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By M. Stelter

Since the first years in copper electrorefining natural products have been used as so called "additives" in the electrolyte. Glue as one of these additives offers a lot of different reactions with the metal ions and also with other additives like thiourea in the electrolyte. For a deep understanding of the effect of these additives it is important to know the routes of possible reactions in the electrolyte as well as the basics of electrocrystallization. Using this knowledge the interpretation of nodulation or inclusions of electrolyte in the cathodes in copper electrorefining is easier than before. Setting up on physical and chemical properties of the electrolyte and the additives practical investigations of the effects of additives in copper electrorefining and their impacts on copper crystallization and cathode quality are presented in this paper. Chemical deposition of glue against time and temperature are only few of the effects that are mainly caused by the use of natural products. In fact parameters like anodic and cathodic polarization are strongly affected by the additives as well as the effects of the additives are strongly affected by current density. This second part of the paper presents results concerning interactions of the above mentioned parameters.

Jan 1, 2007

By L. A. Rapoport, W. J. Leas

The original Burkley-Leverett theory has been extended and a more detailed formulation of the waterflood behavior in linear horizontal systems is presented. Particular consideration has been given to the evaluation of capillary pressure effects and differential equations permitting an explicit evaluation of these effects have been derived. On the basis of the developed theory it is recognized that the flooding behavior is dependent upon the length of the system and the rate of injection. At the same time it has been determined that systems of different lengths yield the same flooding behavior if the injection rates and or the fluid viscosities are properly adjrrsted or "scaled." It has also been found that the sensitivity of the flooding behavior with respect to rate and length decreases as any one of these {actors increases in value and that for sufficiently long systems and high rate.; of water injection the flooding behavior becomes independent of rate and length. or "stabilized." To such stabilized conditions the theory formulated by Buckley and Leverett is applicable. A number of laboratory flooding tests have been made and good agreement Iraq been found between theory and experimental observations. The experimental results are discussed and it is shown that under field conditions the flooding behavior is usually stabilized. As a result of these finding; a procedure is indicated for evaluating field performances either on the basis of tests performed with commonly available core samples or by means of calculations using relative permeability data INTRODUCTION In recent years the development of methods for evaluating oil recovery by waterflooding has been the object of considerable research. A theoretical analysis of the mechanisms involved in the displacement of immiscible fluids was originally established by Buckle!- and Leverettl and experimental investipatio~~s have been made by numerons workers." Many of the experimental results are in mutual agreement and bear out several significant features of the flooding mechanism as predicted by theory. Thus it lias been generally recognized that a flood corresponds to the movement of a steep saturation hank or "front" (primary phase), followed by additional gradual oil displacement (subordinate phase). It has also been found that for any porous medium the flooding behavior is largely dependent upon the oil-water viscosity ratio and that for increasing values of this ratio the relative importance of the primary displacement phase decreases while that of the subordinate phase becomes more pronounced. Although the studies to date have clarified certain aspects of the flooding process. they have given rise to observations of a somewhat contradictory nature that cannot he explained in terms of the original theory. These observations pertain mainly to the effect of injection rate or pressure gradient upon recovery. Some investigators report laboratory tests that indicate incresing oil recoverieq with increasing rates of water injectill, others find the flooding behavior to be independent of and other. mention lower oil recoveries with increased injection rates.3 The conflicting evidence indicated above creates considerable uncertainty with respect to laboratory testing procedures and the utilization of the resulting data for field evaluations. The principal purpose of this paper, then, is to resolve these Uncertainties by means of a comprehensive theoretical and experimental investigation of the flooding meanism. THEORETICAL DEVELOPMENT Derivation of Flooding Equations The mathematical description of transient flow phenomena is based upon the consideration of the various processes occurring during an infinitesimal time interval in an infinitesimal volume element and upon the correlation of these processes with those occurring in the adjacent elements. The volume elements are defined as being infinitesimal in comparison to the overall dimensions of the porous system, yet each sufficiently large so aS to encompass the full range of pore openings encountered throughout the system. If a porous system can arbitrarily be subdivided into an infinite number of volume elements all possessing the same distribution of pore openings and if this distribution is unformly continuous. the system may be said to be homogeneous. Such a homogeneous porous medium is considered in the present studivs. It is furthermore postulatecl that only oil and water are present in the pornu wediu. that they act a- totally incompressible and immiscible fluids. and that gravity effects are negligible. In n linear flow system of unit cross sertional area. as treated here. the infinitesimal volume element.; to he considered are cylindrical ".slices" of thickness dx. oriented perpendicularly to the direction of flow. The equations applicable to any such volume element. at my time. describe the movement. of oil and water across the element:

