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By Wolfgang Sand, Alex Schippers, Tilman Gehrke, Thore Rohwerder, Peter-Georg Jozsa

Metal sulfides are degraded via thiosulfate (pyrite) or via polysulfides and sulfur (sphalerite, galena, chalcopyrite) by leaching bacteria The attack on the crystal lattice is either effected by only iron(III) ions or by iron(III) ions and protons, respectively. Consequently, different endproducts are formed. For a control of ARD-processes, these reactions need to be hown to regulate them. Experiments in percolators up to 65 m3 with inorganic compounds like fluoride, concrete, or SDS resulted in differently lasting inhibition. Microcalorimetric measurements of microbial leach activity allow monitoring of these effects with respect to active bacterial cells, and, in addition, the amount or rate of dissolved metal sulfide allowing prediction of possible endangerment by ARD.

Jan 1, 2000

By J. Szekely, Robert G. Lee

Calculations are presented for the prediction of the combined radiative-convective heat loss from molten steel held in a ladle, covered by initially molten slag. A mathematical formulation is given and numerical solutions are presented of the resultant partial differential equation. It is shown that a slag layer of about 2 to 3 in. thick would prevent any significant heat loss from the top metal surface for Periods of up to 1 hr. For thinner slag layers (or in the absence of the protective slag) appreciable heat losses would occur; plots given in the paper allow the quantitative evaluation of the fall in the metal temperature due to this heat loss. The ironmaking-steel processing operation involves several intermediate steps where the molten metal is held or transfered in ladles. The quantitative assessment of the heat losses occurring under these conditions is of considerable importance in process design considerations since the temperature of the metal may have to meet rigid specifications in any given part of the processing sequence. While the metal is held in a ladle, heat is lost by two mechanisms: i) by conduction into the ladle walls; ii) by radiation and convection from the top surface. Calculations relating to the conductive heat loss, are readily made and information may be found in the literature both on data pertaining to metallurgical situations and on the techniques that are available for performing additional computations.'-3 The evaluation of the combined convective-radiative heat loss is less straightforward, especially when there exists a protective slag layer covering the metal. In this latter case, as the top slag surface loses heat partial solidification may occur and the latent heat thus given up by the slag may represent an effective barrier to the heat loss from the metal. A semiquantitative assessment of the role played by the slag in preventing heat loss from the metal has been made in a previous paper,4 where it was shown that a slag layer 6 in. thick would act as a near-perfect insulator for periods of up to 2 hr. However, this first paper reported on an essentially preliminary investigation that considered only one slag layer thickness; furthermore, the boundary conditions used for the calculations were somewhat restrictive since no allowance was made for changes in the metal temperature. The purpose of this second paper is to extend the scope of the preliminary investigation previously reported by: i) considering several slag layer thicknesses; ii) allowing for variations in the metal temperature; and finally iii) by performing calculations on the net loss from the metal rather than from the slag surface. FORMULATION Consider a slag phase extending from y = 0 to y = L1, covering a metal phase that occupies the region extending from y = Ll to y = L, as illustrated in Fig. 1. Denote the slag and metal temperatures by TS and Tm and assume that initially both slag and metal are molten, having a uniform temperature Ti. At time = zero the surface represented by the y = 0 plane (top slag surface) is brought into contact with cold air, the temperature of which is given as T Thus for time > zero, heat will be transfered from the slag to the air by natural convection and thermal radiation; as a result of this heat loss the slag temperature will fall and after some time a solid phase is formed and a solidification boundary (more realistically described as a zone) will move progressively from y = 0 toward y = L1. Once the region of temperature gradients, moving ahead of the solidification zone, reach the slag-metal interface (y = L1) there will be a net transfer of heat from the metal through the slag to the cold air, across the y = 0 plane. In the formulation of moving boundary problems, involving phase changes that require computer solution, it is convenient to represent both phases by a single equation, making allowance for the latent heat of solidification by assigning an appropriate temperature dependence to the specific heat content. Thus the energy equation for the whole of the slag may be written as follows:

