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By J. P. Allen, D. A. Rice, H. L. Abercrombie

Cobalt, nickel and manganese can be recovered quickly, cleanly and selectively from cobalt-rich manganese ocean crust by leaching in dilute acid solutions in the presence of hydrogen peroxide. Common selective precipitation methods can then be used to recover these metals from the leach liquor. The leaching reaction produces only oxygen as a byproduct, and the waste residue from leaching was tested and found to be nonhazardous under existing EPA specifications. The leaching process is effective in either fresh water or seawater. This research is a part of the Bureau of Mines program to identify the mineral resources of the Exclusive Economic Zone and devise methods, for recovering their valuable components.

Jan 1, 1992

By B. B. A. Luzzat

ALUMINUM is today the most widely used of the nonferrous metals. The technical literature on the aluminum smelting process is, nevertheless, very meager, so that anyone interested in the subject cannot rely on more than a couple of dozen publications.' The patent literature is equally scarce; most patents refer to the production of alumina from aluminum-bearing ores, while not more than a few score significant patents deal with the electrolytic reduction of alumina, which is the real core of the aluminum smelting industry. The "reduction phase" is, from a technical and a scientific point of view, much more interesting than the "alumina phase", which, in effect, is only a combination of such well-known chemical operations as dissolving, precipitating, filtering, drying, and calcining. The electrolytic reduction of alumina, on the other hand, has features which do not appear in any other metal smelting operation. Some of them are of great technical and scientific interest even for those not directly engaged in the production of aluminum. The purpose of this paper is to describe in some detail the basic facts and developments of the reduction phase of aluminum smelting. Two Aspects of the Electrolytic Process The raw material for the reduction process is alumina (Al2O3) . Its purity in general runs as high as 99.50 pct or more. Small differences in the chemical composition generally do not affect the reduction process.* Of more importance are the physical prop- erties of the alumina, since they affect not only its rate of solution in the molten bath but also its heat insulating power.† In the following pages, un- less otherwise stated, it is assumed that a standard "Bayer" alumina is used. The reduction process, by which alumina is broken down into its components, may be roughly defined as its electrolysis in molten cryolite. The oxygen separates at the anode, and the aluminum at the cathode, which forms the bottom of the electrolytic cell. The electrolytic cell (or pot) where the process is carried out is a strongly reinforced steel box. The

Jan 1, 1951

Longwalling has reached a high standard both in Germany and Australia and most improvements should be expected in planning, monitoring and control. Double drum shearer have electric drives to 1000 kW and automatic height control is under development. Conveyor pans to 40mm thickness and chains to 2300 kN breaking load are in use with controls for pretension and load compensation under test.Trends in support are towards two leg shields with loads to 3850 kN per leg and electrohydraulic controls. Expert systems have been devised for planning and diagnosis tasks. With increases in technical standards, staff qualification standards at rising too, drawing attention to training requirements for modem personnel.

Jan 1, 1991

By W. D. Riley

The Bureau of Mines is conducting research on methods for the rapid identification and sorting of mixed scrap metals and alloys so that domestic scrap resources can be fully utilized. One method, spark testing, is the examination of the pattern of sparks that results when a metal or alloy is ground on an abrasive wheel. This technique requires experienced sorters. Bureau researchers have shown that spectrophotometric methods can be used in lieu of the highly skilled sorter. The spectra of a mild steel, an HSLA steel, several stainless steels, and four nickel-base alloys have been measured. Differences in the spectra that are sufficient for identification are apparent.

Jan 1, 1985

By Jean-Luc Collins

"This new tool can be used as a quick guide f or the assessment of the potential economic wealth of any risky capital project. It does provide an unambiguous recommendation of the type ""go or no go"" to the decision-maker simply by comparing two different ratios profit/investment. One ratio determines the minimum value required to at least break even while the other measures a probable value based on the asymptotic theory of statistical extremes.Its application is briefly illustrated by means of an underground gold mine extension project, an oil sands mine project and a polymetallic open pit project.Once a favourable recommendation has been obtained then a detailed ""cash flow after taxes"" analysis can be carried out for the project.IntroductionMany tools are used in financial decision-making such as the payback period, the discounted cash flow, the internal rate of return and the wealth growth rate (Berry , 1971).These tools are useful and meaningful in evaluating normal projects closely related to regular business where the number of assumptions made is usually very small and where the cost of capita! is usually selected as a discount rate or a hurdle value. In situations where a significant number of assumptions have to be made,two problems can emerge, namely:I. the risk involved is underestimated leading to a potential financial disaster; or2. a good opportunity is lost because the approach used in evaluating the project is too conservative.Each assumption has its own degree of uncertainty and it is well known that combining uncertainties together can lead to a total uncertainty of critical proportion. The easiest way to account for risk is to increase the discount rate or the hurdle value, but this approach alone is quite subjective and can easily lead to the problems described above."