Jan 1, 1953

Design and selection of support systems for longwall faces call for in-depth knowledge of strata mechanics and in particular of strata-support interactions. The paper presents the results of field investigations and analysis of a difficult-to-cave roof using powered supports under a massive dolerite sill in Central India using a state-of-the-art datalogger system. The mechanised longwall face was equipped with 4/680 tons chockshields operated on the IFS mode using a 300 K W DERD shearer. The datalogger system was capable of storing data simultaneously in 32 channels. The paper describes the monitoring system and the monitoring programme. The system provided useful information on support behaviour, build-up of leg pressures and face convergence during an intense dynamic periodic weighting phenomenon which destroyed the integrity of almost half of the face supports. At this point, the face had advanced by about 197 metres from the barrier. The paper outlines a post-mortem analysis of this dynamic event and provides a critical evaluation of the data collected for understanding strata support interaction and the behaviour of the massive sill in the overburden.

Jan 1, 1992

By H. F. Moore

We have studied the simple case of repeated stress, without considering impact, which might bring in other factors. This investigation has shown that steel under repeated applications of stress, reversed from positive to negative, will not fail below some fairly clearly defined limiting stress that, so far we can see, does not bear any definite relation to the ordinary elastic limit, being as large as the elastic limit in some cases and about one-half the elastic limit in others. According to one theory, fatigue is the result of changes in crystalline structure by repeated stress. I do not know of any evidence in favor of this theory. The crystals are broken under repeated stress. According to Bauschinger, under repeated stress some inherent property of the material changes its elastic limit; possibly some property of the amorphous cement between the crystals. A third theory is that all fatigue of metals is the result of the spread of damage from little localized overstresses. While I do not feel justified in accepting the last theory rather than the second, I have yet to run across a case of failure of steel or other metal, either in the laboratory or in service, that could not be explained by the gradual spread of damage from some nucleus. We have found, for example, that it is possible to subject a homogeneous steel, like Armco iron or a 0.90 per cent. carbon steel, that has been thoroughly annealed, to one hundred million reversals of stress as high as the elastic limit of the steel with no sign of failure. On the other hand, a complex structured steel, like a chrome-nickel steel that has been hardened with very little drawing, will fail at a stress about 58 per cent. of its elastic limit. Between these two we get a variety of results. In the steel work of any building, there are undoubtedly many thousands of places where structural damage was done—where riveted members were bent into place cold and where the rivets were fitted with drift pins, etc. Locally the steel in the building was stressed beyond its yield point in many places. These little localized overstresses do no damage at all; the building is entirely safe. But if this building were subjected eight or ten times a day to a mild earthquake, these little localized overstresses might be nuclei from which damage would spread

Jan 1, 1922

For the year ending February, 1919 PRESIDENT SIDNEY J. JENNINGS NEW YORK, N. Y. PAST PRESIDENTS L. D. RICKETTS NEW YORK, N. Y. PHILIP N. MOORE ST. Louis, Mo. FIRST VICE-PRESIDENT C. W. GOODALE BUTTE, MONT. TREASURER GEORGE C. STONE, NEW YORK, N. Y. SECRETARY EMERITUS ROSSITER W. RAYMOND, NEW YORK, N. Y. SECRETARY BRADLEY STOUGHTON NEW YORK, N. Y.

