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By C. M. Wai

"Metal species in solid and liquid materials can be extracted by supercritical carbon dioxide containing a suitable ligand. This in situ che1ation-supercritical fluid extraction technique offers several advantages over conventional solvent extraction including minimization of organic liquid waste generation and exposure of personnel to organic vapors. One unique feature of this technique is that metal species can be removed from solid materials directly using supercritical carbon dioxide as a solvent. Several ligand systems including dithiocarbamates, B-diketones, organophosphorus reagents, and macrocyclic compounds have been tested for metal extraction in supercritical carbon dioxide. This novel extraction technique may have important applications for metal recovery and mineral processing.IntroductionSupercritical fluid extraction (SFE) offers several advantages over conventional solvent extraction including the minimization of organic liquid waste generation and exposure of personnel to organic vapors.[1] The high diffusivity, low viscosity, and T-P dependence of solvent strength are some attractive properties which make supercritical fluids excellent candidates for extraction and recovery of organic compounds from solid materials [2] Carbon dioxide is a gas of choice for SFE because of its moderate critical constants (Tc = 31 °·C and Pc = 73 atm), inertness, and availability in purified form. After extraction, the fluid phase is depressurized to separate organic solutes from CO2 gas and the gas can be recycled for repeated use. The SFE technology has been applied to industrial scale operations such as the preparation of decaffeinated coffee and hop extracts."

Jan 1, 1996

By Hardy J. Smith

The rock mass parameters which need be evaluated to estimate the rippability of rock are briefly outlined and their significance is discussed. Several methods used for estimating rippability are compared, and the advantages of taking into account a wide spectrum of rock mass parameters are emphasized. A systematic means of numerically weighing six rock mass parameters to produce a Rippability Rating (RR) is recommended, and a method of correlating this rating with the refraction seismograph method and with tractor horsepower is shown. Although the overall method demonstrated is systematic and yields specific numerical results, an integrated approach is recommended to its application, taking into account: the Rippability Rating; seismic velocity and geologic material; and other engineering judgment factors.

Jan 1, 1986

By Anil K. Ray

This paper discusses in situ studies conducted at an Illinois Basin room-and-pillar coal mine to evaluate the performances of three different types of bolts under similar geologic conditions. The bolt types considered were the fully grouted passive rebar (FGPR), the resin-assisted mechanical anchor (RMAB), and the fully grouted tension rebar (FGTR). During the evaluations, the three types of bolts were installed in a single entry covering a span of three contiguous pillars with almost identical geologic conditions. The performances of the three types of bolts were investigated by instrumentting the bolts prior to installation as primary supports on cycle. Additional data on roof behavior was collected with extensometers and shear meters placed near the instrumented bolts. Excluding some time lapse right after installation, the performance evaluation of the three bolt systems was based on the data collected for over a year. Based on this study, it was found that the axial loads measured in the different bolt types did not show any identifiable patterns under the prevailing geological conditions at the mine. Therefore, the assumption that active bolts must be superior to passive ones is not always valid. Even though the studied mine did not have any thinly laminated, weak rocks in the immediate roof, the passive bolts performed as well as the active systems.

Jan 1, 2012

With more difficult economic conditions and increased competition, the Australian exploration industry is allocating increased resources to developing more effective and efficient exploration technologies. A significant number of new techniques have been developed, and Australian companies are now at the forefront of exploration technology worldwide. These should increase the chances of maintaining Australia's leading position in world mining over the long term.

Jan 1, 1987

By D Craw

A glasshouse experiment was set up to investigate arsenic uptake in rye corn grown in different arsenic rich substrates. Sods of material were taken from various locations and planted with rye corn seeds. The plants grew for 13 weeks after which time the above ground biomass was harvested. Analysis of the rye corn plants showed a narrow range of arsenic concentrations, which did not reflect the arsenic contents of the soil. Comparison of the results from this study with previous work showed the glasshouse rye corn to have lower arsenic concentrations in above ground biomass than rye corn grown in field conditions. The environmental conditions present on the tailings and water-rock interactions were considered the main factors involved with the difference in arsenic uptake between field studies and the glasshouse study. This suggests that bioavailability processes are influenced by a variety of factors and cannot necessarily be predicted by the use of soil factors or glasshouse trials alone as is often done when planning phytoremediation work and mine shut down.

Jan 1, 2007

Reports by researchers in government, industry, and universities of the United States are given for various projects on basic coal research concerning, the metamorphism, physical and chemical properties, and reactions of coal, and how many of these studies can lead to better utilization of coal.

Jan 1, 1968

By Herty, C. H.

