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By R. Herrera-Urbina

Measurements of the electrophoretic mobility of bastnaesite in aqueous solutions of sodium nitrate reveal that the isoelectric point (iep) of this cerium fluocarbonate occurs at about pH 9.3. These results also indicate that the pH affects significantly the electrophoretic mobility of bastnaesite, which becomes more positive as the pH decreases and more negative as the pH increases from the iep. Computations of solid-solution equilibria for the bastnaesite-H2O system closed to the atmosphere as a function of pH indicate that cerium fluoride precipitates in acidic solutions, whereas cerium hydroxide precipitates in alkaline solutions. When the initial amount of bastnaesite is fixed at 0.05 wt.% (the solids concentration used for electrokinetic experiments), these computations reveal that bastnaesite is the only solid phase in the pH range from 5.75 to 8.55, it coexists with CeF3(s) between pH 5.22 and pH 5.74, and with Ce(OH)3(s) between pH 8.56 and pH 10.12. Cerium fluoride and cerium hydroxide are the only solid phase below pH 5.2 and above pH 10.2, respectively. According to these computations, the dissolution-precipitation processes that occur when bastnaesite is equilibrated in aqueous solutions at different pH values determine the solid phases present in the system. In turn, these processes must affect the electrokinetic potential at the solid-solution interface, and they must be considered for explaining electrokinetic measurements as a function of pH when bastnaesite is the original solid phase in aqueous suspensions.

By Nicholas Kyriazi

The Bureau of Mines has been developing breathing and metabolic simulator technology since 1970. Breathing simulation has been widely achieved throughout the world and used in the testing of open-circuit breathing apparatus, but satisfactory metabolism simulation has not been achieved. This situation required that the testing of closed-circuit breathing apparatus, which are the only type used in mines, be done using human test subjects. The goal was a machine that could accurately simulate both the breathing and the metabolic functions of a human being for testing of closed-circuit breathing apparatus. The advantages of using such a machine instead of a human being for testing respiratory protective devices lie in its ability to quantify metabolic input, its repeatability, and the lack of a need to deal with the vagaries of human subjects. This report will describe the breathing and metabolic simulators that have been developed and used by the Bureau over the past 15 yr.

Jan 1, 1986

By R. G. Gillies

The pipeline transport of paste, backfill or thickened tailings slurries is an important component of the tailings disposal process in many mines around the world. These mixtures contain significant fractions of fine (clay) and coarse (sand) particles, causing them to exhibit non-Newtonian flow behaviour and high frictional pressure gradients. There is often economic incentive to operate these pipelines in the laminar flow regime. Irrefutable evidence has shown that coarse particle settling can occur during the laminar flow of these slurries even when static settling tests show no indication of such behaviour. Previously, a ?rule-of-thumb? minimum frictional pressure gradient of ~1.5 to 2 kPa/m was suggested to ensure effective sand transport, based on the results of tests conducted using viscous Newtonian oils. In this paper, we examine the results of laminar flow tests of non-Newtonian, coarse-particle laden slurries conducted with pipeline loops of 50, 100, 150 and 250 mm in diameter. The results indicate that the ratio of the mean wall shear stress to the mean surficial particle stress is a better indicator of laminar flow settling tendency than frictional pressure gradient.

Jan 1, 2007

Use of Impact Crushing for the Enrichment of Low-Grade Colemanite Concentrates This paper presents the results of an investigation into the enrichment of -25+3 mm low grade colemanite concentrates exploiting differential breakage properties of various minerals associated within the ore sample. Boric acid production process requires concentrates containing at least 42 per cent B2O3, hence concentrates below this grade either stock piled or further treated to increase B2O3 content. The low grade concentrate is obtained as a by-product of Emet Colemanite Concentrator and the B2O3 content may vary around 37 - 38 per cent. The sample used in the experimental studies assays 37.52 per cent B2O3. In the experimental procedures the sample was crushed using a laboratory size horizontal shaft impact crusher and the products were classified into different size fractions by screening so that any improvement by size could be observed. In the tests the effects of parameters such as the revolution speed of the crusher and heat treatment was checked. Test results prove that boron contents show a tendency to increase as the particle size decreases. As a result of the experimental studies a colemanite concentrate assaying 42.13 per cent B2O3 is produced with 76.55  per cent recovery. Arsenic content is seen to change inversely proportional with the B2O3 content of the concentrate such that it drops from 1016 ppm from the as received sample to 676 ppm in the concentrate.

