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Gunpowder Copper Limited processes 1,000 tonne/day of Mammoth ore in a conventional flot- ation concentrator. Run of mine ore is prepared for flotation by three stages of crushing and two stages of ball milling. The concentrate, in which the primary copper mineral is chalcocite, is solar dried and exported to Japan. The history of operation is summarised, and plant practice and metallurgical problems are discussed.

Jan 1, 1974

By Thomas M. Gurtowski

The New Pacific Northwest Baseball Park, now known as Safeco Field, is located directly south of the Kingdome in Seattle, Washington, and will be the new home of the Seattle Mariners baseball team. The location of the ball field is shown on Figure 1, Vicinity Map. The seating capacity is 45,600, and outfield distances are 331 feet in left, 405 feet in center, and 326 feet in right field. The overall dimensions of the stadium are 680 by 800 feet. It is bordered on the east by the Burlington Northern Santa Fe Railroad main line. A unique aspect of this ballpark is the retractable roof with a north-south span length of 660 feet. The roof consists of three separate sections that roll on elevated rails running east-west on the north and south sides of the stadium. The soil conditions consisted of near-surface fill underlain with alluvial and Estuarine deposits to depths of 60 to 80 feet. The bearing soils consisted of very dense, glacially overridden deposits. Groundwater is 4 to 7 feet below the ground surface, and the alluvial deposits are subject to liquefaction during a strong motion earthquake.

Jan 1, 1998

By L. Vela

Panoro es una empresa de exploraciones canadiense con un portafolio de 11 proyectos de Cu-Au de gran escala ubicados en la provincia del Batolito de Andahuaylas-Yauri, en Apurímac y Cusco. El proyecto Cotabambas es el más avanzado de ellos y consta de un sistema de pórfidos de Cu-Au (Ag, Mo), a veces emplazado en un ambiente netamente ígneo y volcánico (Cluster 1) y otras veces en el frente de calizas y areniscas del grupo Yura (Cluster 2) donde además se genera mineralización tipo Skarn. Los Clusters 1 y 2 presentan trabajos de mapeo, muestreo de rocas y geofísica, sin embargo, fuera de ellos existen otros 4 prospectos tipo skarn que requieren más estudios.

May 1, 2008

By Daryl E. Radcliffe, Raymond M. Stateham

The Bureau of Mines, under a Cooperative Agreement with the Bear Coal Company, Somerset, Colorado, conducted a large scale evaluation of the effect of time lapse on roof stability. Time lapse in this study is the interval between exposure and permanent support of the mine roof. The study indicates that time lapse is not a critical factor in roof stability provided permanent support is installed before catastrophic failure begins. Concurrently with the time lapse study, investigations were made of stress distribution around resin-grouted bolts, the regional stress field, and anomalous geologic conditions. The behavior of the resin-grouted bolts, at least in the Bear mine, appears to fit the Coulomb-Navier Theory. Geologic conditions are primary factors in trends of roof stability that extend across the mine.

Jan 1, 1982

By J. P. Evans

The modem copper smelter today utilizes tonnage oxygen for smelting concentrates, generating a high strength S02 off-gas leaving the smelter vessel. This gas stream, which also contains any unreacted oxygen, plus C02, N2 and H20, also carries with it the volatilized portion of heavy metals in the feed, plus partly oxidized sulfide concentrates. The time/temperature history and subsequent treatment of this off-gas stream emerging from the smelting furnace exit up to the acid plant can influence the partitioning and segregation of heavy metals in the off-gas circuit. Depending on this history, the type and characteristics of the chemical and physical reactions which. occur in the gas handling system can be influenced. This fact can also be used as a tool to adjust the separation of copper from heavy metals. In this paper, the impact of different time/temperature histories of the gas, due to different furnace geometries .and design, on the subsequent formation and characteristics of the smelter dust is examined. Based on the available data, several case histories drawn from examples using both bath and flash smelting technologies are analyzed from this perspective.