The effect of temperature on the physical properties of structural materials has been the subject of many investigations during the past decade. The literature on the effect of elevated temperatures. is voluminous, and during the last four years a great deal of experimental work has been carried out on the effect of low temperatures on the impact properties of steel. For many engineering purposes it is important to know the shock resistance of steels at low atmospheric temperatures, and with the ever-developing field of refrigeration and separation of materials at low temperatures, the normal limits of atmospheric temperature have been exceeded in practice. Iron and its alloys in the unnotched condition have a high impact strength at low temperatures, but in practice variations in type of notches result either from design or accidentally through scratches and surface or internal defects. A study of notched bar impact tests is, therefore, highly important to the engineer. A survey of the literature on low temperature impact testing indicates that chemical composition, heat treatment and method of testing have been the variables which have been considered in most previous work. In only a few instances has any mention of the steel- making method been mentioned and in these the comparison was between steel-making processes and not between steel-making methods on the same process. In view of the wide variations in impact properties at room temperature, in quench and strain ageing and in grain growth of steels of identical chemical composition, (by this is meant the usual five element analysis reported), it was felt

Jan 1, 1957

By Hua Hou, Xiaofeng Niu, Wei Liang

"The explicit finite difference (EFD) method is used for calculating the casting temperature field during solidification. Because the time step is limited, the computational efficiency of the EFD method is lower. In order to improve the computational efficiency, a fourth-order in space and second-order in time model based on the equivalent specific heat method and the alternating direction implicit (ADI) method is established. The degree of similarity between the simulation results and the experimental results is analyzed. The results show that the simulation results of this high order mathematical model are close to the experimental results.IntroductionThe 3D heat transfer equation of temperature field during solidification process is as the following: [1-3]."

Jan 1, 2013

By E. Sabah

A series of adsorption tests are carried out to understand the ability of cationic surfactants and metal ions to adsorb onto sepiolite. Adsorption tests conducted as a function of heat treatment reveal that sepiolite is rather conducive to the uptake of both organic and inorganic ions. An ion exchange mechanism between surfactant or metal cation and magnesium ion followed by chain-chain association is proposed to explain the incorporation of cationic surfactants into the structure of sepiolite.

Jan 1, 1998

By Cyril Wells, Robert F. Mehl

THE practical importance of a knowledge of the rates of diffusion of carbon and of alloying elements in steel has often been pointed out 1,13 This importance ties chiefly, though by no means only, in the study of carburizing and in the study of reactions involved in the eutectoid inversion in steel The present paper is one of a series in which the rates of diffusion of carbon and of alloying elements in y-Fe and their mutual effects are measured with precision The present paper reports the results of meas¬urements of diffusion coefficients D of manganese in -y-Fe over wide ranges of temperature, and concentration, and of the effect of carbon and impurities and of grain size upon these diffusion coefficients [$] Data on the rate of diffusion of manganese in y-Fe have been reported by Fry2 and by Paschke and Hauttmann 3 Claussen4 calculated the diffusion coefficient D from Fry's data as 3 X 10-10 sq cm per sec at 960°, which will be shown to be incorrect by many orders of magnitude Paschke and Hauttmann gave a rough value of 9 6 X 10-8 sq cm per sec at 1400° Neither of these workers considered the variation of D with concentration and with temperature, and neither studied the effect of carbon METHOD AND MATERIALS Method -The method employed is identical with that used earlier 5 Owing to the volatility of manganese and the consequent loss of manganese from the outer surfaces of the welded diffusion bars, these surfaces were discarded The diffusion anneals were performed in argon, except one (test 18) in which hydrogen was employed for purposes noted below The temperatures reported are accurate to about 3° and constant within I°C , the diffusion times are reported to the nearest half hour The specimens were furnace-cooled after the diffusion anneal at about 2° per min Layers, usually 0 004 in thick, parallel to the welded interface, were machined from the specimens after the diffusion anneal and analyzed for manganese to 0 01 per cent Mn, the distances of these layers from the interface was measured to ±0 0002 in The concentration-penetration curves obtained were analyzed by both the Grube and the Matano solutions e The D values calculated by these two methods do not differ appreciably 5 The Grube solution was used except in tests in which the effect of concentration upon D was greater than 50 per cent, in such cases the Matano method, which explicitly provides for the variation of D with concentration,1 is the more reliable In general, the number of layers machined from the zones of variable composition were large enough to permit the use of the average layer composition as that of the center of the layer In 3 of the 30 tests, however, this is not justified, and the D values