Jan 1, 1993

Since the ecrly 1970's several factcrs have changed. In the East the larger tracts of coal mined with large eauipment are being dePleted, The cost of moving the larger equipment from small tract to small tract becomes eccnomicallv unattractive, Conseauently, the tracts are being mined with smal!er draglines or with loader/truck haulage combination, This has resulted in a major increase in the cost of moving a cubic yard of overburden,

Jan 1, 1989

By Theodore Swann

DURING recent years, there has been a material increase in the use of ferrophosphorus in the steel industry. It has been observed, when rolling sheets, that those made of Southern iron did not have to be rolled at as high a temperature as the others and, consequently, did not stick together. The reason was found to be the phosphorus content of Southern iron. It was therefore thought that an addition of phosphorus to sheet steel of other than Southern origin would give the same result as the use of Southern iron. At first, this addition was made by intro¬ducing phosphate rock in the blast furnace and reducing it together with the iron ore; but, because of the necessity for only small quantities of this grade of iron, the process was not satisfactory. The manufacture of ferrophosphorus was then introduced, so that additions might be made to the open-hearth furnace or ladle. Ferrophosphorus was first manufactured in the blast furnace. This method, however, can only economically produce a grade of product up to about 20 per cent. To produce a higher grade, it would be necessary to charge a larger proportion of phosphate-bearing material; and as the rate of absorption by the iron is low, there would be an increased loss of phosphorus oxides. This feature makes the production of a higher grade ferrophosphorus in the blast furnace uneconomical. The use of high-grade ferrophosphorus in the steel requires a smaller addition and involves, besides the economies in handling, an additional economy in transportation. The alloy with a higher percentage than 20 per cent. can be made only in the electric furnace. In the ordinary operation of the electric furnace in the production of ferrophosphorus, an alloy may be produced containing 26 per cent. phosphorus; this is the limit, for it does not seem possible to produce a higher phosphorus alloy even if large excesses of phosphatic materials are used. The reasons for the difficulty in raising this percentage of phosphorus are not known. The compounds Fe3P, containing 15.6 per cent., and Fe2P, containing 21.7 per cent. phosphorus, have been studied and it appears as if the alloy produced, containing percentages of

Jan 10, 1924

By Donald A. Voigt

This publication is intended as a guide for persons responsible for obtaining classifications and approvals Tor explosive compounds, mixtures, or devices from the U.S. Department of Transportation (DOT). It deals with the procedures for obtaining a recommendation for classification of an explosive compound, mixture, or device through the Bureau of Mines. Completion of the procedures detailed in this guide is necessary to obtain a final classification of an explosive compound, mixture, or device and assignment of an "EX" number by DOT, which will allow the producer to offer the explosive for shipment within the United States. This guide also gives procedures for obtaining United Nations (U.N.) classification for shipping outside the United States.