Sep 13, 2010

By Tomas Astorga

APEC, the Asia Pacific Economic Cooperation is the forum of 18 economies, having a combined GDP of approximately 56% of the total world income, and over 45% of global trade. Its mining sector produces a large portion of the main minerals and metals in the world. In 1997, APEC economies produced 67% of world copper output, 55% of gold, and over 45% of other base metals. Mining in APEC captures more than 60% of the total mining investment in the world. Against this background, the Expert Group on Minerals and Energy Exploration and Development, in short GEMEED, was created in 1996, under the auspices of the APEC Energy Working Group. The sustainable development of mining activities is a main concern in APEC and GEMEED. Several programs related to the subject are actively being pursued by the Expert Group. Among them, it should be noticed the creation of an Environmental Cooperation Sub Group coordinated by Japan, whose main aim is to encourage proposals related to the environmental soundness of mining projects in the region. Also, it should be noted the existence of a Database Steering Committee whose focus is the development of an information network related to mining opportunities in the region GEMEED is a gathering of experts from all the APEC economies. As such, it represents a privileged forum to discuss policy issues related to mining. On this regard, the paper focuses on concrete actions taken by GEMEED to enhance the sustainability of the copper activity in the region.

Jan 1, 1999

By P. L. Sibrell

Electrorefining of Ti in nonaqueous solvents has been studied by the U.S. Bureau of mines as a method for recycling impure scrap Ti. Electrochemical behavior of Ti species was investigated using cyclic voltammetry. Research results showed that Ti metal can be dissolved in polar solvents such as dimethylformamide or dimethyl sulfoxide. However, deposition of Ti from these solvents was not successful. Several solvent systems were investigated for electrodeposition of Ti but no deposits were obtained. Reduction of Ti4+ complexes to Ti3+ proved to be straightforward, but reduction to lower oxidation states could not be confirmed. In dimethylformamide solutions, cyclic voltammetry results demonstrated the reduction of Ti to an oxidation state of less than three, but no Ti metal was identified. In dimethyl sulfoxide solutions containing LiCl, it was possible to deposit Li metal. After adding Ti salts to the solution, electrolysis quickly passivated the electrode. Deposition of Ti was also investigated in solutions of dimethoxyethane and propylene carbonate but, again, no reduction of Ti to oxidation states of less than three occurred. Therefore, the prospects for a nonaqueous electrorefining system for Ti metal do not appear promising.