Jan 1, 1992

By C. G. Fink, G. L. Putnam

The dissolution of gold by cyanide solutions was studied by determining the time required for the solvents to dissolve gold leaf. Minute traces, even 0.5 ppm, of sulphide ion retard the dissolution of gold, and this behavior cannot be accounted for by the presently accepted hypotheses involving oxygen-depletion or thiocyanate formation. On the other hand, traces of the salts of lead, bismuth, mercury, and thallium considerably accelerate the dissolution. The beneficial effect of lead is dependent upon the pH and cyanide ion concentration of the solution. ALTHOUGH cyanide solvents are used very ex-x*. tensively for the recovery of gold from ores and concentrates, the normal rate of solution of the precious metal as determined by Barsky, Swainson, and Hedley,1 and others2 is less than about 3 mg per sq cm of exposed gold surface per hour, corresponding to a corrosion depth of approximately 1.5 microns (0.00006 in.) per hr. Although the slow rate may be increased to some extent in certain cases, as, for example, when the the gold is partially imbedded in iron pyrites,3 the leaching operation is generally the most time-consuming step of the cyanide process. Frequently it is necessary for the leaching solvents to remain in contact with the ores for 50 to 200 hr in order to dissolve all of the gold particles.' Not only does the slow solution rate cause some increase in the capital costs, but the cyanide consumption also may be increased because of vaporization of hydrocyanic acid and secondary reactions with minerals such as malachite (CuCO3 • Cu(OH)2), and pyrrhotite, which often are associated with gold. It is not surprising that numerous attempts have been made to accelerate the dissolution of gold in cyanide solutions. Experimental Gold Leaf Test: The gold leaf test was apparently originated by M. Faraday, who, by means of it, discovered that dilute cyanide solutions would dissolve gold readily in the presence of oxygen. The usefulness and reliability of the test have been discussed elsewhere.5,6 Essentially, the method consists of determining the time required for 5-ml portions of cyanide solvents to dissolve squares of 23 carat gold leaf, 0.5 cm on edge, when shaken in 10-ml test tubes with the solvents. The weight of gold leaf per test was 0.051 mg as determined by the direct weighing of a leaf 8.6x8.6 cm (weight = 15 mg) and measuring the area of the test sample (0.25 sq cm). Gold leaf is of remarkably uniform thickness.6 Since gold leaf, like native gold, contains small amounts of copper and silver, the results are comparable with those one might expect in cyaniding gold ores. As six or more tests can be made simul- taneously, the relative efficiencies of the solvents can be evaluated readily. All dilute solutions of lead, bismuth, thallium and mercury salts were prepared by the ordinary dilution method used by chemists. Our C.P. sodium cyanide and buffering reagents had no detectable amounts of either sulphide ion or heavy metals. Soluble Sulphides in the Cyanide Process: The action of soluble sulphides is of interest in the study of the dissolution of gold in cyanide solutions. That gold ores which contain compounds of arsenic and antimony often are not amenable to direct cyanide treatment is well known, and it said that arsenic and antimony are "cyanicides."7 It is commonly believed that part of the sulphur content of such ores is soluble in alkaline solutions to give sulphide ion, which reacts with the free cyanide content of the leaching solutions to form inert thio-cyanates or reacts with the dissolved oxygen to form sulphites or sulphates.8 A purpose of this paper is to demonstrate that sulphide ion may behave in a manner that cannot be explained by either the oxygen-depletion or thiocyanate formation theories and to prove directly that concentrations of sulphide ion which cannot be detected even by colorimetric methods may retard the dissolution of gold.

Jan 1, 1951

Since the introduction of water cooled test rings the operation of cupelling retort bullion has not alone been sImplified, but has also been the means of concentrating the bullion for the fining test in a much shorter time.The first water cooled test ring which I used was rectangular in shape, inside dimensions 5 ft. 3 in. x 2 ft. IQ in., and made of i in. mild steel plates, with a water space of 9i in. x 3t in. However, it was found that as soon as the filling commenced to wear and the litharge came in contact with the jacket, the plate was gradually affected on the lines of the wash, caused by the blast. After a while the inside steel plate went beyond the factor of safety, and was then substituted on the sides and the front of the test ring by a tin copper plate, which has stood now for the last five years without showing the least signs of wear or leakage.The test remains in use as long as the bottom is regarded as safe, and toward the end of the life of the test the litharge is allowed to work against the copper plate.