Jan 1, 1990

By K. Negishi, H. Izui, Y. Komiya

"Aluminum has the disadvantage of low strength. In order to obtain the high strength composites, crystals were refined in the composites. Grain refinement was approached at two process points, generating new grains and grain growth. It is important for refinement how to control the grain growth. Spark plasma sintering (SPS) technique and TiB2powder addition prevent grain growth. To investigate effects of strain and additives to the alloy, aluminum powder was sintered at 70 MPa and 80 MPa, changing the content of TiB2additive powder by SPS method. As the results, the crystal grain size was finer in the composite sintered at higher sintering pressure and with larger amount of additive, though over 1.0mass% TiB2addition dissuades grain refining. These grain refinements improve hardness and tensile strength of sintered aluminum alloys.INTRODUCTIONAluminum matrix composites have low density, high specific strength, and low cost. Their applications are growing continuously in the field of automotive and aerospace industries. Recent studies to improve their good mechanical and tribological properties use different ceramic materials such as Al2O3(Das, Munroe, & Bandyopadhyay, 1996; Ashwatha & Anthony Xaviorb, 2014),SiC(Hassani, Bagherpour, & Qods, 2014), B4C(Ehsan, Masoud, Touradj, Amir Hossein, & Ali, 2015),TiC(Ehsan, Ali, Masoud, Kamyar, & Touradj, 2017), and TiB2(Fei & Zhong-Hua, 2013).On the other hand, grain refinement is also an important techniques for improving the properties of aluminum alloys. Finer grains improve the mechanical properties of the alloy. For cast and wrought alloys, addition of grain refiners in molten alloys accelerates generation of nucleus and suppresses grain growth. Al-Ti-B alloy is generally added as grain refiners in the molten aluminum alloys(Easton & Stjohn, 2001). Especially, TiB2has very high melting point, low density, and excellent hardness. Therefore, TiB2was selected as additions into aluminum alloys. Liquids reaction leads to high cost, oxidation, discoloration of molten alloy, and clustering of additive powder as compared with solid reaction such as sintering. However, sintering of aluminum alloy powder with ceramic powders is difficult for oxide layer surface. Recently, we take attention to spark plasma sintering (SPS) as advanced sintering process. SPS process can easily sinter a high quality specimen at a lower sintering temperature and in a shorter time than conventional sintering processes. By SPS process, we have sintered titanium powders that are as difficult to be sintered by any other processes as aluminum powders, and improved mechanical properties by adding hard ceramic powders TiC and TiB(Kamegawa, Izui, Komiya, Kobayashi, & Arimoto, 2015; Sampei, Izui, Komiya, Shigimura, & Suzuki, 2015). Furthermore, it is important to consider not only pure aluminum but alloys for solid-solution or precipitation strengthening. Actually, pure Al does not have enough strength compared with the alloys. Al-Cu alloy and Al-Mg alloy demonstrate adequate strength for industrial and commercial sectors. Al-Mg alloy retains good formability, and has high resistance to corrosion. It is therefore used for many applications. We must consider alloying processes. The most cost effective process is blended elemental technology where alloying elements are added to base powder as elemental or master alloy powder (Smugeresky & Dawson, 1981; Yasue, Radjai, Miwa, & Sakaguchi, 2003; Bolzoni, Esteban, Ruiz-Navas, & Gordo, 2012)."

Jan 1, 2018

By Pierre M. Matheron

TRANSMANCHE-LINK is responsible for designing, developing and implementing the project for a fixed link under the English Channel, comprising two running tunnels of diameter 7.6 metres and a service tunnel of diameter 4.8 metres. The three tunnels will all be 50 km long, with 37 km bored through chalk marl at a depth of 40 metres under the sea bed. The tunnels will be driven from both sides of the channel from intermediate addits above the coastline on either side with a 55 m access shaft at Sangatte in France and two "descenderies" or inclined tunnels addits and a shaft at Shakespeare Cliff on the English side. A total of eleven tunnel boring machines will drive the 150 km of tunnels. The major part of the tunnel linings will be built of precast reinforced concrete segments, and two plants have been specially built to produce the necessary 725,000 segments. Seven million cubic metres will be evacuated on wagons along the tunnels and then lifted by belt conveyor on the English side, and by hydraulic mucking from the bottom on the French side. Preliminary work started early in 1987 with manufacture of the first boring machines, construction of five precasting plants, boring of the Sangatte shaft in preparation of the Shakespeare Cliff entrances. The principal project dates are :

Jan 1, 1987

By William Fink

Two of the aluminum-alloy systems previously studied-the alumi-num-titanium and the aluminum-chromium-exhibit a peritectic reaction at the extreme aluminum end of the diagram. Preliminary work indi-cated that the aluminum-zirconium and certain other aluminum systems were similar in this respect. The present paper, the twentieth of a series from the Aluminum Research Laboratories, reports the results of a recent investigation of equilibrium relations in aluminum-zirconium alloys of high purity, which confirm the preliminary observations. PREVIOUS INVESTIGATIONS There has been only one investigation of the aluminum end of the aluminum-zirconium system. Sykes1 prepared and studied alloys containing 0 to 70 per cent Zr. The lowering of the freezing point of aluminum by the addition of zirconium was found to be very little, if any (less than 2°C.). He placed the solid solubility of zirconium in aluminum at room temperature between 0.57 and 0.97 per cent. A few other investigators have attempted to determine the com-position of the intermetallic compounds occurring in this system. Hönigschmid2 obtained the compound ZrAl3 as a by-product during the preparation of ZrSi2. He made no attempt to prepare other aluminum-zir-conium compounds. Weiss and Newmann3 prepared an alloy by heating aluminum with a double fluoride of potassium and zirconium. When this alloy was treated consecutively with caustic soda and hydrochloric acid, there was a residue, which contained approximately 72 per cent Zr and 28 per cent Al (Zr3Al4). Marden and Rich4 prepared an alloy in the same way, treated it with caustic soda, and obtained a residue of silver-white crystals, which contained 70 per cent Zr and 30 per cent Al (Zr3Al4).