Jan 1, 2010

By V. Riihimäki, M. Luotamo

The Unit of Toxicological Risk Assessment of the Finnish Institute of Occupational Health (FIOH) is conducting a 'Health Risk Assessment for Metallic Chromium and Trivalent Chromium' under the sponsorship of the International Chromium Development Association (ICDA) and the International Stainless Steel Forum (ISSF). This risk assessment will be conducted in accordance with the current European Union legislation in force (Council Regulation 793/93/EEC, Commission Regulation 1488/94/EEC, Dir. 67/548/EEC), but also to meet the regulatory obligations as set out in the European Commission REACH legislation proposal (Consultation Document, the Registration, Evaluation, Authorisation and Restrictions of CHemicals). Further aims include outlining the criteria for the setting of occupational exposure limits for metallic chromium and trivalent chromium compounds. Human Health Risk Assessment according to the current legislation shall entail hazard identification of the toxic end points (acute toxicity, irritation/corrosivity, sensitisation, repeated dose toxicity, mutagenicity, carcinogenicity, reproductive toxicity) including, as appropriate, dose (concentration) - response assessment, and derivation of the N(L)OAELs (No (Lowest) Observed Adverse Effect Level) and/or DNELs (Derived No Effect Level). Exposure assessments for workers, consumers and humans exposed via the environment take into account all the known intended uses. Risk characterisation will compare the typical and/or reasonable worst case exposure estimates to the N(L)OAELs or DNELs to determine Margins of Safety (MOS) for all human populations by each exposure scenario and type of effect, followed by conclusions about the presence or absence of risk. Although all of the key elements of existing legislation remain in REACH, the principal change is that, the burden of proof will be transferred from the member state authorities to industry. The new proposed format of Chemical Safety Report (CSR) will include Risk Management Measures (RMM) as an essential part of the report in addition to the risk assessment. The RMM plays a role in the evaluation of further testing needs and advocating reasons for possible waiwer of requirements. The research programme started in March 2002 and will be completed within the time frame of two years.

Jan 1, 2004

Plant for the production of sulphuric acid from pyrites flotation concentrates was commissioned at Cockle Creek during 1956, to meet increasing demands for commercial acid and superphosphate. Pyrite was chosen as raw material because of the uncertain supplyposition of imported brimstone and the desirability of utilising domestic sulphur.Desulphurisation of the pyrite is performed by two 40-ton per day roasters of the Turbulent Layer type operated under licence from the Badische Analin and Soda Fabrik (B.A.S.F.) organisation. These units are the first of their kind commissioned in the southernhemisphere. Pyrite is fed to the roasters in the as-received un-dried condition. Waste heat steam production is coupled with electricity generation within the plant. Sulphur dioxide is produced at comparatively high strengths and cleaned by conventional cyclone and hot electro-filter equipment.The acid unit has a capacity of 100 mono tons of sulphuric acid per day and includes cooling and wash towers, mist precipitators, a single stage drying tower, 4-pass oxidation section and absorption system.INTRODUCTIONSulphuric acid has been manufactured at Cockle Creek Works since 1913, when the first chamber nitration plant was commissioned. The raw material was brimstone roasted in Herreschoff furnaces. Since that time three additional chamber units have been constructed and have produced acid from brimstone, zinc concentrates, pyrites and -spent oxide, according to changing economic and supply factors.Three chamber units are still in operation. Contact processes have become increasingly important since the first Schroder-Grillo unit was commissioned in 1923. Six of these 5-ton per day units were operating in the mid-thirties, but have since been demolished. Two 15 ton Chemico hot gas contact units commenced operation in 1937 and 1938, and although modified, are still in service.The increasing demand over recent years for sulphuric...

Jan 1, 1957

By C McHugh, F Oppolzer, B Rogers, A Stokes

Rio Tinto has embarked on a journey to use automation to improve the performance of its surface mines. The driver for automation has more to do with improving the accuracy and consistency of mining processes and less to do with cost savings through labour reduction.A key task in most surface mines is blasthole drilling. The degree to how well this is done cascades through the downstream mining process. It impacts scheduling, excavation, slope stability, material handling, beneficiation, ore loss and final product blending. Improved blasthole drilling was identified as an objective that has a significant business case in most of Rio TintoÆs surface mines.This paper describes Rio TintoÆs multi-drill automation project, which has developed a robust system for automating most of the functions on several Caterpillar SKSS16 drill rigs. Automated drilling is currently being trialled in production at the West Angelas iron ore mine in the Pilbara region of Western Australia. A description of the essential elements of the automated multi-drill system is given together with an overview of how automated drilling is performed remotely from the operating bench.A review of the performance and benefits of the automated multi-drill system is given together with future plans to extend the functionality of automated drills.CITATION:McHugh, C, Stokes, A, Oppolzer, F and Rogers, B, 2012. Automated multi-drills in Rio Tinto, in Proceedings Eighth Open Pit OperatorsÆ Conference , pp 83-88 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 18, 2012

