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By James R. Myers

A source of clean gas containing sulfur dioxide and sufficient oxygen for convers.ion to sulfur trioxide ?is essential to the production of sulfuric acid. S02 containing gases obtained from roasting sulfide ores are heavily contaminated with inorganic dust and volatile impurities. If not removed, these contaminants will reduce product acid quality, foul the catalyst beds and mist eliminators, and accelerate equipment corrosion. This paper reviews conventional gas cleaning systems for metallurgical acid plants, followed by a discussion of modern systems utilizing DynaWave Scrubber technology. This technology is based on a unique approach to? gas scrubbing that can concurrently accomplish several gas cleaning/processing tasks scrubbing liquid is injected into the gas stream to create. a "Froth Zone". This is a region of extreme turbulence, with a very high rate of liquid .surface renewal. It efficiently removes both particulate matter and gas contaminants, and is also a cost effective quenching device for gases as hot as 1250º C. Smelter

Jan 1, 1992

By A. C. Fieldner

THE older coal chemist had a much simpler conception of coal than we have today. To him coal was a mineral composed essentially of carbon, hydrogen, oxygen, nitrogen, sulfur, ash, and water, in various proportions. His studies on the constitution of coal were directed along the conventional lines of proximate and ultimate chemical analyses and making deductions from these data without any real appreciation of the fact that coal is a conglomerate of various chemical compounds, including many of the most complex structures known to organic chemistry. The view of the modern coal chemist is well expressed by Franz Fischer, I who says that while proximate and ultimate analyses are important both from the scientific and technical point of view, they tell the chemist no more concerning the number and kinds of chemical compounds that constitute coal than the reader would learn of the contents of a book if told that the printed contents consisted of 15 per cent. of the letter "e," 5 per cent. of the letter "n," 1 per cent. of the letter "g," 4 per cent. of the letter "b," etc. As the reader must have the grouping of letters into words and words into sentences, so the chemist must have the grouping of atoms into molecules and the proportion of each molecular compound in the coal aggregate before he acquires an adequate knowledge of the constitution of coal. Modern investigators2 are laying the foundation of a new chemistry of coal based on the biochemistry of plants and the chemical changes involved in processes of fermentation and decay. As

Jan 5, 1925

By Henry B. Estabrooks

As was the case with many other mining companies, the management of Tennessee Copper Company' viewed with some interest reports in various trade and technical journals of the successful use of ammonium nitrate-fuel oil mixtures as an explosive in coal stripping., construction, open pit mining and finally in underground salt mines. The apparently simple transition from the "interested" stage to a point where in excess of 80% of the ex¬plosives used is ammonium nitrate may be of interest. The Tennessee Copper Company operates five mines in the "Copper Basin" of Polk County which lies on the extreme southeast corner of Tennessee. The ore is a massive sulfide principally pyrrhotite and pyrite with some tough lime silicates as gangue while the walls are greywacke interbedded with schist. Average total production is 28,000 tons per 5-day week and an average of 422 feet of development per week. Development work consists of 8'x 8?, 6?x 7?, 5'x 7? and 4'x 6? drifts driven with drifter drills using 1-5/8" carbide detachable bits and 5'x 5' raises driven with stopers using 1-5/8" bits.

Jan 1, 1962

The Boleo project is located in Mexico close to the town of Santa Rosalia on the Baja Peninsula. The Boleo deposit contains copper, cobalt, zinc and manganese values as oxides with minor sulfides. The Boleo deposit is metallurgically challenging due to: 1) the requirement to recover four separate metals; 2) the presence of high levels of clay in the deposit resulting in difficult solid-liquid separations, and; 3) the need to use seawater for the bulk of the processing. Baja Mining, Bateman Engineering and SGS Lakefield Research have collaborated to develop and test a process flowsheet to recover copper, cobalt, zinc and manganese products at Boleo. The key steps in the flowsheet are: ? Feed preparation (scrubbing and ball milling of oversize) in copper raffinate ? Ore leaching using oxidative and reductive leaching ? CCD washing using high rate thickening technology ? Copper SXlEW ? Treatment of a bleed solution for cobalt, zinc and manganese recovery The process for cobalt, zinc and manganese recovery involves iron and aluminum removal followed by cobalt/zinc bulk extraction using CSIRO's DSX solvent extraction system and selective zinc and cobalt stripping. The zinc strip solution is evaporated to produce zinc sulfate monohydrate crystals to market and cobalt is recovered via a further SXlEW process as high purity metal. Manganese is precipitated as manganese carbonate from the DSX raffinate solution. This paper will review the Boleo process flowsheet and provide detailed results from the 2006 pilot plant operation conducted at SGS Lakefield in Canada.

