out until the 1960 1 s when Placer (PNG) Pty. Ltd. with Mt. Isa Mines commenced an extensive exploration program. The property was brought to production in 1990 by the Porgera Joint Venture group consisting of Mount Isa Mines Ltd, Rennison Goldfield Consolidated Ltd. and Placer Dome Inc, each with a 30% ownership and the Government of Papua New Guinea with a 10% share. Placer Dome Inc. is the manager of the property with construction under the direction of the Placer Dome Technical Services group."

Jan 1, 1992

By Fred C. Bond

AN improved method of measuring the surface area of a comminution product down to any desired particle size has been developed. The method is largely graphical, and requires relatively little calculation. It can be used with materials containing large amounts of clay, or excess fines of any kind. The surface area S is expressed in terms of square meters per 100 c.c. of solids. This expression is based upon volume rather than weight, and is considered to be more suitable for crushing and grinding problems, where the machines ordinarily are operated under constant volume conditions. It has the advantage that surface areas of different materials can be compared directly, even though their specific gravities may be unknown. The "specific surface" of a material, or the number of square centimeters of surface area per gram, is equal to 100S divided by the specific gravity. Particle diameters are expressed in microns, K being the diameter of the largest particle present and L the grind limit, or lower size limit of the particles formed directly by grinding. The value of K does not always coincide exactly with the diameters of the largest particles retained on the coarsest testing sieve, since the largest particles formed in crushing and grinding are often slabby, or have other irregular shapes. L has been chosen as 0.700 microns, or number 27.5 in the size number series, for reasons to be explained later. S is the total surface area of all particles larger than L microns in diameter. When a homogeneous comminution product is separated into fractions whose diameters bear a constant geometrical relationship p to each other, and the log per cent weight retained upon each size and passing the next larger size is plotted against the log diameter, a straight line results, which is called the distribution line, and which has a slope in called the distribution modulus. The distribution line can be extended to any desired limiting size, and the total surface area of all particles larger than that size can be calculated. The equation of the distributi0n line is [w = Cx" [I]] where w is the per cent weight retained on each successive sieve; x is the particle diameter; and C is the per cent weight retained on an opening of unit diameter.2 Theoretically, the distribution line can be extended to include infinitely small particles. When it is so extended, and the assumption is made that no fine particles are present other than those accounted for by the equation; the log per cent cumulative weight passing any series of sizes, plotted against the log diameter passed, will result in a straight line lying parallel to and above the plotted distribution line.

Jan 1, 1941

By Emily Wortman-Wunder

Attendees at December?s Arizona SME Section Conference at the Hilton El Conquistador Resort outside of Tucson, AZ were feeling optimistic and ready to get to work after a year of steady growth and recovery in the mining industry. During the two-day event (Dec. 5-6, 2010) and the preceding American Mining Hall of Fame banquet and awards ceremony, the focus was on copper, worldwide population growth and regulatory pressures, with several smart new projects featured alongside updates to traditional large-scale copper development projects. Keynote speaker Timothy Snider, chair of the University of Arizona?s Lowell Institute for Mineral Resources, hit the mood of cautious optimism when he analyzed the global demand for resources, using the case example of copper. Over the next 20 years, he said, the world?s population is expected to grow to 9.2 billion and the average annual per capita copper use is expected to rise from 2.2 to 4.5 kg (5 to 10 lb). The increase in demand will provide tremendous opportunity for mining companies, he said, but cautioned that the opportunities are balanced by negative influences on demand and pressures on supply. While demand for copper is currently growing, Snider noted that there were significant downward pressures on demand as well. These included a western world that is overbuilt, in-creasing use of substitute materials in new construction and the rise of wireless devices. He also noted new regulatory pressures, and pointed out that resource development now had to occur within a context of sustainability on several levels.

Jan 1, 2011

By J. W. Walker, G. J. Heuer, E. W. Hough

An improved apparatus is described for the deterrni-nation of interfacial tension* by the pendant drop method in the pressure range from 15 to 15000 psi and the temperature range from 100º td 280°F. The chief characteristics of this apparatus are reliability and ease of operation. Temperature control was accomplished by means of an electrically heated jacket which could he completely removed while cleaning the apptrratus. The cell was designed so that the camera could he placed about I in, from the window without overheating the carnera lens. Separate "0" rings employed to seal each window and corresponding window backup plate gave very reliable window operation at 10,000 psi. An extra pistorr-cylinder combination was added so that a high compression ratio could he attained when gas was employed as one phase in the pendant drop cell. Other essential parts of the system were similar to an apparatus already described.' The interfacial tension for carbon dioxide and water varies from about 69 dynes/cm at 15 psi to about 19 dynes/cm at 1,250 psi for 100°F. For pressure.r between t,500 and 3,500 psi, the interfacial tension is between 32 and 24 dynes/cm at this temperature. The interfacial tension at 280°F varies from about 50 dynes/cm at 200 psi to about 17 dynes /cm at 10,000 psi. The maximum surface excess for carbon dioxide, assuming the surface excess of water to be zero, occurs at about 1,500 psi jor the 100°F isotherni and Itas a value of about -79 X 1014 mol/sq cm. At 160°F this maximum IS shifted to about 2,000 psi and has a value of about 10 X 1014 111ol/.sq cm. Other maxima, us well as several minima, are present at these and other temperatures. Judging from the data on the solubility of water in carbon dioxide at elevtrted pressures2,3, it appears that the principal maxinza natned are in regions of increasing solubility of the water in the carbon dioxide rich phase. INTRODUCTION AND APPARATUS A pendant drop interfacial tension apparatus which would accommodate an opaque liquid in a gas phase was constructed several ycars ago' for industrial purposes. This apparatus was used as a starting point for the present development. The objective of the present development was to enhance reliability and convenience of operation. Other articles'" have described pendant drop apparatus which could not accommodate a gaseous phase adjacent to the windows. A schematic diagram of the apparatus is shown in Fig. 1. The water used followed the path; A, intro-