Search Documents

By Kazuhiro Nisizono, Takashi Kuroki, Nobuyuki Mori, Keisaku Ogi

"The improvement of critical current density and mechanical property is essential to the practical application of the superconductive oxides. A solidification technique is developed in this study for the growth of columnar or single Y123 crystal with finely dispersed Y211 and Ag particles through a monotecto-peritectic reaction of Li.(Ba-Cu-Ag-0 rich liquid)+ Y211-+ Y123+Lz(Ag rich liquid). The large solidification rate and temperature gradient can refine the Ag and Y211 particles. But Ag-free region is widely formed along the crystal growth direction in the central part of the Y123 cell. Since this phenomenon occurs because of the cellular growth, it is necessary to narrow Y123 cell width or to grow Y123 crystal with flat freezing interface. By controlling crystal growth direction using a seed crystal, Y123 columnar or single crystal with uniformly dispersed fine Ag particles are obtained. The· behavior of Ag and Y211 particles during the solidification of Y123 crystal is simulated by the peritectic growth model of faceted Y123 crystals.IntroductionY-Ba-Cu-0 superconducting oxide (YBCO) with high critical temperature also has excellent superconducting characteristic under the high magnetic field. The critical current density (Jc) has been enhanced by ·using unidirectional-solidification technique, which can overcome the weak-link problem at grain boundaries and control the crystal orientation and the distribution of Y211 particles which give effective magnetic flux pinning centers in the Yl23 matrix [1-4].In addition to improving superconducting properties, it is necessary to improve mechanical property for the practical application. The silver addition to the melt-textured YBCO superconducting oxide has been reported as the effective method to improve mechanical properties without degrading superconducting properties. Since the material properties are considered to be largely affected by silver particle size, form, dispersion state etc. in the Y123 phase, it is important to control Ag distribution in YBCO/Ag composites. Besides, it is also reported that the silver addition improve the corrosion resistance to the water and CO2 [5,6]. Nishizono et al. [7-9] have reported that the silver distribution in the YBCO/Ag composites is largely affected by the solidification condition, but yet some unclear points are also remained. YBCO has been also fabricated by the zone melting method [10-12], and Furuya et al. [5] and Hirano et al. [13] have reported the fabrication of silver added YBCO composites, but the distribution and behavior of Ag are not investigated in detail"

Jan 1, 2000

By R. J. Leary

Iron and steel scrap has accounted for 45 to 50 percent of the metallics used by the steel industry. In an electric furnace which utilizes a 100-percent cold charge consisting of about 99 percent scrap and 1 percent pig iron, sensible heat from molten pig iron is not present as it is when hot metal is charged to open hearths and converters. A study of means for more efficient utilization of iron and steel scrap in steelmaking indicated that the time and fuel requirements to melt scrap were important cost factors, particularly in arc-furnace steelmaking. A process to preheat scrap economically prior to charging into the arc furnace has been developed, utilizing efficiently the heat from combustion of fossil fuels as a substitute for electric-arc heating in the initial stage of arc-furnace steelmaking. Scrap is loaded into a portable vertical cylindrical furnace body that is open at the top and has a perforated dropout door at the bottom. In the heating operation, the furnace body containing scrap is placed upon a hollow base connected to a flue, and then the burner and combustion-chamber unit is lowered on top of the furnace body. The stream of hot-combustion products flows down through the bed of scrap imparting heat to it, and the cooled gases exhaust through the flue. After the heating operation the furnace body containing hot scrap is transported to the arc furnace for charging. Thus, the furnace body serves as a charging bucket for top-charged arc furnaces, enabling this preheating process to be integrated into existing material-handling patterns in many arc-furnace plants.

Jan 1, 1961

By G. A. Bezuidenhout, S. Bradshaw, W. Malan

"The purpose of the study was to investigate the feasibility of SiC reduction of low-grade concentrates from Lonmin’s Rowland and Easterns operations with respect to metal fall and PGM recovery. These concentrates are rich in SiO2 and MgO with low concentrations of chalcopyrite and Cr2O3. Pd is the most abundant of the PGMs. SiC reduction of samples was conducted at 1600? with 2.5-3.5 kg SiC per 100 kg concentrate.PGM recoveries for Easterns concentrate were better than for Rowland. More than 85% of the Ir and Pd and almost 60% of the Pt were recovered with 3.5 kg SiC per 100 kg concentrate. SEM of slag samples showed little entrainment of metallic prills compared to Rowland samples. This was attributed to the relatively higher melt viscosities of the Rowland concentrate. In order to decrease slag viscosity and to enhance PGM recovery, the FeO content of the Easterns concentrate was increased with the addition of 10 kg converter slag per 100 kg concentrate. Ir and Pd recoveries were increased to about 95%, while Pt recovery was around 70%. On the basis of these results an optimum feed ratio between Easterns and Rowland concentrates and converter slag is proposed. Carbothermic reduction of the optimum charge was also compared to SiC reduction. Carbothermic reduction yielded a marginally higher metal fall; however, the calculated gas emissions and energy requirements were higher than for SiC reduction."