Jan 1, 2007

By Fredy Gutiérrez, Nilton Apaza

En el año 2012, a causa de la situación inestable de la operación y por contar con una visión no muy proyectada al crecimiento organizacional, Raura se encontraba inmersa en una situación económica muy crítica y a punto de declarar su cierre. Por ese motivo, se replantea la visión estratégica de la operación y se alinea a la filosofía de la excelencia operacional por etapas. La principal apuesta de Raura es ser considerada una empresa de clase mundial, para lo cual, bajo un nuevo enfoque de gestión, en los últimos 5 años se implementaron diversas decisiones estratégicas que tuvieron impactos positivos. Así, se logró ser una de las operaciones más rentables de la división minera del grupo Breca.

Sep 20, 2019

By N. N. Moelbs

The U.S. Bureau of Mines is conducting research on many topics relating to the hazards of coal mining, increased production, and protection of the environment. One area of research that has received scant attention in recent years is that of water inflows, probably because few fatalities in the United States have been attributed to them. As mining goes deeper, the problem of water in 1ow could increase dramatically because of adjacent or overlying mines in which huge water pools are impounded. Inaccurate mine maps and ineffective barriers can constitute a serious problem for operators both from gradual inflows and sudden inrushes of water. This report describes a wide but ineffective barrier that permitted an average 240-gpm inflow to a developing mine from an adjacent mine. The anomalous geologic structure that facilitated this leakage is described, demonstrating that size, alone, is no assurance against serious leakage. Some recommendations for managing serious water inflow are included.

Jan 1, 1989

By Q. Han

A modified cast-on method has been developed to reinforce aluminum castings with steel insert. Defect-free bond between the steel insert and the aluminum casting has been consistently obtained. Data obtained from a push-out experiment indicated that the bond strength was much higher than that obtained using the Al-Fin approach. This paper introduces this modified method in four sections: the coating of the steel pins, the cast-in method, microstructure characterization, and the bond strength. The section on the coating of the steel pins contains coating material selection, electro-plating technique for plating Cu and Ni on steel, and diffusion bonding of the coatings to the steel. The section on cast-in method deals with factors that affecting the quality of the metallurgical bond between the coated steel and the aluminum castings. The results of microstructure characteristics of the bonding are presented in the microstructure characterization section. A push-out experiment and the results obtained using this method is described in the section of bond strength/mechanical property.

Jan 1, 2015

By A. Kar

A mathematical model is presented for pure titaqium deposition from titanium tetrabromide on a stainless-steel (SS 304) substrate. Five three-dimensional, transient, and nonlinear partial differential equations are used to account for the diffusion of various species inside the deposition chamber and the thermal decomposition of titanium tetrabromide, titanium dibromide, and titanium monobromide at the surface of the substrate in order to determine the thickness of the titanium film deposited on the substrate. The effects of various process parameters on the deposition and shape of titanium films are examined, and under certain conditions, the deposited titanium films are found to have volcanic profiles.

Jan 1, 1992

By H. Y. Sohn

The purpose of this article is to analyze critically and quantitatively the effect of chemical equilibrium on the overall rates of fluid-solid reactions. It is shown through a mathematical analysis that a reaction with a small equilibrium constant (a positive standard free energy of reaction) is more likely to be rate-controlled by pore diffusion or mass transfer than a reaction with a large equilibrium constant. The overall reaction rate of the former also tends to be slow. Furthermore, the apparent activation energy of such a reaction approaches the standard enthalpy of reaction (M-f'), rather than the true activation energy of the chemical reaction. The Law of Additive Reaction Times developed by the author is shown to apply to equilibrium-limited fluid-solid reactions and to be useful in quantitatively analyzing the behavior of such reactions.

Jan 1, 2003

By K. Sanjay

Factorial optimisation technique has been used to develop regression equations at different time intervals for extraction of manganese from precipitated manganese oxide/hydroxide in sulphuric acid using charcoal as the reductant. The three parameters chosen for a 23 full factorial design were : acid concentration, amount of carbon and temperature. The regression equations were used to predict >> 90% extractions as well as kinetic data.

