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By Brett P. Spigarelli

To meet the growing need for CO2 capture and storage technology, Michigan Technological University is researching CO2 capture and storage using alkali solutions1. Without implementing emission controls, world energy emissions will rise from 29.7 billion t in 2007 to 42.4 billion t in 2035. The first objective of the project was to determine the optimal amount of alkali in solution for CO2 absorption. This was accomplished using theoretical equilibrium calculations and experimental absorption data for alkali solutions of 1, 2, 3, 4 and 5 weight %. As the % alkali in solution increased, so, too, did the ionic strength of the solution. Theoretical calculations took into account the effect increasing ionic strength will have on the solubility of gaseous CO2. The calculations assumed negligible formation of H2CO3, constant temperature and constant pressure. In the experimental setup, a 16% CO2 /balance air gas mixture was bubbled through an Erlenmeyer flask filled with an alkali solution. The gas exiting the flask was fed to a gas analyzer to record the % CO2 in the exhaust gas stream. The % CO2 absorbed was taken as the % CO2 in the exhaust gas minus the % CO2 in the feed. Theoretical calculations found that as the % alkali in solution increases, the solubility of CO2 decreases. This was verified by experimental data, which found that a 2% alkali solution, by weight, was the ideal solution for CO2 absorption. Current research is focused on using the 2% alkali solution for permanent storage of CO2 via mineral carbonation to produce a value-added product.

May 1, 2012

This report, which updates and supersedes the Office of Surface Mining's 10-year progress report published in 1987, deals with the accomplishments of the regulatory and abandoned mine land reclamation programs during the first 15 years of the Surface Mining Control and Reclamation Act of 1977 (SMCRA). Part 1 is an illustrated description of on-the-ground accomplishments; Part 2 presents statistical information for the 15-year period. The data in this statistical report are organized in two sections: national statistics and state statistics. The national statistics provide an overview of coal mining and the implementation of SMCRA since 1977. The information reported for the states presents a brief description of the coal reserves in each area, accompanied by detailed statistics and graphs that relate each state to the nation as a whole. The statistics compiled in this report are from the Office of Surface Mining's files, computer data systems, and annual reports. During the early years of the program, many of the data categories were evolving and changing; therefore, data reported over the 15-year period are not complete for all states for all years, and where data was unavailable or zero, a dash (-) is shown for that item. The data sources used to compile the tables and graphs are listed and described in detail on page 76. Due to the number of requests for this information in the past, statistical information about coal mining and its regulation will be available each year as an appendix to the Office of Surface Mining's Annual Report to Congress. Beginning in Fiscal Year 1993, this information will be compiled and published on an annual basis. For more information about this report, call or write the: Public Affairs Office Office of Surface Mining 1951 Constitution Ave., N. W. Washington, D.C. 20240 (202) 208-2553

Jan 1, 1992

By H. M. Chance

(Butte Meeting, August, 1913.) ADEQUATE treatment of the difficulties surrounding the valuation of mineral lands requires that agreement be first reached defining value as understood for the purpose of appraisal. To define value as the price of a product is not sufficient, and does not assist us in using the factors that cause variations in values and in relative values. The real value of any product depends primarily upon its relation to the necessities, comforts and pleasures of mankind. As the necessities, comforts and pleasures of the civilized races differ-from those of more primitive man, the value of products varies with the degree of civilization and the environment of the consumer. Coal has no value to the savages of warm climates, and arrow-head flint none to the residents of New York. It has long been recognized that what has. been termed ?intrinsic value " must be limited to materials that are essential to existence-air, water, food. But " intrinsic value " cannot be measured in monetary terms. The intrinsic value of a bushel of wheat is due to the fact that it will support the life of an individual for a certain definite time, but this fact does not enable us to measure or to express that value in monetary terms. It has often been proposed to adopt as a measure of the value of any product the quantity of labor necessary to produce it, but this method is of limited application, and will not apply to what may be termed " intrinsic values." For many reasons it might be well, while assenting to the fact that any material may be intrinsically valuable, to abandon the use of the term "intrinsic value." One of these reasons is the tendency to confuse the idea of " intrinsic value with a value that is conferred by economic conditions, that is purely artificial and that may be permanent or evanescent. Intrinsic value must from its nature be permanent and unchangeable.