Jan 1, 2015

By A. Nieto

A dump edge and vehicle proximity warning system is being developed at the Colorado School of Mines using GPS and wireless local area networks to improve the safety of off-highway trucks in open pit mines. After two years of research, software development, and testing in the laboratory, field tests are currently being carried out at operating limestone quarries and open pit mining operations to evaluate the effectiveness of the system under rugged operating conditions. This paper describes the progress made on this NIOSH-funded project and discuss, tests carried out recently, at the Morenci open pit copper mine in Arizona.

Jan 1, 2002

By Otis W. Freeman

Production of oil in Indiana during 1944 is estimated at approximately 4,950,000 bbl., a decline of 6 per cent from the preceding year. Shortage of labor and material, together with governmental regulations resulting from the war, largely account for the drop in output and limited new developments. Three new pools were discovered in the state during 1944. Two of these, New Harmony, South, and Hovey, West, are in Posey County. Six wells in the New Harmony, South, field produced 66,422 bbl. of oil last year. A third field, Cato, in Pike County, did not market the oil from its discovery well during 1944. Several wells discovered oil in the Henderson field of Jay County along the Ohio state line. An important south extension of the St. Thomas field in Knox County was discovered during the year. Active drilling took place in the Inman, East, and Upton fields, Posey County, both discovered in 1943. Twenty-two wells in Inman, East, produced 151,1gr bbl. in 1944 and 12 in Upton produced 107,052 bbl. Owensville, and especially Owensville, North, in Gibson County, made large gains in production as a result of active drilling. The Dodds Bridge field in Sullivan County continued good production from deep sands reached in 1942. The Griffin continued to be the largest producer among the oil pools of Indiana, accounting for 2,004,180 bbl., over 40 per cent of the state's output. The next largest producing fields are Mt. Vernon and New Harmony, both in Posey County. The largest gas well brought in during 1944 was in the Rockport field, Spencer County, and had an initial output of 2,680,000 cu. ft. per day. The most productive gas fields in Indiana are Rockport, Spencer County, Greensburg, Decatur County, and Unionville, Monroe County. Total production in the state is . hard to estimate, as considerable gas is consumcd in farm homes and for other local uses, and never is reported, but was near 1500 million cubic feet. Some oil from the Trenton field is also used locally and is unreported from pipe-line runs. A total of 606,145 ft. of new hole was drilled in Indiana in 1944. Most of the completions were in Posey and Gibson counties, although wells were drilled in 36 different counties. During the year 331 wells were completed. Of these, 145 found oil in commercial quantities and 28 were gas wells. The initial production of the 145 oil wells was 11,908 bbl. per day. Settled production would be less, of course. The largest wells reported during the year were two on the J. W. Mann farm, in the Mt. Vernon field, with a flush flow of 500 to 800 bbl. each.. Six pools, all small "one well" affairs, were abandoned in 1944; i.e., Fleenor and Patoka in Gibson County, Grafton and Rapture in Posey County, Vaughn in Vandei-bwgh County and Millersburgh, Warrick County.

Jan 1, 1945

By T. M. Ahmed

Sherritt International Corporation experienced corrosion failures with the 316L stainless steel tubing in a high-pressure still condenser employed for ammonia recovery. A detailed failure analysis was conducted on the condenser tubing to determine the mode and the root cause of the failure. The analysis included both optical and scanning electron microscopy (SEM) of the inner and outer surfaces of the tube as well as characterization of the corrosion products using energy-dispersive X-ray spectroscopy (EDX). Results revealed that the corrosion attack was confined to the first ?100 mm of the tubing at the inlet where the tube was connected to the top tubesheet. The tube suffered both external stress-corrosion cracking (SCC) and crevice corrosion from the shell side (water side), and wall thinning of the inner surface (the tube side) due to erosion corrosion. It was evident that failure of one of the tubes occurred due to SCC that penetrated the whole wall thickness and resulted in a leak failure. Some prevention measures are proposed to avoid this type of corrosion attack in the future.