Jan 1, 1901

By T. K. Akopyan, E. A. Naumova, V. V. Doroshenko, N. A. Belov

"A qualitative and quantitative analysis of the new Al-Ca-Mn-Fe phase diagram in the region of the aluminium corner is carried out using both thermodynamic calculations and experimental methods. Using the obtained data, the principal possibility of creating both cast and wrought sparingly alloyed aluminium alloys with calcium, manganese, scandium and zirconium at allowable iron contents of up to 0.4% that do not require solution treatment and quenching is justified. At the selected concentrations, the entire amount of manganese (1%) is practically included in the aluminium matrix, while calcium (~2%) and iron are in the multiphase eutectic, which has a fine structure. The joint introduction of 0.25% Zr and 0.1% Sc into the alloy leads to precipitation hardening due to the formation of the L12-Al3(Zr,Sc) phase during annealing. Based on the experimental data for the model multicomponent Al2CaMnFeZrSc alloy, it is shown that such alloys can combine high mechanical properties and good manufacturability during both casting and metal forming. This is due to the combination of a narrow temperature range of solidification with a fine eutectic structure.INTRODUCTION Hardening in branded aluminium alloys (both cast and wrought) is generally achieved by heat treatment of the T6 type, including quenching and artificial aging (Zolotorevskiy, 2007; Kaufman, 2004; Mondolfo, 1976). Heat treatment significantly increases the cost of the final products. Therefore, industrial companies are interested in developing alloys that can be hardened to the desired level without quenching. To solve this problem, alloys with scandium are the most suitable (Toropova, 1998; RØyset, 2005). This element (usually in an amount of ~0.3%) is one of the most effective hardeners in aluminium alloys, due to the formation of Al3Sc (L12) phase secondary precipitates, the size of which is less than 10 nm (Knipling, 2010; Fuller, 2005). These nanoparticles are formed during the annealing via decomposition of the supersaturated aluminium solid solution (hereinafter referred to as (Al)). This feature allows us to significantly increase the strength of aluminium alloys by simple annealing (at ~300°C), i.e., without heat treatment, including quenching. However, scandium is a very expensive metal, so its use as an additive is severely limited. The most effective method is the introduction of scandium together with zirconium (Lefebvre, 2009; Booth-Morrison, 2012). The optimal combination is the introduction of ~0.1% Sc together with 0.20–0.25% Zr, which, according to (Belov, 2006), gives approximately the same strengthening effect as the introduction of 0.3% Sc."

Jan 1, 2018

By D. B. Stephens

Milling operations throughout the world have created vast amounts of waste by-products, or tailings, which are often disposed on the land surface. The wastes may be disposed behind dams, on untreated ground, or on compacted clay or synthetic liners of impoundments and trenches. Often one of the principle concerns of environmental regulatory agencies is whether seepage from the waste pile could move through the vadose zone to the water table and possibly contaminate an aquifer. The seepage may be generated by the drainage of liquids initially deposited along with the tailings or by infiltrating meteoric water which leaches solutes from the tailings. The purpose of this article is to discuss some of the commonly held assumptions regarding storage of seepage wastes in the unsaturated zone. The significance of recent studies of water movement in dry climates which pertain to tailings site selection will be presented. The paper is relevant not only to seepage from impoundments at mill sites, but to many other fluid waste impoundments as well in part this article reinforces earlier work by Stephens and Siegel (1980) and an excellent review paper by McWhorter (1985). The present report addresses considerations in porous media; for a discussion of the effects of fractures and anisotropy in the unsaturated-zone, refer to the paper by McWhorter (1985).

Jan 1, 1985

By M. F. He

There are three polymorphic modifications in pyrrhotite (monoclinic, hexagonal and orthorhombic), with monoclinic and hexagonal polymorph being more abundant. The floatability of different crystalline structures of pyrrhotite (monoclinic and hexagonal) is studied in this paper. It is shown that the floatability difference of monoclinic and hexagonal is obvious and that the flotation recovery of monoclinic pyrrhotite is greater than that of hexagonal pyrrhotite using different collectors . Using butyl dithiophosphate as collector, the flotation recovery of pyrrhotite is higher than when sodium diethyl dithiocarbamate and sodium butyl xanthate are used as the collectors. Monoclinic and hexagonal pyrrhotites are more easily activated by Cu2+ in acidic conditions than in alkaline conditions, while Cu2+ can not activate hexagonal pyrrhotite when sodium diethyldithiocarbamate was used as the collector. By the measurement of contact angle, it is indicated that monoclinic and hex-agonal pyrrhotite float well and are easily activated by Cu2+when dithiophosphate was used as the collector. Using sodium diethyl dithiocarbamate as a collector, the flotation behavior of pyrrhotite was investigated. The relationship between potential and pH range for pyrrhotite flotation was established. The results show that the flotation of pyrrhotite is dependent on pulp potential at certain pH values.