By A. C. Losekamp, J. B. Conway

Thermal-expansion data for, tungsten, rhenium, tantalum, .molybdenum, niobium, W-25 pct Re, Ta-10 pct W, ant1 Mo-50 pct Re are presented covering the range from room tempature to 2500°C. In these measureMents, made in a resistively heated tungsten tube furnace operating in a helium atmosphere, data for rod and sheet specimens were found to be identical; in addition, arc-cast and sintered tungsten were found to yield essentially identical results. Optical rneasurenlents of thermal expansion .made in any atmosphere other- than vacuum are subject to a refraction error which can be quite substantial. Specimens tested in helium appear shorter than when tested in racuum and hence a special correction factor must be applied to the helium data in order to obtain accurate results. WHILE it is true that linear thermal-expansion data for many of the refractory metals have been measured to very high temperatures, it is also true that except in a few instances the data from various investigators are not in good agreement. This is particularly evident in the case of tantalum and niobium although some tungsten data have been reported which differ by as much as 40 pct from the data of other investigators. Due to the sensitivity of both tantalum and niobium with respect to impurity absorption during exposure to high temperatures, it is probable that this single factor accounts for the majority of the discrepancies in the thermal-expansion data for these metals. However, this same factor can probably not be employed to explain the existing differences in the tungsten data. In all probability, these are due to errors in the measurement technique, to material composition variations, or to changes which take place in the material during the heating process (e.g., additional densifica-tion resulting from heating a sintered specimen above the original sintering temperature). In view of the discrepancies which exist in the linear expansion data reported for many of the refractory metals, the current study was initiated in an attempt to resolve such differences. Also, no high-temperature linear thermal-expansion data were found to be available for several refractory metals. Providing such data was another objective of the current investigation. MATERIALS In this study test specimens were employed in either rod or sheet form and in several instances both arc-cast and sintered material were employed. Material compositions are presented in Table I. Helium gas was fed to the furnace at a rate of about 0.5 SCFH and no special purification procedures were employed. However, the helium contained less than 50

Jan 1, 1967

By W. A. Ahrens, J. H. McNamara, J. G. Franek

"An economical, pollution-free process has been developed for the hydrometallurgical extraction of copper from sulphide ores. The extracted copper, in the form of cuprous chloride (CuC/), is converted by reduction to copper metal. The metal is melted and fire -refined into wire bars which meet the standards of electrolytic tough pitch (ETP) copper wirebars. IntroductionThe successful development of the Cyprus Copper Process has been an evolutionary series of events covering a time span of some nine years. The original process, based on an electrolytic membrane cell principle , was abandoned in 1975 because of technical, economic and pollution problems. During the past four years, the pilot plant has been reconstructed based on a new flowsheet and operated successfully in several campaigns, some for as long as four months. The pilot-plant hydro section operates at a 225-lblhr copper rate. In October 1977, a feasibility study was completed by Jacobs Engineering, Pasadena, California. The study showed favourable economic and technical feasibility. Jacob's studies in 1978-79 revealed favourable comparative economics with other known pyrohydro processes and favourable economies of scale.The Cyprus Copper Process converts copper concentrates of varying composition into copper metal, which has been proven to be equivalent in every way to electrolytic tough pitch copper, suitable for electrical applications. This is accomplished at capital and operating costs which are estimated to be lower than those associated with any other known currently applicable technology. Also, the total energy requirement is equal to or less than any other known process and the process is essentially pollution free."