Jan 1, 2005

By William Petruk, Donald Leroux, Michael Cooper

"Brunswick's primary flotation circuit (CuPb) produces a low grade concentrate containing considerable amounts of undesirable sphalerite and pyrite. To determine the cause of the poor selectivity, a series of Quantitative Mineralogical Analyses (QMA) were performed on several CuPb circuit streams. It was observed that significant fractions of sphalerite and pyrite reporting to the concentrate was liberated, meaning that their depression was not complete. The study highlighted the need for some R&D efforts to be spent in sulphide flotation fundamentals.IntroductionThe viability of many mining projects strongly depends on the performance of their concentrators. More than ever, competitive grade concentrate and high metal recoveries are criteria of paramount economic importance. The selectivity of solid/solid separation processes used in concentrators must be maintained at high levels or continuously improved.Flotation is the solid/solid separation process used by most base metal producers. In spite of its low operating cost, flotation remains a very complex process. To make it selective, precise reagent dosages and electrochemical conditions must be maintained. The difficulty in controlling flotation lies in the numerous heterogeneous reactions that can take place between the different solid, liquid and gaseous phases involved. This complex chemistry makes flotation selectivity difficult to understand and, therefore, to improve from a theoretical point of view.Brunswick Mining and Smelting, near Bathurst N.B., operates a 10500 tpd concentrator which produces four concentrates through five stages of sequential flotation (Figure I). Various reagents are added at key process stages while the ore undergoes different electrochemical conditions. Although the selectivity is important at all stages, the performance of the very first separation, the CuPb circuit, is the most critical. It is here where mineral misplacement to the wrong stream has the greatest economic consequences."

Jan 1, 1996

By J. E. Gill, A. R. Byers

The Surf and Pugsley gold-copper mines; owned and operated by Surf Inlet Consolidated Gold Mines; Limited; are about 6 miles inland from; the head of Surf inlet; on Princess Royal island; Skeena mining division; British Columbia. Surf inlet is a fiord 360 miles in an air line northwest of; Vancouver.

Jan 1, 1954

By L. B. Pankratz

The heat content above 298.15° K was determined for crystalline vanadium silicide of the composition V3Si. This substance has a minor thermal anomaly (probably a heat-capacity maximum) near 560° K; the extra heat absorption is about 50 cal/mole. The original heat-content data are presented, and smooth values of the heat content and the corresponding entropy increments are listed for the temperature range from 298.15° to 1,500° K. Equations representing the heat- content values and derived heat capacities are also included.

Jan 1, 1963

By Donald Cummings

CERTAIN dusts are dangerous when inhaled, but most hazardous of all dusts are quartz or other forms of pure crystalline silica. The inhalation of dusts containing silica in combination with other elements gives rise to changes in the lung which differ from those produced by pure silica. As a generality, silicates are less dangerous than pure crystalline silica and vary greatly among themselves in harmfulness. Repeated analyses have shown that approximately 70 per cent of the total number of particles involved in any dust-producing operation are below 1 to 2 microns in diameter. (A micron is. approximately 1/25,000 in.) Similar studies of dusts recovered from silicotic lungs post mortem have demonstrated essentially the same size frequency distribu-tion, except that the upper limit of size retained in the air sacs is approxi-mately 10 microns. Experiments carried on by Gardner and the author have further demonstrated that greater changes were produced by a fixed weight of very fine quartz particles (2 to 3 microns and smaller) than by the same weight of slightly larger particles (8 to 10 microns). Any attempt to control a dust hazard should therefore be directed toward the removal from the working atmosphere of particles less than 10 microns in size, and particularly those below 3 microns. All industrial hygienists agree on this matter, but there remains considerable dispute as to the lower limit of particle size capable of causing injury. It has been gen-erally conceded, however, that particles of harmful dusts smaller than ¼ to ½ micron are not essentially concerned in the development of pulmonary fibrosis. This opinion is partly substantiated by the existence of large numbers of these small particles in practically all atmospheres that are, not associated with any known hazard. Such particles are so small that they have very little mass, fail to settle even in quiet air, and probably are not easily retained in the lung. Until further research proves that they are involved in the dangers provoked by the inhalation of certain dusts, engineers will generally agree that it is better to dis-regard them.