Jan 1, 2014

By P. N. Worsey, M. Schmidt

Many advanced military systems and civilian power generation concepts postulate the availability of compact sources of electrical power capable of delivering gigawatts over microsecond time scales. For example, such a compact power source is essential for future practical pulsed high-powered microwave sources. An explosive-driven flux-compression power generator (EDPG) could fill this requirement. A basic strength of this concept capitalizes on the inherent high energy density storage capacity of modern chemical explosives. It relies on the physics of magnetic flux compression to convert that stored chemical energy into very large amounts of electrical power over short time scales. The generator also has the additional advantage of employing the same types of explosives that are already routinely used in conventional munitions. However, the self-destructive nature of this type of power generator places serious limitations on power pulse-lengths and ranges of applications. This paper describes how a multi-disciplinary team led by researchers from the University of Missouri-Rolla (UMR), Texas Tech University (TTU), and Texas A&M University was awarded a grant by the U.S. Air Force Office of Scientific Research to perform basic research to resolve several fundamental EDPG problem areas. Described are the utilization of UMR’s extensive explosives research expertise and facilities to investigate questions of energy conversion efficiency and the mechanics of energy production. Also, UMR explosives researchers will provide inputs to improved dynamic computer models of the complex, intertwined physics and chemistry operative in these devices. In addition to explosives expertise, UMR provides facilities for basic explosives material research, as well as the storage, machining, and formulation of explosives. UMR researchers are also using test facilities and data collection equipment at the Rock Mechanics and Explosives Research Center and at the UMR Experimental Mine to perform “proof of principle” and subscale tests of explosive-driven flux-compression power generator components. An integral part of the paper is a description of the development of an extreme intensity flash system by UMR and TTU to allow for the high-speed photography of EDPGs in operation. This multi disciplinary research program offers major advances regarding the size, weight, and electrical characteristics of compact EPDGs. Such breakthroughs could dramatically accelerate the practical realization of systems currently under study. Also, these power sources may have far reaching relevance to other Department of Defense and certain commercial compact power applications.

Jan 1, 2000

By Walter E. Duncan

The ores treated at the concentrating plant of the Mahoning Mining Co. at Rosiclare, III., come largely from the blanket replacement deposits of the northeastern part of Hardin County, Illinois, and consist of complex mixtures of galena, sphalerite and fluorspar in a gangue of quartz, limestone and sandstone. The several minerals are so intimately inter-grown that they are not liberated at the sizes usually treated by gravity concentration in the usual fluorspar plant. For this reason, an all-flotation method of concentration was developed in cooperation with the station of the U. S. Bureau of Mines at Rolla, Mo.1 This flotation separation made possible the commercial production of four concentrates: (I) lead, (2) zinc, (3) acid-grade fluorspar and (4) metallurgical-grade fluorspar.2,3 Although fluorspar had been floated in Canada in 1921 and a plant at Rosiclare had been floating fluorspar since March 1929, fluorspar flotation was given considerable impetus by the Mahoning developments, since some features of the separation were quickly adopted by other fluorspar companies. The Bureau of Mines6 reports that in the 10 years preceding 1938 only 50,552 tons of fluorspar flotation concentrates were produced in the United States. The rise from this almost nominal figure to 153,750 tons (largely acid grade) in one year (1944)6 is indicative of the activity in fluorspar flotation occasioned by the war. The industry thus proved to be in a position to expand and keep up reasonably well with the requirements imposed upon it by such developments as occurred in high octane aviation gasoline alkylation, in the use of Freon as a refrigerant and as carrier in the Aerosol "bug bomb," and in the atomic bomb project as well as in the expansion of other activities requiring hydrofluoric acid; for example, the aluminum industry. Despite the fact that the greater portion of acid-grade fluorspar produced in the last few years went directly into war uses, the future of the acid-grade field still appears bright. As a result of the activity in fluorine chemistry during the war, it seems likely that in the relatively near future almost every phase of human endeavor will find some fluorine compound involved. The other three concentrates produced deserve some attention in these introductory remarks. The lead concentrates first produced contained both zinc and fluorspar but these did not interfere with their marketing. As will be pointed out later, the quality has steadily improved until today it is a relatively high-grade product. Although some zinc smelters accept concentrates containing limited quantities of fluorspar, it is a very objectionable impurity. Since flotation methods fail in the complete removal of the fluorspar, chemical methods were developed for