Jan 1, 1980

By John L. Lamont, Walter Crafts

STUDIES of the effect of composition of steel on hardenability by Grossmann,1 and as-quenched hardness by Field2 and by the authors,3 have made it possible to predict the results of quenching when the composition and cooling rate are known. In order to extend the application of the hardenability calculation to the quenched and tempered condition in which steel is finally used, a survey has been made of the hardness changes caused by tempering. From this study a method has been developed for the prediction of hardness and tensile strength of steel in the tempered condition. The method of calculation was developed from Rockwell C hardness tests on quenched and tempered Jominy specimens and is expressed in Rockwell C hardness units. It is of an additive type in which the degree of softening from as-quenched hardness is estimated. Tempered properties may be calculated within about plus or minus 5 Rockwell C hardness or plus or minus 15,000 lb. per sq. in. tensile strength. This degree of accuracy is less than that necessary for the control of heat-treatment, but is adequate for the comparative evaluation and selection of alloy steels. The formula indicates that tempered hardness is primarily dependent on as- quenched hardness and, as in the hardening reaction, the progress of tempering is controlled mainly by the carbon content- Alloys tend to retard softening by a secondary hardening mechanism in which the alloy appears to migrate from ferrite to the carbide phase. The factors for the effects of alloys in tempering vary so much from the effects of alloys in hardening that different steels of equivalent hardenability may, after lie heat-treatment, differ considerably in tensile strength. PROCEDURE In developing the method for calculating tempered Rockwell C hardness, simple and complex steels were tested over a range from 0.08-to 0.65 per cent carbon and up to 2.68 per cent manganese, 2.18 silicon, 3.50 chromium, 4.94 nickel, and 1.06 molybdenum. The steels were made as small induction-furnace heats at the Union Carbide and Carbon Research Laboratories, Inc. The accuracy of the method was finally checked on a variety of carbon, low-alloy and high- alloy types of heat-treating steels produced under commercial conditions. The method was based on a study of tempered Jominy bars, and its validity was tested by correlation with the center hardness and tensile strength of oil-quenched and tempered bars from ¼ to 4 in. in diameter. The method of calculation was derived from the differences in Rockwell C hardness between as-quenched and quenched and tempered Jominy specimens. Prenormalized Jominy hardenability specimens quenched from a normal temperature for austenitization were used to obtain a range of as-quenched Rockwell C

Jan 1, 1946

By Y. Yhang, D. C. Sego

ABSTRACT This paper evaluates the potential of freeze-thaw dewatering using Albian mature fine tailings (MFT). Freezing tests were first performed to study the effect of freezing rate on dewatering efficiency. Lower freezing rate resulted in higher thawed solids content and shear strength. Subsequently, large strain consolidation tests were conducted to investigate consolidation behaviour and how it is affected by freeze-thaw. The consolidation behaviour was presented in terms of effective stress versus void ratio and permeability versus void ratio. The results can be used to predict the field behaviour of Albian MFT and optimize the application of freeze-thaw for MFT dewatering.

Jan 1, 2014

By R Lethlean

The mining industry in its drive to optimise equipment use and minimise cost simply to remain profitable in an uncertain commodity market needs to develop a greater understanding of equipment capabilities and cost. The factors influencing mobile equipment fleet cost and performance commence at the time of mine planning and continue to exert an influence over the life of the mine. These factors must be understood at the early stages of any operationÆs planning process as they continue to impact both positively and negatively on fleet performance and operating cost throughout the life of the mine. The key factors examined in this paper include: grades; rolling resistance; fragmentation and truck loading.