Jan 1, 1969

By A. S. Trimble, J. C. Hower

The petrographic composition of sized coal produced through the progressive grinding of a Central Appalachian high-volatile bituminous coal blend was analyzed for multiple sets either by removing fine, -200-mesh, coal after each test iteration or by retaining the fine coal in progressive test fractions. With prolonged grinding, coarser fractions tend to become depleted in vitrinite and vitrinite-rich microl ithotypes, leading to progressively harder-to-grind coal remaining in the oversize, +200-mesh, fractions. The latter trend is shown both by the maceral and microlithotype composition of the coal and by the increased slope and fractal dimension of size frequency distribution, implying an increase in hardness and resistance to grinding of the oversize coal.

Jan 1, 2000

By A. N. Brown

Rock breakage by drilling and blasting is fundamental to every hard-rock mining operation. The subject was an apt choice for a mining school because many technological changes have taken place since the subject was last presented some ten years ago. However, because of the development of surface mining, it was decided that two schools should be held: one for underground mining, and the other for surface mining. The School on Underground Mining was held at the University of the Witwatersrand in February 1986.Copper 87 COPPER 87 is an international conference organized by metallurgical and academic institutions of two of the largest producers of copper in the world, Chile and Canada.

Jan 1, 1986

A FACT not generally understood about the Engineering Societies Library on Thirty-ninth Street in New York -in particular, not realized by many of the great indus-tries of the country-is that it is a free public institution. To utilize its valuable facilities one does not have to be a member of the national engineering societies (which shoul-der its financial deficit each year). Anyone, at any place in the world, can use the library. A man in California, or in South America, or in Persia, can write or cable to the Library staff and receive information on the same basis as any engineer living in New York. For example, a few months ago an American mining en-gineer in China needed additional geological information about a district which he was about to explore. He cabled his need to the Engineering Societies Library and the next steamer brought him the data he wanted. A phosphorus company in Alabama wished to obtain a translation from the Norwegian of an article on cement which they had heard about. They wrote to the Engineer-ing Societies Library; the article was located, and a trans-lation made and sent them.

Jan 12, 1927

This paper illustrates the application of numerical modeling methods, in conjunction with limit-equilibrium techniques, to the location of critical slip surfaces in slope-stability problems. Initially, the Spencer slice-based method of analysis is introduced, together with a dynamic-programming algorithm for slip-surface location. This limit-equilibrium method is assessed critically through the use of an illustrative problem. The technique is then extended to locate the critical slip surface for a similar slope, but with more complex constitutive and yield relationships for the material comprising the slope. To this end, the use of the stress field generated from a finite-difference program, together with a dynamic-programming search routine, is presented as an advanced technique of slope-stability analysis for engineers.

Jan 1, 1993

The Committee on a Standard Gauge have been constantly engaged, since their appointment, in the duties assigned to them.§ They have corresponded with different persons interested in the manufacture and use of gauges in this country, and have received from several of them important information. They have also entered into correspondence with the governments of England, France, Gerniany, and Russia through their Consuls, ant1 with Austria directly. The Consuls of Germany and France