Jan 1, 1947

To reduce needless paging of persons by all phones in a mine or mill, while retaining all-location page capability. Approach Standard pager phones of any manufacturer are modified to include the option of selective calling and message holding. How It Works All commercial mine pager phones presently rely upon voice paging via a loud-speaker. When a page is initiated, every phone in the system broadcasts the audible voice page, even phones in locations where the desired person could not possibly be. The advantage of this scheme is that whole-mine paging occurs. The disadvantage is that persons soon begin ignoring pages because they occur all the time, and most are for someone else. Also, it requires considerable battery power from all phones making it necessary to change batteries very frequently, even in phone locations where personnel rarely go. In addition, if a voice page is made and not heard, there Is no way to leave the message. Therefore, persons who at a later time come near a phone, have no way of knowing a page was made and was not acknowledged. This results in situations that often have a direct bearing on safety and productivity.

Jan 1, 1980

Jan 1, 1938

By J. H. Slater

THERE is nothing particularly new about the use of sinter in a blast-furnace burden. For many years flue dust has been sintered at the various blast-furnace plants to put it in a form that could be recharged to the furnace with some assurance that it would stay in the second time. This paper is not a compilation of scientific data but only an attempt to give our experience with sinter. There are some unexplained discrepancies in the tests given here, such as the flue dust produced and iron tonnages, but the results given are the results that were obtained. Sinter is not the cure-all for blast-furnace problems. A good coke is still the most important factor in good furnace operation. However, good sinter is a big help. As flue dust is produced under varying operating conditions and fluctuates greatly in carbon content, it is difficult to produce from flue dust alone a uniform sinter, which will give satisfactory blast-furnace results. Sinter made from flue dust alone will change in character with every carbon variation. Almost invariably flue dust con-tains carbon in excess of the amount necessary to make good sinter, and this excess must be burned out, This, of course, necessitates reduction of the speed of the sintering machine and thus a decrease in tonnage, An alternative is to dilute with a carbon-free material to use up the excess carbon. High-carbon material when sintered results in a very dense, undesirable prod-uct, since the excess heat melts the charge into a hard, nonporous mass, and tends to form refractory silicates.

Jan 1, 1940

By P. Bevilacqua, G. Ferrara

Hydrocyclones and other dynamic separators are normally fed with pulps consisting of water and solid particles. The solids usually consist of particles of different sizes, shapes and densities. Except in the special case of monocharacteristic particles, the particles are segregated by these differences in size, shape and density. Segregation is magnified by the high values of centrifugal acceleration in the hydrocyclones. This paper develops a segregation theory that indicates the major variables involved. Experimental data on segregation under different operating conditions for mixtures of magnetite and/or ferrosilicon and nonmagnetic minerals are reported.

Jan 1, 1997

By M. A. Kessick

Current treatment and disposal procedures are compared for clay slimes resulting from the extraction of Alberta oil sands, the extraction of Florida phosphate matrix, the recovery of diamonds from kimberlite deposits in South Africa, the recovery of kaolin from clay deposits in southwest England and the upgrading of bauxite ore. Published research in the area is reviewed, and common trends which are emerging in the disposal of clay slimes are discussed.