Jan 1, 1996

By W. R. Reed, J. P. Rider

"The National Institute for Occupational Safety and Health (NIOSH) Office of Mine Safety and Health Research (OMSHR) has recently developed a series of models utilizing computational fluid dynamics (CFD) to study airflows and respirable dust distribution associated with a medium-sized surface blasthole drill shroud with a dry dust collector system. CFD models were constructed in ANSYS FLUENT Version 15. Previously run experiments conducted in the NIOSH full-scale drill shroud laboratory were utilized to validate the models. The setup values in CFD models were calculated using experimental data obtained from the drill shroud laboratory and measurements of test material particle size. Subsequent simulation results were compared with the experimental data for test scenarios, including 0.14 m3/s (300 cfm) bailing airflow with 2:1, 3:1, and 4:1 dust collector-to-bailing airflow ratios and 0.24 m3/s (500 cfm) bailing airflow cases with 2:1, 3:1 and 4:1 dust collector-to-bailing airflow ratios. For the 2:1 and 3:1 ratios, results showed the calculated dust concentrations from the CFD models were within the 95% confidence intervals of the lab experimental dust concentrations. This paper describes the methodology used to develop the CFD models, to calculate the model dust input, and to validate the models based on experimental data. Problem regions were identified and revealed by the simulation of a dry dust collector system. The simulation results could be used for future development of dust control methods for a surface mine blasthole drill shroud. INTRODUCTION In surface mines, production drilling is an essential process in blasting which fractures the hard rock overburden for removal. Holes with a predetermined pattern, diameter, and depth are drilled into the overburden to introduce explosives. During the drilling process, considerable amounts of respirable dust are produced. Past research conducting area sampling at blasthole drills has documented time-weighted average respirable dust concentrations ranging from 8.68 to 95.15 mg/m3 [1] and 1.04 to 52.30 mg/m3 [2]. These high dust concentrations, which may contain silica, can lead to respirable dust over-exposures for the drill operator, drill helper, and other personnel in the vicinity. These over-exposures can lead to silicosis, an occupational lung disease that has no cure and is ultimately fatal. In order to prevent the development of silicosis to mine workers, the Mine Safety and Health Administration (MSHA) regulates the exposure to respirable dust. For metal/nonmetal (M/NM) mines, MSHA has adopted the threshold limit values recommended in 1973 by the American Conference of Governmental Industrial Hygienists (ACGIH) [3]. The total airborne dust standard is 10 mg/m3. However, if the sample contains greater than 1 percent quartz (the most common form of crystalline silica), a respirable dust standard is calculated with the following equation: Respirable dust standard = (10 mg/m3) / (% respirable quartz + 2)"

Jan 1, 2016

By H. R. Oliveira, C. R. Aragonez de Vasconcellos

Pipeline operation and maintenance necessarily involves geotechnical studies at points and areas with deflagrated instabilities or still to map and monitor areas prone to geotechnical problems. Landslides, erosions and debris flows are some examples of natural hazards, that not rarely, can bring high consequences to pipelines, sometimes leading them to high stresses levels and ruptures. Bolivia-Brazil Natural Gas Pipeline has 2.593 kilometers since Rio Grande City in Bolivia until Canoas City, in south Brazil. The pipeline crosses a lot of types of geological fields and difficult topography. The south spread of the pipeline has the most prone areas to geotechnical hazards because of its hard topography combined with the variety of geological materials, such as, colluvium deposits and debris flow areas. The aim of this paper is to present the right-of-way geotechnical risks that affect pipelines, presenting some practical remedial works done by TBG at Bolivia-Brazil Natural Gas Pipeline as well as the integrity plan and the adopted actions in way to prevent geotechnical accidents.

Jan 1, 2005

By S. Chander

The formation of surface films on pyrite has been studied through electrochemical techniques of cyclic voltametry and AC impedance measurements. The characteristics of the surface films depend upon the conditions of oxidation and the source of pyrite. At potentials near 0.0 V, some pyrites have large values of polarization resistance showing a certain degree of passivity. Some pyrites show more passivation than the others, however. On oxidation, metastable phases of Fe(OH2) and Fe(OH3) form which transform to more stable 3 phases on aging. The growth of surface films near the corrosion potential of pyrite follows a linear kinetics which is attributed to a chemical (or an electrochemical) reaction as the rate determining step. The surface film is considered to be a hydroxide or an oxide rather than sulfur because the later is expected to be limited to a monolayer in alkaline solutions. This study has also demonstrated that AC impedance measurements can be used to study the growth characteristics of films at mineral/ solution interfaces.