Jan 9, 1918

By Shad M. Sargand, Glenn A. Hazen, A M. M Jayasuriya

Various types of waves originate from a blast source to propagate through rock/soil media away from the blast. Input vibration to a structure depends on the soil-structure interaction which varies with the dynamic properties at the intersection as well as the stress and strain levels developed from the vibration of the structure-ground system. Hence it is important to study such effects on the response of a structure due to blast loads and this knowledge can be used in the design and control of blasts that are carried out close to buildings, highways and other structures.

Jan 1, 1994

By G. R. Addie

The Hydraulic Institute has completed the task of developing a new ANSI/HI standard 12.1-12.6 (2005) for rotodynamic (centrifugal) slurry pumps covering nomenclature, definitions, applications, and operation. The standard provides examples of the different slurry pump types and contains an extensive section on pump and slurry definitions. The effect of slurry on pump performance is covered along with the pumping of froth. Reference is also made to ANSI/HI standard 9.6.7 (2004), which contains a new method for pump performance correction when handling viscous fluids. Classification of slurry services is established and then is used to determine limitations on velocities and total head per pump in order to obtain acceptable wear performance. The new service class, head per stage and other limits are directly related to capital and other cost considerations that will affect solids transport system economics. The writers review the contents of the new standard, highlight the main points, and discuss the reason for the slurry classification, corresponding limits and expected implications, particularly with respect to operating costs of the pumps in solids transport systems.

Jan 1, 2007

"There mines are located in out of the way places, where timber is scarce and its price high, the problem of protecting it from fire risk is of considerable practical importance. Scarcity of timber for mining purposes is commonly met with in the more arid parts of the country, where, so, mine timbers are most likely to become dry, and inflammable, and where, therefore, the risk from fire is accentuated. Any effective and cheap method of securing adequate protection of such timber at the lowest possible cost is worthy of careful investigation. The use of magnesite cement has been suggested in this connection.The necessary qualities for any substance for the use suggested above may be summarized as follows: It should be resistant to abrasion, and to impact and structural stresses. It should be durable when subjected to the action of the elements, and stable to any minor derangements of the base on which it is placed. It must be relatively unaffected by changes in temperature, by the action of water, and should adhere to the material on which it is placed, and it should also be free from shrinkage cracks due to setting up the material, Magnesite cement appears to fulfill the various conditions outlined above.The elasticity of such cement is the outstanding quality which makes it desirable for exterior work. It also possesses the ability to adhere to all materials in a marked degree. Its freedom from expansion and contraction after setting is one of the principal reasons for its adhesive quality. It may be applied to old brick or stone walls, even tho they have been repeatedly covered with paint, and the quality of adhearing to wood makes it possible to secure a weather-proof protection to the wooden casings and trim of exterior openings. The quality of adhesion and elasticity is easily proved by applying a 1/2"" layer to a 1"" board which has been first covered with metal lath. Such a board, about 8 feet long, may be repeatedly deflected about 3"" in the center without breaking the bond to the board, or causing any cracks to appear in the magnesia cement. The ability to resist fire as well as the possession of insulating qualities are also desirable characteristics of magnesia cement stucco.Magnesite cement stucco should be applied in two coats, each 1/4"" thick on various surfaces such as wood lath, metal lath, sheathing board, brick, hollow tile, or stone; care being taken as regards the presence of lime, unless the same has been rendered, or become inert as with very old, walls. The first coat made up to a consistency that works easily under the trowel is applied in the usual manner. No water should be added to the liquid chloride as it would alter its density, and injure the work. The second or finishing coat is then applied. The aggregates are different in each, and no other dry material should be added to them as they come to the trade. The cement may be applied in zero weather without damage. Setting is quite slow under such conditions, but the cement ultimately becomes hard. It should always be applied to a dry surface excepting that under certain conditions it is desirable to apply a solution of magnesium chloride before using the stucco."