Jan 1, 1939

By William Mikulas Lars Thomassen, Clair Upthegrove

Little work has been done in the field of the nickel-tin binary system. The complete diagram has been investigated on two occasions, but the results are in very poor agreement. The structure of a compound NiSn and the solubility of tin in nickel have been determined by X-ray methods. Several investigations have been made of the liquidus curve, and the compositions of the eutectics have been determined. A study of the literature, however, shows that there is no satisfactory agreement between the data presented in the various papers. The present investigation was undertaken in an attempt to determine the equilibrium conditions, and to correlate X-ray with metallographic data. The equilibrium diagram was determined by thermal and metallographic means, and the solubility of tin in nickel further investigated with X-rays. Powder diagrams were made of the intermetallic compounds, and three of the structures were partly determined. NO attempt was made to determine the range of homogeneity of the intermetallic compounds. Review of the Literature Vigorouxl prepared alloys of tin and nickel containing 74 and 92 per cent of tin. By treating these alloys with very dilute nitric acid or with sodium hydroxide he was able to separate residues, both of which analyzed 66.7 per cent tin. This corresponds to the compound NiSn and was reported as such. Guillet2 made the first investigation of the complete binary diagram Fig 1) The maximum point of the liquidus is at 43.5 per cent nickel. Several solid solution areas were found, and the compound NiSn was included on the strength of Vigoroux's work. The investigation was

Jan 1, 1937

By Andrzej Tejchman

A method of improvement of a subsoil under bored pile base by injection is presented. The method employs a special chamber attached to the reinforcement at the bottom of the drilled borehole. The chamber is made of semi-permeable textile bag. The injection entered under high pressure into the bag, causes prestressing of subsoil under the pile base. The results of load tests of piles improved in this manner have shown a substantial increase of their capacity together with simultaneous reduction of settlements. This technology has been implemented for four constructions such as trestle bridges in Gdynia and Warszawa and the bridges in Szczecin and Gdansk. The injection effects are shown based on the load test results.

Jan 1, 2002

By D. M. Doyle

"The Strathcona Concentrator operations, the application of control systems in the crushing, flotation and tailing fill sections, and current and future computer control concepts are described in this paper.The computer has been used for reporting and monitoring roles and operating the on-stream analyzer since start up of the mill in 1968, while over the past twenty months, it has been used for process control. The systems which have been developed include:1. The blending of pentlandite concentrate with pyrrhotite concentrate to produce a special product of constant nickel analysis.2. The blending of cement with tailing fill to produce backfill of consistent cement content.3. The supervisory control of xanthate, frother and pH to the flotation circuits to maintain the nickel copper concentrate grade within narrow limits.IntroductionThe Strathcona Concentrator is currently treating 7,200 tons per day of an ore which contains nickel associated with the minerals pentlandite (28 -32% Ni) and pyrrhotite (0.3 -1.0% Ni). The ratio of the nickel minerals varies from 4 to 15 parts of pyrrhotite to 1 part of pentlandite over the orebody. The production of a high grade concentrate re4uires the separation of this small quantity of .oentlandite from the much greater proportion of pyrrhotite and gangue and is complicated by the presence of two pyrrhotite minerals differing in nickel content, floatability and magnetic susceptibility."

Jan 1, 1974

By W. H. Pomroy

Spontaneous combustion fires in deep metal mines, through relatively infrequent, are nonetheless cause for considerable concern because they pose a direct threat to the safety of miners and are quite disruptive to mine operations. They often occur in remote, inactive, or abandoned sectors of a mine where access for firefighting is difficult or impossible. Over half of all noncoal mine fires that last more than 24 hours are caused by spontaneous combustion. The most common means of fire control for spontaneous combustion fires is sealing and/or Flooding the affected zone. This process is never easy, but it is made especially difficult (and hazardous) if the fire grows in size and intensity to the point where underground fire- fighting crews must wear self-contained breathing apparatus owing to mine air contamination. The Bureau of Mines has developed and in-mine tested a mineworthy fire detection system capable of sensing the earliest traces of spontaneous combustion, thus enabling mine personnel to initiate fire control operations before hazardous atmospheres are created. This paper discusses system design within the context of the harsh mine environment, and describes laboratory and in-mine performance tests of prototype equipment.