Jan 7, 1913

By R. L. Wooten

When discussing what Coal Mine Safety in the future will be, it is important to examine three areas which at present provide significant parameters to the industry. These three areas are: 1) Safety improvements in mining equipment; 2) Labor-management relations; and, 3) The politics of coal mine safety. EQUIPMENT Over the past several decades significant safety improvements have been made in the types of equipment now in use in most operations. Many of these improvements have evolved through mandates from either the U. S. Bureau of Nines, MESA, MSHA; and in some instances, the states. Cabs and canopies are examples of federal mandates while the use of ATRS initially was a state mandate.

Jan 1, 1985

By Kim A. Lapakko, David A. Antonson, Jon R. Wagner

This study examined the potential of mixing rotary kiln fines (RK fines), a waste product generated when limestone is converted to lime (CaO), with acid producing mine waste to provide 1) short-term mitigation by neutralizing acid produced by iron sulfide oxidation and 2) long-term mitigation by facilitating the passivation of iron sulfide mineral surfaces. Five loadings of RK fines were mixed with 75 g of Duluth Complex rock to produce neutralization potential (NP) added: acid potential (AP) quotients of 0,0.11,0.22,0.66 and 1.1. The mixtures were subjected to wet-dry cycling laboratory testing for 585 weeks. The rock alone produced acidic drainage, with pH decreasing below 4 after about 20 weeks of reaction and ultimately reaching the approximate range of 3.3 to 3.5; sulfate release did not decrease over time. The RK fines elevated pH and inhibited sulfate release for time periods which increased with the mass of RK fines present. The pH of drainage from the 0.11 quotient (NP added1AP) loading decreased below 6.0 after 75 weeks of dissolution and decreased to 3.6 after 117 weeks, at which time the reactor was terminated. The duplicate 0.22 quotient loadings of RK fines decreased below 6.0 after 95 and 170 weeks. The former was terminated after 117 weeks, and the latter reached a minimum pH of 2.8 after 512 weeks. Drainage pH from the 0.66 quotient decreased below 6 after 581 weeks. For the drainages which acidified, the cumulative calcium release prior to pH decreasing below 6.0 was 92 to 103 percent of that initially present as calcium carbonateloxide in the RK fines. The pH of drainage from the 1.1 quotient typically remained above 8.0 throughout the period of record. Sulfate concentrations in the drainages decreased while the neutralizing fraction of the RK fines was present, but increased after this fraction was depleted.

Jan 1, 2000

By Wm. O. Vanderburg

This paper describing the milling methods at the Hughesville concentrator of the St. Joseph Lead Co., Hughesville, Mont., is one of a series of similar papers being prepared by the U. S. Bureau of Mines on practices at the various mills in the United States. The writer expresses his thanks for the courtesies extended by the officials of the company while visiting the property and acknowledges the assistance and helpful suggestions given by R. H. Willcomb, general manager, and Carl Martin, mill superintendent, of the Hughesville Division f the St. Joseph Lead Co.; and E. D. Gardner, supervising engineer, U. S. Bureau f Mines, Southwest Experiment Station, Tucson, Ariz., in gathering and compiling the data herein presented.

Jan 1, 1931

By W. M. Snoddy

The Montana Tunnels diatreme is a low-grade polymetallic ore body containing economically mineable quantities of gold, silver, lead, and zinc. Widely varying gold grades combined with the general erratic nature of the mineralization create a complex sampling, assaying, and ore control problem. In order to maximize productivity and profitability, a variety of procedures have been used. These include differing sample size, frequency and method. In addition, assay techniques have been adjusted and refined to fit specific requirements, the result of which is an accurate, functional sampling and ore control system.