Dec 1, 1919

By Juan E. Rassmuss

Durante mucho tiempo la explotación del azufre en el interior del Perú, ha sido de manera regular dado su bajo consumo nacional y cotización en el mercado peruano. Asi, solo ciertos yacimientos ubicados en el norte de nuestro país producen y generan divisas que no sobrepasan los 6 millones de soles. En el marco de esta situación, el objetivo del siguiente estudio, pretende reactivar el consumo nacional de los yacimientos del Sur del país, -en tanto volumen e importancia comercial por medio del uso de un método de beneficio apropiado. La formación de los yacimientos del Sur, a diferencia de los de Piura y Bayovar, se da por la emanación postvolcánica de gases sulfurosos, generandoimpregnaciones de azufre en las lavas y tufos del Terciario Superior y Cuaternario. Posteriormente se produjeron fracturas en las zonas contíguas de los volcanes, formando depósitos lenticulares de extensión variable. Dichos depósitos son superficiales puesto que solo cerca de este espacio se puede mantener la oxidación del sulfuro de hidrógeno y los gases están a temperatura baja para depositar azufre. En cuanto al costo del azufre tenemos el costo de explotación, beneficio, transporte y embarque. Finalmente, se deduce que la fundición del azufre como la filtración, soliflucción pueden ser favorables en el uso de métodos de explotación menos costosos, asi como el incremento de la explotación depende de un mercado común estable y de un cálculo exacto de los costos de producción.

Jul 20, 1956

By R. W. Nesbitt

The TAG and Broken Spur hydrothermal mounds are located on the Mid Atlantic Ridge (MAR) at 260N and 290N (respectively). Both were initially discovered by exploratory work from surface vessels and both have since been investigated by submersibles. The discovery of TAG resulted from a NOAA Trans-Atlantic Geotraverse (Rona et al. 1975) which fortuitously sampled low temperature materials on the east wall of the MAR rift valley and follow up operations (Rona et al. 1986) located the high temperature (365°C) mound some 5km to the west. In 1994, ODP deep sea drilling (Leg 158) at over 3,500 metres of water recovered core to a depth of 150 m below surface (Herzig et al. 1998) and for the first time allowed a geological interpretation of an active mound. The Broken Spur mound was accidentally discovered in 1993 when sulphide fragments were observed on a deep-sea towed camera system (Murton 1993). Later that year, exploratory submersible dives by Alvin located the hydrothermal field and the area was again explored by submersible in 1994 and 1997. Despite the amount of work carried out, our geological understanding of the MAR mounds is limited. Much effort has gone into measuring fluid chemistry whilst practical difficulties have inhibited good geological mapping of the sulphide areas. It is clear from both TAG and Broken Spur that the mounds are not necessarily located in the areas of highest heat potential. Indeed, TAG is some 2 km from the rift valley axis and has been operational for several tens of thousands of years. Hence, heat availability is not a major consideration and the most obvious control is a structural one. Mapping on Broken Spur indicates a series of isolated vent-sulphide areas, concentrated around a minor graben. Their distribution, size and nature all indicate that they are residual parts of a much larger sulphide body which was at least the size of the present TAG field. The evidence is for a cyclical pattern of mound growth -mass wasting? rejuvenation and the Broken Spur mound appears to be in the rejuvenation stage of the cycle. Mound cyclicity must be related to the supply of hot water which itself is a function of the connectivity of fracture systems. Hence, we return to the theme that the major controls in mound development are structural ones.

Jan 1, 1998

By R. W. Lawrence

Sulphide is an effective reagent in the precipitation of base metals for both metal winning and environmental control. BioteQ Environmental Technologies Inc. has successfully demonstrated in industrial plants that biogenic sulphide reagent can be generated cost effectively and used to win metals such as copper, zinc and nickel from low-grade leach solutions and wastewater. Commercial plants in which sulphide reagent is used to produce high quality treated effluents for discharge directly to the environment are also in operation. Operations utilizing biogenic sulphide reagent for copper recovery from acid drainage and low grade leach solutions are discussed, including those at Bisbee, Arizona, commissioned in 2004 and at the Dexing mine in China, scheduled for commissioning in 2007. In addition, a new application of BioteQ's technology for the recovery of copper from gold-cyanide solutions, and the regeneration of cyanide, utilizing biogenic sulphide in place of chemical sulphide reagents in the SART process is described.