Jan 1, 1987

By A. H. Glenn, J. E. Graham

Oil operators engaged in drilling on the Continental Shelf of Louisiana and Texas are in agreement that adverse weather and wave action are two of the greatest hazards to the safety and efficiency of their work. It was ami-pated when the offshore operations commenced that such would be the case, and experience to date has verified this assumption. Because atmospheric conditions and wave action involve tremendous amounts of energy it is highly unlikely that it will be possible to control any but the most localized weather and wave phenomena within the foreseeable future. Thus. as long as the offshore operations involve the movement of small craft and barges over exposed waters, and the transfer of personnel and heavy equipment from these craft to either fixed structures or larger craft at close quarters, the weather and wave problem will remain. Taking into consideration the persistence of the wave and weather problem and the improbability of achieving a direct solution, the Humble Oil & Refining Company, in planning its offshore campaign investigated the possibility of forecasting wave and weather conditions in order to provide warnings of dangerous conditions and increase efficiency in day-to-day planning of work. It was recognized that predictions of wave and weather conditions based on meteorology and oceanography, both geophysical sciences, are not 100 per cent accurate and application of forecasts in the offshore work was dependent on whether they provided information which was sufficiently greater in accuracy than the layman's guess to be worth the expenditure involved. During World War 11. meteorology and oceanography were used with success in reducing danger resulting from environmental conditions and increasing efficiency of operations exposed to the elements. This success was partially the result. of improvement in the scientific techniques involved and the procurement and distribution of observational data, and partially due to the large scope of the military operations which meant that a reduction of losses of a relatively small percentage of the total cost amounted to a large figure expressed in terms of dollars. Since the offshore drilling involves an extremely large financial investment, it was considered that the experience of the Armed Services in successfully employing meteorology and oceanography might be duplicated in the oil industry. In addition. the oil industry's successful experience in utilizing seismology, geology, and terrestrial magnetism; all geophysical sciences, indicated that meteorology and oceanography, also of the family of geophysical sciences and sharing their scientific assets and liabilities, might be profitably put to use. Since the immediate problem involving the sciences of meteorology and oceanography in the offshore campaign is wave action, a program was inaugurated within the Humble Oil & Refining Company during June 1947. the purpose of which was to ascertain the applicability and limitations of wave forecasting in the offshore campaign. A summary of the effective wave forecasting techniques developed during the war was prepared in the form of a forecasting manual for the Continental Shelf off Grand Isle, Louisiana, by Bates and Glenn. After completion of this manual, experimental forecasts were prepared daily over a two-month period by Graham and Thompson to determine the accuracy of the forecasts. It was considered that the accuracy of the experimental forecasts justified a more extensive test under actual operating conditions in the offshore work and the firm of A. H. Glenn and Associates was set up under the sponsorship of the Humble Oil & Refining Company to work with the Humble Grand Isle District in providing forecasts of wave and weather conditions over a one-year period. This paper discusses the service now provided to the Grand Isle District, its applicability and limitations. TYPE OF FORECASTS REQUIRED It was apparent before the commence-mence of the forecasting service that a specialized type of forecast was required. Many of the weather elements of interest to the general public, such as rain and temperature, are of minor concern to offshore operators. On the other hand, such elements as wave height and wind speed and direction are of great concern in the offshore operations since variations in wave height of a few feet in the critical range divide safe from hazardous working conditions. To be of utility. a forecasting service for the offshore work must provide detailed forecasts of the elements which affect the operation. With this in mind, it was decided that forecasts would include the following information: average wave heights to the nearest foot, wind speeds within a range of approximately 5 miles per hour, and wind directions within 221 degrees. Since the procedure for forecasting these elements involves thorough analysis of weather data, it was decided to include a generalized forecast of weather conditions such as rain and cloud cover, although these are of secondary importance.