Jan 1, 1991

By Brian E. Ladd

"A load test program was performed on two auger cast piles constructed in the Inner Coastal Plain geology of North Carolina. Both test piles were installed through Coastal Plain deposits and into underlying Piedmont residual soils; one test pile was embedded into partially weathered rock (PWR). The recommended 100-ton design load was confirmed by a test program that included instrumenting the piles with strain gages. The two piles performed differently during the load tests due to the effect of embedment into PWR. Loading Test Pile No. 1, which was not embedded into PWR, to failure at about 230% of the design compressive load allowed for evaluation of the mobilization of the ultimate shaft and end bearing resistances. Mobilization pile resistance was evaluated by comparing shaft and end bearing resistances to top of pile deflection (d) normalized by the pile diameter (D). For Test Pile No. 1, the ultimate average shaft resistance was achieved at d /D of about 7.5% and ultimate end bearing resistance at d /D of about 9.5%. Test Pile No. 2, embedded into PWR, achieved a d /D of only about 4% at 200% of the design load and was not loaded to failure. Shaft resistance was mobilized at a different rate within each individual geologic layer, i.e. ultimate shaft resistance did not occur simultaneously for all geologic layers. As the available total shaft resistance was exceeded and end bearing mobilized, the unit shaft resistances reduced from the peak values. A modified Davisson offset using d /D of about 6.5% appears applicable for evaluating the ultimate capacity of auger cast piles in the Inner Coastal Plain.INTRODUCTIONAuger-cast-in-place (ACIP) piling was developed in the 1940’s and patented in 1956 (Neely, 1991). Since patent expiration in 1973, ACIP piles are abundantly used in the United States, particularly in the southeast. However, most literature addresses driven piles constructed in sand and clay with lesser discussion of drilled piles. Conventional design methodologies (a- method, ß-method, SPT or CPT correlations, etc.) are based on data derived from numerous projects in a great variety of geologies. O’Neil (2001) notes that there are significant levels of uncertainty in the “universal” databases as evidenced by coefficients of variation of 0.35 to 0.40 for geotechnical parameters (su, SPT-Nvalue, etc.) used to estimate pile capacities.There is a need to develop local databases developed from data obtained from load tests that measure shaft resistance and end bearing. This paper presents the results of load tests conducted on axially loaded auger-cast-in-place piles constructed in the Inner Coastal Plain geology of North Carolina. Shaft resistance, end bearing, and movements that initiated mobilization of these resistances are described. The information presented herein can be used to refine geotechnical correlations and parameters applied in auger cast pile design methodologies."

Jan 1, 2017

By Roberto J. Guardia, Ted Lewtas, Peter Rasmussen, Klaus Winkler

As part of the Lake Fort Smith Water Supply Dam Enlargement project, located in northwest Arkansas, microtunneling methods were used to install two side-by-side,1.53m (60-in) inside-diameter steel pipes between the intake structure shaft and the lake. The 46.6 m- (153 ft-) and 41.7 m- (137 ft-) long tunnels were excavated in Pennsylvanian sedimentary bedrock ranging from coarse sandstone to siltstone and shale-like claystone. The intake tunnels were constructed 18.3 m (60 ft) below lake level from the dry shaft. Special installation methods and procedures described herein were used to complete the lake taps. Installation difficulties that caused minor delays are also reviewed. After the excavation of the Intake shaft was completed, the two lake taps were installed in approximately ten weeks with the same microtunneling machine.