Jan 1, 1935

By R. A. Puchner

The location of a decline shaft portal can have far reaching implications if the geotechnical conditions are not suited for safe and cost effective excavation. Ideally the portal should be positioned in an area where the excavation requires minimal support and the portal can be formed in reasonably competent rock. In many cases, however, the shaft is linked to an underground mining plan and the shaft may have to pass through poor ground conditions. Determining the optimal position at which tunnelling can commence i.e. the portal, is critical and requires a thorough geotechnical investigation. Methods used to acquire information for the assessment of the ground conditions are discussed in this paper. Selection of the appropriate methods is dependent on the anticipated ground conditions, the phase of investigation and restrictions due to site access and budget. Non-invasive techniques are often used during preliminary phases and invasive techniques for the detailed investigation. The methods used during each phase of investigation are discussed. Two case studies are then presented to provide examples of the investigative methods used in two different environments. The first being a flat featureless site with thick soils and deeply weathered bedrock, while the second is a mountainous site with differentially weathered rocky outcrops. Based on these cases, it is clear that an understanding of the geology and geomorphology of the site is vital to the final geotechnical assessment. Key words: Decline shaft, boxcut, geology, geomorphology, geotechnical, portal.

Jan 1, 2009

By B. Tougas

Recycling of titanium represents an important economic activity due to high cost of the material and the amount of returns of machined parts which represent the bulk of finished titanium products (typical "buy to fly" of 10 in the aeronautic industry). In the present work, the metallurgical quality of 76 mm in diameter and 20 cm ingots poured in coated graphite mold will be assessed against the nature and condition of application of 4 coatings namely aluminum oxide, yttrium oxide, zirconium oxide and zirconium oxide with 4% aluminum oxide. The metallurgical quality has been evaluated in terms of alpha case thickness, microstructure and composition. Microhardness from surface will be assessed against casting conditions. Least square regression analysis have been use to optimize casting conditions.

Jan 1, 2011

By Laage L. W

line fires pose a serious threat to the safety of all underground personnel. Early knowledge of the location of a fire in a complex underground mine would greatly reduce the associated risks by enabling miners to choose the safest escape routes, rescue teams to concentrate searches where survivors would most likely be found, and fire fighters to select the most efficient route to the fire and the most effective fire fighting strategy. Once'the fire's location is known, other related aspects of the fire can also be inferred, such as intensity, fuel, and growth Rate.

Jan 1, 1988

By G. A. Campbell

This paper considers the international market trends of the rare earths and how they are strongly influenced by the by-product/co-product nature of their mining and processing. The two main economic minerals for the rare earths are bastnasite and monazite. Monazite is primarily a by-product of mining ilmenite and rutile and is affected by changes in these markets as well as the presence of thorium. Bastnasite is a by-product of mining iron ore in China and a stand-alone product in the USA. The paper will use conceptional relationships and empirical data to delineate the various by-products/co-products relationships and how they determine observed international market behavior.

Jan 1, 1996

By Abell RS, Wyborn D, Solomon M, Stuart-Smith PG, Henderson GAM

The two major massive sulphide deposits in the Silurian rocks of southern NSW, Captains Flat and Woodlawn, differ from classical Kuroko deposits in several ways, e.g. they lie on the flanks of felsic volcanic piles in volcano-sedimentary marine sequences, are relatively thin and large compared to individual Kuroko deposits, show prominent banding in lead-zinc ore, and contain arsenopyrite. Qualified stuctural and stratigraphic correlations of the various fault-bounded remnant Silurian sequences that host these deposits provide the basis for a new interpretation of the regional geological setting that also differs from that of the Kuroko deposits (Ohmoto, Tanimura, Date, Takahashi, 1983), and sheds further light on the distribution of volcanogenic massive sulphide deposits in the Silurian rocks of NSW.

Jan 1, 1987

By D. W. Gunkle

Processing of various ores and materials in a reducing atmosphere has been done for many years. However, the typical device currently used is a large, often high maintenance, expensive piece of equipment; the rotary kiln. While it is a very reliable and a proven technology, the rotary kiln also has its limitations. It is limited by its ability to process very fine materials without creating a huge dust loss to the air pollution control equipment. This leads us towards the development of an alternate technology; the Gas Suspension System. Gas suspension preheating of various materials has been in commercial use since the early 1950's, but recently has been expanded to include Gas Suspension Reduction. Laboratory experience has proven successful on several materials; Nickel Laterite Fines, Iron Ore Fines, Fluorspar, and Clays. The gas suspension reduction system has many advantages over the conventional reduction kiln when processing fines. They are; lower cost, more fuel efficient, able to process fines, less real estate required, etc.