Jan 1, 1985

By Daniel W. H. Su, Gregory J. Hasenfus

This paper demonstrates that finite-element modeling can be used to predict in situ coal pillar strength, especially under non ideal conditions where interface friction and roof and floor deformation are the primary controlling factors. Despite their differences in approach, empirical, analytical, and numerical pillar design methods have apparently converged on fundamentally similar concepts of coal pillar mechanics. The finite-element model results, however, are not intended to suggest a new pillar design criterion. Rather, they illustrate the site-specific and complex nature of coal pillar design and the value of using modeling procedures to account for such complex site-specific conditions. Because of the site-specific nature of coal pillar design, no single pillar design formula or model can apply in all instances. Understanding and accounting for the site-specific parameters are very important for successful coal pillar design. More work remains before the century-old problems related to pillar design are finally solved. Future research should focus on the cross-linkage of empirical, analytical, and numerical pillar design methods.

Jan 5, 1999

By V. F. Bannikov, A. P. Kozlov

"The purpose of this study was to develop a theoretical and technology framework for designing new combined technologies for processing tailings containing non-ferrous and noble metals using dry separation. The main goals of the study were: identifying the distribution patterns of valuable components in various fractions in dry separation processes; examining the patterns identified for different types of non-ferrous and noble metal tailings; developing a theoretical and technology foundation for the development of innovative technologies for the efficient processing of tailings with minimal process water consumption. To examine the possibility of efficient recovery of valuable components from refractory tailings using dry separation, an experimental laboratory unit was designed and built, composed of novel or modified lab equipment: plasma unit for increasing the magnetic susceptibility of Fe - containing minerals; magnetic separator supporting isodynamic and polygradient fields; pneumatic separator for the dry separation of finely dispersed mineral mixtures; dielectric separator using the resonant frequency of the electric field. The laboratory unit supports various modifications and combinations of the lab equipment. The experimental studies led to the development of a unified process scheme for lab tests of mature and non-ferrous smelter tailings using dry separation methods.INTRODUCTION The huge amount of waste from mining and processing of mineral resources Russia inherited from the extensive use of mineral resources in the Soviet Union and amount of waste continue to grow. Often the content of valuable non - ferrous, rare and noble metals in waste exceeds the balance contents in natural ores of the developed deposits. The availability of a rich scientific reserve for the creation highly effective innovative technologies for waste processing determines the necessity of the acceleration in the resolution of problems of the complex assessment, capitalization and involvement in the processing of technogenic resources in Russia (Chanturiya and Kozlov, 2014.)."

Jan 1, 2018

By R. H. Terhune

THE enormous production of pig-iron, together with the many difficult and interesting problems with which its manufacture is fraught, 11as secured to this industry the exclusive attention of scientists with reference to the chemistry of iron, while some of the minor departments of its metallurgy have suffered neglect. Particularly is

By Vutukuri VS, Budavari S

During recent years many investigators have suggested large spacing to burden ratios to improve the fragmentation obtained in blasting. In spite of these suggestions, most operators still use a conventional ratio of 1 to 2. From single hole longitudinal charge tests in laboratory, it is shown that burden controls the fragmentation. The burden for obtaining uniform fragmentation is smaller than the burden to obtain maximum breakage. Tests on two or three holes show that a larger spacing to burden ratio can be used for smaller burdens, but it is not possible for the larger burdens chosen to obtain maximum breakage. By using finite element analysis evidence is presented to show the effect of spacing and burden relationship on blasting results.

Jan 1, 1975

By A. L. Mular

Steady-state material balances calculated from data measured at various locations around process units are useful for many purposes, such as metallurgical accounting, on-line control, and the development of mathematical models. Often it is possible to calculate material balances by several independent procedures when excess measurement information, i.e., redundant data, is available. Clearly, if the data were collected without measurement errors, a theoretical condition never found in practice, all material balances calculated from redundant data would be in agreement. The real situation is that error exists in practical measurements, so that the results of material balances determined from available optional procedures differ. Consequently, best fit computational procedures to improve the material balances by taking measurement errors into account have been formulated. Such procedures can be used also to judge whether measurements are grossly in error due to either faulty observations or defective data sensing devices. A variety of mathematical techniques are available which serve to adjust raw data. The adjusted data permit mass balancing that does not depend on the computational method. To illustrate the need for an adjustment procedure, Table 1 shows a raw data set acquired around the Brenda Mines Ltd. No. 4 grinding circuit shown schematically in Fig. 1. At least seven optional ways to calculate a circulating load ratio may be employed. These are shown in Table 2 where, depending upon the calculation [ ]

Jan 1, 1979