Jan 1, 2005

By B. Trafton, H. L. Hartman

An earlier paper1 introduced a rapid solution for mine ventilation network problems, employing the digital computer. In this paper, refinements and additions to the computer program which expand its scope of application and a solution to a ventilation network having a coal-mine configuration are presented. The revised program-written in FORTRAN for the IBM 7074 computer in Penn State's Computation Center-is applicable to any mine ventilation network employing natural splitting and having its fan located externally. It accomplishes the following: 1) Distributes an assumed total quantity of air flow among all airways of the network, performing iterations until an acceptable level of error is attained and the flow in each airway is known. 2) Computes the pressure drop (head loss) in all airways and the overall network and mine head losses. 3) Determines the operating point for the mine and a given fan, adjusting all air flows and head losses to the actual values. The basis of analysis used is the Hardy Cross method of successive approximation for solution of any fluid network, explained in detail in the earlier article. In brief, corrections to assumed air flows are computed for all the loops of a network; following distribution to the airways of each loop, the process is repeated until acceptable accuracy is attained. When a hand or desk-calculator solution is used, there is advantage to close approximation of the actual flows in the original assumption of air-flow distribution in the network. Since publication of the previous paper, in which assumption of initial quantities was also necessary in the computer solution, the program has been modified to make the first distribution itself, assigning the total quantity to one specified path in a split and then proceeding to correct the flows. The number of iterations required for a high-accuracy solution is little affected, at least in networks of few loops, 10 to 15 being sufficient to reduce the error to 1 pct or less. The principal limitation of the original program was that it contained no provision for handling a fan. Further, it did not determine the overall head loss in the network and was not designed for multiple parallel openings, such as occur in coal mines. The revised program was written to overcome these disadvantages and also to print out the adjusted flows for all airways, corrected for the system operating point. At the present time, the program can handle only an external fan. The procedure employed in solving a ventilation network is now as follows: 1) Input data consisting of airway characteristics and loop designation along with assumed direction of flow, for each branch of the network and any trunk airways, are fed into the computer. 2) Employing the resistance relationship, where R is resistance, K is friction factor, P is perimeter, L is length, A is area, and n is number of airways (where multiple intakes and returns are employed); values are computed for all airways. 3) An arbitrary, continuous route of flow through the circuit—from beginning to end—is selected and the path identified by airway numbers and read in. 4) Based on a total assumed quantity of flow Q (usually 100,000 cfm.) the computer employs the procedure described in the previous article in distributing quantities of flow among all the airways until a satisfactory level of accuracy has been attained (in the current program, the machine is turned off when the cumulative corrective error in cfm, is reduced to five times the number of airways). 5) Airway head losses H are calculated by the relation H = R Q2 and cumulated along the original designated flow route to find the overall head loss for the network. Trunk airways are then included to obtain the mine head.

Jan 1, 1964

By John G. Palmer

Continued development of an especially impregnated silica gel capable of reversible chemical detection of carbon monoxide (CO) was reported. The affects of changes in mine-related ambient conditions on the detection catalyst's response were explored. Temperature, humidity, and several interfering gases were found to affect the detection catalyst. The interferents include hydrogen sulfide, nitrogen dioxide, acetylene (and methylacetylene), and ammonia. High humidity decreased the detection catalyst's sensitivity to carbon monoxide for some formulations. Increasing temperature generally decreased the reaction time of the detection catalyst with carbon monoxide. Badges and carriers for the visual presentation of the detection catalyst were constructed. Several variations of these devices included provisions for absorbants and filtering agents which help protect the detection catalyst from gaseous interferents. A variety of catalyst support agents were tested in an effort to find the most suitable. Included were alumina, magnesium oxide, magnesium silicate, and several forms of silica gel. In addi tion to free-flowing forms of these sorbents, thin layer chromatography plates coated with cellulose, alumina, and silica gel and newly developed PTFE entrained silica gels were examined. A limited physical, chemical, and mechanistic characterization of the detection catalyst and the materials used to prepare it has been carried out. Metal component ratio studies, spectral, analytical, pH, and rate measurements were done.

Jan 1, 1982

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Jan 1, 1981

Many parameters are important when considering the performance of a concentrator. These include metallurgical performance, such as throughput, metal recovery and final concentrate grade and operating costs, such as power consumption, water usage, reagents and spare parts. In most operations the objective is to maximise metallurgical performance and minimise operating costs, ideally without a large investment in new capital items. A number of projects have been carried out at Newcrest MiningÆs Cadia Valley Operations (CVO) with the aim of improving metallurgical performance and minimising operating costs. This paper focuses on the installation of newly designed flotation mechanisms in various cells in the Cadia flotation circuit and describes the effect these changes had on performance and operating costs.