Jan 1, 1998

By D. G. Sediako

Chemical composition and the casting/rolling production routes determine the cost and properties of the wrought material. For example, the coarse-grained structure frequently associated with DC casting requires complex rolling schedules to refine the grain size. Hot forming (rolling/forging/extrusion) results in a strong crystallographic texture, which is responsible for the tension-compression strength asymmetry frequently exhibited by magnesium alloys. Understanding the influence of alloy composition on texture evolution during forming provides useful practical information to optimize industrial hot-forming technologies for magnesium alloys. In this study, a series of Mg-based alloys containing varying combinations of Al, Rare Earths, Zn, Ca, and Sr were subjected to identical casting and extrusion processes in order to isolate the effects of alloy composition on texture evolution. Textures were measured by neutron diffraction at the NRC Canadian Neutron Beam Centre. The ability of neutrons to penetrate deeply into materials allowed information to be retrieved from all regions of the bulk specimens without destructive and time-consuming sectioning operations, thereby providing true bulk texture data. {1010} , (0002), {1011}, and {1012} pole figures were generated for all of the as-processed alloys, from which Orientation Density Functions were obtained. The were then used to reconstruct the pole figures and to extract semi-quantitative texture data showing how the (0002) and {1010} planes align themselves with respect to the extrusion axis. It was found that varying the concentration of aluminum (3-4 wt%) and Rare Earths (2-3 wt%) in AE alloys had a weak effect on texture development. All of the alloys showed similar magnesium extrusion textures, in which the (0002) poles align themselves preferentially with the extrusion axis. The substitution of Sr for Rare Earths also did not have a significant impact on texture development. On the other hand, while the presence of small amounts of Zn and Rare Earths did not have a strong effect on texture development, alloys with higher concentrations of these alloying additions (in combination) showed an enhanced tendency for the {1010} poles to align themselves with the extrusion axis. The addition of Ca also enhanced the alignment of the {1010} poles with the extrusion axis. These textures can complicate further processing and introduce a significant anisotropy that could influence creep properties.

Jan 1, 2007

By Donald O. Capstick

A mineral survey of a 13,525-acre portion of the 21,875-acre Owyhee Canyon Wilderness Study Area in northern Nevada was conducted by the U.S. Bureau of Mines in 1984. Two samples from sand and gravel deposits in the study area contained minor placer gold typical of the Owyhee River area. The gold-bearing gravels are too low grade or of insufficient volume to support commercial placer mining operations. The sand and gravel deposits might have minor local construction uses.

Jan 1, 1986

By A. Andreas

The transportation of mine products incurs a cost which can have a significant bearing on the competitive position of the product. This statement not only holds true for the transportation of the finished product but certainly as much for the in- plant haulage of the raw materials. Extensive literature is available both in North America and Europe on all aspects 02 these questions and to cite only a few of them: Pipelining of slurries, oil and gas, shipping of minerals and oil from the Arctic by icebreaking tankers, airlifting of metals or concentrates, etc. This paper is concerned with movable crushing plants as opposed to stationary and their influence on the in-plant transportation, that is trucks vs. belts.

Jan 1, 1973

The products of the steel tube industry play an important part in the production,' transrzission and refining of oil. Steel tube manufacturing is already well established in Australia and supplies the petroleum industry with its requirements" within the .present limitations of the various tube plants., With the discovery of oil in commercial quantities in this country, the steel tube industry could be expected to extend its scope to cover a much wider range; of oil country tubular goods, line pipe and refinery. Tubing.

Jan 1, 1962

By A. Eugene Lillstrom

I N the development of iron mines and production of iron ore from the Marquette range, drilling blast-holes is an important phase of the mining cycle. The ground drilled in ore production can be classified into two main categories, soft hematite and hard hematite or magnetite. Within these categories the material exhibits a wide range of penetrability by percussion drills. Development work encounters various types of rock. Slate and altered basic intrusives constitute the softer types commonly encountered. Harder materials are represented mainly by greywacke, quartzite, iron formation, and diorite.

Jan 12, 1951

Knowledge of initial ground pressures or in-situ stresses and mechanical properties and geological conditions is of great importance in drivage and maintenance of a mine roadway. Field measurements of the in-situ stresses and the geological and mechanical properties have been carried out. However, these methods are really impractical in using in underground mines. Alternatively, back analysis method using measured displacements during drivage of roadway can be used. The paper presents discussion on some problems in applying inverse formulation of back analysis to a roadway driven in an in- homogeneous rock mass. The back analysis is formulated by 2-0 finite element method. The inverse procedure is carried out using a microcomputer, but for the multi-rock layer, a larger computer or a main-frame computer is used due to an iterative procedure.

Jan 1, 1990