Jan 1, 1941

The Waste Isolation Pilot Plant (WIPP) is a geologic repository for disposal of transuranic waste and is operated by the US Department of Energy. The repository is located at a depth of 655 min the Permian age salt beds of the Salado Formation. The exhaust air from the facility is independently monitored by the Environmental Evaluation Group to verify compliance with regulatory release limits for radioactive materials. A May 1995 video inspection of the exhaust shaft identified fluid migration into the uppermost 25 m of the shaft. Since then, water has been observed flowing in from cracks in the shaft lining between 16and 25 m below surface level at an estimated rate of between 5 and15 m3/d. This water inflow has not only negatively impacted the equipment in the shaft, associated duct-work and monitoring equipment located at the top of the shaft, but also challenged efforts to verify compliance at the WIPP. This paper provides an analysis of these effects.

Jan 1, 2004

By Roger M. Turpening

This study was performed to examine the feasibility of using seismic shear waves to detect the presence of abandoned coal mines. !he Antiquity Coal Mine near Antiquity, Ohio was used as a region of known voids. No attempt was made here to accurately locate the mine tunnels if detection was obtained. The results of this study were positive. Sharp changes in the amplitude of the received shear waves were clear indications of the presence of a fluid (gas or liquid) filled region between the source and receivers. When moving the source showed no change in the received signals it was concluded that the voids existed beneath the sensors. Prior to these tests drilling (SM-3) had determined that a void did exist in this area. This void was confirmed by this shear wave test and two additional voids were found.

Jan 1, 2012

By C. McAllister, D. Preece, J. Berendzen

The Multiple Blasthole Fragmentation (MBF) model was developed recently and has been reported in previous papers. The MBF model accepts inputs from the blast design, such as: location and orientation of each blast hole, stemming length, blast hole diameter, multiple decking, bench height, initiation sequence, etc. It models the effect on fragmentation of delay timing with its associated scatter for each blast hole. MBF has a statistical modeling capability for geological random variation of the attenuation of particle velocities. Also simulated is wave reinforcement due to the interaction of simultaneously arriving waves or diminishing cooperative contribution from long delay intervals between charges.

Jan 1, 2016

Table 1.-Aden: Production of mineral commodities [ ]

Jan 1, 1967

By G. G. Richards

The zinc slag fuming process is used to recover zinc from molten iron-calcium silicate slags by treatment with pulverized coal and air. The rate of zinc fuming is controlled by the complex interaction of several kinetic factors including the rate of entrainment of coal in the slag, the extent of the coal-slag reaction and the rate of ferrous oxide oxidation to ferric oxide. This paper briefly outlines the mechanism of fuming and, on this basis, optimization of process parameters is discussed. Modelling analysis and recent industrial trials at Cominco show that coal entrainment in the slag, bath temperature, and bath depth are critical variables affecting process rate and efficiency. The first step in process optimization is to assess coal bypass of the bath. In general, changes which promote operation at a higher temperature, greater coal entrainment in the slag and extended residence time of the coal in the bath increase fuming performance. Coal entrainment is controlled by injection conditions whereas bath temperature is a function of coal combustion and ferrous oxide oxidation. Residence time of the coal is largely a function of bath depth. The implication of model predictions for continuous fuming is shown.

Jan 1, 1994

The quality of iron ore fines in terms of high iron content and low levels of deleterious impurities such as Silica, Alumina, Sulphur and Phosphorous is a critical parameter, in sintering and subsequent iron and steel making processes. As the higher-grade ores become depleted, there will be a stronger focus on treating lower-grade haematite/goethite ores and developing suitable beneficiation techniques to reduce the levels of impurities. Innovative flow sheets, based on new and commercially available technologies, is required. These will be needed to include gravity concentration devices, which can handle coarse and fine feed sizes. In this paper, efforts made to reduce the silica and alumina content of a low grade iron ore fines (<1.0 mm size) sample from the Pilbara region in Western Australia are described. The feed sample, a goethite abundant lower grade iron ore fines, which was a plant reject assaying 48.66% Fe with 13.61% SiO2and 5.09% Al2O3 was investigated. To this end, an experimental campaign was undertaken, and beneficiation studies were conducted on the sample using a Floatex Density Separator (FDS), a gravity device which can be operated for size classification and/or relative density separation. The objective was to produce high-quality iron ore material suitable as sinter feed. An iron concentrate with a grade around 57.0% Fe (Calcined Fe of about 63.0%) was achieved while recovering around 67.0% of the feed weight. In addition, a rejection of substantial content of Silica (>75%) and Alumina (>66%) was achieved while securing >77% iron recovery. On the other hand, sharp classification efficiency with low values of imperfection around 0.20 was obtained. Consequently, the response of the lower grade iron ore sample to FDS application, has vast potential to reject deleterious impurities as a single stage separating beneficiation equipment. Remarkably, it was demonstrated, that a great amount of goethite, abundant in lower grade iron ore fines/plant rejects, which are currently being either stockpiled and/or dumped as waste, can be treated using FDS application and potentially can add a significant value to the iron ore mining industry by recovering additional iron ore fines. Keywords: deleterious impurities, beneficiation techniques, classification, relative density separation