Jan 1, 2009

By T. A. Chepushtanova, B. Mishra, E. O. Kilibayev, V. A. Luganov

"The paper contains the results of studying about modification of pyrite and arsenopyrite specific surface and porosity at their thermal decomposition. The studying of specific surface was carry out by B.E.T. – adsorption of nitrogen at his boiling-point. In our work were using the electron-microscopical, X-ray structure analysis and chemical analysis. There was established that the decomposition of pyrite and arsenopyrite accompany by increasing of pores volume from 0.303 · 10-3 to 1.23 · 10-3 at increasing of pyrite degree of decomposition about 41 % and then decrease about 0.131 · 10-3 m3/g at degree of decomposition near 100 %. The surface area of pores increase from 0.31 to 1.085 m2/g with following lowering due to enlargement and confluence of minor, small pores. Increasing of porosity accompany with increasing of particles windage that appear the result of heightened dust-furnace partially decomposing pyrite and arsenopyrite particles by air flow from furnace reaction zone. This explains heightened contention of sulfide sulfur in roast dust of sulfide concentrate. 1. INTRODUCTION As a result of ore base exhaustion of ferrous and nonferrous metallurgy at metallurgical treatment are involving more complicated and less qualitative ores. Magnetiting ores content considerable quantity of pyrite complicative the technology of iron extraction. At the same time the pyrite concentrates wining at dressing content different nonferrous metals in industrial quantities. Extracting ores of nonferrous metals are contenting considerable quantity of arsenic at the present time. Extraction of base metals from complicated raw materials demands new technologies. Arsenic contenting in ores is necessary to utilize (waste burial) in more ecological compatible form. Arsenic on acting metallurgical and chemical enterprises from technological cycle is withdrawing in the form of arsenate – arsenite cakes, burial of their may lead to seriously ecological problems as times goes by. In Kazakh National Technical University is carry out the cycle of researching by pyrite, arsenopyrite and arsenate – arsenite cakes treatment with the object of arsenic withdrawal in sulfide form – in more ecological and safe form and with the object of preparation of initial ore raw materials to following pyro- and hydrometallurgical treatment. As a result of sulfidizing of arsenate – arsenite cakes by pyrite are forming the volatile arsenic forms and pyrrhotite of variable structure."

Jan 1, 2008

By A. Bauer

This paper describes the trends in recent years in explosives formulated to produce larger blast-hole spacings and over-all lower drilling and blasting costs in hard formations. A consideration of current rotary drilling costs per ft of hole and per ton of muck versus hole diameter indicates that it is now possible that we shall see much further use of lower-energy-content, lower-cost slurries and dry mixes, and larger-diameter and, in many instances, cheaper blast holes. These will be drilled on current or slightly larger blast patterns to yield the same energy input per ton of rock and similar fragmentation at lower costs.

Jan 1, 1968

By A. M. Gaudin

A GREAT number of hypotheses has been advanced to explain the complex phenomena that are encountered in flotation. In the days of bulk-oil flotation, when a large quantity of oil was employed, it was observed that the oil-mineral aggregate floated above the ore-pulp because of its lesser density. With the advent of froth-flotation this phase of the theory had to be modified to take into account the presence of air bubbles. The reason why the mineral-bearing froth of today rises to the top of flotation cells is, of course, because the air-mineral aggregate, with whatever reagent may be associated with it, is lighter than the pulp. In an attempt to explain froth-flotation the fact has been emphasized that certain minerals are wetted and therefore remain in water; while others are not wetted and therefore become associated in preference with air. Such an "explanation" does not explain facts, it merely states them; for instance, it does not explain why minerals are wetted under some circumstances and not wetted under others. Going somewhat further, the wetting or nonwetting of minerals by water has been ascribed' to differences in the angles of contact between oil droplets and mineral surface at the surface of the minerals. This explanation, however, was abandoned when soluble flotation reagents came to replace the so-called "insoluble" reagents. Another theory, sponsored about 10 years ago by Ralston,2 involves the effects of electric charges at the surface of the minerals particles and air bubbles. This theory, unfortunately, was not developed as fully as it seems desirable.