Jan 1, 1879

By Paul B. Crawford, Bobby L. Landrum

An electrical model study has been mode to estimate the effect of horizontal fractures in thick reservoirs on pattern conductivity. For the patterns studied, it is shown that fracturing all the wells in the pattern in-creases the conductivity considerably more than frac-turing only single wells. For certain conditions one large fracture is more effective in increasing conductivity than several fractures of half the radius. Particularly in thick reservoirs and with large fractures, the center of the pay is found to be more responsive than other locations. For the seven-spot pattern fracturing the center well is more effective in increasing pattern con-ductivity than fracturing all outer wells with fractures of the same size. INTRODUCTION Although commercial fracturing has been used for some time very little quantitative information is known about the effects of fractures on reservoir behavior. The purpose of this work was to estimate the effect of horizontal fractures in thick reservoirs on the con-ductivity of various flooding and cycling patterns.2 Circular fractures originating at the wellbore and extending symmetrically into the pay were considered. ANALYSIS Electrical models were used in making this study. Horizontal fractures were simulated by copper sheets shaped like the fractures and of a proportional size; the wellbore was simulated by a copper wire. A dilute salt solution served as a conducting medium. A con-ductivity bridge was used to measure the conductivities of the various patterns studied. EFFECT OF HORIZONTAL FRACTURES ON CONDUCTIVITY Fig. 1 shows the effect on square and staggered line drive patterns of horizontal fractures located in the center of the pay. The model is shown schematically in the insert. The upper and lower groups of lines show the effect on conductivity when all wells are fractured, and when only one well is fractured, respectively. In general, pattern conductivities are substantially improved by fracturing all wells. Fig. 2 shows the effect of multiple horizontal frac-tures on the conductivity of a line-drive pattern. At

Jan 1, 1958

The following very cordial letter, addressed to the President of the American Institute of Mining Engineers by the President of the graduates of the School of Mines of Saint-Etienne, will he deeply appreciated by all American engineers and will perhaps be of use to engineers going "Over There." Members are requested to communicate the substance of this letter to friends or acquaintances in France: Dear Mr. President: Now that the American armies are crossing the ocean to come to our side in the defence of the liberty of the world, and the intellectual elite of your great country is very ably cooperating with us in this supreme struggle, we ardently desire to give them a whole-hearted reception upon their arrival on the shores of France. The representatives of your illustrious association will be more especially welcome among their French colleagues, and both at Saint-Etienne and at Pans, we desire that their sojourn he rendered comfortable and congenial in every way possible. We therefore put ourselves unreservedly at their disposal. At Paris especially those of our colleagues

Jan 7, 1918

By E. G. Davis

The Bureau of Mines investigated gaseous direct reduction of low-grade iron ore concentrates in a continuous fluid-bed reactor. These studies were made in a 4-inch diameter fluid-bed reactor using hydrogen alone, and oxygen-or air-reformed natural gas as the reductants. The percent reduction is directly dependent on the mole ratio of hydrogen in the reducing gas to the oxygen associated with the iron oxide in the ore. Two-and three-stage fluid bed tests were simulated by repeated continuous tests. The results showed that percent reduction of the final product was dependent on the mole ratio of the quantity of hydrogen in the gas of each stage to oxygen in the iron oxide of the initial ore feed. Reduction as high as 87 percent in the single stages and as high as 94 percent in the multistages was obtained when either hydrogen or reformed natural gas was used as the reducing gas. Magnetic separation and concentration of the highly reduced fluid-bed product yielded a high metallic iron concentrate analyzing 85 percent total iron and 80 percent metallic iron with total iron recovery as great as 90 percent. Agglomeration of the high-grade metallized concentrate produced hard pellets analyzing 85 percent total iron and 78 percent metallic iron. Green pellets, with good strength, were made without any binder in a drum pelletizer. Direct melting of the high-metallic fluid-bed product in a basic lined arc furnace produced a nearly pure iron which contained 0.09 C and 0.01 P with 95 percent recovery of the metallic iron in the metal.