Sep 1, 2012

By S. H. Lau

Rapid 3D characterization of multiphase mineral particles in a variety of mineral processing applications is described, including: mineral liberation analysis, grain size, mineral exposure analysis, particle damage, and pore network structure for fluid flow simulation in heap leaching. While micro X-ray computed tomography systems (microCTs) have been used for many years, industrial adoption is limited due to a variety of reasons, including insufficient resolution, the general lack of imaging contrast to differentiate different mineral phases within a multiphase mineral particle and the lack of automated 3D mineral processing software. For example, resolution with industrial CTs and desktop microCT is of the order of tens of microns to a few microns at best, depending on specimen size and CT configuration. We describe a novel lab-based X-ray microscope, XRM, which overcomes these resolution and contrast limitations, notably as the industry is going towards finer grains and more complex ore bodies. Using lens-based optics and detectors (similar to its XRM counterpart in synchrotron beam lines), resolution of the lab based system is in the submicron range with contrast better than conventional microCTs. Hence, visualization, differentiation and segmentation of most mineral phases of interest to the industry are now feasible. Coupling these high resolution and high contrast tomography images with a suite of customized 3D segmentation algorithms and analysis software, applications in mineral liberation analysis for process control, particle damage assessment and other mineral processing applications can be achieved. This non invasive 3D technique which requires relatively little sample preparation is currently being considered for coal, industrial minerals, and base/precious metal ores, complementing existing microscopy techniques such as QEMSCAN and MLA for a variety of applications

Sep 1, 2012

POSITIONS VACANT No. 175. At a mine in Missouri: general designer on timber work for concentrator power house and general mill work; two draftsmen on all kinds of mine and null work; two tracers, good letterer and map tracer; one transit man for surveys who can plot his work accurately.

Jan 1, 1917

By W. W. Adams, T. D. Lawrence, D. R. White

"This paper presents the results of the eleventh yearly accident-prevention contest, the National Safety Competition of 1935, conducted by the United States Bureau of Mines. Participating in the competition were 336 mines and Quarries in 37 States. Five mining or quarrying companies, each the leader in its group for having established the best safety record during the year, were awarded the national safety trophies 'Sentinels of Safety.Since these annual contests were begun 11 years ago the scope of the competition has been broadened materially, both as to the number of plants participating and as to the number of man-hours of exposure to accident hazards. Moreover, marked progress in the pre¬vention of accidents has been achieved, as is indicated by an almost constant downward course in the accident-frequency rates for the contest group as a whole during the past 11 years. On the other hand, the accident-severity rates for the group showed an upward trend during the first part of the period and a downward trend during the latter part, except in 1930 and 1934, when two disastrous explosions occurred with heavy loss of life, and in 1935, when there was an increase in the number of fatalities although no major disasters occurred. The accident rate for 1935, both as to frequency and severity, was higher than for 1934.The National Safety Competition is conducted by the Bureau of Mines in the interest of safety in the mining and quarrying industries. This object is accomplished directly through the efforts of the competing companies and their employees to win first place in the competition and thereupon receive well-merited and national recognition for their achievement. Indirectly the purpose of the contest is accomplished through studies by the Bureau of Mines of the fasts contained in the accident reports which the competing companies furnish to enable the Bureau to compute the accident rates that are the basis for determining the winners of the contest.The statistics that constitute the basis for determining the winning companies and the relative standing of all companies are prepared uniformly without regard to the States in which the companies operate, or to differences in classes of accidents covered by State laws relating to compensation for injuries resulting from industrial accidents."

Jul 1, 1936

This paper investigates the adequacy of current gas monitoring techniques to adequately detect spontaneous combustion in underground coalmines. Despite being in the 21st century spontaneous combustion continues to occur in underground coalmines sometimes being detected only at a very advanced stage. Control of the incident is often then very expensive and time consuming. The adequacy needs to be assessed not only from the point of view of the analysis technique be it tube bundle, gas chromatograph or real time sensor but also the number, location and sampling frequency of the monitoring locations. Recommendations are made to optimise monitoring processes and recognise limitations of current techniques.

Jan 1, 2005