Jan 1, 2007

By Weatherstone N

Ironstone outcrops on the Savage River were discovered by State Government Surveyor C. P. Sprent in 1877. The limonitic outcrops were initially regarded as the surface expressions of pos- sible tin-bearing lodes, the tin deposits at Mt. Bischoff to the east having been found in 1871. By the turn of the century, shafts, adits and trenches had been developed on the deposits in the unsuccessful quest for gold, silver and base metals. The deposits were first reported as a possible source of iron ore by Tasmania Department of Mines (TDM) geologists in 1919. Modern exploration began in 1956 with the area registering the best magnetic response during an aeromagnetic survey of North- western Tasmania by the Bureau of Mineral Resources (BMR). The area had previously been reserved by TDM in anticipation of the lifting of the iron ore embargo. Reconnaissance Geologi- cal mapping (TDM) and grid-based magnetometer surveys (BMR) indicated that resources of iron-bearing material could approach hundreds of millions of tons. This provided the incentive for two diamond drill holes funded by TDM which demonstrated iron mineralisation in substantial tonnages, suitable grades and, fol

Jan 1, 1988

By William H. Sutherland

INTRODUCTION Coal workers' pneumoconiosis and sili- cosis are only two of several diseases which are rlassed as pneumoconiosis. These are respiratory diseases caused by dusts which are inhaled and accumulated in the lungs. The individual particles of dust cannot be seen by the human eye. They are so small that they escape the natural cleansing mechanism of the nose and air passages and make their way down to the terminal air sacs of the lung where they injure the cells and cause the formation of scar tissue. Consequently, if there is exposure to high concentrations of dust over a period of time - usually, a number of years - the amount of scar tissue increases and begins to impair breathing. As a result, the miner develops shortness of breath, coughing and wheezing ad-if exposure continues - this progresses to permanent disability and frequently to death. Death is often due to pulmonary heart disease, the effect of stress on the heart 2s it tries to compensate for the weakened lungs. Specifically, silicosis is an occupational lung disease caused by the accumulation of free silica (quartz) in the lungs. Silicosis is considered the most important form of pneumoconiosis, not only because of its seriousness as a respiratory crippler, but also because of the large number of workers who risk contracting it in a variety of occupations. Quartz is one of the most common substances of the earth's crust, estimated at about 60 percent. Silicosis has been found in coal, metal and granite miners, as well as in other workers, such as sandblasters and pottery makers. Silicosis is also known to predispose the lung to tuberculosis and to increase the chances that a worker will contract chronic bronchitis and emphysema. The seriousness of silicosis was tragically brought to public attention about 50 years ago. During 1932-34, workers were involved in digging a tunnel through rock at Gauley Bridge, West Virginia. While their exposure time was relatively short, they developed silicosis because of the high concentrations of quartz. By 1936, 476 workers had died of silicosis and about 1500 were believed to have the disease (Washington Post, 1982). It is difficult to tell how many coal miners have silicosis. Because x-rays and breathing function tests do not show the difference the type of pneumoconiosis is generally diagnosed by the miner's work history. For example, if a worker

Jan 1, 1986

By John V. Beall

Back in the days when it was possible to tell one sports season from another, the football season began the last Saturday in September and ended on Thanksgiving Day for most teams. There were one or two post-season bowl games on New Year Day; but that was it. Actually, ten weeks of football, counting preseason practice, was about all a player could stomach without going stale. Not that the boys were any softer back then; quite the contrary, a good player usually played 60 minutes of ball. We must admit that we played lots of football in those days too---but not on Saturday. Particularly we remember the Monday after the Saturday when Columbia beat the Georgia Tech team which was led by the great back, Frank Sinkowitch, by a score of 7 to 3. That Saturday Mr. Little actually played 14 men: that is there were three backfield substitutions, each of which was for a few minutes only. Georgia seemed to have a progressive coach because he alternated two squads by quarters.