Jan 1, 1972

By Lester L. Hirst, Henry H. Storch, A. C. Fieldner

Experimental work on liquefaction of coal was taken up by the Bureau of Mines in 1936 when it became evident that a prudent policy from the national point of view should include preparation for the time when gradual exhaustion of petroleum resources would require supplementing the growing demand for motor fuel with gasoline and diesel oil from coal. At that time (1936) certain foreign nations that had no home sources of petroleum, especially Germany, England, and Japan, were conducting active research and at least two of them were producing liquid fuel from coal on a commercial scale. Germany was reported to have an annual producing capacity of 800,000 metric tons of gasoline per year, and England had just put into operation the Billingham plant of Imperial Chemical Industries for the hydrogehation of bituminous coal and tar by the Bergius-I.G. process. The annual capacity of this plant was about 150,000 long tons of gasoline per annum (3500 bbl. per day). With these developments taking place in foreign countries, it seemed important to undertake a long-range program of fundamental research in this country to establish a sound groundwork for the evaluation of foreign work on synthetic liquid fuels and at the same time to obtain data on the oil yields and operating difficulties using various kinds of American coals and lignite to the hydrogenation process. The results of such research would be useful in determining the yields and quality of liquid products obtainable from various coals so that American industry would be in position to select the most suitable coals and make rapid progress in establishing this new industry when the commercial need should arise. It was hoped, also, that progress in a better understanding of the chemistry of coal hydrogenation would reduce the cost of the process materially. To carry out this program, a small continuous unit capable of hydrogenating 100 Ib. of coal in 24 hr. was installed at the Central Experiment Station of the Bureau of Mines at Pittsburgh, Pa. Small steel autoclaves or bombs of 0.3 gal. (1.2 liters) capacity also were used for batch-hydro-genation experiments in the study of the chemical fundamentals of the process. Much valuable assistance was obtained in planning the experimental program and designing the equipment from the Fuel Research Station of Great Britain and the Fuel Laboratories of the Mines Department of Canada, where such investigations had been in progress for several years. Equipment and General Procedure of Research The industrial liquefaction of coal by the Bergius-I.G. hydrogenation process as practiced at Billingham, England, from

Jan 1, 1944

By Horace V. Winchell

The laws here referred to are those which define the status of the prospector for mineral deposits in the soil or beneath it, establish his methods of procedure, protect him in his possession while searching for the subterranean treasures, and give him assurance of title when all required conditions have been fulfilled and valuable minerals discovered. Regulations for the operation of mines and the safety and health of mine employees are likewise subjects of Federal and State legislation, but are not within the scope of the present program. Various features of our present laws will be discussed in detail by able students of the subject, and specific remedies will be proposed for the most glaring defects. It is my purpose to present in this paper a summary review of the reasons why revision is needed and demanded by the great majority of those in daily contact with the industry. Reason Number One The first objection to the continuance of the present law is that it was not planned by its framers and the Congress which passed it to apply to many of the kinds of mineral deposits, nor to the mining conditions, which are controlled by it to-day. In 1866, under the title, "An Act granting the right of way to ditch and canal owners over the public lands, and for other purposes," was surreptitiously smuggled into existence our first mining law (14 Stats. at Large, Chap. 262, p. 251). This law provided that "whenever any person or association of persons claim a vein or lode of quartz or other rock in place, bearing gold, silver, cinnabar or copper, having previously occupied and improved the same according to the local customs or rules of miners in the district where the same is situated," etc., a patent might be granted an certain conditions. This was evidently an Act intended to validate claims already initiated, and to accord Federal recognition to mining locations made in

Jan 1, 1915

By Jr. Cook

Panned stream-sediment,geochemistry-based gold exploration in those parts of the southeastern Piedmont proximal to the Fall Line must take into account potential contamination from basal fluvial gravels of the Coastal Plain. Anomalies attributable to the incorporation of placer gold of Coastal Plain origin into modern Piedmont drainages have been identified in portions of Lee, Macon, and Tallapoosa counties, Alabama, and Baldwin and Hancock counties, Georgia. Identification of such multicyclic anomalies must be based on knowledge of the local maximum Cretaceous transgression, paleotopography, modern and paleofluvial system dynamics, and fineness trends and Au-Ag zoning in gold grains.

Jan 1, 1988

By S. Raghavan

An investigation of the possibility of improving the grinding characteristics of a gabbro ore containing copper and nickel sulfides via a thermal shock treatment technique has been carried out. The results obtained indicate that the breakage characteristics of the gabbro are particles can be significantly improved by preheating the are particles to a temperature around 400°C followed by rapid water quenching. For a given power input and feed size, the thermally treated material produces a product of much finer distribution than the untreated material. An assessment of the improvement in grindability has been made by calculating feed size selection functions for untreated and heat-treated materials.