Jan 1, 1978

By Frank G. Horino

A rock mechanics program (composed of laboratory and field tests) was initiated by the Bureau of Mines in an effort to determine the causes of pillar instability at the Fletcher mine, near Bunker, Mo. Compressive strength, Young's modulus, shear strength, and the angle and coefficient of internal friction were determined on drill cores obtained from 16 different locations in the mine. Results of the laboratory tests showed that highly mineralized zones and brecciated zones in pillars could significantly affect pillar strengths and stability in locations where extraction ratios exceeded the normal design ratio of approximately 78%. High-angle fractures that were present in Some locations also may have contributed to pillar deterioration. In the field tests, in situ stress determinations were made in one pillar to establish the pillar-loading conditions and to evaluate the stability of the pillar. Continued monitoring of stresses in the pillar showed a gradual decrease in compressive stress, indicating that the pillar was probably in the postfailure state. A second stress determination was made in a vertical hole in the underlying igneous rock that was exposed on one section of the mine. Horizontal stresses were compressive and larger than would be expected from gravity loading.

Jan 1, 1978

By M D. Melville, B C. T Macdonald, J Dixon

The acidic and metal rich waters that are generated from acid sulfate soil (ASS) drainage can have damaging impacts upon ecosystems. The most obvious impact has been the discolouration of water and occasional fish kills. ASSÆs produce these acidic and metal rich waters when pyrite in soil is oxidised. Land management techniques are an essential long-term requirement to minimise the amount of pyrite oxidation. Acidic water that cannot be prevented through land management can be neutralised by other techniques. Powdered lime is the most common material in agriculture that is applied directly to soils and waters. Powdered lime can be expensive and if applied dry it may aggregate. Since the aggregated particles of lime are larger they could sink rapidly in the water column and not react. In waters with high concentrations of dissolved iron and aluminium the lime particles may become coated with a metal oxy-hydroxide precipitate, which will decrease its reactivity. A unique lime-dispensing machine, the Waterways Lime Spreader, has been developed to neutralise acidic waterways. The Waterways Lime Spreader can produce a solution rich in fine lime from larger limestone fragments. The current size of the machine means only 3.5 grams per second of limestone can be emitted. This output will neutralise low acidity waters, however, for high acidity waters the time for neutralisation can be long. More reactive chemicals such as hydrated lime or increasing the size of the machine will reduce this neutralisation time. The Waterways Lime Spreader is also capable of producing slurry mixtures if powdered materials are required. Trials with the Waterways Lime Spreader were undertaken in part of the Clothiers Creek catchment located in northeast NSW, Australia. A small drain with a water volume of 4 m3 was neutralised with crushed limestone to pH 6.9 from an initial pH of 2.6 and an acidity of 902 mg/L CaCO3 in 160 minutes. In comparison a drain with a slightly larger volume of 6 m3 that had an initial pH of 3.2 and an acidity of 753 mg/L CaCO3 was neutralised with hydrated lime to pH 11.8 in five minutes. The Waterways Lime Spreader has been used successfully to neutralise water from acid sulfate soils. It is expected that future applications of the machine may be for the neutralisation of acid rock drainage or acidified lakes.

Jan 1, 2003

By D. P. Wilkinson

There are significant global environmental and supply issues with existing energy paths today . Global emission and fuel regulations, global fuel and power structure, energy security, and cost are driving new technology and non-conventional approaches . Fuel cells will play a significant role in the strategy to effect positive global change, increase fuel efficiency and decrease dependency on traditional fossil fuels. Fuel cells do not require recharging, just refuelling and a wide range of fuels are possible with hydrogen being the most desirable. Technical progress as well as investments in fuel cells for transportation, stationary, portable, and micro fuel cell applications have been dramatic in recent years. The present view is very optimistic for fuel cell power generation and the status is presently at the field trial level, or early commercialization stage, moving into volume commercialization. A number of demonstration programs are in progress worldwide such as the California Fuel Cell Partnership which involves original equipment manufacturers (OEMs), fuel providers, transit authorities, state and government bodies. Fuel cells and a hydrogen infrastructure are key to a long-term solution to global energy issues. Fuel cells will need to be competitive on an economic basis with the established and highly developed internal combustion engine and other forms of power generation There has been significant technical progress in a number of fuel cell areas including power density, transient / dynamic response, multiple fuels, cost potential, reliability and durability. However, significant technology gaps still remain today. This presentation will focus on the status and progress of the fuel cell today, current fuel cell research and development, the challenges going forward, and the future view of the fuel cell and it's impact on global energy issues.

Jan 1, 2005