Jan 1, 1970

By C D. Rawlings

An assessment is made of the potential for thick seam underground mining of black coal in Australia. A brief summary is given of the geo-mechanical environment and previous mining history existing in a number of areas of particular interest from the point of view of thick seam mining. A classification of thick seam mining methods is presented with emphasis on the critical geo-mechanical parameters influencing the performance of such methods. A summary is made of perceived geo-mechanical research requirements related to thick seam mining in Australian coalfields.

Jan 1, 1980

By Patrik Ericsson

During the 90?s Atlas Copco and LKAB developed a pioneering fully automatic long hole production drilling system based on the Atlas Copco Simba W469 drill rigs. These drill rigs have since then drilled about 8.000.000 drill meters at the LKAB Kiruna and Malmberget mines. In 2005 LKAB ordered three new Atlas Copco Simba W6 C, to complement Simba W469s still in operation. These new Simbas are based on the latest generation computerized drilling technology have proven to meet the expectations of LKAB and now form a base for future automation in Kiruna and Malmberget mines. This paper will present experiences from the introduction of Simba W6 C in LKAB Kiruna and Malmberget mines. The paper will also elaborate on the latest developments in remote access and remote control technology making it a common automation option available for all computerized Atlas Copco drill rigs.

May 1, 2007

By R. V. Ramani, R. Stefanko, P. C. Thakur

The effects of diesel exhaust on mine ventilation systems are discussed. Mathematical models for emission of gaseous pollutants from diesel engines and their dispersion into mine air have been developed. Situations likely to prevail in mines were originally modeled using partial differential equations, but only simplified solutions are presented here. Validity of these models has been established by field observation of the growth of carbon monoxide concentrations in mine air environment. Consequently, these models can be used for air requirement calculations for diesel engines in underground mines.

Jan 1, 1977

EXECUTIVE COMMITTEE OF THE BOARD OF DIRECTORS L E Young. Chairman -. Donald H McLaughlan, Vice-Chairman A B Kinzel Earle E Schumacher John R Suman FINANCE COMMITTEE OF THE BOARD OF DIRECTORS Erle V Daveler, chairrnan Phillip Kraft Clyde E Weed

Jan 1, 1949

By R. E. Thill

An ultrasonic, pulse-immersion apparatus and method are described for determining the effects of moisture on the dynamic elastic properties of rock. The method provides an alternative approach for assessing the moisture sensitivity of rocks. Ultrasonic wave velocities are continuously monitored in immersed rock samples as a function of water absorption and time up to saturation. Moisture effects on compressional wave velocity vary as a function of the type of rock and the time and amount of water absorption. Regression analyses are used to curve-fit plots of the data and to derive empirical expressions for compressional wave velocity as a function of water content for different categories of rock. Results indicate that compressional wave velocity can be used to predict both the moisture content and its effect on strength and deformational properties of rock. These results have potential for detecting or monitoring bad roof conditions in situations where the mine rock exhibits strength degradation with moisture absorption.

Jan 1, 1986

By Dirk van Zvl

The design of cover systems for reclamation schemes in tailings requires estimation or determination of tailings materials properties such as compressibility, shear strength and consolidation characteristics. It is very difficult and expensive to obtain truly undisturbed tailings samples for laboratory testing. In situ testing methods have been developed for economically obtaining large amounts of information. Two of these methods are described, the piezocone and the flat plate dilatometer. Both of these methods provide a rapid means of detailed material identification in a nearly continuous fashion for the entire depth investigated. The equipment is described and typical data from a uranium tailings impoundment is presented. The results are compared and the advantages and disadvantages of these methods are discussed.

Jan 1, 1984