Jan 1, 1981

Ellsworth Daggett, who joined the Institute in 1873, and had beeu a prominent figure in the mining profession of Utah and other Western states for many years, died in San Francisco, Jan. 5, 1923. Mr. Daggett was a contemporary and intimate friend of Clarence King, James D. Hague, R. W. Raymond, and other Nestors of the mining engineering profession prominent in the last quarter of the nineteenth century. He was born at Canandaigua, N. Y., May 24, 1845; graduated from Sheffield Scientific School in 1864; pursued post-graduate courses there for two years, and for one year at the Bergakademie, in Berlin. He was in active practice as mining engineer from 1866 to 1914, but devoted most of his time during the World War to the perfecting of a submarine torpedo. He was connected with the United States Geological Exploration of the Fortieth Parallel in 1870. The plates illustrating mining industry, Volume III of the reports of that survey, were engraved from drawings obtained in the field during progress of the survey and prepared for the engraver by Mr. Daggett. He operated the Winnamuck mine and smelter at Bingham Cation, Utah, in the early seventies; the mines and mill at Cusihuiriachic, Chihuahua, 18867; and the Berlin mine near Austin, Nevada, 1904-6. On June 24, 1874, Mr. Daggett married Miss June Spencer, of Salt Lake City, who survives him, residing in New Haven, Corn. Appointed United States Surveyor General for Utah by President Harrison, in 1888, he was the first engineer to hold that office in Utah. He reorganized the mineral division of the office, required the courses of mineral surveys to be referred to the true meridian determined by solar or stellar observations, and did much to improve the accuracy and reliability of such surveys. Mr. Daggett was a member of the Alta and University Clubs of Salt Lake City, and president of the latter from 1890 to 1892; he was also a member of the Century Club, New York. Through his instrumentality, irrigation was brought to considerable tracts of land in northeastern Utah, and Daggett County of that state is named for him. Re wrote numerous technical papers, and an economic review entitled "A Quarter of a Century of Prices," in which was shown the close relation

Jan 1, 1923

By Clarice L. Amaral, Ricardo Melamed

Clay-coating has been used as an environmental technology tool for the immobilization of toxic elements. The mechanisms of arsenate retention in clays suggest that not only the system pH is of fundamental importance in the process but also the character of metals and ligands that compose the electrolyte system. The goal of this study was to investigate the interactions between system pH and electrolyte ions on the retention of arsenate in an Oxisol soil. The sorption of arsenate decreases with the increase in system pH, reflecting the competitive sorption of arsenate with OH groups. Solutions containing Ca tend to favour the immobilization of arsenate in a relatively broad pH range.

Jan 1, 1998

By Dennis Molvik, Roberto J. Guardia, Brad Cowles, Rick Andrews, Robert A. Robinson

A 220-meter (m) segment of the Henderson/ ML King Combined Sewer Overflow(CSO) consists of two 1.8-meter-inside diameter (I.D.) pipe-jacked tunnels that pass beneath Interstate-5 and the BNSF and UPRR railroads. A seismic tomography survey was conducted to develop a 3-dimensional profile of the tunnel zone and better define potential obstructions. The tomography was conducted through three 11 cm high-density polyethylene (HDPE) pipes installed in a triangular pattern around the future tunnel alignments using horizontal directional drilling methods. The pipe-jacked tunnels have been successfully completed, thus permitting a comparison between the predicted obstructions and those actually encountered. The top HDPE tomography pipe was also used to monitor settlements with an experimental horizontal profiler above the advancing tunnels during construction and located two areas of ground loss beneath I-5 that were subsequently grouted.