Jan 1, 1927

By Smith N. S, Rholl S. A, Otterness R. E

The Bureau of Mines is conducting research to develop blast designs for the control of fragmentation and rock displacement and the reduction of overall mining costs. This Bureau experiment, a program of 25 reduced-scale blasts conducted at the University of Missouri-Rolla's experimental quarry, determined the effects on fragmentation of changes in burden, spacing, explosive diameter, and stemming-explosive length. Combined with previous work at this experimental quarry examining air gap, delay, and decoupling effects, this experiment provided a data base of over 50 shots. The fragmented rock, 1000 to 3000 kg from each 3- to 4-hole blast in the 1 m bench of massive dolomite, was completely screened to assess fragmentation. The explosive used for all the tests was extra dynamite initiated by seismic caps fired from a sequential blasting machine with delays of 5.2- to 13-ms/m of burden. Empirical equations were developed which predicted the effect of shot design parameters on the fragmentation. These formulas predicted the average fragment size of each of the 25-shots to within 13 percent. For spacing to burden ratios of 1, 1.4 and 2, there were optimum burden to explosive diameter ratios (B/de) of 30, 26 and 20, respectively. Decreasing the B/d. ratio beyond these levels resulted in little or no reduction in the average size. For B/de ratios above these levels the average size increased but, at least a 15 percent reduction in the average size results when the shot design parameters are optimized.

Jan 1, 1990

By O. C. Blade

This report on the properties of aviation gasolines and aviation jet fuels produced in the United States during 1953 was made under a co-operative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. Analytical data are presented for 101 samples of aviation gasoline which include, for the second time in this series of reports, data on some samples of grade 108/135 aviation fuel. Data also are given for 32 samples of aviation jet fuel. The analyses were made on samples typical of the manufacturers' production in their laboratories and the results sub-mitted to the Bureau of Mines for compilation. The products of 19 manufacturers of aviation gasolines and of 19 producers of aviation jet fuels are represented.

Jan 1, 1954

By William G. Pariseau

There are important phenomena in rock and soil mechanics that cannot be explained in terms of theories of homogeneous, isotropic materials. Subsidence of strata about mine openings is an example. In-situ stress measurements in nonisotropic sedimentary and metamorphic rocks is another. Patterns of joints, faults, fractures, and similar geologic features impart directional mechanical properties to rock masses that are locally isotropic or anisotropic. On the geologic scale, the nonhomogeneity of composite rock masses may, in certain instances, be dealt with as homogeneous anisotropy. The mechanics of large rock masses can, therefore, be expected to involve considerations of anisotropy. The source of the anisotropy is not relevant. Once the scale of observation is selected and the material is defined accordingly, the analysis of stress and deformation proceeds without regard to the numerical values of the material constants. There are also important phenomena in rock and soil mechanics that cannot be explained in terms of linear elasticity, theory. For the mechanical description of anisotropic geologic materials capable of deforming beyond the limit of purely elastic strains, a plasticity theory is required. The purpose of this chapter is to present a plasticity theory for anisotropic rocks and soils. The proposed theory is based on the work of Hill in anisotropic metal plasticity and represents an extension of his work so as to include anisotropic geologic materials. The point of departure from metal plasticity theory begins with the inclusion of the normal stresses as linear terms in the yield condition, which plays a central role in plasticity. Once the yield condition is established, the plastic strain increments are obtained immediately through the principle of normality. For practical applications, some simplification of the three-dimensional theory is re-

Jan 1, 1972

By Manuel Gomez

Low-temperature carbonization product yields for 129 coals representative of 12 Utah coalfields were estimated, using regression equations developed from heating value and proximate and ultimate analysis data. It was shown that yields of char, tar plus light oil, water of decomposition, and gas, as well as the gas volume and the heating value of the gas, could be predicted with reasonable accuracy. Published and experimental results from eight Utah coals carbonized at selected temperatures in the 4500 to 1,000° C range were used to determine the effect of temperature on product yields. Carbonization temperature, heating value) oxygen, and volatile matter of coal appear to be the principal variables influencing carbonization product yields. Data presented show that the heating value and the residual volatile matter in low-temperature char may be predicted using relationships developed from proximate analysis data for 220 coals.

Jan 1, 1967