Jan 1, 1998

By G. van der Westhuizen, F. E. du Plessis

Ticor South Africa operates a dry mill at the town of Empangeni in the province of KwaZulu-Natal on the east coast of South Africa. The dry mill processes a non-magnetic mineral stream constituting rutile, leucoxene and zircon as major minerals, and minor quantities of ilmenite and other non-valuable minerals. For plant control and optimization, continuous ‘real time’ information about the mineral and chemical compositions in various plant streams is required. The current practice is to take samples at regular intervals and submit them for mineralogical(grain counting) and chemical analyses. However, these methods are time consuming, and in the case of manual grain counting, tedious and operator dependent. Until now an on-line or real-time instant mineral quantification system, which will be of great value in a plant operations environment, has not been available. Blue Cube Systems has developed a mineral quantification system using spectral mineral analysis. It measures and quantifies the composition of mineral samples instantly, providing consistent data in real time. A series of process stream samples from the dry mill mentioned above were used to evaluate the Blue Cube Systems instant mineral quantifier. This article will •describe the procedure of setting up and evaluating the Blue Cube Instant MineralQuantifier equipment •present its results, and •discuss the intended applications.

Jan 1, 2003

By Robert Hopler

Your petitioner further alleges that at various times, to wit, from 1872 until June 30, 1895, during the existence of the combination and conspiracy in restraint of trade among the various States herein- before described, there were organized under the laws of various of the several States of the Union various corporations having for their object the manufacture and shipment and sale of a high explosive commonly known as dynamite, which said explosive is commonly used for the same purposes as those for which blasting powder is used;

Jan 1, 2013

By William H. McLemore

Geologists searching for carbonate rocks suitable for chemical uses traditionally have relied on extensive laboratory testing in order to locate strata or zones that might be suitable for mining. However, when considering the significant time and costs involved in sampling and performing chemical analyses, any exploration technique whereby fewer samples and analyses are needed would be of great value. In other words, if the exploration geologist could "zero-in" on select areas, considerable time and money could be saved. In general, the major-element chemistry of carbonate rocks is determined by the abundance of the minerals present. CaO occurs with CO2 as the mineral calcite, which is the primary mineral comprising allochems, matrix and sparry cement; MgO is found in high-magnesium calcite (many calcite fossil species contain appreciable amounts of MgO in solid solution), dolomite, and chlorite; iron occurs in pyrite and in limonitic stylolites, as well as in chloritic and glauconitic clay minerals; materials containing abundant Si02 are microcrystalline quartz (chest) silt-sized quartz, and clay minerals; and Al203 is found primarily in illitic, kaolinitic, and chloritic clay minerals. The presence or absence of these minerals determines the chemical composition of the carbonate rooks.

Jan 1, 1983

By Thomas. Lisa, Mark Coleman

Schenck Process is an established customer-driven solutions provider, utilising its knowledge, expertise and technologies to transform production processes. Operating across several industries Schenck Process have developed quality solutions from their range of equipment to solve problems and fill holes in other people’s processes. In the non-ferrous metals industries Schenck Process have been using their Clyde Brand solutions in Pneumatic Transport to solve problems on smelter sites for a number of years, handling of concentrates, additives and metallurgical dusts. Working alongside clients around the world they have developed a number of dust handling systems for flash furnaces from New Boliden, through Codelco to PASAR. Solving handling issues in dust collection has proved to suit Schenck Process range of equipment well and now a series of solutions are available. Solutions have been developed to handle materials up to 600°C and can convey over 1 km. Conveying to remote location for disposal, injecting directly into a furnace through lances, return to furnace burner feed, or deliver and dose into leaching reactors, Schenck Process are ready to ‘make processes work’. Historic solutions at New Boliden and Codelco demonstrate a range of material application and the long term performance of the equipment. Recent installations at Pasar utilise the Schenck new ProPhaseTM equipment and handle the Waste Heat Boiler and ESP dusts directly and simplify the dust train. The paper will seek to show how this equipment can bring benefit in handling high temperature materials directly and eliminate several traditional steps that are often unreliable. The systems can be paired with Schenck Process new PHASiQTM and STREAMiQTM control systems which are complete PC, HMI, PLC, Interface system with full SCADA, Data Storage and IoT ready remote interrogation and support available. Installed in this challenging environment the systems are ready for smelter use. The systems can be also joined to our new E-nizingTM web portal. A perfect partnership to deliver the trend in ‘Big Data’ while providing visibility and off site support. The paper will show how these systems can deliver reliable equipment and remote support for these often isolated sites as well as delivering rapid return on investment. This paper discusses a step change in simplifying Flash Furnace Dust handling which Schenck believes shows the truth of Schenck Process Solutions claim that ‘we make processes work’.

Jan 1, 2019