Jan 1, 1949

By Michael Moats, Adirek Janwong

The use of cylinder electrowinning cells, such as emew® technology, for the recovery of silver from primary and secondary sources has been growing. In this study, common operating parameters used in silver electrowinning were evaluated for recycling applications. Silver powders were produced from an industrial solution in a laboratory scale emew® cell. A design of experiments was employed to evaluate the effects of HNO3 concentration, iron concentration, current density and solution flow rate on current efficiency, particle size, bulk density, and crystallographic orientation. Current efficiency was affected by each parameter with increasing HNO3 concentration having a strong negative effect, increasing iron concentration and current density having moderate negative effects and increasing flow rate having a positive effect over the ranges examined. Finer particles were produced with increasing current density and decreasing flow rate. Bulk density increased when HNO3 concentration increased. The crystallographic orientation of all powders was dominated by the (111) plane. Increasing flow rate decreased the relative intensity of (200) direction. Based on these observations, silver electrowinning in cylindrical cells can operate at high current efficiency and produce larger powders at low HNO3 concentration, low iron concentration, low current density and high flow rate.

Jan 1, 2014

By D. C. Fraser, W. J. Scott

"Airborne electromagnetic surveys were flown during 1965 in the Moose River area of Ontario. The systems used were INPUT Mark II and the Canadian Aero Otter. Anomalies indicated by both systems were located on the ground with vertical-loop EM. Two such anomalies were drilled, with no explanation being found in the bedrock geology. Subsequent seismic, resistivity and gravity surveys indicated that the sources of these anomalies lay in the overburden. Current work in the similar geological environment of the Winisk River area has shown that comparable AEM anomalies can still be misleading. The lesson to be, learned from these experiences is that additional geophysical work can help to resolve doubtful cases before drilling decisions are made."

Jan 1, 1973

By Shen Zhengchang

Based on the flotation features of coarse particle mineral, a new type of impeller & stator unit is developed. Particles suspension state generated by this impeller & stator unit under different speeds are tested in laboratory, and critical impeller speed suit for coarse particles flotation is presented. Comparing particle suspension parameters of the new impeller & stator unit with that of KYF impeller and stator unit, it comes up that the distance between the interface of two slurry circulation channels and the cell bottom is larger in the flotation cell with new impeller & stator unit. The test results indicate that the new type of impeller & stator unit is suitable for processing coarse particles due to its good suspension capacity for coarse particles. Keywords: coarse particles, flotation, suspension, critical speed, impeller and stator unit

Sep 1, 2012

By Diógenes Uceda

"El presente texto revisa los problemas medioambientales relacionados con la hidrometalurgia. Las operaciones de hidrometalurgia tienen el potencial de impacto sobre el medio ambiente puesto que utilizan productos químicos tóxicos tales como ácidos, bases y agentes complejantes como el cianuro. Asimismo, los residuos de lixiviación son generalmente metaestables y bajo almacenamiento producen grandes cantidades de lixiviados contaminantes en condiciones de alta pluviometría. En ese sentido, el objetivo del metalurgista es diseñar procesos que maximicen la estabilidad de los residuos sólidos, mientras se minimiza o elimina la emisión de especies químicas perjudiciales en los flujos de agua descargados de las plantas de procesos."

Sep 1, 2016

By Donald M. Hausen

Microscopic evaluation of trace quantities of metalliferous phases in flotation products requires counting large numbers of particles. Particle counts of many thousands may be required for precision, but cannot be obtained practically by conventional microscopic techniques. A less tedious microscopic method for evaluating trace sulfides in mill tailings was developed for the O'okiep Mining Co. in South Africa. Hundreds of thousands of particles were evaluated by this method called "gross-counting." Gross-counting consists of counting microscopic fields rather than point-counting individual particles. Total counts are calculated by multiplying the average number of particles per field by the total number of fields examined over the entire mount. Total gross-counts range from about 20,000 particles for +200 to 100,000 or more for -400 mesh size material in lucite mounts. Sulfides and metallic particles in each field are identified and tallied along with field counts. Totals for each type of metallic particle are divided by the total gross-count to give volume percent which is corrected to weight percent by specific gravity factors.

Jan 1, 1973

[*E. O'C. Acker '86 Jinzoc Adachl '88 T. H. Aldrich '96 *Truman H. Aldrich '78 Walter H. Aldridge '89 *Anson W. Allen '87 John H. Allen '84 *Thomas Andrews '94 *William R. Analeby '90]

Jan 1, 1946