Jan 1, 2005

By L. H. Shang

The 319 Al-Si alloy is one of the most prominently used aluminium-based alloys in motor vehicle and engine applications, Microporosity present in 319 alloy castings reduces the load bearing capacity of the castings, The quantitative prediction of microporosity levels in Al-Si castings has been a subject of much interest for several years. In this research a new criteria function, tf 1,98 R13° (tf: local solidification time, R: cooling rate) was developed by multiple regression analyses, correlating thermal data from simulation studies to experimentally obtained microporosity values. This new criteria function gives a general prediction of microporosity in 319 Al-Si castings.

Jan 1, 2005

By Bahram Samani

The Bafq - Saghand ore belt (metallogenic zone) is the main region, where the major discovered Uranium resources are located. This belt is a unique Upper Precambrian terrane experienced Katanga ? Pan African tectono ? thermal events. The oldest sialic crust was formed during the middle Proterozoic and followed by K-granite intrusions of Lufilian Cycle (850-800 M.Y.).This event caused Tectono ? Magmatic ? Activization (T.M.A) characterized by intracontinental rifting and associated ore formations. This zone was considered as an iron ore belt in 1960s ? 1970s, and U ? Th ? REE belt in 1980s ? 1990s, but by new discovered of U ? Mo (Co, Au, As, Cu) mineralization is assigned as a U - Polymetal zone, hosting the full sequences of iron oxide (Cu, Au, U) ore forming groups. On the basis of detailed investigations this zone is characterized by the following peculiarities: This zone is the vestigial vessel of Gondwana basement, where the oldest granite and the first platform clastic cover is exposed. This zone is marginal part of Precambrian continental crust, consolidated in 1.3-1.0 B.a. The sub mature continental crust experienced Lufilian Orogenic and Katanga ? Pan African Tectono ? Thermal event by intercontinental rifting, and ore mineralizations. The ore forming stages were sequential processes, started by enriched mantle derived metallogeny, and ended by interaction of silanes/ HACONS (derived from outer core) with crust. The magnetite- apatite (REE, Ti) metallogeny developed from alkaline- ultrabasic magmatic differentiation, capable to from Au- Ni- Sulfide intrusive massifs during 850- 800 Ma. Degassing of silanes/HACONS from deeper level, not only caused mantle enrichment, and plume upwelling as a frontal load, but also played the main role to develop regional Si (-Na-K-Mg-Ca-Co3) metasomatism, and formation of U- Th- Ti- REE- (apatite, magnetite) deposits. The latest (583-510 Ma old) felsic magmatism was major IGU from U-Mo (-Co-As-Au-?Cu?) hydrothermal vein- type deposits. The albitite- type U- Ti- REE (Th) mineralization could be formed by interaction of ascending, and descending solutions along the deep- rooted structural conduits.

May 1, 2007

By R. J. Pearce, I. Whittle, J. J. Stobbs

The oxidation kinetics of UCu5 in carbon dioxide have been studied over the temperature range 350° to 850°C. At any one temperature, two successive parabolic rate constants are obtained. Up to 650°C, the temperature dependence of the reaction is snzall and the first parabolic rate constant is higher than the second. At temperatures of 690°C and above, there is a very marked temperature dependence and the second rate constant is the higher. Metallo-graphic examination has shown that attack proceeds via internal oxidation. THE oxidation behavior of the U-Cu intermetallic compound, UCu5, in carbon dioxide was briefly examined during investigations aimed at selecting oxidation-resistant uranium-alloy coatings.' It was found that an extremely thick, coherent scale was formed coated at the scale-gas interface with a thin, apparently continuous layer of copper. A more detailed investigation of the oxidation of UCus has now been made. Previous published work2 has been limited to a brief examination of UCu5 in connection with the oxidation of a U-1 wt pct Cu alloy in carbon dioxide. No attempt was made to explain its behavior, but the work indicated that attack proceeded by intern oxidation, with the formation of a layer of copper on the surface of the specimen. EXPERIMENTAL UCus was prepared by arc melting the stoichio-metric amounts of high-purity copper* and uran-

Jan 1, 1965